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Etude Et Optimisation De La Limite De Detection En Spectrophotometrie Dabsorption Atomique Contribution A La Comprehension Des Mecanismes En Milieu Eaux Naturelles
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Book Synopsis ETUDE ET OPTIMISATION DE LA LIMITE DE DETECTION EN SPECTROPHOTOMETRIE D'ABSORPTION ATOMIQUE. CONTRIBUTION A LA COMPREHENSION DES MECANISMES EN MILIEU EAUX NATURELLES by : HELENE.. LE GARREC
Download or read book ETUDE ET OPTIMISATION DE LA LIMITE DE DETECTION EN SPECTROPHOTOMETRIE D'ABSORPTION ATOMIQUE. CONTRIBUTION A LA COMPREHENSION DES MECANISMES EN MILIEU EAUX NATURELLES written by HELENE.. LE GARREC and published by . This book was released on 1997 with total page 155 pages. Available in PDF, EPUB and Kindle. Book excerpt: A la limite de détection définie par l'impact est le meilleur paramètre d'optimisation en spectroscopie d'absorption atomique à atomisation électrothermique (SAAET) quand il s'agit d'atteindre les meilleures limites de quantification, mais les 11 mesures nécessaires à sa détermination sont matériellement impossibles à effectuer systématiquement. Un calcul statistique simple et une étude expérimentale sur le bruit affectant les signaux d'atomisation blancs intègres ont permis de montrer les conséquences de l'intégration sur les limites de détection qu'il est possible d'annoncer et de définir une nouvelle grandeur d'optimisation, la limite de détection estimée ou DLE, calculée sur une seule atomisation. Cette grandeur est très proche de la limite de détection instrumentale (IUPAC) quand un procédé d’affectations correctes du zéro est employé. L’introduction de la contribution d'un signal non-spécifique à l'expression de la DLE permet de traiter également le cas des échantillons naturels. Une démarche d'optimisation de la méthode, fondée sur le suivi de la DLE a l'aide de matrices d-optimales, a pu ainsi être proposée en considérant indépendamment deux catégories de paramètres. Pour les facteurs spectroscopiques, cette méthode d'optimisation est appliquée au cadmium, manganèse, cuivre et étain et pour les facteurs électrothermiques, a la détermination du cadmium, du manganèse et du cuivre dans un milieu naturel complexe, l'eau de mer. L’abaissement des limites de quantification en saaet passe aussi par une meilleure connaissance de la chimie complexe se produisant à haute température dans l'atomiseur. Des conditions expérimentales particulières sont proposées pour permettre des études cinétiques de signaux génères en présence de matrices minérales. Ces conditions, testées pour le manganèse et le cuivre en présence de quelques matrices nitrate et sulfate, ont conduit a la proposition de schémas raisonnables de réactions d'atomisation et de décomposition des matrices.
Book Synopsis Contribution à l'étude des applications de la spectrophotométrie d'absorption atomique avec flamme en molysmologie des milieux aquatiques (eaux et sédiments) by :
Download or read book Contribution à l'étude des applications de la spectrophotométrie d'absorption atomique avec flamme en molysmologie des milieux aquatiques (eaux et sédiments) written by and published by . This book was released on 1980 with total page 62 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis CONTRIBUTION A L'ETUDE DE DOSAGES PAR SPECTROPHOTOMETRIE D'ABSORPTION ATOMIQUE by : AGNES.. EXANDIER
Download or read book CONTRIBUTION A L'ETUDE DE DOSAGES PAR SPECTROPHOTOMETRIE D'ABSORPTION ATOMIQUE written by AGNES.. EXANDIER and published by . This book was released on 1984 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Détermination de traces d'éléments en spectrophotométrie d'absorption atomique by : Bernard Hircq
Download or read book Détermination de traces d'éléments en spectrophotométrie d'absorption atomique written by Bernard Hircq and published by . This book was released on 1976 with total page 115 pages. Available in PDF, EPUB and Kindle. Book excerpt: RAPPEL THEORIQUE SUR LA RAIE SPECTRALE ET LE COEFFICIENT D'ABSORPTION. L'ETUDE EST MENEE EN PARTANT DE QUELQUES MICROLITRES DE SOLUTION DE L'ELEMENT A DOSER DEPOSES SUR FILAMENT METALLIQUE (RHENIUM) OU DE GRAPHITE: LIMITES DE SENSIBILITE DANS LES CONDITIONS OPTIMALES POUR AG, AS, AU, HG, SE, SN, PB, CD, ZN, DANS LE CAS DU FILAMENT METALLIQUE. APPLICATION DU FILAMENT DE GRAPHITE AU DOSAGE D'IMPURETES DANS L'URANIUM. CET EXAMEN PERMET DE CONSTATER LES EFFETS DE L'ATOMISATION: L'ABSORPTION D'UN RAYONNEMENT PAR UN "NUAGE ATOMIQUE". ON ETUDIE CE "NUAGE ATOMIQUE" QUANT A SA FORME ET A LA REPARTITION DES CONCENTRATIONS, A L'AIDE D'UN SPECTROPHOTOMETRE, EN FONCTION DES PARAMETRES EXPERIMENTAUX. APPLICATION A LA DETERMINATION DE GRANDEURS PHYSIQUES. ETUDE DU DEPOT EFFECTUE SUR LE GENERATEUR D'ATOMES ET LA TRANSFORMATION D'UNE MATRICE (CAS DE U) AU COURS DES CYCLES THERMIQUES IMPOSES AU SUPPORT D'ATOMISATION
Book Synopsis Gas-cooled Nuclear Reactors by : France. Commissariat à l'énergie atomique
Download or read book Gas-cooled Nuclear Reactors written by France. Commissariat à l'énergie atomique and published by . This book was released on 2006 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Scientific Basis for Nuclear Waste Management XXII: Volume 556 by : David J. Wronkiewicz
Download or read book Scientific Basis for Nuclear Waste Management XXII: Volume 556 written by David J. Wronkiewicz and published by . This book was released on 1999-11-24 with total page 1370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Safe and effective management of nuclear waste provides a broad range of challenges for materials science. Waste processing, waste form and engineered barrier properties, interactions between engineered and geological systems, radiation effects, chemistry and transport of waste species, and long-term predictions of repository performance are just some of the scientific problems facing modern society. This book, the 22nd in a very successful series from MRS, offers an international and inter-disciplinary perspective on the issues, and features developments in both fundamental and applied areas. Topics include: development and characterization of ceramic waste forms; ceramic waste form corrosion; glass waste form processing; glass formulation, properties and structure; glass waste form corrosion; spent nuclear fuel; performance assessment; repository backfill; flow and transport; natural analogues; container corrosion; metal waste form corrosion; radionuclide speciation and solubility; radionuclide sorption; microbial effects; radiation effects; cement waste forms and waste treatment.
Book Synopsis Fluorine Magnetic Resonance Imaging by : Ulrich Flogel
Download or read book Fluorine Magnetic Resonance Imaging written by Ulrich Flogel and published by CRC Press. This book was released on 2016-10-26 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past decade, fluorine (19F) magnetic resonance imaging (MRI) has garnered significant scientific interest in the biomedical research community owing to the unique properties of fluorinated materials and the 19F nucleus. Fluorine has an intrinsically sensitive nucleus for MRI. There is negligible endogenous 19F in the body and thus there is no background signal. Fluorine-containing compounds are ideal tracer labels for a wide variety of MRI applications. Moreover, the chemical shift and nuclear relaxation rate can be made responsive to physiology via creative molecular design. This book is an interdisciplinary compendium that details cutting-edge science and medical research in the emerging field of 19F MRI. Edited by Ulrich Flögel and Eric Ahrens, two prominent MRI researchers, this book will appeal to investigators involved in MRI, biomedicine, immunology, pharmacology, probe chemistry, and imaging physics.
Book Synopsis Biotechnology and Sustainable Development by : Ismail Serageldin
Download or read book Biotechnology and Sustainable Development written by Ismail Serageldin and published by CABI. This book was released on 2003 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on the first scientific conference convened at the Library of Alexandria, 'Biotechnology and Sustainable Development: Voices of the South and North', which was held in Alexandria, Egypt, in March 2002, this book contains overviews of agriculture, health, ethics and the environment. It discusses how dramatic improvements in food security, health, and lifestyle could accrue to the poor people of developing countries through the applications of new technologies.
Book Synopsis From Microphysics to Macrophysics by : Roger Balian
Download or read book From Microphysics to Macrophysics written by Roger Balian and published by Springer Science & Business Media. This book was released on 2007-06-26 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt: This popular, often cited text returns in a softcover edition to provide a thorough introduction to statistical physics and thermodynamics, and to exhibit the universal chain of ideas leading from the laws of microphysics to the macroscopic behaviour of matter. A wide range of applications illustrates the concepts, and many exercises reinforce understanding. Volume II applies statistical methods to systems governed by quantum effects, in particular to solid state physics, explaining properties due to the crystal structure or to the lattice excitations or to the electrons. The last chapters are devoted to non-equilibrium processes and to kinetic equations, with many applications included.
Book Synopsis Lasers in Materials Processing by : Edward A. Metzbower
Download or read book Lasers in Materials Processing written by Edward A. Metzbower and published by ASM International(OH). This book was released on 1983 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Applied Mineralogy in the Mining Industry by : W. Petruk
Download or read book Applied Mineralogy in the Mining Industry written by W. Petruk and published by Elsevier. This book was released on 2000-11-29 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: Techniques of performing applied mineralogy investigations, and applications and capabilities of recently developed instruments for measuring mineral properties are explored in this book intended for practicing applied mineralogists, students in mineralogy and metallurgy, and mineral processing engineers. The benefits of applied mineralogy are presented by using in-depth applied mineralogy studies on base metal ores, gold ores, porphyry copper ores, iron ores and industrial minerals as examples. The chapter on base metal ores includes a discussion on the effects of liberation, particle sizes and surfaces coatings of Pb, Cu, Fe, Ca and So4- on the recoveries of sphalerite, galena and chalcopyrite. The chapter on gold discusses various methods of determining the quantities of gold in different minerals, including 'invisible' gold in pyrite and arsenopyrite, so that a balance of the distribution of gold among the minerals can be calculated. This book also discusses the roles of pyrite, oxygen, moisture and bacterial (thiobacillus ferrooxidans) on reactions that produce acidic drainage from tailings piles, and summarizes currently used and proposed methods of remediation of acidic drainage.
Book Synopsis Four Laws That Drive the Universe by : Peter Atkins
Download or read book Four Laws That Drive the Universe written by Peter Atkins and published by OUP Oxford. This book was released on 2007-09-06 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: The laws of thermodynamics drive everything that happens in the universe. From the sudden expansion of a cloud of gas to the cooling of hot metal, and from the unfurling of a leaf to the course of life itself - everything is directed and constrained by four simple laws. They establish fundamental concepts such as temperature and heat, and reveal the arrow of time and even the nature of energy itself. Peter Atkins' powerful and compelling introduction explains what the laws are and how they work, using accessible language and virtually no mathematics. Guiding the reader from the Zeroth Law to the Third Law, he introduces the fascinating concept of entropy, and how it not only explains why your desk tends to get messier, but also how its unstoppable rise constitutes the engine of the universe.
Book Synopsis Flexoelectricity in Liquid Crystals by : Agnes Buka
Download or read book Flexoelectricity in Liquid Crystals written by Agnes Buka and published by World Scientific. This book was released on 2013 with total page 299 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book intends to give a state-of-the-art overview of flexoelectricity, a linear physical coupling between mechanical (orientational) deformations and electric polarization, which is specific to systems with orientational order, such as liquid crystals. Chapters written by experts in the field shed light on theoretical as well as experimental aspects of research carried out since the discovery of flexoelectricity. Besides a common macroscopic (continuum) description the microscopic theory of flexoelectricity is also addressed. Electro-optic effects due to or modified by flexoelectricity as well as various (direct and indirect) measurement methods are discussed. Special emphasis is given to the role of flexoelectricity in pattern-forming instabilities. While the main focus of the book lies in flexoelectricity in nematic liquid crystals, peculiarities of other mesophases (bent-core systems, cholesterics, and smectics) are also reviewed. Flexoelectricity has relevance to biological (living) systems and can also offer possibilities for technical applications. The basics of these two interdisciplinary fields are also summarized.
Book Synopsis X-Ray and Neutron Reflectivity: Principles and Applications by : Jean Daillant
Download or read book X-Ray and Neutron Reflectivity: Principles and Applications written by Jean Daillant and published by Springer Science & Business Media. This book was released on 2003-07-01 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: The reflection of and neutrons from surfaces has existed as an x-rays exp- imental for almost it is in the last technique fifty Nevertheless, only years. decade that these methods have become as of enormously popular probes This the surfaces and interfaces. to be due to of several appears convergence of intense different circumstances. These include the more n- availability be measured orders tron and sources that can over (so reflectivity x-ray many of and the much weaker surface diffuse can now also be magnitude scattering of thin films and studied in some the detail); growing importance multil- basic the realization of the ers in both and technology research; important which in the of surfaces and and role roughness plays properties interfaces; the of statistical models to characterize the of finally development topology its and its characterization from on roughness, dependence growth processes The of and to surface scattering experiments. ability x-rays neutro4s study four five orders of in scale of surfaces over to magnitude length regardless their and also their to ability probe environment, temperature, pressure, etc. , makes these the choice for buried interfaces often probes preferred obtaining information about the microstructure of often in statistical a global surfaces, the local This is manner to complementary imaging microscopy techniques, of such studies in the literature witnessed the veritable by explosion published the last few Thus these lectures will useful for over a resource years.
Book Synopsis Scientific Basis for Nuclear Waste Management XXIII: Volume 608 by : Robert W. Smith
Download or read book Scientific Basis for Nuclear Waste Management XXIII: Volume 608 written by Robert W. Smith and published by . This book was released on 2000-10-09 with total page 800 pages. Available in PDF, EPUB and Kindle. Book excerpt: This long-standing symposia series has become the premier, international forum for scientific and engineering issues related to all levels and types of radioactive wastes and their management. Topics include: fuel cladding and spent nuclear fuel; container fabrication and corrosion; performance assessment; repository performance; radionuclide sorption and transport; cement-based materials and waste containment; corrosion of ceramic wasteforms; structure and characterization of ceramics; radiation effects; natural analogs; wasteform characterization and processing; and corrosion and characterization of glass wasteforms.
Author :Nihon Genshiryoku Kenkyūjo Publisher :Paris, France : Nuclear Energy Agency, Organisation for Economic Co-operation and Development ISBN 13 : Total Pages :370 pages Book Rating :4.3/5 (91 download)
Book Synopsis Basic Studies in the Field of High-temperature Engineering by : Nihon Genshiryoku Kenkyūjo
Download or read book Basic Studies in the Field of High-temperature Engineering written by Nihon Genshiryoku Kenkyūjo and published by Paris, France : Nuclear Energy Agency, Organisation for Economic Co-operation and Development. This book was released on 2002 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: In response to increasing interest in high-temperature, gas-cooled reactors (HTGRs) in many countries and the need for improved materials for nuclear applications in high-temperature environments, the NEA organised a Second Information Exchange Meeting on Basic Studies in the Field of High-temperature Engineering. These proceedings provide an overview of the activities being carried out in eight countries, the improvement of material properties for HTGR application, in-core monitoring methods and properties of irradiated graphite, and HTGR fuel fabrication and performance.
Book Synopsis Physical Properties of Amorphous Materials by : David Adler
Download or read book Physical Properties of Amorphous Materials written by David Adler and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Institute for Amorphous Studies was founded in 1982 as the international center for the investigation of amorphous mate rials. It has since played an important role in promoting the und er standing of disordered matter in general. An Institute lecture series on "Fundamentals of Amorphous Materials and Devices" was held during 1982-83 with distinguished speakers from universities and industry. These events were free and open to the public ,and were attended by many representatives of the scientific community. The lectures themselves were highly successful inasmuch as they provided not only formal instruction but also an opportunity for vigorous and stimulating debate. That last element could not be captured within the pages of a book I but the lectures concentrated on the latest advances in the field I which is why their essential contents are he re reproduced in collective form. Together they constitute an interdisciplinary status report of the field. The speakers brought many different viewpoints and a variety of back ground experiences io bear on the problems involved I but though language and conventions vary I the essential unity of the concerns is very clear I as indeed are the ultimate benefits of the many-sided approach.
