Electrochemistry Spectroscopy And Reactivity Of Uranium Complexes Supported By Ferrocene Diamide Ligands

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Electrochemistry, Spectroscopy, and Reactivity of Uranium Complexes Supported by Ferrocene Diamide Ligands

Author : Selma Duhovic
Publisher :
ISBN 13 :
Total Pages : 291 pages
Book Rating : 4.:/5 (828 download)

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Book Synopsis Electrochemistry, Spectroscopy, and Reactivity of Uranium Complexes Supported by Ferrocene Diamide Ligands by : Selma Duhovic

Download or read book Electrochemistry, Spectroscopy, and Reactivity of Uranium Complexes Supported by Ferrocene Diamide Ligands written by Selma Duhovic and published by . This book was released on 2012 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work culminates a systematic study of various uranium complexes supported by ferrocene diamide ligands. Chapter 1 reports the synthesis of 1,1'-ferrocene diamines and describes their electronic and steric properties in both neutral and oxidized forms. Chapter 2 describes an efficient synthesis of uranium dialkyl complexes supported by a single 1,1'- ferrocene diamide ligand, while Chapter 3 explores their reactivity with several aromatic heterocycles. Chapter 4 focuses on the electrochemical behavior of ferrocene-based uranium halide, alkyl, aryloxide, and amide ligands. Finally, Chapter 5 explains electrochemical, spectroscopic, and magnetic properties of uranium bis(1,1'-diamidoferrocene) complexes in an attempt to establish how well uranium mediates electronic communication between two iron centers.

Uranium Complexes Supported by a Ferrocene Diamide Ligand

Author : Marisa Jennifer Monreal
Publisher :
ISBN 13 :
Total Pages : 436 pages
Book Rating : 4.:/5 (764 download)

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Book Synopsis Uranium Complexes Supported by a Ferrocene Diamide Ligand by : Marisa Jennifer Monreal

Download or read book Uranium Complexes Supported by a Ferrocene Diamide Ligand written by Marisa Jennifer Monreal and published by . This book was released on 2011 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Novel Transformations Using Uranium and Group 5 Metal Complexes Supported by 1,1'-diamidoferrocene Ligands

Author : Michael Joseph Lopez
Publisher :
ISBN 13 :
Total Pages : 80 pages
Book Rating : 4.:/5 (869 download)

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Book Synopsis Novel Transformations Using Uranium and Group 5 Metal Complexes Supported by 1,1'-diamidoferrocene Ligands by : Michael Joseph Lopez

Download or read book Novel Transformations Using Uranium and Group 5 Metal Complexes Supported by 1,1'-diamidoferrocene Ligands written by Michael Joseph Lopez and published by . This book was released on 2013 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt: These studies describe the use of the redox-active 1,1'-diamidoferrocene ligand on uranium and group 5 metals. A novel terminal uranium-imide complex was synthesized using the bulky 2,6-dimesitylphenyl imide substituent as support. Although the uranium-imide was shown to be sterically accessible through the accommodation of another 2,6-dimesitylphenyl amide group, further reactivity was not seen, with the exception of sulfur. Electron transfer between the iron contained in the 1,1'-diamidoferrocene ligand and group 5 metals was more apparent than with uranium. A control reaction between ferrocene and niobium pentachloride suggested the formation of ferrocenium via electron transfer from iron to niobium. The use of a reduced tantalum and niobium precursors is required for coordination by 1,1'-diamidoferrocene ligands to prevent side reactions.

Ligand Influences on Properties of Uranium Coordination Complexes

Author : Boris Kosog
Publisher :
ISBN 13 :
Total Pages : 228 pages
Book Rating : 4.:/5 (823 download)

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Book Synopsis Ligand Influences on Properties of Uranium Coordination Complexes by : Boris Kosog

Download or read book Ligand Influences on Properties of Uranium Coordination Complexes written by Boris Kosog and published by . This book was released on 2012 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Bioinorganic Photochemistry

Author : Grazyna Stochel
Publisher : John Wiley & Sons
ISBN 13 : 9781405193276
Total Pages : 398 pages
Book Rating : 4.1/5 (932 download)

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Book Synopsis Bioinorganic Photochemistry by : Grazyna Stochel

Download or read book Bioinorganic Photochemistry written by Grazyna Stochel and published by John Wiley & Sons. This book was released on 2009-06-10 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioinorganic photochemistry is a rapidly evolving field integrating inorganic photochemistry with biological, medical and environmental sciences. The interactions of light with inorganic species in natural systems, and the applications in artificial systems of medical or environmental importance, form the basis of this challenging inter-disciplinary research area. Bioinorganic Photochemistry provides a comprehensive overview of the concepts and reactions fundamental to the field, illustrating important applications in biological, medical and environmental sciences. Topics covered include: Cosmic and environmental photochemistry Photochemistry of biologically relevant nanoassemblies Molecular aspects of photosynthesis Photoinduced electron transfer in biosystems Modern therapeutic strategies in photomedicine The book concludes with an outlook for the future of environmental protection, discussing emerging techniques in the field of pollution abatement, and the potential for bioinorganic photochemistry as a pathway to developing cheap, environmentally friendly sources of energy. Written as an authoritative guide for researchers involved in the development of bioinorganic photochemical processes, Bioinorganic Photochemistry is also accessible to scientists new to the field, and will be a key reference source for advanced courses in inorganic, and bioinorganic chemistry.

Charge-Trapping Non-Volatile Memories

Author : Panagiotis Dimitrakis
Publisher : Springer
ISBN 13 : 3319487051
Total Pages : 215 pages
Book Rating : 4.3/5 (194 download)

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Book Synopsis Charge-Trapping Non-Volatile Memories by : Panagiotis Dimitrakis

Download or read book Charge-Trapping Non-Volatile Memories written by Panagiotis Dimitrakis and published by Springer. This book was released on 2017-02-14 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the technology of charge-trapping non-volatile memories and their uses. The authors explain the device physics of each device architecture and provide a concrete description of the materials involved and the fundamental properties of the technology. Modern material properties, used as charge-trapping layers, for new applications are introduced. Provides a comprehensive overview of the technology for charge-trapping non-volatile memories; Details new architectures and current modeling concepts for non-volatile memory devices; Focuses on conduction through multi-layer gate dielectrics stacks.

Phosphorus-31 NMR Spectroscopy

Author : Olaf Kühl
Publisher : Springer Science & Business Media
ISBN 13 : 3540791183
Total Pages : 138 pages
Book Rating : 4.5/5 (47 download)

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Book Synopsis Phosphorus-31 NMR Spectroscopy by : Olaf Kühl

Download or read book Phosphorus-31 NMR Spectroscopy written by Olaf Kühl and published by Springer Science & Business Media. This book was released on 2008-08-22 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nuclear Magnetic Resonance is a powerful tool, especially for the identification of 1 13 hitherto unknown organic compounds. H- and C-NMR spectroscopy is known and applied by virtually every synthetically working Organic Chemist. Con- quently, the factors governing the differences in chemical shift values, based on chemical environment, bonding, temperature, solvent, pH, etc. , are well understood, and specialty methods developed for almost every conceivable structural challenge. Proton and carbon NMR spectroscopy is part of most bachelors degree courses, with advanced methods integrated into masters degree and other graduate courses. In view of this universal knowledge about proton and carbon NMR spectr- copy within the chemical community, it is remarkable that heteronuclear NMR is still looked upon as something of a curiosity. Admittedly, most organic compounds contain only nitrogen, oxygen, and sulfur atoms, as well as the obligatory hydrogen and carbon atoms, elements that have an unfavourable isotope distribution when it comes to NMR spectroscopy. Each of these three elements has a dominant isotope: 14 16 32 16 32 N (99. 63% natural abundance), O (99. 76%), and S (95. 02%), with O, S, and 34 14 S (4. 21%) NMR silent. N has a nuclear moment I = 1 and a sizeable quadrupolar moment that makes the NMR signals usually very broad and dif cult to analyse.

Supramolecular Chemistry in the 3rd Millennium

Author : Catherine E. Housecroft
Publisher : MDPI
ISBN 13 : 3036514635
Total Pages : 264 pages
Book Rating : 4.0/5 (365 download)

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Book Synopsis Supramolecular Chemistry in the 3rd Millennium by : Catherine E. Housecroft

Download or read book Supramolecular Chemistry in the 3rd Millennium written by Catherine E. Housecroft and published by MDPI. This book was released on 2021-08-18 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue is one of the first for the new MDPI flagship journal Chemistry (ISSN 2624-8549) which has a broad remit for publishing original research in all areas of chemistry. The theme of this issue is Supramolecular Chemistry in the 3rd Millennium and I am sure that this topic will attract many exciting contributions. We chose this topic because it encompasses the unity of contemporary pluridisciplinary science, in which organic, inorganic, physical and theoretical chemists work together with molecular biologists and physicists to develop a systems-level understanding of molecular interactions. The description of supramolecular chemistry as 'chemistry beyond the molecule' (Jean-Marie Lehn, Nobel Lecture and Gautam R. Desiraju, Nature, 2001, 412, 397) addresses the wide variety of weak, non-covalent interactions that are the basis for the assembly of supramolecular architectures, molecular receptors and molecular recognition, programed molecular systems, dynamic combinatorial libraries, coordination networks and functional supramolecular materials. We welcome submissions from all disciplines involved in this exciting and evolving area of science.

Anion Receptor Chemistry

Author : Jonathan L Sessler
Publisher : Royal Society of Chemistry
ISBN 13 : 1847552471
Total Pages : 431 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Anion Receptor Chemistry by : Jonathan L Sessler

Download or read book Anion Receptor Chemistry written by Jonathan L Sessler and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 431 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anion recognition plays a critical role in a range of biological processes, and a variety of receptors and carriers can be found throughout the natural world. Chemists working in the area of supramolecular chemistry have created a range of anion receptors, drawing inspiration from nature as well as their own inventive processes. This book traces the origins of anion recognition chemistry as a unique sub-field in supramolecular chemistry while illustrating the basic approaches currently being used to effect receptor design. The combination of biological overview and summary of current synthetic approaches provides a coverage that is both comprehensive and comprehensible. First, the authors detail the key design motifs that have been used to generate synthetic receptors and which are likely to provide the basis for further developments. They also highlight briefly some of the features that are present in naturally occurring anion recognition and transport systems and summarise the applications of anion recognition chemistry. Providing as it does a detailed review for practitioners in the field and a concise introduction to the topic for newcomers, Anion Receptor Chemistry reflects the current state of the art. Fully referenced and illustrated in colour, it is a welcome addition to the literature.

Ligand Design in Metal Chemistry

Author : Mark Stradiotto
Publisher : John Wiley & Sons
ISBN 13 : 1118839811
Total Pages : 448 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Ligand Design in Metal Chemistry by : Mark Stradiotto

Download or read book Ligand Design in Metal Chemistry written by Mark Stradiotto and published by John Wiley & Sons. This book was released on 2016-09-01 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: The design of ancillary ligands used to modify the structural and reactivity properties of metal complexes has evolved into a rapidly expanding sub-discipline in inorganic and organometallic chemistry. Ancillary ligand design has figured directly in the discovery of new bonding motifs and stoichiometric reactivity, as well as in the development of new catalytic protocols that have had widespread positive impact on chemical synthesis on benchtop and industrial scales. Ligand Design in Metal Chemistry presents a collection of cutting-edge contributions from leaders in the field of ligand design, encompassing a broad spectrum of ancillary ligand classes and reactivity applications. Topics covered include: Key concepts in ligand design Redox non-innocent ligands Ligands for selective alkene metathesis Ligands in cross-coupling Ligand design in polymerization Ligand design in modern lanthanide chemistry Cooperative metal-ligand reactivity P,N Ligands for enantioselective hydrogenation Spiro-cyclic ligands in asymmetric catalysis This book will be a valuable reference for academic researchers and industry practitioners working in the field of ligand design, as well as those who work in the many areas in which the impact of ancillary ligand design has proven significant, for example synthetic organic chemistry, catalysis, medicinal chemistry, polymer science and materials chemistry.

Molecular Metal-Metal Bonds

Author : Stephen T. Liddle
Publisher : John Wiley & Sons
ISBN 13 : 3527335412
Total Pages : 590 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Molecular Metal-Metal Bonds by : Stephen T. Liddle

Download or read book Molecular Metal-Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2015-06-22 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.

Uranium

Author : Tom Zoellner
Publisher : Penguin
ISBN 13 : 9780670020645
Total Pages : 360 pages
Book Rating : 4.0/5 (26 download)

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Book Synopsis Uranium by : Tom Zoellner

Download or read book Uranium written by Tom Zoellner and published by Penguin. This book was released on 2009 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: A history of the powerful mineral element explores its role as a virtually limitless energy source, its controversial applications as a healing tool and weapon, and the ways in which its reputation has been used to promote war agendas in the middle east.

Molecular Materials

Author : Duncan W. Bruce
Publisher : John Wiley & Sons
ISBN 13 : 1119972957
Total Pages : 455 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Molecular Materials by : Duncan W. Bruce

Download or read book Molecular Materials written by Duncan W. Bruce and published by John Wiley & Sons. This book was released on 2011-04-04 with total page 455 pages. Available in PDF, EPUB and Kindle. Book excerpt: “... the book does an excellent job of putting together several different classes of materials. Many common points emerge, and the book may facilitate the development of hybrids in which the qualities of the “parents” are enhanced.” –Angew. Chem. Int. Ed. 2011 With applications in optoelectronics and photonics, quantum information processing, nanotechnology and data storage, molecular materials enrich our daily lives in countless ways. These materials have properties that depend on their exact structure, the degree of order in the way the molecules are aligned and their crystalline nature. Small, delicate changes in molecular structure can totally alter the properties of the material in bulk. There has been increasing emphasis on functional metal complexes that demonstrate a wide range of physical phenomena. Molecular Materials represents the diversity of the area, encapsulating magnetic, optical and electrical properties, with chapters on: Metal-Based Quadratic Nonlinear Optical Materials Physical Properties of Metallomesogens Molecular Magnetic Materials Molecular Inorganic Conductors and Superconductors Molecular Nanomagnets Structured to include a clear introduction, a discussion of the basic concepts and up-to-date coverage of key aspects, each chapter provides a detailed review which conveys the excitement of work in that field. Additional volumes in the Inorganic Materials Series: Low-Dimensional Solids | Molecular Materials | Porous Materials | Energy Materials

Fundamentals and Applications of Anion Separations

Author : Bruce A. Moyer
Publisher : Springer Science & Business Media
ISBN 13 : 9780306479113
Total Pages : 382 pages
Book Rating : 4.4/5 (791 download)

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Book Synopsis Fundamentals and Applications of Anion Separations by : Bruce A. Moyer

Download or read book Fundamentals and Applications of Anion Separations written by Bruce A. Moyer and published by Springer Science & Business Media. This book was released on 2004-06-17 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book documents the proceedings of the symposium "Fundamentals and Applications of Anion Separations" held during American Chemical Society National Meeting in Chicago, Illinois, August 25-30, 200I. Nearly 40 papers devoted to discussions on anion separation related to fundamental research and applications were presented. The symposium, sponsored by Osram Sylvania, BetzDearbom, and the Separation Science & Technology Subdivision of the Industrial & Engineering Chemistry Division of the American Chemical Society was organized by Bruce A. Moyer, Chemical Sciences Division, Oak Ridge National Laboratory, P.O. Box 2008, Building. 4500S, Oak Ridge, TN 37831-6119, and Raj P. Singh, Chemicals and Powders R&D, Osram Sylvania, Chemical and Metallurgical Products Division, Towanda, PA 18848. It drew presenters from Australia, the Czech Republic, France, Germany, Japan, South Africa, Thailand, the United Kingdom, and the United States. Separations constitute an integral part of chemical industry. Chemical products typically originate in resources that must be concentrated and purified, chemically transformed, and subjected to fmal purification. Effluent streams from the processes must be treated to recycle reusable components and to remove environmentally harmful species. Some industrial processes are devoted to environmental cleanup after pollution has occurred. In addition, many analytical methods require a separation for preconcentration, or a separation may be an inherent part of the analysis itself. Micro separations occurring at membranes or interfaces are also related phenomena employed for ion sensing. Many species targeted for separation are naturally anionic. Although the standard separations techniques ofextraction, ion exchange, adsorption, precipitation, etc.

Computational Modeling of Homogeneous Catalysis

Author : Feliu Maseras
Publisher : Springer Science & Business Media
ISBN 13 : 0306477181
Total Pages : 373 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Computational Modeling of Homogeneous Catalysis by : Feliu Maseras

Download or read book Computational Modeling of Homogeneous Catalysis written by Feliu Maseras and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent results on a wide array of catalytic processes are collected in this volume. The book illustrates the importance of computational modelling in homogeneous catalysis by providing up-to-date reviews of its application to a variety of reactions of industrial interest.

The Rare Earth Elements

Author : David A. Atwood
Publisher : John Wiley & Sons
ISBN 13 : 111863263X
Total Pages : 994 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis The Rare Earth Elements by : David A. Atwood

Download or read book The Rare Earth Elements written by David A. Atwood and published by John Wiley & Sons. This book was released on 2013-02-19 with total page 994 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lanthanides are of great importance for the electronic industries, this new book (from the EIBC Book Series) provides a comprehensive coverage of the basic chemistry, particularly inorganic chemistry, of the lanthanoid elements, those having a 4f shell of electrons. A chapter is describing the similarity of the Group 3 elements, Sc, Y, La, the group from which the lanthanoids originate and the group 13 elements, particularly aluminum, having similar properties. Inclusion of the group 3 and 13 elements demonstrates how the lanthanoid elements relate to other, more common, elements in the Periodic Table. Beginning chapters describe the occurrence and mineralogy of the elements, with a focus on structural features observed in compounds described in later chapters. The majority of the chapters is organized by the oxidation state of the elements, Ln(0), Ln(II), Ln(III), and Ln(IV). Within this organization the chapters are further distinguished by type of compound, inorganic (oxides and hydroxides, aqueous speciation, halides, alkoxides, amides and thiolates, and chelates) and organometallic. Concluding chapters deal with diverse and critically important applications of the lanthanoids in electronic and magnetic materials, and medical imaging.

Biocatalysis

Author : Qayyum Husain
Publisher : Springer Nature
ISBN 13 : 3030250237
Total Pages : 341 pages
Book Rating : 4.0/5 (32 download)

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Book Synopsis Biocatalysis by : Qayyum Husain

Download or read book Biocatalysis written by Qayyum Husain and published by Springer Nature. This book was released on 2019-09-03 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces readers to industrially important enzymes and discusses in detail their structures and functions, as well as their manifold applications. Due to their selective biocatalytic capabilities, enzymes are used in a broad range of industries and processes. The book highlights selected enzymes and their applications in agriculture, food processing and discoloration, as well as their role in biomedicine. In turn, it discusses biochemical engineering strategies such as enzyme immobilization, metabolic engineering, and cross-linkage of enzyme aggregates, and critically weighs their pros and cons. Offering a wealth of information, and stimulating further research by presenting new concepts on enzymatic catalytic functions in basic and applied contexts, the book represents a valuable asset for researchers from academia and industry who are engaged in biochemical engineering, microbiology and biotechnology.