Development Of A Multipolymer Reaction And Polyfunctional Polymeric Catalysts

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Development of a Multipolymer Reaction and Polyfunctional Polymeric Catalysts

Author : 鍾韻盈
Publisher : Open Dissertation Press
ISBN 13 : 9781374680098
Total Pages : pages
Book Rating : 4.6/5 (8 download)

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Book Synopsis Development of a Multipolymer Reaction and Polyfunctional Polymeric Catalysts by : 鍾韻盈

Download or read book Development of a Multipolymer Reaction and Polyfunctional Polymeric Catalysts written by 鍾韻盈 and published by Open Dissertation Press. This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Development of a Multipolymer Reaction and Polyfunctional Polymeric Catalysts" by 鍾韻盈, Wan-ying, Cecilia, Chung, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled DEVELOPMENT OF A MULTIPOLYMER REACTION AND POLYFUNCTIONAL POLYMERIC CATALYSTS Submitted by Chung Wan Ying Cecilia for the Degree of Doctor of Philosophy at The University of Hong Kong in March 2008 Polymer-supported reagents and catalysts have long been used in organic synthesis because they simplify product purification and can often be recycled. Simultaneously using two or more such polymeric reagents and catalysts are known as multipolymer reactions. A complementary extension of this concept is to use a single polymer that contains two or more different reagent and/or catalyst groups. We have developed several such polyfunctional polymeric reagents and catalysts. The scientific literature regarding multipolymer reactions and polyfunctional polymers in the context of organic synthesis was reviewed. The synthesis and application of both a monofunctional triflimide polymer and an analogous bifunctional triflimide/amine polymer were described. The monofunctional polymeric triflimide reagent was used together with an amine base to transform a series of phenols into the corresponding aryl triflates. However, the bifunctional triflimide/amine polymer was not effective in such aryl triflate synthesis. A multipolymer reaction system was presented for the selective and catalytic aerobic oxidation of primary benzylic alcohols to aldehydes. Polymer-supported 2,2'-bipyridine and 2,2,6,6-tetramethyl-piperidine-1-oxyl radical (TEMPO) were synthesized and used simultaneously as ligands for copper(II) to generate the catalytically active species required for the oxidation reactions. The recyclablility of these polymers was also examined. The synthesis of two polyfunctional polymers, one soluble and the other insoluble, were reported. Both 2,2'-bipyridine and TEMPO were attached to the same polymer backbone and these were successfully utilized in the same aerobic oxidation reactions previously performed in the multipolymer reaction system. DOI: 10.5353/th_b3970744 Subjects: Organic compounds - Synthesis Chemical reactions Polymers Catalysts

Development of a Multipolymer Reaction and Polyfunctional Polymeric Catalysts

Author : Wan-ying Chung (Cecilia)
Publisher :
ISBN 13 :
Total Pages : 358 pages
Book Rating : 4.:/5 (228 download)

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Book Synopsis Development of a Multipolymer Reaction and Polyfunctional Polymeric Catalysts by : Wan-ying Chung (Cecilia)

Download or read book Development of a Multipolymer Reaction and Polyfunctional Polymeric Catalysts written by Wan-ying Chung (Cecilia) and published by . This book was released on 2008 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Development of Polyfunctional Polymeric Catalysts

Author : Kar-wing Kwong (Cathy)
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (32 download)

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Book Synopsis Development of Polyfunctional Polymeric Catalysts by : Kar-wing Kwong (Cathy)

Download or read book Development of Polyfunctional Polymeric Catalysts written by Kar-wing Kwong (Cathy) and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Development of Polyfunctional Polymeric Catalysts

Author : Kar-Wing Cathy Kwong
Publisher :
ISBN 13 : 9781374682641
Total Pages : pages
Book Rating : 4.6/5 (826 download)

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Book Synopsis Development of Polyfunctional Polymeric Catalysts by : Kar-Wing Cathy Kwong

Download or read book Development of Polyfunctional Polymeric Catalysts written by Kar-Wing Cathy Kwong and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer Supported Chemical Reactions

Author : P. Hodge
Publisher : iSmithers Rapra Publishing
ISBN 13 : 9780080417394
Total Pages : 124 pages
Book Rating : 4.4/5 (173 download)

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Book Synopsis Polymer Supported Chemical Reactions by : P. Hodge

Download or read book Polymer Supported Chemical Reactions written by P. Hodge and published by iSmithers Rapra Publishing. This book was released on 1991 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer supported chemical reactions may include those using supported substrates, reagents and catalysts, and this report describes all three types. In all cases the most frequent reason for the use of a polymeric support will be the ease of separation of the supported and the low molecular c099 species. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.

Development of New Catalysts for Living Polymerizations

Author : Phillip Dene Hustad
Publisher :
ISBN 13 :
Total Pages : 604 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Development of New Catalysts for Living Polymerizations by : Phillip Dene Hustad

Download or read book Development of New Catalysts for Living Polymerizations written by Phillip Dene Hustad and published by . This book was released on 2002 with total page 604 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Amine Functionalized Polymeric Catalysts and Reagents

Author : Jinni Lu
Publisher : Open Dissertation Press
ISBN 13 : 9781361302767
Total Pages : pages
Book Rating : 4.3/5 (27 download)

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Book Synopsis Amine Functionalized Polymeric Catalysts and Reagents by : Jinni Lu

Download or read book Amine Functionalized Polymeric Catalysts and Reagents written by Jinni Lu and published by Open Dissertation Press. This book was released on 2017-01-26 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Amine Functionalized Polymeric Catalysts and Reagents" by Jinni, Lu, 陆今妮, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Polymer-supported reagents and catalysts, which allow for simple product separation and easy recycling, have been widely studied in the context of organic synthesis. The past decade has witnessed a number of new variations of polymeric materials, and among the most frequently immobilized functionalities are amines that possess versatile synthetic utilities. Polymers with new structures and improved properties for use in synthesis have been continuously developed since the support may impact the chemical reactions in which they are used in various ways. A new heterogeneous polystyrene-based amine, rasta resin-DMAP, has been synthesized and used in addition reactions of carbon dioxide to epoxides to afford cyclic carbonate products. This new material was found to be a more efficient catalyst than divinylbenzene cross-linked polystyrene supported DMAP, and was readily recycled without significant loss of catalytic activity. Compared to polymers bearing a single functionality, polymers possessing multiple different functional groups attached to a single polymer backbone would have greater potential utility, especially in reactions requiring multiple catalysts or reagents. As an example of this concept, a bifunctional polystyrene bearing both DMAP and piperazine groups has been prepared and applied as an organocatalyst for decarboxylative Doebner-Knoevenagel reactions of arylaldehydes and mono-ethyl malonate to produce (E)-,-unsaturated esters in high yields. Additionally, both non-cross-linked and cross-linked bifunctional polystyrenes featuring amine and thiourea groups have been developed, and their catalytic performance were evaluated in reactions of nitroalkenes with either nitroalkanes or sulfur ylides. Both polymers proved to be efficient catalysts in these reactions and the insoluble polymer demonstrated high recyclability. Control experiments using monofunctional polymers indicated that both catalytic groups of these bifunctional polymers are essential and they could work cooperatively to achieve efficient catalysis. Finally, a second generation bifunctional phosphine-amine polymer, rasta resin-PPh3-NBniPr2, was prepared and examined in tandem Wittig-reductive aldol reactions. In these reaction cascades, the phosphine oxide groups generated from the Wittig reaction served as the catalyst for the reductive aldol reaction, and moderate yields of structurally diverse -hydroxy ketones could be obtained from one-pot processes involving 5 sequential reactions. DOI: 10.5353/th_b4775252 Subjects: Amines Polymers Catalysts Supported reagents

Polymer-supported Reactions in Organic Synthesis

Author : Philip Hodge
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 498 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Polymer-supported Reactions in Organic Synthesis by : Philip Hodge

Download or read book Polymer-supported Reactions in Organic Synthesis written by Philip Hodge and published by John Wiley & Sons. This book was released on 1980 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Alkene Polymerization Reactions with Transition Metal Catalysts

Author : Y. V. Kissin
Publisher : Elsevier Science & Technology
ISBN 13 : 9781435628755
Total Pages : 592 pages
Book Rating : 4.6/5 (287 download)

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Book Synopsis Alkene Polymerization Reactions with Transition Metal Catalysts by : Y. V. Kissin

Download or read book Alkene Polymerization Reactions with Transition Metal Catalysts written by Y. V. Kissin and published by Elsevier Science & Technology. This book was released on 2008 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Kinetic investigation of different supported catalysts for the polymerization of propylene under industrially relevant conditions

Download Kinetic investigation of different supported catalysts for the polymerization of propylene under industrially relevant conditions PDF Online Free

Author : Joana Kettner
Publisher : Cuvillier Verlag
ISBN 13 : 3736960034
Total Pages : 176 pages
Book Rating : 4.7/5 (369 download)

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Book Synopsis Kinetic investigation of different supported catalysts for the polymerization of propylene under industrially relevant conditions by : Joana Kettner

Download or read book Kinetic investigation of different supported catalysts for the polymerization of propylene under industrially relevant conditions written by Joana Kettner and published by Cuvillier Verlag. This book was released on 2019-05-14 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: Scope of the work is the kinetic investigation of two fourth generation Ziegler-Natta catalysts as well as a supported metallocene catalyst for the polymerization of propylene under industrially relevant conditions and the development of simplified phenomenological kinetic models describing the polymerizations. Therein, the influence of different reaction conditions (temperature, pressure, hydrogen concentration) and, in particular, the effect of prepolymerization on catalyst kinetics as well as on polymer characteristics are studied. The Ziegler-Natta catalysts were investigated under gas-phase conditions in a 5 l horizontal stirred tank reactor operating in semi-batch mode. Both catalysts showed a similar kinetic behavior as well as hydrogen response at the different reaction conditions. Applying a prepolymerization led to an increase in activity at higher reaction temperatures as well as an improved polymer morphology. The impact of prepolymerization is catalyst specific and depends on the catalyst activity reached at main polymerization temperature. The supported metallocene catalyst was studied under bulk conditions in liquid propylene using a special 250 ml reaction calorimeter. A focus was set on procedure development (in-situ and external prepolymerization) with the target of defined prepolymerization conditions and early access to the kinetic profile. Final kinetic measurements were carried out using the developed external prepolymerization procedure. Based on the experimental studies, simplified phenomenological kinetic models are developed for each catalyst type enabling the quantitative description of the polymerization reactions at the different reaction conditions including the effect of prepolymerization. Main hypothesis for the mathematical description of the prepolymerization effect is that particle overheating at the beginning of the polymerization is the major reason for lower activities obtained when no prepolymerization is applied. For particle modeling, a quasi-homogeneous particle model is assumed considering particle growth and particle heat-transfer. As similar kinetic behaviors were observed for both Ziegler-Natta catalysts, the same kinetic model can be used; differences can only be described by the catalyst specific amount of polymerization active component. A similar kinetic model approach is used to describe the bulk polymerization with metallocene catalyst. Differences regarding the different polymerization regime, in particular monomer concentration in the polymer particle, hydrogen concentration in liquid phase, are considered. With the estimated sets of kinetic parameters, average activities and average molecular weights can be calculated as well as activity profiles of the catalysts can be quantitatively described at the different reaction conditions.

Development of Functionalized Polymers Using Bis(phenoxyimine)titanium and [alpha]-diimineNickel(II) Catalysts for the Production of New Polyolefin Architectures

Download Development of Functionalized Polymers Using Bis(phenoxyimine)titanium and [alpha]-diimineNickel(II) Catalysts for the Production of New Polyolefin Architectures PDF Online Free

Author : Amelia Marie Anderson
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (671 download)

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Book Synopsis Development of Functionalized Polymers Using Bis(phenoxyimine)titanium and [alpha]-diimineNickel(II) Catalysts for the Production of New Polyolefin Architectures by : Amelia Marie Anderson

Download or read book Development of Functionalized Polymers Using Bis(phenoxyimine)titanium and [alpha]-diimineNickel(II) Catalysts for the Production of New Polyolefin Architectures written by Amelia Marie Anderson and published by . This book was released on 2010 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Decades of research in the area of metal-catalyzed olefin polymerization, since the initial discoveries by Ziegler and Natta in the 1950s, has lead to the development of a wide variety of transition metal catalysts as well as numerous polymer architectures. Although early work in the field focused on heterogeneous catalysis, Kaminsky's discovery of the scavenger/activator methylaluminoxane in 1980 facilitated a renaissance in the area of homogeneous catalysts. Today, many commercial polyolefin materials are still limited to linear homopolymers, random copolymers, or blends thereof. Therefore, our efforts have focused on the endfunctionalization and random incorporation of polar functional groups into polyolefins to produce polymers with improved properties and more complex architectures than traditional linear polymers. Initial work in this area focused on the development of well-defined long-chain branched polymers from end-functionalized polypropylene. Although many star polymers have been produced using anionic, cationic and radical methods, semicrystalline polypropylene materials with similar structures from coordinationinsertion polymerization were not known. Using a non-living bis(phenoxyimine)titanium catalyst, allyl-terminated syndiotactic polypropylene was produced and utilized in the production of alcohol-, azide- and amine-terminated polymers. These end-functionalized macromolecules were employed in the synthesis of a variety of well-defined branched polymers including star, miktoarm star and H- polymers. In an effort to produce branched polyolefin materials with high molecular weight, a norbornene-terminated polymer was synthesized from the allyl-terminated syndiotactic polypropylene. Using ring-opening metathesis polymerization, a number of high molecular weight polypropylene comb polymers were produced. All of the branched, syndiotactic polypropylene materials were analyzed further in an effort to related branching with observed polymer properties. To produce polyolefins with improved properties, a series of random copolymers derived from propylene and a polar, hydrogen bonding monomer were produced using Ni(II) [alpha]-diiminecatalysts. By varying the reaction temperature, hydrogen bonding polypropylene materials with a range of microstructures were produced. At high reaction temperatures, regioirregular, amorphous polypropylene was obtained, whereas, decreasing reaction temperature lead to highly regioregular, isotactic polypropylene. Utilizing the living nature of the Ni(II) [alpha]-diiminecatalysts, a series of triblock copolymers containing hydrogen bonding moieties in the midblock were also produced. The mechanical properties of all materials were investigated and generally observed to improve upon incorporation of small amounts (~1%) of the ureidopyrimidinone. For the branched and hydrogen bonding polymer reported herein, functionalization of polypropylene allowed for the synthesis of new polyolefin architectures.

Living Catalysts for Cyclohexdiene Polymerization

Author :
Publisher :
ISBN 13 :
Total Pages : 6 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis Living Catalysts for Cyclohexdiene Polymerization by :

Download or read book Living Catalysts for Cyclohexdiene Polymerization written by and published by . This book was released on 1996 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: ROMP polymerization has become an important method for the preparation of polyphenylenevinylenes and polynaphthylenevinylene. The new route allows the band gap and processing properties of the polymers to be varied by the use of side chains and functional groups. These materials are being used to fabricate electroluminescent devices with tunable colors. New techniques have been developed for the synthesis of the starting barrelenes and benzobarrelenes. These synthesis start from the ICI diol system that was used in the preparation of polyparaphenylene. A key to these developments is the availability of well defined catalysts, considerable effort has been devoted to the design and synthesis of new complexes that will catalyze the ROMP polymerization reaction and to develop new procedures which will control the molecular weight and livingness of those systems know. The students involved in this work have gained experience in polymer synthesis, catalyst development and the fabrication of devices.

Development of Polymer-bound and Homogeneous Reagents and Catalysts for Organic Synthesis

Author : Myun-Jung Jin
Publisher :
ISBN 13 :
Total Pages : 174 pages
Book Rating : 4.:/5 (254 download)

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Book Synopsis Development of Polymer-bound and Homogeneous Reagents and Catalysts for Organic Synthesis by : Myun-Jung Jin

Download or read book Development of Polymer-bound and Homogeneous Reagents and Catalysts for Organic Synthesis written by Myun-Jung Jin and published by . This book was released on 1990 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Applications of Polymers

Author : Raymond Seymour
Publisher : Springer Science & Business Media
ISBN 13 : 146845448X
Total Pages : 154 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Applications of Polymers by : Raymond Seymour

Download or read book Applications of Polymers written by Raymond Seymour and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt: Natural polymers, such as proteins, starch, cellulose, hevea rubber, and gum which have been available for centuries, have been applied as materials for food, leather, sizings, fibers, structures, waterproofing, and coatings. During the past century, the use of both natural and syn thetic polymers has been expanded to include more intricate applications, such as membranes, foams, medicinals, conductors, insulators, fibers, films, packaging and applications requiring high modulus at elevated temperatures. The topics in this symposium which are summarized in this book are illustrative of some of the myriad applications of these ubiquitous mater ials. As stated in forecast in the last chapter in this book, it is cer tain that revolutionary applications of polymers will occur during the next decades. Hopefully, information presented in other chapters in this book will catalyze some of these anticipated applications. It is appropriate that these reports were presented at an American Chemical Society Polymer Science and Engineering Division Award Symposium honoring Dr. O.A. Battista who has gratifying to note that Phillips Pet roleum Company, which has paved the way in applications of many new poly mers, is the sponsor of this important award. We are all cheerfully expressing our thanks to this corporate spon sor and to Distinguished Professor Raymond B. Seymour of the University of Southern Mississippi who served as the organizer of this symposium and editor of this important book.

Polymer Science and Engineering

Author : National Research Council
Publisher : National Academies Press
ISBN 13 : 0309049989
Total Pages : 193 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Polymer Science and Engineering by : National Research Council

Download or read book Polymer Science and Engineering written by National Research Council and published by National Academies Press. This book was released on 1994-01-01 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers are used in everything from nylon stockings to commercial aircraft to artificial heart valves, and they have a key role in addressing international competitiveness and other national issues. Polymer Science and Engineering explores the universe of polymers, describing their properties and wide-ranging potential, and presents the state of the science, with a hard look at downward trends in research support. Leading experts offer findings, recommendations, and research directions. Lively vignettes provide snapshots of polymers in everyday applications. The volume includes an overview of the use of polymers in such fields as medicine and biotechnology, information and communication, housing and construction, energy and transportation, national defense, and environmental protection. The committee looks at the various classes of polymersâ€"plastics, fibers, composites, and other materials, as well as polymers used as membranes and coatingsâ€"and how their composition and specific methods of processing result in unparalleled usefulness. The reader can also learn the science behind the technology, including efforts to model polymer synthesis after nature's methods, and breakthroughs in characterizing polymer properties needed for twenty-first-century applications. This informative volume will be important to chemists, engineers, materials scientists, researchers, industrialists, and policymakers interested in the role of polymers, as well as to science and engineering educators and students.

Conducting Polymer Hybrids

Author : Vijay Kumar
Publisher : Springer
ISBN 13 : 3319464582
Total Pages : 338 pages
Book Rating : 4.3/5 (194 download)

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Book Synopsis Conducting Polymer Hybrids by : Vijay Kumar

Download or read book Conducting Polymer Hybrids written by Vijay Kumar and published by Springer. This book was released on 2016-11-02 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive survey about conducting polymers and their hybrids with different materials. It highlights the topics pertinent to research and development in academia and in the industry. The book thus discusses the preparation and characterization of these materials, as well as materials properties and their processing. The current challenges in the field are addressed, and an outline on new and even futuristic approaches is given. “Conducting Polymer Hybrids” is concerned with a fascinating class of materials with the promise for wide-ranging applications, including energy generation and storage, supercapacitors, electronics, display technologies, sensing, environmental and biomedical applications. The book covers a large variety of systems: one-, two-, and three-dimenstional composites and hybrids, mixed at micro- and nanolevel.

Textbook of Polymer Science

Author : Fred W. Billmeyer
Publisher : John Wiley & Sons
ISBN 13 : 0471031968
Total Pages : 598 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Textbook of Polymer Science by : Fred W. Billmeyer

Download or read book Textbook of Polymer Science written by Fred W. Billmeyer and published by John Wiley & Sons. This book was released on 1984-03-21 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Third Edition of the classic, best-selling polymer science textbook surveys theory and practice of all major phases of polymer science, engineering, and technology, including polymerization, solution theory, fractionation and molecular-weight measurement, solid-state properties, structure-property relationships, and the preparation, fabrication and properties of commercially-important plastics, fibers, and elastomers.