Author : Nenad Miljkovic
Publisher :
ISBN 13 :
Total Pages : 185 pages
Book Rating : 4.:/5 (867 download)
Book Synopsis Development and Characterization of Micro/nano Structured Surfaces for Enhanced Condensation by : Nenad Miljkovic
Download or read book Development and Characterization of Micro/nano Structured Surfaces for Enhanced Condensation written by Nenad Miljkovic and published by . This book was released on 2013 with total page 185 pages. Available in PDF, EPUB and Kindle. Book excerpt: Micro/nanostructures have long been recognized to have potential for heat transfer enhancement in phase-change processes by achieving extreme wetting properties, which is of great importance in a wide range of applications including thermal management, building environment control, water harvesting, desalination, and industrial power generation. This thesis focuses on the fundamental understanding of water vapor condensation on superhydrophobic surfaces, as well as the demonstration of such surfaces for enhanced condensation heat transfer performance. We first studied droplet-surface interactions during condensation on superhydrophobic surfaces to understand the emergent droplet wetting morphology. We demonstrated the importance of considering local energy barriers to understand the condensed droplet morphologies and showed nucleation-mediated droplet-droplet interactions can overcome these barriers to develop wetting states not predicted by global thermodynamic analysis. To minimize these droplet-droplet interactions and ensure the formation of favorable morphologies for enhanced condensation heat transfer, we show that the structure length scale needs to be minimized while ensuring the local energy barriers satisfy the morphology dependent criteria. This mechanistic understanding offers insight into the role of surface-structure length scale and provides a quantitative basis for designing surfaces optimized for condensation in engineered systems. Using our understanding of emergent droplet wetting morphology, we experimentally and numerically investigated the morphology dependent individual droplet growth rates. By taking advantage of well-controlled functionalized silicon nanopillars, the growth and shedding behavior of both suspended and partially wetting droplets on the same surface during condensation was observed. Environmental scanning electron microscopy was used to demonstrate that initial droplet growth rates of partially wetting droplets were 6 times larger than that of suspended droplets. A droplet growth model was developed to explain the experimental results and showed that partially wetting droplets had 4-6 times higher heat transfer rates than that of suspended droplets. Based on these findings, the overall performance enhancement created by surface nanostructuring was examined in comparison to a flat hydrophobic surface. These nanostructured surfaces had 56% heat flux enhancement for partially wetting droplet morphologies, and 71% heat flux degradation for suspended morphologies in comparison to flat hydrophobic surfaces. This study provides fundamental insights into the previously unidentified role of droplet wetting morphology on growth rate, as well as the need to design nanostructured surfaces with tailored droplet morphologies to achieve enhanced heat and mass transfer during dropwise condensation. To create a unified model for condensation capable of predicting the surface heat transfer for a variety of surface length scales, geometries, and condensation conditions, we incorporated the emergent droplet wetting morphology, individual droplet heat transfer, and size distribution. The model results showed a specific range of characteristic length scales (0.5 - 2 ptm) allowing for the formation of coalescence-induced jumping droplets with a 190% overall surface heat flux enhancement over conventional flat dropwise condensing surfaces. This work provided a unified model for dropwise condensation on micro/nanostructured superhydrophobic surfaces and offered guidelines for the selection of ideal structured surfaces to maximize heat transfer. Using the insights gained from the developed model and optimization, a scalable synthesis technique was developed to produce functionalized oxide nanostructures on copper surfaces capable of sustaining superhydrophobic condensation. Nanostructured copper oxide (CuO) films were formed via chemical oxidation in an alkaline solution resulting in dense arrays of sharp CuO nanostructures with characteristic heights and widths of -1 pm and -300 nm, respectively. Condensation on these surfaces was characterized using optical microscopy and environmental scanning electron microscopy to quantify the distribution of nucleation sites and elucidate the growth behavior of individual droplets with characteristic radii of -1 to 10 pm at supersaturations