Degradation of MTBE and TBA in Aqueous Solution by Ozone/UV Process

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Publisher :
ISBN 13 :
Total Pages : 462 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Degradation of MTBE and TBA in Aqueous Solution by Ozone/UV Process by : Temesgen Garoma Ararsso

Download or read book Degradation of MTBE and TBA in Aqueous Solution by Ozone/UV Process written by Temesgen Garoma Ararsso and published by . This book was released on 2004 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: Methyl tert-butyl ether (MTBE) is currently the leading contaminant of groundwater in the United States. The widespread presence of MTBE along with its degradation by-product, tert-butyl alcohol (TBA), in groundwater has created great concern in the scientific community because MTBE and TBA are suspected as possible human carcinogens. In this research, the degradation of MTBE and TBA in aqueous solution by O33/UV process has been investigated. Laboratory studies were conducted using a semi-batch reactor under various experimental conditions, i.e., incident UV light intensity, influent ozone gas concentration, and water quality in terms of varying bicarbonate concentration. Furthermore, the O33/UV process was modeled by using oxalic acid as a probe chemical. Oxalic acid was oxidized by O33/UV process under various experimental conditions; and the model successfully predicted the residual concentration of oxalic acid. In order to understand the degradation mechanisms of MTBE and TBA, a comprehensive kinetic model that describes the degradations of MTBE, TBA and their intermediates by O33/UV process was proposed. The model was calibrated using experimental data on MTBE and TBA spiked in synthetic solution. An attempt was made to verify the kinetic model using different sets of experimental data. The model predicted well the removal of MTBE and TBA; however, the accumulation and decay of some primarily intermediates were predicted with slight variations. Finally, real groundwater samples contaminated with MTBE and TBA were oxidized by O33/UV process under various experimental conditions. It was observed that the removal rate of MTBE and TBA was reduced by the presence of other gasoline components, such as BTEX. Furthermore, for groundwater sample without iron the kinetic model predicted the degradation of MTBE as well as accumulation and decay of reaction intermediates with slight variations. In conclusion, this research provides valuable information on the degradation mechanisms of MTBE, TBA, and their intermediates. The O33/UV process was very successful in degrading MTBE and TBA in aqueous solution. Moreover, it was observed that the reaction intermediates react well in the O33/UV process, and complete mineralization could be achieved, if desired.

Handbook of MTBE and Other Gasoline Oxygenates

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Publisher : CRC Press
ISBN 13 : 0824752015
Total Pages : 381 pages
Book Rating : 4.8/5 (247 download)

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Book Synopsis Handbook of MTBE and Other Gasoline Oxygenates by : Halim Hamid

Download or read book Handbook of MTBE and Other Gasoline Oxygenates written by Halim Hamid and published by CRC Press. This book was released on 2004-03-11 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook presents the outlook for future production and consumption of MTBE and other oxygenates worldwide and studies new catalytic systems and modern methods for the synthesis and commercial production of methyl tertiary-butyl ether (MTBE) and related ethers. The scope of this sophisticated guide extends from process chemistry fundamentals and reaction kinetics to environmental remediation technologies and industry responses to conflicting calls for MTBE phase-out and higher-octane products. Well-illustrated with over 200 figures and tables, this authoritative Handbook details bioremediation, air stripping, and oxidation and adsorption processes for MTBE removal.

Fuel Oxygenates

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Publisher : Springer Science & Business Media
ISBN 13 : 3540726411
Total Pages : 422 pages
Book Rating : 4.5/5 (47 download)

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Book Synopsis Fuel Oxygenates by : Damià Barceló

Download or read book Fuel Oxygenates written by Damià Barceló and published by Springer Science & Business Media. This book was released on 2007-08-03 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals mainly with the problems associated with the contamination of groundwater by MTBE and TBA, but ETBE is also considered. The book, written by recognized specialists in the field, is organized in sections covering state-of-the-art analytical methods, including specific isotopic analysis, occurrence in the environment, transport and degradation processes, treatment technologies and human health risks.

Removal of MTBE with Advanced Oxidation Processes

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Publisher : IWA Publishing
ISBN 13 : 1843398613
Total Pages : 270 pages
Book Rating : 4.8/5 (433 download)

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Book Synopsis Removal of MTBE with Advanced Oxidation Processes by : Michael Kavanaugh

Download or read book Removal of MTBE with Advanced Oxidation Processes written by Michael Kavanaugh and published by IWA Publishing. This book was released on 2004-01-01 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this project was to perform a careful evaluation of the technical and economic feasibility of advanced oxidation processes (AOPs) for methyl tertiary butyl ether (MTBE) removal. Specifically, the first objective of this project was to identify and fill data gaps related to the implementation and operation of AOPs with respect to MTBE removal. The second objective was to select and optimize the design of the most promising AOP(s) as a function of water quality parameters. The third objective was to determine conceptual-level engineering costs for these selected AOPs. The AOP technologies that were evaluated as part of this study included ozone/peroxide, continuous wave UV/peroxide, pulsed UV/peroxide, and E beam. The AOP technologies were compared with treatment costs, qualitative factors (e.g., technology reliability, flexibility), and influent and treated water quality considerations. Based on the comparative analysis, it was concluded that all the AOP technologies that were evaluated in this study are capable of removing MTBE at 95% or higher efficiencies. Ozone/peroxide and continuous UV/peroxide appear to be the most feasible technologies for AOP treatment of MTBE in drinking water sources. Originally published by AwwaRF for its subscribers in 2003

Advanced Oxidation Processes for Water Treatment

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Publisher : IWA Publishing
ISBN 13 : 1780407181
Total Pages : 712 pages
Book Rating : 4.7/5 (84 download)

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Book Synopsis Advanced Oxidation Processes for Water Treatment by : Mihaela I. Stefan

Download or read book Advanced Oxidation Processes for Water Treatment written by Mihaela I. Stefan and published by IWA Publishing. This book was released on 2017-09-15 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Oxidation Processes (AOPs) rely on the efficient generation of reactive radical species and are increasingly attractive options for water remediation from a wide variety of organic micropollutants of human health and/or environmental concern. Advanced Oxidation Processes for Water Treatment covers the key advanced oxidation processes developed for chemical contaminant destruction in polluted water sources, some of which have been implemented successfully at water treatment plants around the world. The book is structured in two sections; the first part is dedicated to the most relevant AOPs, whereas the topics covered in the second section include the photochemistry of chemical contaminants in the aquatic environment, advanced water treatment for water reuse, implementation of advanced treatment processes for drinking water production at a state-of-the art water treatment plant in Europe, advanced treatment of municipal and industrial wastewater, and green technologies for water remediation. The advanced oxidation processes discussed in the book cover the following aspects: - Process principles including the most recent scientific findings and interpretation. - Classes of compounds suitable to AOP treatment and examples of reaction mechanisms. - Chemical and photochemical degradation kinetics and modelling. - Water quality impact on process performance and practical considerations on process parameter selection criteria. - Process limitations and byproduct formation and strategies to mitigate any potential adverse effects on the treated water quality. - AOP equipment design and economics considerations. - Research studies and outcomes. - Case studies relevant to process implementation to water treatment. - Commercial applications. - Future research needs. Advanced Oxidation Processes for Water Treatment presents the most recent scientific and technological achievements in process understanding and implementation, and addresses to anyone interested in water remediation, including water industry professionals, consulting engineers, regulators, academics, students. Editor: Mihaela I. Stefan - Trojan Technologies - Canada

From Microorganisms to Engineered Systems

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Publisher :
ISBN 13 :
Total Pages : 340 pages
Book Rating : 4.3/5 (121 download)

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Book Synopsis From Microorganisms to Engineered Systems by : Xiaolin Wang

Download or read book From Microorganisms to Engineered Systems written by Xiaolin Wang and published by . This book was released on 2003 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt:

White's Handbook of Chlorination and Alternative Disinfectants

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Publisher : John Wiley & Sons
ISBN 13 : 1118210557
Total Pages : 1109 pages
Book Rating : 4.1/5 (182 download)

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Book Synopsis White's Handbook of Chlorination and Alternative Disinfectants by : Black & Veatch Corporation

Download or read book White's Handbook of Chlorination and Alternative Disinfectants written by Black & Veatch Corporation and published by John Wiley & Sons. This book was released on 2011-09-20 with total page 1109 pages. Available in PDF, EPUB and Kindle. Book excerpt: New edition covers the latest practices, regulations, and alternative disinfectants Since the publication of the Fourth Edition of White's Handbook of Chlorination and Alternative Disinfectants more than ten years ago, the water industry has made substantial advances in their understanding and application of chlorine, hypochlorite, and alternative disinfectants for water and wastewater treatment. This Fifth Edition, with its extensive updates and revisions, reflects the current state of the science as well as the latest practices. Balancing theory with practice, the Fifth Edition covers such important topics as: Advances in the use of UV and ozone as disinfectants Alternative disinfectants such as chlorine dioxide, iodine, and bromine-related products Advanced oxidation processes for drinking water and wastewater treatment New developments and information for the production and handling of chlorine Latest regulations governing the use of different disinfectants For each disinfectant, the book explains its chemistry, effectiveness, dosing, equipment, and system design requirements. Moreover, the advantages and disadvantages of each disinfectant are clearly set forth. References at the end of each chapter guide readers to the primary literature for further investigation. Authored and reviewed by leading experts in the field of water and wastewater treatment, this Fifth Edition remains an ideal reference for utilities, regulators, engineers, and plant operators who need current information on the disinfection of potable water, wastewater, industrial water, and swimming pools.

Green Chemistry for Dyes Removal from Waste Water

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Publisher : John Wiley & Sons
ISBN 13 : 1118721187
Total Pages : 412 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Green Chemistry for Dyes Removal from Waste Water by : Sanjay K. Sharma

Download or read book Green Chemistry for Dyes Removal from Waste Water written by Sanjay K. Sharma and published by John Wiley & Sons. This book was released on 2015-02-25 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of synthetic chemical dyes in various industrial processes, including paper and pulp manufacturing, plastics, dyeing of cloth, leather treatment and printing, has increased considerably over the last few years, resulting in the release of dye-containing industrial effluents into the soil and aquatic ecosystems. The textile industry generates high-polluting wastewaters and their treatment is a very serious problem due to high total dissolved solids (TDS), presence of toxic heavy metals, and the non-biodegradable nature of the dyestuffs in the effluent. The chapters in this book provide an overview of the problem and its solution from different angles. These problems and solutions are presented in a genuinely holistic way by world-renowned researchers. Discussed are various promising techniques to remove dyes, including the use of nanotechnology, ultrasound, microwave, catalysts, biosorption, enzymatic treatments, advanced oxidation processes, etc., all of which are "green." Green Chemistry for Dyes Removal from Wastewater comprehensively discusses: Different types of dyes, their working and methodologies and various physical, chemical and biological treatment methods employed Application of advanced oxidation processes (AOPs) in dye removal whereby highly reactive hydroxyl radicals are generated chemically, photochemically and/or by radiolytic/ sonolytic means. The potential of ultrasound as an AOP is discussed as well. Nanotechnology in the treatment of dye removal types of adsorbents for removal of toxic pollutants from aquatic systems Photocatalytic oxidation process for dye degradation under both UV and visible light, application of solar light and solar photoreactor in dye degradation

Photocatalysts in Advanced Oxidation Processes for Wastewater Treatment

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Publisher : John Wiley & Sons
ISBN 13 : 1119631394
Total Pages : 320 pages
Book Rating : 4.1/5 (196 download)

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Book Synopsis Photocatalysts in Advanced Oxidation Processes for Wastewater Treatment by : Elvis Fosso-Kankeu

Download or read book Photocatalysts in Advanced Oxidation Processes for Wastewater Treatment written by Elvis Fosso-Kankeu and published by John Wiley & Sons. This book was released on 2020-06-10 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalysts in Advanced Oxidation Processes for Wastewater Treatment comprehensively covers a range of topics aiming to promote the implementation of photocatalysis at large scale through provision of facile and green methods for catalysts synthesis and elucidation of pollutants degradation mechanisms. This book is divided into two main parts namely “Synthesis of effective photocatalysts” (Part I) and “Mechanisms of the photocatalytic degradation of various pollutants” (Part II). The first part focuses on the exploration of various strategies to synthesize sustainable and effective photocatalysts. The second part of the book provides an insights into the photocatalytic degradation mechanisms and pathways under ultraviolet and visible light irradiation, as well as the challenges faced by this technology and its future prospects.

Guidelines for Drinking-water Quality

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Publisher : World Health Organization
ISBN 13 : 9789241545037
Total Pages : 260 pages
Book Rating : 4.5/5 (45 download)

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Book Synopsis Guidelines for Drinking-water Quality by : World Health Organization

Download or read book Guidelines for Drinking-water Quality written by World Health Organization and published by World Health Organization. This book was released on 1993 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume describes the methods used in the surveillance of drinking water quality in the light of the special problems of small-community supplies, particularly in developing countries, and outlines the strategies necessary to ensure that surveillance is effective.

Fuel Oxygenates

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Publisher : Springer
ISBN 13 : 9783540726401
Total Pages : 411 pages
Book Rating : 4.7/5 (264 download)

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Book Synopsis Fuel Oxygenates by : Damià Barceló

Download or read book Fuel Oxygenates written by Damià Barceló and published by Springer. This book was released on 2007-09-03 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals mainly with the problems associated with the contamination of groundwater by MTBE and TBA, but ETBE is also considered. The book, written by recognized specialists in the field, is organized in sections covering state-of-the-art analytical methods, including specific isotopic analysis, occurrence in the environment, transport and degradation processes, treatment technologies and human health risks.

Alternatives for Managing the Nation's Complex Contaminated Groundwater Sites

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Publisher : National Academies Press
ISBN 13 : 0309278139
Total Pages : 423 pages
Book Rating : 4.3/5 (92 download)

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Book Synopsis Alternatives for Managing the Nation's Complex Contaminated Groundwater Sites by : National Research Council

Download or read book Alternatives for Managing the Nation's Complex Contaminated Groundwater Sites written by National Research Council and published by National Academies Press. This book was released on 2013-02-27 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: Across the United States, thousands of hazardous waste sites are contaminated with chemicals that prevent the underlying groundwater from meeting drinking water standards. These include Superfund sites and other facilities that handle and dispose of hazardous waste, active and inactive dry cleaners, and leaking underground storage tanks; many are at federal facilities such as military installations. While many sites have been closed over the past 30 years through cleanup programs run by the U.S. Department of Defense, the U.S. EPA, and other state and federal agencies, the remaining caseload is much more difficult to address because the nature of the contamination and subsurface conditions make it difficult to achieve drinking water standards in the affected groundwater. Alternatives for Managing the Nation's Complex Contaminated Groundwater Sites estimates that at least 126,000 sites across the U.S. still have contaminated groundwater, and their closure is expected to cost at least $110 billion to $127 billion. About 10 percent of these sites are considered "complex," meaning restoration is unlikely to be achieved in the next 50 to 100 years due to technological limitations. At sites where contaminant concentrations have plateaued at levels above cleanup goals despite active efforts, the report recommends evaluating whether the sites should transition to long-term management, where risks would be monitored and harmful exposures prevented, but at reduced costs.

Remediation Engineering

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Publisher : CRC Press
ISBN 13 : 1498773362
Total Pages : 628 pages
Book Rating : 4.4/5 (987 download)

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Book Synopsis Remediation Engineering by : Suthan S. Suthersan

Download or read book Remediation Engineering written by Suthan S. Suthersan and published by CRC Press. This book was released on 2016-11-25 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt: "This second edition of Remediation Engineering will continue to be the seminal handbook that regulators must have on-hand to address any of the remediation issues they are grappling with daily. The book is wide-ranging, but specific enough to address any environmental remediation challenge." —Patricia Reyes, Interstate Technology Regulatory Council, Washington, DC, USA "This book offers the researcher, teacher, practitioner, student, and regulator with state-of-the-art advances in conducting site investigations and remediation for common and emerging contaminants. It is revolutionary in its approach to conducting subsurface investigation, which greatly influences a successful and appropriate response in assessing and addressing environmental risk. This book is a giant leap forward in understanding how contaminates behave and how to reduce risk to acceptable levels in the natural world." —Daniel T. Rogers, Amsted Industries Incorporated, Chicago, Illinois, USA "This text is a superb reference and a good tool for learning about state-of-the-art techniques in remediation of soil and groundwater. [It] will become a ready reference at many companies as the engineering community creates increased value from remediation efforts around the world." —John Waites, AVX Corporation, Fountain Inn, South Carolina, USA Remediation Engineering was first published in 1996 and quickly became the go-to reference for a relatively young industry, offering the first comprehensive look at the state-of-the-science in treatment technologies of the time and the contaminants they applied to. This fully updated Second Edition will capture the fundamental advancements that have taken place during the last two decades within all the subdisciplines that form the foundation of the remediation engineering platform. It covers the entire spectrum of current technologies that are employed in the industry and also discusses future trends and how practitioners should anticipate and adapt to those needs. Features: Shares the latest paradigms in remediation design approach and contaminant hydrogeology Presents the landscape of new and emerging contaminants Details the current state of the practice for both conventional technologies, such as sparging and venting Examines newer technologies such as dynamic groundwater recirculation and injection-based remedies to address both organic and inorganic contaminants. Describes the advances in site characterization concepts such as smart investigations and digital conceptual site models. Includes all-new color photographs and figures.

Organic Pollutants in the Water Cycle

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Publisher : John Wiley & Sons
ISBN 13 : 352760863X
Total Pages : 368 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Organic Pollutants in the Water Cycle by : Thorsten Reemtsma

Download or read book Organic Pollutants in the Water Cycle written by Thorsten Reemtsma and published by John Wiley & Sons. This book was released on 2006-12-13 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first in-depth and comprehensive reference on the most pertinent polar contaminant classes and their behavior in the whole water cycle includes, among others, industrial chemicals, consumer products, polar herbicides and pharmaceuticals. All chapters are uniformly structured, covering properties, pollution sources, occurrence in wastewater, surface water, and groundwater as well as water treatment aspects, while ecotoxicological and assessment aspects are also covered. Among the authors are leading experts in their relevant fields, many of whom provide here groundbreaking research results. The result is an up-to-date information source for researchers and professionals working in water quality monitoring, water supply, or wastewater treatment, as well as environmental and water chemists, geochemists, ecologists, chemists and engineers.

Drinking Water Contaminant Candidate List

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Publisher :
ISBN 13 :
Total Pages : 8 pages
Book Rating : 4.3/5 (121 download)

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Book Synopsis Drinking Water Contaminant Candidate List by :

Download or read book Drinking Water Contaminant Candidate List written by and published by . This book was released on 1998 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemistry of Ozone in Water and Wastewater Treatment

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Publisher : IWA Publishing
ISBN 13 : 1843393131
Total Pages : 306 pages
Book Rating : 4.8/5 (433 download)

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Book Synopsis Chemistry of Ozone in Water and Wastewater Treatment by : Clemens von Sonntag

Download or read book Chemistry of Ozone in Water and Wastewater Treatment written by Clemens von Sonntag and published by IWA Publishing. This book was released on 2012-08-31 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: Even though ozone has been applied for a long time for disinfection and oxidation in water treatment, there is lack of critical information related to transformation of organic compounds. This has become more important in recent years, because there is considerable concern about the formation of potentially harmful degradation products as well as oxidation products from the reaction with the matrix components. In recent years, a wealth of information on the products that are formed has accumulated, and substantial progress in understanding mechanistic details of ozone reactions in aqueous solution has been made. Based on the latter, this may allow us to predict the products of as yet not studied systems and assist in evaluating toxic potentials in case certain classes are known to show such effects. Keeping this in mind, Chemistry of Ozone in Water and Wastewater Treatment: From Basic Principles to Applications discusses mechanistic details of ozone reactions as much as they are known to date and applies them to the large body of studies on micropollutant degradation (such as pharmaceuticals and endocrine disruptors) that is already available. Extensively quoting the literature and updating the available compilation of ozone rate constants gives the reader a text at hand on which his research can be based. Moreover, those that are responsible for planning or operation of ozonation steps in drinking water and wastewater treatment plants will find salient information in a compact form that otherwise is quite disperse. A critical compilation of rate constants for the various classes of compounds is given in each chapter, including all the recent publications. This is a very useful source of information for researchers and practitioners who need kinetic information on emerging contaminants. Furthermore, each chapter contains a large selection of examples of reaction mechanisms for the transformation of micropollutants such as pharmaceuticals, pesticides, fuel additives, solvents, taste and odor compounds, cyanotoxins. Authors: Prof. Dr. Clemens von Sonntag, Max-Planck-Institut für Bioanorganische Chemie, Mülheim an der Ruhr, and Instrumentelle Analytische Chemie, Universität Duisburg-Essen, Essen, Germany and Prof. Dr. Urs von Gunten, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Dübendorf, and Ecole Polytechnique Federal de Lausanne, Lausanne, Switzerland.

Advanced Oxidation Processes

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Publisher : BoD – Books on Demand
ISBN 13 : 1789848903
Total Pages : 184 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Advanced Oxidation Processes by : Ciro Bustillo-Lecompte

Download or read book Advanced Oxidation Processes written by Ciro Bustillo-Lecompte and published by BoD – Books on Demand. This book was released on 2020-06-10 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Oxidation Processes – Applications, Trends, and Prospects constitutes a comprehensive resource for civil, chemical, and environmental engineers researching in the field of water and wastewater treatment. The book covers the fundamentals, applications, and future work in Advanced Oxidation Processes (AOPs) as an attractive alternative and a complementary treatment option to conventional methods. This book also presents state-of-the-art research on AOPs and heterogeneous catalysis while covering recent progress and trends, including the application of AOPs at the laboratory, pilot, or industrial scale, the combination of AOPs with other technologies, hybrid processes, process intensification, reactor design, scale-up, and optimization. The book is divided into four sections: Introduction to Advanced Oxidation Processes, General Concepts of Heterogeneous Catalysis, Fenton and Ferrate in Wastewater Treatment, and Industrial Applications, Trends, and Prospects.