Copperi Catalyzed Borylation And Cross Coupling Reactions

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Copper-Mediated Cross-Coupling Reactions

Author : Gwilherm Evano
Publisher : John Wiley & Sons
ISBN 13 : 1118690478
Total Pages : 682 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Copper-Mediated Cross-Coupling Reactions by : Gwilherm Evano

Download or read book Copper-Mediated Cross-Coupling Reactions written by Gwilherm Evano and published by John Wiley & Sons. This book was released on 2013-09-23 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing comprehensive insight into the use of copper in cross-coupling reactions, Copper-Mediated Cross-Coupling Reactions provides a complete up-to-date collection of the available reactions and catalytic systems for the formation of carbon-heteroatom and carbon-carbon bonds. This essential reference covers a broad scope of copper-mediated reactions, their variations, key advances, improvements, and an array of academic and industrial applications that have revolutionized the field of organic synthesis. The text also discusses the mechanism of these transformations, the use of copper as cost-efficient alternative to palladium, as well as recently developed methods for conducting copper-mediated reactions with supported catalysts.

Copper Catalysis in Organic Synthesis

Author : Gopinathan Anilkumar
Publisher : John Wiley & Sons
ISBN 13 : 3527347372
Total Pages : 504 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Copper Catalysis in Organic Synthesis by : Gopinathan Anilkumar

Download or read book Copper Catalysis in Organic Synthesis written by Gopinathan Anilkumar and published by John Wiley & Sons. This book was released on 2020-12-07 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: The most current information on growing field of copper catalysis Copper Catalysis in Organic Synthesis contains an up-to-date overview of the most important reactions in the presence of copper catalysts. The contributors—noted experts on the topic—provide an introduction to the field of copper catalysis, reviewing its development, scope, and limitations, as well as providing descriptions of various homo- and cross-coupling reactions. In addition, information is presented on copper-catalyzed C–H activation, amination, carbonylation, trifluoromethylation, cyanation, and click reactions. Comprehensive in scope, the book also describes microwave-assisted and multi-component transformations as well as copper-catalyzed reactions in green solvents and continuous flow reactors. The authors highlight the application of copper catalysis in asymmetric synthesis and total synthesis of natural products and heterocycles as well as nanocatalysis. This important book: Examines copper and its use in organic synthesis as a more cost-effective and sustainable for researchers in academia and industry Offers the first up-to-date book to explore copper as a first line catalyst for many organic reactions Presents the most significant developments in the area, including cross-coupling reactions, C–H activation, asymmetric synthesis, and total synthesis of natural products and heterocycles Contains over 20 contributions from leaders in the field Written for catalytic chemists, organic chemists, natural products chemists, pharmaceutical chemists, and chemists in industry, Copper Catalysis in Organic Synthesis offers a book on the growing field of copper catalysis, covering cross-coupling reactions, C–H activation, and applications in the total synthesis of natural products.

Copper(I) Catalyzed Borylation and Cross-coupling Reactions

Author : Antonius Eichhorn
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (15 download)

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Book Synopsis Copper(I) Catalyzed Borylation and Cross-coupling Reactions by : Antonius Eichhorn

Download or read book Copper(I) Catalyzed Borylation and Cross-coupling Reactions written by Antonius Eichhorn and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Cross-Coupling Reactions

Author : Norio Miyaura
Publisher : Springer
ISBN 13 : 354045313X
Total Pages : 253 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Cross-Coupling Reactions by : Norio Miyaura

Download or read book Cross-Coupling Reactions written by Norio Miyaura and published by Springer. This book was released on 2003-07-01 with total page 253 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists do not hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of “metal-catalyzed organic syntheses”. An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).

Oxidative Cross-Coupling Reactions

Author : Aiwen Lei
Publisher : John Wiley & Sons
ISBN 13 : 3527336885
Total Pages : 243 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Oxidative Cross-Coupling Reactions by : Aiwen Lei

Download or read book Oxidative Cross-Coupling Reactions written by Aiwen Lei and published by John Wiley & Sons. This book was released on 2016-11-14 with total page 243 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first handbook on this emerging field provides a comprehensive overview of transition metal-catalyzed coupling reactions in the presence of an oxidant. Following an introduction to the general concept and mechanism of this reaction class, the team of authors presents chapters on C-C cross-coupling reactions using organometallic partners, C-Heteroatom bond forming reactions via oxidative couplings, and C-H couplings via C-H activation. The text also covers such groundbreaking topics as recent achievements in the fields of C-C and C-X bond formation reactions as well as C-H activation involving oxidative couplings. With its novel and concise approach towards important building blocks in organic chemistry and its focus on synthetic applications, this handbook is of great interest to all synthetic chemists in academia and industry alike.

Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

Author : Aiwen Lei
Publisher : Springer
ISBN 13 : 3662581043
Total Pages : 192 pages
Book Rating : 4.6/5 (625 download)

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Book Synopsis Transition Metal Catalyzed Oxidative Cross-Coupling Reactions by : Aiwen Lei

Download or read book Transition Metal Catalyzed Oxidative Cross-Coupling Reactions written by Aiwen Lei and published by Springer. This book was released on 2018-12-14 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a comprehensive text covering the research and development trends in the booming field of transition metal catalyzed oxidative cross-coupling reactions. Oxidative cross-coupling reaction is a new method to forming chemical bonds besides the traditional cross-coupling reactions. This book provides the answers to how this coupling reaction occurs and what its advantages are. The palladium, copper and iron catalyzed oxidative cross-coupling reactions as the main focuses of interest are described in detail. The oxidative cross-coupling reactions catalyzed by other metals and transition-metal-free oxidative coupling reactions are also introduced.This book provides a useful reference source for researchers and graduates in the field of transition metal catalyzed coupling reactions. It is also valuable to researchers working in pharmaceutical companies, fine organic chemical companies, and etc.

Copper-catalyzed Cross-coupling Reactions

Author : Craig G. Bates
Publisher :
ISBN 13 :
Total Pages : 292 pages
Book Rating : 4.:/5 (618 download)

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Book Synopsis Copper-catalyzed Cross-coupling Reactions by : Craig G. Bates

Download or read book Copper-catalyzed Cross-coupling Reactions written by Craig G. Bates and published by . This book was released on 2005 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Copper(I)-Catalyzed Stereoselective Borylation Reactions

Author : Yu Ozawa
Publisher : Springer Nature
ISBN 13 : 9819910986
Total Pages : 236 pages
Book Rating : 4.8/5 (199 download)

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Book Synopsis Copper(I)-Catalyzed Stereoselective Borylation Reactions by : Yu Ozawa

Download or read book Copper(I)-Catalyzed Stereoselective Borylation Reactions written by Yu Ozawa and published by Springer Nature. This book was released on 2023-05-30 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanisms are analyzed with state-of-the-art DFT and other computational methods. In this book, the author synthesizes some multi-substituted alkenyl and allylic boronates via borylation reactions using a copper(I)/diboron catalyst system. Those compounds contain novel densely substituted and distorted structures, which have not been accessed by other methods. The high stereoselectivities are achieved by the optimization of the catalyst, especially the ligand. Some new ligands are also developed in this book. Furthermore, the derivatization of the borylation products is demonstrated to access the sterically demanding complex molecules. Also, the author performs computational analysis to reveal how the catalyst controls the selectivities. The deep insight into the reaction mechanism provides guides for rational catalyst design for not only copper(I) catalysis but also other transition metal catalysis. Thus, the content should be of interest to academic and industrial scientists in a wide range of areas.

Copper in N-Heterocyclic Chemistry

Author : Ananya Srivastava
Publisher : Elsevier
ISBN 13 : 012821547X
Total Pages : 506 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Copper in N-Heterocyclic Chemistry by : Ananya Srivastava

Download or read book Copper in N-Heterocyclic Chemistry written by Ananya Srivastava and published by Elsevier. This book was released on 2020-11-13 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Copper in N-Heterocyclic Chemistry provides an overview of copper-catalyzed synthesis and functionalization of N-heterocyclic compounds, covering all recent developments in a way that is ideal for researchers and students working in the area of synthetic organic chemistry and medicinal chemistry. The book explores N-heterocyclic compounds as unique structural units in the development of natural products and pharmaceuticals, along with the remarkable progress made in the area of high atom economic strategies, and more recently, copper-catalyzed C-H activation and its applications in organic synthesis. Readers will find troubleshooting protocols, as well as the advantages and limitations of each method discussed. As copper catalysts show versatile chemical reactivity in many aspects, including their oxidation states 0–3 are accessible and their ability to facilitate bond formations due to their ability to serve as Lewis acids, oxidizing agents and catalysts, this book is an ideal resource on the topics explored. Discusses novel synthetic methods developed over the past decade for copper-catalyzed synthesis of N-heterocyclic compounds Covers the most recent methodologies adapted in synthetic chemistry for applications in natural products and pharmaceuticals Includes troubleshooting protocols, as well as the advantages and limitations of each method discussed in detail

Mechanistic Studies of Copper-catalyzed Transformations

Author : Amanda Elisabeth King
Publisher :
ISBN 13 :
Total Pages : 213 pages
Book Rating : 4.:/5 (667 download)

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Book Synopsis Mechanistic Studies of Copper-catalyzed Transformations by : Amanda Elisabeth King

Download or read book Mechanistic Studies of Copper-catalyzed Transformations written by Amanda Elisabeth King and published by . This book was released on 2009 with total page 213 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Visible-light Induced Copper Catalyzed C-C, C-N, and C-O Cross-Coupling Reactions

Author : 魏珀
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (126 download)

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Book Synopsis Visible-light Induced Copper Catalyzed C-C, C-N, and C-O Cross-Coupling Reactions by : 魏珀

Download or read book Visible-light Induced Copper Catalyzed C-C, C-N, and C-O Cross-Coupling Reactions written by 魏珀 and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Imines in Copper-catalyzed Cross-coupling Reactions

Author : Daniel Black
Publisher :
ISBN 13 :
Total Pages : 436 pages
Book Rating : 4.:/5 (253 download)

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Book Synopsis Imines in Copper-catalyzed Cross-coupling Reactions by : Daniel Black

Download or read book Imines in Copper-catalyzed Cross-coupling Reactions written by Daniel Black and published by . This book was released on 2006 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The purpose of this study was to develop new catalytic methods to mediate carbon-carbon bond forming reactions with imines under mild conditions and in a general manner. We found that copper catalysts were compatible in cross-coupling of a range of mild organometallic reagents, providing simple, efficient routes to alpha-substituted amides and amines." --

Atypical Elements in Drug Design

Author : Jacob Schwarz
Publisher : Springer
ISBN 13 : 3319277421
Total Pages : 162 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Atypical Elements in Drug Design by : Jacob Schwarz

Download or read book Atypical Elements in Drug Design written by Jacob Schwarz and published by Springer. This book was released on 2016-04-29 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: Medicinal chemistry is both science and art. The science of medicinal chemistry offers mankind one of its best hopes for improving the quality of life. The art of medicinal chemistry continues to challenge its practitioners with the need for both intuition and experience to discover new drugs. Hence sharing the experience of drug research is uniquely beneficial to the field of medicinal chemistry. Drug research requires interdisciplinary team-work at the interface between chemistry, biology and medicine. Therefore, the topic-related series Topics in Medicinal Chemistry covers all relevant aspects of drug research, e.g. pathobiochemistry of diseases, identification and validation of (emerging) drug targets, structural biology, drugability of targets, drug design approaches, chemogenomics, synthetic chemistry including combinatorial methods, bioorganic chemistry, natural compounds, high-throughput screening, pharmacological in vitro and in vivo investigations, drug-receptor interactions on the molecular level, structure-activity relationships, drug absorption, distribution, metabolism, elimination, toxicology and pharmacogenomics. In general, special volumes are edited by well known guest editors.

C-C Cross Couplings with 3d Base Metal Catalysts

Author : Xiao-Feng Wu
Publisher : Springer Nature
ISBN 13 : 3031328671
Total Pages : 403 pages
Book Rating : 4.0/5 (313 download)

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Book Synopsis C-C Cross Couplings with 3d Base Metal Catalysts by : Xiao-Feng Wu

Download or read book C-C Cross Couplings with 3d Base Metal Catalysts written by Xiao-Feng Wu and published by Springer Nature. This book was released on 2023-06-13 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents recent progress on 3d base metal catalyzed C-C cross coupling reactions. The contributions provide detailed discussions on the use of cheap metal catalysts such as Cr, Mn, Fe, Co, Ni, Cu, and Zn to construct Csp2-Csp2, Csp2-Csp3 and Csp3-Csp3 bonds with a variety of substrates. These non-noble metal catalyst have many advantages such as being inexpensive, having low toxicity and are environmentally benign. Therefore the use of cheap metal catalysts in organic synthesis has gained much attention in efforts to develop more sustainable synthetic green chemistry. Each chapter is written by international experts in the field and is a great resource for students, researchers and chemists working in industry to gain an overview on the latest developments.

Copper- and Nickel-catalyzed Cross-coupling Reactions

Author : A. Sofia E. Karlström
Publisher :
ISBN 13 : 9789172651104
Total Pages : 64 pages
Book Rating : 4.6/5 (511 download)

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Book Synopsis Copper- and Nickel-catalyzed Cross-coupling Reactions by : A. Sofia E. Karlström

Download or read book Copper- and Nickel-catalyzed Cross-coupling Reactions written by A. Sofia E. Karlström and published by . This book was released on 2000 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Copper-Mediated Cross-Coupling Reactions

Author : Gwilherm Evano
Publisher : John Wiley & Sons
ISBN 13 : 1118060458
Total Pages : 851 pages
Book Rating : 4.1/5 (18 download)

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Book Synopsis Copper-Mediated Cross-Coupling Reactions by : Gwilherm Evano

Download or read book Copper-Mediated Cross-Coupling Reactions written by Gwilherm Evano and published by John Wiley & Sons. This book was released on 2013-11-11 with total page 851 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing comprehensive insight into the use of copper in cross-coupling reactions, Copper-Mediated Cross-Coupling Reactions provides a complete up-to-date collection of the available reactions and catalytic systems for the formation of carbon-heteroatom and carbon-carbon bonds. This essential reference covers a broad scope of copper-mediated reactions, their variations, key advances, improvements, and an array of academic and industrial applications that have revolutionized the field of organic synthesis. The text also discusses the mechanism of these transformations, the use of copper as cost-efficient alternative to palladium, as well as recently developed methods for conducting copper-mediated reactions with supported catalysts.

Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis

Author : Koji Kubota
Publisher : Springer
ISBN 13 : 9811049351
Total Pages : 222 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis by : Koji Kubota

Download or read book Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis written by Koji Kubota and published by Springer. This book was released on 2017-06-27 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes state-of-the-art borylation chemistry using copper(I) catalysis. Enantioselective reactions are included to afford a variety of functionalized, complex organoboronate esters, which will find wide application in asymmetric synthesis, drug discovery, and material science. Organoboron compounds are recognized as useful reagents in organic synthesis; therefore, great effort has been devoted to the development of a simple, mild, and efficient method for their preparation in the past several years. However, the synthesis of functionalized organoboron compounds remains a challenging issue because known reactions often require the use of highly reactive organometallic carbon nucleophiles. This book focuses on conceptually new, formal nucleophilic copper(I)-catalyzed borylation reactions with diboron compounds that show high selectivity and excellent functional group compatibility. Theoretical studies based on density functional theory calculations to understand the reaction mechanisms have also been described. Advances in this novel borylation chemistry will allow the rapid and efficient synthesis of complex molecules with potentially interesting properties in combination with the boron functionalization process.