Continuous Manufacturing of Direct Methanol Fuel Cell Membrane Electrode Assemblies

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ISBN 13 :
Total Pages : 452 pages
Book Rating : 4.:/5 (769 download)

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Book Synopsis Continuous Manufacturing of Direct Methanol Fuel Cell Membrane Electrode Assemblies by : Babar Masood Koraishy

Download or read book Continuous Manufacturing of Direct Methanol Fuel Cell Membrane Electrode Assemblies written by Babar Masood Koraishy and published by . This book was released on 2010 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Methanol Fuel Cells (DMFC) provide an exciting alternative to current energy storage technologies for powering small portable electronic devices. For applications with sufficiently long durations of continuous operation, DMFC's offer higher energy density, the ability to be refueled instead of recharged, and easier fuel handling and storage than devices that operate with hydrogen. At present, materials and manufacturing challenges impede performance and have prevented the entry of these devices to the marketplace. Higher-performing, cost-effective materials and efficient manufacturing processes are needed to enable the commercialization of DMFC. In a DMFC, the methanol-rich fuel stream and the oxidant are isolated from one another by a proton-conducting and electrically insulating membrane. Catalysts in the electrodes on either side of the Membrane Electrode Assembly (MEA) promote the two simultaneous half-reactions which allow the chemical energy carried in the fuel and oxidant to be converted directly into electricity. The goal of this research effort is to develop a continuous manufacturing process for the fabrication of effective DMFC MEAs. Based on the geometry of the electrode and materials used in the MEA, we propose a roll-to-roll process in which electrodes are coated onto a suitable substrate and subsequently assembled to form a MEA. Appropriate coating methods for electrode fabrication were identified by evaluating the requirements of continuous manufacturing processes; an appropriate set of these processes was then reduced to practice on a custom-designed flexible test bed designed explicitly for this project. After establishing baseline capabilities for several candidate methods, a spraying process was selected and a continuous manufacturing process concept was proposed. Finally, key control parameters of the spraying process were identified and their influence tested on actual MEAs to define optimal operating conditions.

Direct Methanol Fuel Cells

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ISBN 13 : 9781608768653
Total Pages : 0 pages
Book Rating : 4.7/5 (686 download)

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Book Synopsis Direct Methanol Fuel Cells by : Antonio Salvatore Aricò

Download or read book Direct Methanol Fuel Cells written by Antonio Salvatore Aricò and published by . This book was released on 2010 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with an analysis of materials issues, status of technologies and potential applications of direct methanol fuel cells. The principle of operation of direct methanol fuel cells and the status of knowledge in the basic research areas are presented. The technology of direct methanol fuel cells is discussed in this book with particular regard to fabrication methodologies for the manufacturing of catalysts, electrolytes membrane-electrode assemblies, stack hardware and system design.

Direct Methanol Fuel Cell Technology

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Publisher : Elsevier
ISBN 13 : 0128191597
Total Pages : 565 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Direct Methanol Fuel Cell Technology by : Kingshuk Dutta

Download or read book Direct Methanol Fuel Cell Technology written by Kingshuk Dutta and published by Elsevier. This book was released on 2020-02-25 with total page 565 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Methanol Fuel Cell Technology presents the overall progress witnessed in the field of DMFC over the past decade, highlighting the components, materials, functions, properties and features, designs and configurations, operations, modelling, applications, pros and cons, social, political and market penetration, economics and future directions. The book discusses every single aspect of DMFC device technology, the associated advantages and drawbacks of state-of-the-art materials and design, market opportunities and commercialization aspects, and possible future directions of research and development. This book, containing critical analyses and opinions from experts around the world, will garner considerable interest among actual users/scientists/experts. - Analyzes developments of membrane electrolytes, electrodes, catalysts, catalyst supports, bipolar plates, gas diffusion layers and flow channels as critical components of direct methanol fuel cells - Includes modeling of direct methanol fuel cells to understand their scaling up potentials - Discusses commercial aspects of direct methanol fuel cells in terms of market penetration, end application, cost, viability, reliability, social and commercial perception, drawbacks and prospects

Membrane Electrode Assembly (MEA) Design for Power Density Enhancement of Direct Methanol Fuel Cells (DMFCs)

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (713 download)

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Book Synopsis Membrane Electrode Assembly (MEA) Design for Power Density Enhancement of Direct Methanol Fuel Cells (DMFCs) by : Laam Angela Tse

Download or read book Membrane Electrode Assembly (MEA) Design for Power Density Enhancement of Direct Methanol Fuel Cells (DMFCs) written by Laam Angela Tse and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Micro-direct methanol fuel cells (micro-DMFC) can be the power supply solution for the next generation of handheld devices. The applications of the micro-DMFCs require them to have high compactness, high performance, light weight, and long life. The major goal of this research project is to enhance the volumetric power density of direct methanol fuel cells (DMFCs). A performance roadmap has been formulated and showed that patterning the planar membrane electrode assembly (MEA) to 2-D and 3-D corrugated manifolds can greatly increase the power generation with very modest overall volume increases. In this project, different manufacturing processes for patterning MEAs with corrugations have been investigated. A folding process was selected to form 2D triangular corrugations on MEAs for experimental validations of the performance prediction. The experimental results show that the volumetric power densities of the corrugated MEAs have improved by about 25% compared to the planar MEAs, which is lower than the expected performance enhancement. ABAQUS software was used to simulate the manufacturing process and identify the causes of deformations during manufacture. Experimental analysis methods like impedance analysis and 4 point-probes were used to quantify the performance loss and microstructure alteration during the forming process. A model was proposed to relate the expected performance of corrugated MEAs to manufacturing process variables. Finally, different stacking configurations and issues related to cell stacking for corrugated MEAs are also investigated.

Influence of Membrane-electrode Interface on Long-term Performance of Direct Methanol Fuel Cells

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ISBN 13 :
Total Pages : 5 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Influence of Membrane-electrode Interface on Long-term Performance of Direct Methanol Fuel Cells by :

Download or read book Influence of Membrane-electrode Interface on Long-term Performance of Direct Methanol Fuel Cells written by and published by . This book was released on 2004 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Long-term stability of direct methanol fuel cells (DMFCs) is one of the most critical requirements for the successful launch of this technology to commercial market. When a DMFC is operated for extended periods of time, performance decreases continuously. The performance decay in continuous operation of DMFCs is caused by several different attributes, such as surface oxidation of platinum at the cathode, loss of catalytic active surface area, interfacial failure between membrane and electrode, changing hydrophobicity of backing layers or ruthenium crossover. Among those attributes, the interfacial incompatibility between membrane and electrode becomes more important when alternative polymer electrolyte membranes (PEM) are used with Nafion-bonded electrode. In earlier work, we demonstrated that the direct methanol fuel cells (DMFCs) using alternative fully aromatic hydrocarbon based PEMs initially outperformed the DMFCs using industrial standard Nafion membranes. Nonetheless, the longer-term performance of the alternative system deteriorated rather faster probably due to the interfacial incompatibility. In this presentation, the effect of interfacial incompatibility of membrane electrode assemblies (MEAs) on long-term DMFC performance is presented in a systematic manner. A series of disulfonated poly(arylene ether) copolymers having different ion exchange capacity and fluorine content was prepared. The effects of chemical structure of the PEMs on interfacial compatibility and long-term performance were investigated and compared with Nation control membraneelectrode assembly.

Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology

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Publisher : Elsevier
ISBN 13 : 0857095471
Total Pages : 437 pages
Book Rating : 4.8/5 (57 download)

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Book Synopsis Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology by : Christoph Hartnig

Download or read book Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology written by Christoph Hartnig and published by Elsevier. This book was released on 2012-03-19 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs) technology are promising forms of low-temperature electrochemical power conversion technologies that operate on hydrogen and methanol respectively. Featuring high electrical efficiency and low operational emissions, they have attracted intense worldwide commercialization research and development efforts. These R&D efforts include a major drive towards improving materials performance, fuel cell operation and durability. In situ characterization is essential to improving performance and extending operational lifetime through providing information necessary to understand how fuel cell materials perform under operational loads.This two volume set reviews the fundamentals, performance, and in situ characterization of PEMFCs and DMFCs. Volume 1 covers the fundamental science and engineering of these low temperature fuel cells, focusing on understanding and improving performance and operation. Part one reviews systems fundamentals, ranging from fuels and fuel processing, to the development of membrane and catalyst materials and technology, and gas diffusion media and flowfields, as well as life cycle aspects and modelling approaches. Part two details performance issues relevant to fuel cell operation and durability, such as catalyst ageing, materials degradation and durability testing, and goes on to review advanced transport simulation approaches, degradation modelling and experimental monitoring techniques.With its international team of expert contributors, Polymer electrolyte membrane and direct methanol fuel cell technology Volumes 1 & 2 is an invaluable reference for low temperature fuel cell designers and manufacturers, as well as materials science and electrochemistry researchers and academics. - Covers the fundamental science and engineering of polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs), focusing on understanding and improving performance and operation - Reviews systems fundamentals, ranging from fuels and fuel processing, to the development of membrane and catalyst materials and technology, and gas diffusion media and flowfields, as well as life cycle aspects and modelling approaches - Details performance issues relevant to fuel cell operation and durability, such as catalyst ageing, materials degradation and durability testing, and reviews advanced transport simulation approaches, degradation modelling and experimental monitoring techniques

Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology

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Publisher : Elsevier
ISBN 13 : 085709548X
Total Pages : 522 pages
Book Rating : 4.8/5 (57 download)

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Book Synopsis Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology by : Christoph Hartnig

Download or read book Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology written by Christoph Hartnig and published by Elsevier. This book was released on 2012-02-20 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs) technology are promising forms of low-temperature electrochemical power conversion technologies that operate on hydrogen and methanol respectively. Featuring high electrical efficiency and low operational emissions, they have attracted intense worldwide commercialization research and development efforts. These R&D efforts include a major drive towards improving materials performance, fuel cell operation and durability. In situ characterization is essential to improving performance and extending operational lifetime through providing information necessary to understand how fuel cell materials perform under operational loads.Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology, Volume 2 details in situ characterization, including experimental and innovative techniques, used to understand fuel cell operational issues and materials performance. Part I reviews enhanced techniques for characterization of catalyst activities and processes, such as X-ray absorption and scattering, advanced microscopy and electrochemical mass spectrometry. Part II reviews characterization techniques for water and fuel management, including neutron radiography and tomography, magnetic resonance imaging and Raman spectroscopy. Finally, Part III focuses on locally resolved characterization methods, from transient techniques and electrochemical microscopy, to laser-optical methods and synchrotron radiography.With its international team of expert contributors, Polymer electrolyte membrane and direct methanol fuel cell technology will be an invaluable reference for low temperature fuel cell designers and manufacturers, as well as materials science and electrochemistry researchers and academics. Polymer electrolyte membrane and direct methanol fuel cell technology is an invaluable reference for low temperature fuel cell designers and manufacturers, as well as materials science and electrochemistry researchers and academics. - Details in situ characterisation of polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs), including the experimental and innovative techniques used to understand fuel cell operational issues and materials performance - Examines enhanced techniques for characterisation of catalyst activities and processes, such as X-ray absorption and scattering, advanced microscopy and electrochemical mass spectrometry - Reviews characterisation techniques for water and fuel management, including neutron radiography and tomography, and comprehensively covers locally resolved characterisation methods, from transient techniques to laser-optical methods

IEF-3 Report 2007

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Publisher : Forschungszentrum Jülich
ISBN 13 : 3893364978
Total Pages : 175 pages
Book Rating : 4.8/5 (933 download)

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Book Synopsis IEF-3 Report 2007 by :

Download or read book IEF-3 Report 2007 written by and published by Forschungszentrum Jülich. This book was released on with total page 175 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advanced Membrane Electrode Assemblies for Fuel and Water Management in Direct Methanol Fuel Cells

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ISBN 13 :
Total Pages : 192 pages
Book Rating : 4.:/5 (688 download)

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Book Synopsis Advanced Membrane Electrode Assemblies for Fuel and Water Management in Direct Methanol Fuel Cells by : Christian E. Shaffer

Download or read book Advanced Membrane Electrode Assemblies for Fuel and Water Management in Direct Methanol Fuel Cells written by Christian E. Shaffer and published by . This book was released on 2010 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Characterisation of Direct Methanol Fuel Cell Membrane Electrode Assembly for Portable Applications

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ISBN 13 :
Total Pages : 1 pages
Book Rating : 4.:/5 (921 download)

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Book Synopsis Characterisation of Direct Methanol Fuel Cell Membrane Electrode Assembly for Portable Applications by :

Download or read book Characterisation of Direct Methanol Fuel Cell Membrane Electrode Assembly for Portable Applications written by and published by . This book was released on with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Optimizing Membrane Electrode Assembly of Direct Methanol Fuel Cells for Portable Power

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (435 download)

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Book Synopsis Optimizing Membrane Electrode Assembly of Direct Methanol Fuel Cells for Portable Power by : Fuqiang Liu

Download or read book Optimizing Membrane Electrode Assembly of Direct Methanol Fuel Cells for Portable Power written by Fuqiang Liu and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Novel Process for Improved Long-term Stability of DMFC Membrane-electrode Assemblies

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ISBN 13 :
Total Pages : 13 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Novel Process for Improved Long-term Stability of DMFC Membrane-electrode Assemblies by :

Download or read book Novel Process for Improved Long-term Stability of DMFC Membrane-electrode Assemblies written by and published by . This book was released on 2004 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, we introduce a new process for fabrication of Nafion(reg. sign)-based membrane-electrode assemblies for direct methanol fuel cell (DMFC). The process relies on modified formulation of catalyst inks and high-temperature treatment of the MEA, both leading to improved long-term performance stability relative to standard MEAs used in DMFC testing at LANL. Unrecoverable performance loss of the novel MEA after 3000-hour life test at a cell voltage of 0.50 V has been estimated to be (almost equal to)10 mV (at 100 mA cm−2). This number compares favorably with the performance loss of standard MEA, measured at (almost equal to) 60 mV under the same conditions. Most of the gains are due to improved prope rties of the Pt-Ru anode. In particular, better stability of the anode helps to reduce loss in the catalyst surface area over time, providing net performance gain of 25-30 mV over the standard anode. Improved anode stability also reflects on long-term performance of the cathode thanks to reduced methanol crossover at long operating times of the cell ((almost equal to) 15 mV gain).

IEF-3 Report 2009

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Publisher : Forschungszentrum Jülich
ISBN 13 : 3893365850
Total Pages : 229 pages
Book Rating : 4.8/5 (933 download)

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Book Synopsis IEF-3 Report 2009 by :

Download or read book IEF-3 Report 2009 written by and published by Forschungszentrum Jülich. This book was released on 2009 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fuel Cell Engineering

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Publisher : Academic Press
ISBN 13 : 0123868750
Total Pages : 481 pages
Book Rating : 4.1/5 (238 download)

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Book Synopsis Fuel Cell Engineering by :

Download or read book Fuel Cell Engineering written by and published by Academic Press. This book was released on 2012-08-14 with total page 481 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fuel cells are attractive electrochemical energy converters featuring potentially very high thermodynamic efficiency factors. The focus of this volume of Advances in Chemical Engineering is on quantitative approaches, particularly based on chemical engineering principles, to analyze, control and optimize the steady state and dynamic behavior of low and high temperature fuel cells (PEMFC, DMFC, SOFC) to be applied in mobile and stationary systems. - Updates and informs the reader on the latest research findings using original reviews - Written by leading industry experts and scholars - Reviews and analyzes developments in the field

Engineering the Membrane Electrode Assembly of Direct Methanol Fuel Cells Using Novel Graphene Architecture

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (19 download)

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Book Synopsis Engineering the Membrane Electrode Assembly of Direct Methanol Fuel Cells Using Novel Graphene Architecture by : Prabhuraj Balakrishnan

Download or read book Engineering the Membrane Electrode Assembly of Direct Methanol Fuel Cells Using Novel Graphene Architecture written by Prabhuraj Balakrishnan and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Direct Methanol Fuel Cells

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ISBN 13 :
Total Pages : 366 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Direct Methanol Fuel Cells by : Electrochemical Society. Energy Technology Division

Download or read book Direct Methanol Fuel Cells written by Electrochemical Society. Energy Technology Division and published by . This book was released on 2001 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Energy Technology, Physical Electrochemistry and Battery Divisions."

Manufacturing processes for solid polymer fuel cell membrane electrode assemblies

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (594 download)

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Book Synopsis Manufacturing processes for solid polymer fuel cell membrane electrode assemblies by : H. G. C. Hamilton

Download or read book Manufacturing processes for solid polymer fuel cell membrane electrode assemblies written by H. G. C. Hamilton and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: