Construction of the Novel Core/interfacial Crosslinked Inorganic/organic Hybrid Micelle Based on Functionalized Polyhedral Oligomeric Silsesquioxane (POSS) Via Thiol-ene "click" Chemistry

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ISBN 13 :
Total Pages : 50 pages
Book Rating : 4.:/5 (913 download)

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Book Synopsis Construction of the Novel Core/interfacial Crosslinked Inorganic/organic Hybrid Micelle Based on Functionalized Polyhedral Oligomeric Silsesquioxane (POSS) Via Thiol-ene "click" Chemistry by : Ziran Chen

Download or read book Construction of the Novel Core/interfacial Crosslinked Inorganic/organic Hybrid Micelle Based on Functionalized Polyhedral Oligomeric Silsesquioxane (POSS) Via Thiol-ene "click" Chemistry written by Ziran Chen and published by . This book was released on 2013 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supramolecular structures formed by the spontaneous self-assembly of block copolymers in selective solvents have been the focus of academic interest over the last decade. The recent development of "living radical polymerization" synthesis methods has expanded the range of functional block polymers and improve the controllability of block length,6−10 which lead spherical polymer micelles and nanoparticles into significant potential in application. However, the spontaneous dissociation of micelles under their critical micelle concentration (CMC) always limits further applications.18,19,22 Later, the emergence of cross-linked micelle solved this problem.21 By cross-linking the core or shell of micelle, it leads to the formation of robust nanoparticles, which prevent the dissociation below CMC.21,22 In this work, to explore new and efficient crosslink strategy, stable spherical inorganic-organic hybrid micelles were prepared by covalent crosslinking of micellar core/interface, via thiol-ene click chemistry. Amphiphilic block copolymer, poly(ethylene oxide)-block-polystyrene with vinyl-funcitonalized polyhedral oligomeric silsesquioxanes (VPOSS) randomly distributed on the PS block (PEO-b-PS/VPOSS), was designed to form the core-crosslinked micelles by self assembly in a mixture of dimethylformamide (DMF) and water with PS/VPOSS as core and PEO as corona. Meanwhile, another polymer, PEO-b-PS with a VPOSS precisely located at the junction point of two blocks was synthesized to form the interfacial crosslinked micelles with VPOSS nanoparticles distributed on the interface between micellar core and shell in DMF/water solution. The stability of the micelles were greatly enhanced by crosslinking of vinyl groups on VPOSS moieties under UV irradiation with pentaerythritol tetrakis(3-mercaptobutylate) as crosslinking agent. The process is fast, efficient, and environmental tolerant. The crosslinked micelles can sustain their spherical morphology in organic solvent. The self assembly and crosslinking process were fully studied by Dynamic Light Scattering (DLS), and Transmission Electron Microscopy (TEM).

Thiol-X Chemistries in Polymer and Materials Science

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Publisher : Royal Society of Chemistry
ISBN 13 : 184973660X
Total Pages : 337 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Thiol-X Chemistries in Polymer and Materials Science by : Andrew B. Lowe

Download or read book Thiol-X Chemistries in Polymer and Materials Science written by Andrew B. Lowe and published by Royal Society of Chemistry. This book was released on 2013 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive resource on thiol-x chemistries for postgraduates, academics and industrial practitioners interested in polymer and materials applications from leading experts in the field.

Polymer/POSS Nanocomposites and Hybrid Materials

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Publisher : Springer
ISBN 13 : 3030023273
Total Pages : 470 pages
Book Rating : 4.0/5 (3 download)

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Book Synopsis Polymer/POSS Nanocomposites and Hybrid Materials by : Susheel Kalia

Download or read book Polymer/POSS Nanocomposites and Hybrid Materials written by Susheel Kalia and published by Springer. This book was released on 2018-11-27 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS’ role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.

Biomimetic and Bioinspired Membranes for New Frontiers in Sustainable Water Treatment Technology

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Publisher : BoD – Books on Demand
ISBN 13 : 9535136615
Total Pages : 236 pages
Book Rating : 4.5/5 (351 download)

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Book Synopsis Biomimetic and Bioinspired Membranes for New Frontiers in Sustainable Water Treatment Technology by : Amira Abdelrasoul

Download or read book Biomimetic and Bioinspired Membranes for New Frontiers in Sustainable Water Treatment Technology written by Amira Abdelrasoul and published by BoD – Books on Demand. This book was released on 2017-12-06 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomimetic and bioinspired membranes are the most promising type of membrane for multiple usage scenarios, including commercial separation applications as well as water and wastewater treatment technologies. In recent years, aquaporin biomimetic membranes (ABMs) for water purification have raised considerable interest. These membranes display uniquely favorable properties and outstanding performances, such as diverse interactions, varied selective transport mechanisms, superior stability, high resistance to membrane fouling, and distinct adaptability. Biomimetic membranes would make a significant contribution to alleviate water stress, environmental threats, and energy consumption.

Introduction to Sol-Gel Processing

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Publisher : Springer Nature
ISBN 13 : 3030381447
Total Pages : 716 pages
Book Rating : 4.0/5 (33 download)

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Book Synopsis Introduction to Sol-Gel Processing by : Alain C. Pierre

Download or read book Introduction to Sol-Gel Processing written by Alain C. Pierre and published by Springer Nature. This book was released on 2020-03-10 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a broad, general introduction to the processing of Sol-Gel technologies. This updated volume serves as a general handbook for researchers and students entering the field. This new edition provides updates in fields that have undergone rapid developments, such as Ceramics, Catalysis, Chromatropgraphy, biomaterials, glass science, and optics. It provides a simple, compact resource that can also be used in graduate-level materials science courses.

Giant Molecules

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Publisher :
ISBN 13 :
Total Pages : 208 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Giant Molecules by : Herman Francis Mark

Download or read book Giant Molecules written by Herman Francis Mark and published by . This book was released on 1970 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Alternating Copolymers

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Publisher : Springer Science & Business Media
ISBN 13 : 1475791399
Total Pages : 292 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Alternating Copolymers by : J.M.G. Cowie

Download or read book Alternating Copolymers written by J.M.G. Cowie and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examination of the early literature attests to the fact that the study of copolymerization was initiated when polymer science was in its infancy. It has continued to grow to a subject of major importance and has been a source of interest to both academic and industrialist alike. The wide spectrum of structures and properties available in the statistical copolymer has made this a fruitful field of exploration, but one particular and more restricted form which has held its own fascination for many is the limiting case of the strictly alternating copolymer. This is formed, in the ideal situation, when two monomers in a reaction mixture add consecutively to create a polymer chain with a regular {ABABAB} structure, irrespective of the monomer feed ratio. When this happens the resulting copolymer will always have the same composition, a feature which can be advantageous but also somewhat restrictive, as the ability to vary the properties is then limited. Within a series entitled Speciality Polymers it seems appropriate then to deal with this subject, particularly as no previous attempt has been made to draw together the various facets of alternating copolymerization into one volume. It also seems timely to present a more unified picture of the subject which will also illustrate the progress made.

Handbook of Fluorous Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527604499
Total Pages : 624 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Handbook of Fluorous Chemistry by : John A. Gladysz

Download or read book Handbook of Fluorous Chemistry written by John A. Gladysz and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edited by the leading experts John Gladysz, Dennis Curran, and István Horváth, this handbook is the first to summarize all the essential aspects of this emerging field of chemistry. Whether the reader is seeking an introduction to the concept of fluorous biphase catalysis, summaries of partition coefficients involving fluorous and organic solvents, or information on the latest fluorous mixture separation techniques, this authoritative compilation of contributions, written by the world's top authors, provides key information needed for successfully working with the diverse and fascinating families of fluorous molecules. The large number of reliable experimental procedures in particular makes this the ideal guide for newcomers wanting to use this elegant method in the laboratory. In addition, experts will also find a wealth of important information concisely contained in one ready reference. The result is an indispensable resource for everyone currently working or intending to work in this field.

Block Copolymers in Solution

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Publisher : John Wiley & Sons
ISBN 13 : 0470016973
Total Pages : 300 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis Block Copolymers in Solution by : Ian W. Hamley

Download or read book Block Copolymers in Solution written by Ian W. Hamley and published by John Wiley & Sons. This book was released on 2005-12-13 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique text discusses the solution self-assembly of block copolymers and covers all aspects from basic physical chemistry to applications in soft nanotechnology. Recent advances have enabled the preparation of new materials with novel self-assembling structures, functionality and responsiveness and there have also been concomitant advances in theory and modelling. The present text covers the principles of self-assembly in both dilute and concentrated solution, for example micellization and mesophase formation, etc., in chapters 2 and 3 respectively. Chapter 4 covers polyelectrolyte block copolymers - these materials are attracting significant attention from researchers and a solid basis for understanding their physical chemistry is emerging, and this is discussed. The next chapter discusses adsorption of block copolymers from solution at liquid and solid interfaces. The concluding chapter presents a discussion of selected applications, focussing on several important new concepts. The book is aimed at researchers in polymer science as well as industrial scientists involved in the polymer and coatings industries. It will also be of interest to scientists working in soft matter self-assembly and self-organizing polymers.

Block Copolymers

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Publisher : John Wiley & Sons
ISBN 13 : 0471461342
Total Pages : 445 pages
Book Rating : 4.4/5 (714 download)

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Book Synopsis Block Copolymers by : Nikos Hadjichristidis

Download or read book Block Copolymers written by Nikos Hadjichristidis and published by John Wiley & Sons. This book was released on 2003-04-28 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers may be classified as either homopolymers, consisting of one single repeating unit, or copolymers, consisting of two or more distinct repeating units. Block copolymers contain long contiguous blocks of two or more repeating units in the same polymer chain. Covering one of the hottest topics in polymer chemistry, Block Copolymers provides a coherent overview of the synthetic routes, physical properties, and applications of block copolymers. This pioneering text provides not only a guideline for developing synthetic strategies for creating block copolymers with defined characteristics, but also a key to the relationship between the physical properties of block copolymers and the structure and dynamics of materials. Covering features of the chemistry and physics of block copolymers that are not found in comparable texts, Block Copolymers illustrates the structure-activity relationship of block copolymers and offers suggestions for the design of specific applications. Divided into five sections-Block Copolymers includes chapters on: * Block Copolymers by Chemical Modification of Precursor Polymers * Nonlinear Block Copolymers * Adsorption of Block Copolymers at Solid-Liquid Interfaces * Theory of Block Copolymer Segregation * Phase Transformation Kinetics * Block Copolymer Morphology * Block Copolymer Dynamics Polymer chemists, physicists, chemical engineers, and materials scientists, as well as graduate students in polymer science, will find Block Copolymers to be an invaluable text.

Polymer Composites with Functionalized Nanoparticles

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Publisher : Woodhead Publishing
ISBN 13 : 0128140658
Total Pages : 513 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Polymer Composites with Functionalized Nanoparticles by : Krzysztof Pielichowski

Download or read book Polymer Composites with Functionalized Nanoparticles written by Krzysztof Pielichowski and published by Woodhead Publishing. This book was released on 2018-09-22 with total page 513 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer Composites with Functional Nanoparticles: Synthesis, Properties, and Applications reviews the latest research in the area of polymer nanocomposites and functionalized nanoparticles, providing an introduction for those new to the field, and supporting further research and development. The book helps researchers and practitioners better understand the key role of nanoparticle functionalization for improving the compatibility of inorganic metallic nanomaterials with organic polymers, and for the fabrication of nanostructured materials with special properties. A range of nanoparticles, such as carbon nanotubes are covered, along with descriptions of the methods of functionalization to support better compatibility with polymer matrices. The book also discusses the various applications of this technology, including uses in electronics and the medical and energy industries. Summarizes the latest research in functionalized nanoparticles for modification of polymer matrices, providing a valuable platform for further research Includes functionalization of a range of nanoparticles for incorporation into nanocomposites, including carbon nanotubes, graphene, gold and silver, silica and clay Provides detailed coverage of application areas, including energy, electronics, biomedical applications, and end-of-life considerations

Applications of Polyhedral Oligomeric Silsesquioxanes

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Publisher : Springer Science & Business Media
ISBN 13 : 904813787X
Total Pages : 440 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Applications of Polyhedral Oligomeric Silsesquioxanes by : Claire Hartmann-Thompson

Download or read book Applications of Polyhedral Oligomeric Silsesquioxanes written by Claire Hartmann-Thompson and published by Springer Science & Business Media. This book was released on 2011-01-03 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: The commercial availability and decreasing cost of polyhedral oligomeric silsesquioxanes in recent years has opened up the field to everybody who wishes to apply these unique properties in their own technologies. This is the first book to provide a comprehensive overview of these applications, and covers the synthesis, characterization and history of polyhedral oligomeric silsesquioxanes, their use as metallasilsesquioxane catalysts, their effect upon polymer properties and plastics performance, and their use in superhydrophobic nanocomposites, and electronics, energy, space and biomedical applications. "Applications of Polyhedral Oligomeric Silsesquioxanes" is a valuable reference for those working across a range of disciplines, including chemists, materials scientists, polymer physicists, plastics engineers, surface scientists, and anybody with a commercial or academic interest in plastics, composite materials, space materials, dental materials, tissue engineering, drug delivery, lithography, fuel cells, batteries, lubricants, or liquid crystal, LED, sensor, photovoltaic or biomedical devices.

Controlled and Living Polymerizations

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Publisher : John Wiley & Sons
ISBN 13 : 9783527324927
Total Pages : 640 pages
Book Rating : 4.3/5 (249 download)

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Book Synopsis Controlled and Living Polymerizations by : Krzysztof Matyjaszewski

Download or read book Controlled and Living Polymerizations written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2009-09-28 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites

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Publisher : Elsevier
ISBN 13 : 0128213582
Total Pages : 578 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites by : Sabu Thomas

Download or read book Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites written by Sabu Thomas and published by Elsevier. This book was released on 2021-03-25 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications

Controlled/living Radical Polymerization

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Publisher :
ISBN 13 :
Total Pages : 506 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Controlled/living Radical Polymerization by : Krzysztof Matyjaszewski

Download or read book Controlled/living Radical Polymerization written by Krzysztof Matyjaszewski and published by . This book was released on 2000 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.

Handbook of Fluoropolymer Science and Technology

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Publisher : John Wiley & Sons
ISBN 13 : 1118850084
Total Pages : 671 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Handbook of Fluoropolymer Science and Technology by : Dennis W. Smith

Download or read book Handbook of Fluoropolymer Science and Technology written by Dennis W. Smith and published by John Wiley & Sons. This book was released on 2014-05-05 with total page 671 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Fluoropolymer Science and Technology A comprehensive handbook on fluoropolymer synthesis, characterization, and processing Fluoropolymers, one of the more durable classes of polymer materials, are known to enable novel technologies as a result of their remarkable properties. As key components in industry applications, fluoropolymers have established commercial interest and scientists have discovered more efficient approaches of handling them. This book reviews up-to-date fluoropolymer platforms as well as recently discovered methods for the preparation of fluorinated materials. It focuses on synthesis, characterization, and processing aspects, providing guidelines for practicing scientists and engineers. In addition, the book covers: Concepts and studies from leading international laboratories, including academia, government, and industrial institutions Emerging technologies and applications in energy, optics, space exploration, fuel cells, microelectronics, gas separation membranes, biomedical instrumentation, and more Current environmental concerns associated with fluoropolymers, relevant regulations, and growth opportunities Overall, the chapters provide coverage of chemical methods and help the reader further understand how fluoropolymer research provides solutions for material challenges. The concepts in this book also inspire professionals to identify new markets and funding sources for fluoropolymer research and development.

Applications of Nanomaterials in Sensors and Diagnostics

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Publisher : Springer Science & Business Media
ISBN 13 : 3642360254
Total Pages : 290 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Applications of Nanomaterials in Sensors and Diagnostics by : Adisorn Tuantranont

Download or read book Applications of Nanomaterials in Sensors and Diagnostics written by Adisorn Tuantranont and published by Springer Science & Business Media. This book was released on 2014-07-08 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent progress in the synthesis of nanomaterials and our fundamental understanding of their properties has led to significant advances in nanomaterial-based gas, chemical and biological sensors. Leading experts around the world highlight the latest findings on a wide range of nanomaterials including nanoparticles, quantum dots, carbon nanotubes, molecularly imprinted nanostructures or plastibodies, nanometals, DNA-based structures, smart nanomaterials, nanoprobes, magnetic nanomaterials, organic molecules like phthalocyanines and porphyrins, and the most amazing novel nanomaterial, called graphene. Various sensing techniques such as nanoscaled electrochemical detection, functional nanomaterial-amplified optical assays, colorimetry, fluorescence and electrochemiluminescence, as well as biomedical diagnosis applications, e.g. for cancer and bone disease, are thoroughly reviewed and explained in detail. This volume will provide an invaluable source of information for scientists working in the field of nanomaterial-based technology as well as for advanced students in analytical chemistry, biochemistry, electrochemistry, material science, micro- and nanotechnology.