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Characterization And Optimization Of Growth And Electronic Structure Of Organic Thin Films For Applications In Organic Electronics
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Book Synopsis Characterization and Optimization of Growth and Electronic Structure of Organic Thin Films for Applications in Organic Electronics by : Daniel Käfer
Download or read book Characterization and Optimization of Growth and Electronic Structure of Organic Thin Films for Applications in Organic Electronics written by Daniel Käfer and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The studies of thermal stability of molecular structures grown on oxide metal crystals by means of temperature programmed desorption (TPD) by : Karol Cieslik
Download or read book The studies of thermal stability of molecular structures grown on oxide metal crystals by means of temperature programmed desorption (TPD) written by Karol Cieslik and published by Karol Cieslik. This book was released on with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic thin film devices’ performance depends on their properties, such as the crystallinity of the active layer and the specific arrangement of molecules in it. The morphology of molecular structures can be studied using imaging techniques (such as atomic force microscopy AFM, scanning tunneling microscopy STM, and scanning electron microscopy SEM),but to gain a more complete understanding of their nature, temperature programmed desorption (TPD) may be used. During a TPD experiment, the temperature of the adsorbate-adsorbent system is increased linearly while simultaneously the number of desorbing molecules is measured. The resulting TPD spectrum may be used to determine the type of structure (monolayer, multilayer) and the desorption energy associated with it. Furthermore, the thermal stability of observed structures, as determined by the temperatures at which desorption occurs, is evident from the TPD spectra. Thus, TPD measurements may lead to a better understanding of the growth and characteristics of molecular structures which may be of use for potential applications in organic electronics. The first aim of this thesis was the assembly and calibration of the TPD system. The optimal parameters of the mass spectrometer (ionizer’s emission current and electron energy) were determined. Moreover, the linear heating of the samples using direct resistive heating was established. The optimal mass-to-charge ratio for para-hexaphenyl (6P) was determined based on the mass spectrum of 6P. The final test of the TPD system was a comparison of the measured TPD spectrum of 6P film grown on mica(001) with the one published in the literature. The second aim was the measurement of spectra of 6P films on ion-beam modified (110) surfaces of TiO2. Two substrates of different topographies (determined by STM) were studied: one with deep ripples (height modulation of 2.6nm) and one with shallow ripples (height modulation of 0.76nm).In the case of the deep-rippled sample, the effect of molecular film coverage, and the desorption from the sample holder on the measured spectra was investigated. In contrast, the shallow-rippled sample was only studied in the context of the effect of desorption from the sample holder on the spectra. The morphology of 1.91nm thin film of 6P on the deep-rippled sample was studied using SEM, while the morphology of a 0.57nm thin 6P film on shallow-rippled TiO2(110) was determined using STM and AFM. Additionally, the desorption of 6P powder from an effusion cell was studied for comparison of the bulk and thin-film desorption parameters. The optimal parameters for the spectrometer’s ionizer were determined to be: emission current of 700μA, electron energy of 37eV, and use of two filaments. The chosen mass-to-charge ratio was 229.35, e.i. 6P with 2+ charge. The TPD spectrum of 1.91nm of 6P on mica(001) contained a multilayer peak at temperature 222℃ which was in agreement with published data. Due to desorption from the sample holder, all spectra in the TPD experiments showed additional peaks and an increase in background intensity. This effect was almost completely eliminated by covering parts of the holder with tantalum sheets during the molecule deposition process. The TPD spectra for 6P grown on both samples contained two peaks: one which began at approximately 180℃ and ended at different temperatures depending on coverage and another which began at 300℃(the complete spectrum for the deep-rippled sample was not measured, but the peak ended at 550℃ for the shallow-ripples sample). The first peak is due to multilayered molecular structures, which, based on morphologies of the samples, can be identified as originating from standing-molecule islands and laying-molecule nanoneedles in the case of deep-rippled, and laying-molecule nanoneedles for shallow-rippled TiO2(110). The second peak is probably due to a monolayer of 6P molecules laying directly on the TiO2 surface (such a layer was observed for the shallow-rippled sample).
Book Synopsis Metal Based Thin Films for Electronics by : Klaus Wetzig
Download or read book Metal Based Thin Films for Electronics written by Klaus Wetzig and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: This up-to-date handbook covers the main topics of preparation, characterization and properties of complex metal-based layer systems. The authors -- an outstanding group of researchers -- discuss advanced methods for structure, chemical and electronic state characterization with reference to the properties of thin functional layers, such as metallization and barrier layers for microelectronics, magnetoresistive layers for GMR and TMR, sensor and resistance layers. As such, the book addresses materials specialists in industry, especially in microelectronics, as well as scientists, and can also be recommended for advanced studies in materials science, analytics, surface and solid state science.
Book Synopsis Growth and Characterization of Novel Thin Films for Microelectronic Applications by : Mahmoud Vahidi
Download or read book Growth and Characterization of Novel Thin Films for Microelectronic Applications written by Mahmoud Vahidi and published by . This book was released on 2013 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: I studied the properties of novel Co2FeAl0.5Si0.5 (CFAS), ZnGeAs2, and FeS2 (pyrite) thin films for microelectronic applications ranging from spintronic to photovoltaic. CFAS is a half metal with theoretical spin polarization of 100%. I investigated its potential as a spin injector, for spintronic applications, by studying the critical steps involved in the injection of spin polarized electron populations from tunnel junctions containing CFAS electrodes. Epitaxial CFAS thin films with L21 structure and saturation magnetizations of over 1200 emu/cm3 were produced by optimization of the sputtering growth conditions. Point contact Andreev reflection measurements show that the spin polarization at the CFAS electrode surface exceeds 70%. Analyses of the electrical properties of tunnel junctions with a superconducting Pb counter-electrode indicate that transport through native Al oxide barriers is mostly from direct tunneling, while that through the native CFAS oxide barriers is not. ZnGeAs2 is a semiconductor comprised of only inexpensive and earth-abundant elements. The electronic structure and defect properties are similar in many ways to GaAs. Thus, in theory, efficient solar cells could be made with ZnGeAs2 if similar quality material to that of GaAs could be produced. To understand the thermochemistry and determine the rate limiting steps of ZnGeAs2 thin-film synthesis, the (a) thermal decomposition rate and (b) elemental composition and deposition rate of films were measured. It is concluded that the ZnGeAs2 thin film synthesis is a metastable process with an activation energy of 1.08±0.05 eV for the kinetically-limited decomposition rate and an evaporation coefficient of ~10-3. The thermochemical analysis presented here can be used to predict optimal conditions of ZnGeAs2 physical vapor deposition and thermal processing. Pyrite (FeS2) is another semiconductor that has tremendous potential for use in photovoltaic applications if high quality materials could be made. Here, I present the layer-by-layer growth of single-phase pyrite thin-films on heated substrates using sequential evaporation of Fe under high-vacuum followed by sulfidation at S pressures between 1 mTorr and 1 Torr. High-resolution transmission electron microscopy reveals high-quality, defect-free pyrite grains were produces by this method. It is demonstrated that epitaxial pyrite layer was produced on natural pyrite substrates with this method.
Download or read book Thin Films written by Fatma Sarf and published by BoD – Books on Demand. This book was released on 2024-01-17 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the growth of nanomaterials as thin films. It covers the recent development of thin films using different techniques, such as electrodeposition. It also discusses the widespread use of electrochemical and magnetic applications. This book brings together multidisciplinary chapters written by leading specialists in the field.
Book Synopsis Inorganic and Organic Thin Films by : Yu Song
Download or read book Inorganic and Organic Thin Films written by Yu Song and published by John Wiley & Sons. This book was released on 2021-04-21 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: Learn more about foundational and advanced topics in polymer thin films and coatings besides species with this powerful two-volume resource The two-volume Inorganic and Organic Thin Films: Fundamentals, Fabrication, and Applications delivers a foundational resource for current researchers and commercial users involved in the design and fabrication of thin films. The book offers newcomers to the field a thorough description of new design theory, fabrication methods, and applications of advanced thin films. Readers will discover the physics and chemistry underlying the manufacture of new thin films and coatings in this leading new resource that promises to become a handbook for future applications of the technology. This one-stop reference brings together all important aspects of inorganic and polymeric thin films and coatings, including construction, assembly, deposition, functionality, patterning, and characterization. Explorations of their applications in industries as diverse as information technology, new energy, biomedical engineering, aerospace, and oceanographic engineering round out this fulsome exploration of one of the most exciting and rapidly developing areas of scientific and industrial research today. Readers will also learn from: A comprehensive introduction to the progress of thin films and coatings as well as fundamentals in functional thin films and coatings An exploration of multi-layered magnetic thin films for electron transport control and signal sensing, including giant magnetoresistance, colossal magnetoresistance, tunneling magnetoresistance, and the quantum anomalous Holzer effect An in time summary of high-quality magneto-optics, nanophotonics, spin waves and spintronics using bismuth-substituted iron garnet thin films as examples A thorough discussion of template-assisted fabrication of nanostructure thin films for ultrasensitive detection of chemicals and biomolecules A treatment of biomass derived functional films and coatings Perfect for materials scientists and inorganic chemists, Inorganic and Organic Thin Films will also earn a place in the libraries of solid state physicists and physical chemists working in private industry, as well as polymer and surface chemists who seek to improve their understanding of thin films and coatings.
Book Synopsis Characterization of Organic Thin Films by : Abraham Ulman
Download or read book Characterization of Organic Thin Films written by Abraham Ulman and published by Butterworth-Heinemann. This book was released on 1995 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: Characterization of Organic Thin Films will help materials scientists, physicists, chemists, and biologists develop a fundamental understanding of structure-properties relationships which in turn makes possible molecular engineering of advanced materials and opens new opportunities in molecular manufacturing.
Book Synopsis Interface Controlled Organic Thin Films by : Horst-Günter Rubahn
Download or read book Interface Controlled Organic Thin Films written by Horst-Günter Rubahn and published by Springer Science & Business Media. This book was released on 2009-06-12 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic semiconductors are a central topic of advanced materials research. The book is aiming at bridging the gap between the development and production of devices and basic research on thin film characterisation using cutting-edge techniques in surface and interface science. Topics involve organic molecular-based sensors; interfaces in organic diodes and transistors; mobility in organic field effect transistors and space charge problems; integration of optoelectronic nanostructures; nonlinear optical properties of organic nanostructures; the wetting layer problem; how to get from functionalized molecules to nanoaggregates; optical, electrical and mechanical properties of organic nanofibers as well; as near field investigations of organic thin films.
Book Synopsis Recent Advances in Thin Films by : Sushil Kumar
Download or read book Recent Advances in Thin Films written by Sushil Kumar and published by Springer Nature. This book was released on 2020-08-27 with total page 721 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume comprises the expert contributions from the invited speakers at the 17th International Conference on Thin Films (ICTF 2017), held at CSIR-NPL, New Delhi, India. Thin film research has become increasingly important over the last few decades owing to the applications in latest technologies and devices. The book focuses on current advances in thin film deposition processes and characterization including thin film measurements. The chapters cover different types of thin films like metal, dielectric, organic and inorganic, and their diverse applications across transistors, resistors, capacitors, memory elements for computers, optical filters and mirrors, sensors, solar cells, LED's, transparent conducting coatings for liquid crystal display, printed circuit board, and automobile headlamp covers. This book can be a useful reference for students, researchers as well as industry professionals by providing an up-to-date knowledge on thin films and coatings.
Book Synopsis Organized Organic Ultrathin Films by : Katsuhiko Ariga
Download or read book Organized Organic Ultrathin Films written by Katsuhiko Ariga and published by John Wiley & Sons. This book was released on 2012-09-24 with total page 329 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handy reference is the first comprehensive book covering both fundamentals and recent developments in the field with an emphasis on nanotechnology. Written by a highly regarded author in the field, the book details state-of-the-art preparation, characterization and applications of thin films of organic molecules and biomaterials fabricated by wet processes and also highlights applications in nanotechnology The categories of films covered include monomolecular films (monolayers) both on a water surface and on a solid plate, Langmuir-Blodgett films (transferred multilayer films on a solid plate from a water surface), layer-by-layer films (adsorbed multilayer films on a solid support), and spontaneously assembled films in solution.
Book Synopsis Ellipsometry of Functional Organic Surfaces and Films by : Karsten Hinrichs
Download or read book Ellipsometry of Functional Organic Surfaces and Films written by Karsten Hinrichs and published by Springer Science & Business Media. This book was released on 2013-10-24 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ellipsometry is the method of choice to determine the properties of surfaces and thin films. It provides comprehensive and sensitive characterization in contactless and non-invasive measurements. This book gives a state-of-the-art survey of ellipsometric investigations of organic films and surfaces, from laboratory to synchrotron applications, with a special focus on in-situ use in processing environments and at solid-liquid interfaces. In conjunction with the development of functional organic, meta- and hybrid materials for new optical, electronic, sensing and biotechnological devices and fabrication advances, the ellipsometric analysis of their optical and material properties has progressed rapidly in the recent years.
Book Synopsis Growth and Characterization of Organic Thin Films by : Tolulope Abodunrin Ogundimu
Download or read book Growth and Characterization of Organic Thin Films written by Tolulope Abodunrin Ogundimu and published by . This book was released on 2007 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt: Copper phthalocyanine and Buckminster fullerene have many applications in electronic devices, thus proper understanding of these materials is essential. In this work, thin films of the pure materials and composites, were vapour deposited on to room temperature substrates to mimic the conditions used in industry. The growth modes of both C60 and CuPc were found to be Volmer-Weber. For the composite films it was found that the clustering texture seen under SEM was suppressed with 5 wt.% C60, and 30 wt.% suppressed the CuPc alpha-phase crystallites. The thermal stability of the composite was found to be improved over that of the pure films up to 140°C. It was concluded that CuPc molecules migrate through the film, but the migration is inhibited by C60 due to the strong intermolecular interactions. The improved thermal stability of the composite is due to the interactions slowing the kinetics of the phase transformations.
Book Synopsis Optical Thin Films and Structures by : Tsvetanka Babeva
Download or read book Optical Thin Films and Structures written by Tsvetanka Babeva and published by MDPI. This book was released on 2021-06-22 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is devoted to the design, application and characterization of thin films and structures, with special emphasis on optical applications. It comprises ten papers—five featured and five regular—authored by scientists all over the world. Diverse materials are studied and their possible applications are demonstrated and discussed—transparent conductive coatings and structures from ZnO doped with Al and Ga and Ti-doped SnO2, polymers and nanosized zeolite thin films for optical sensing, TiO2 with linear and nonlinear optical properties, organic diamagnetic materials, broadband optical coatings, CrWN glass molding coatings, and silicon on insulator waveguides.
Book Synopsis In Situ Characterization of Thin Film Growth by : Gertjan Koster
Download or read book In Situ Characterization of Thin Film Growth written by Gertjan Koster and published by Elsevier. This book was released on 2011-10-05 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced techniques for characterizing thin film growth in situ help to develop improved understanding and faster diagnosis of issues with the process. In situ characterization of thin film growth reviews current and developing techniques for characterizing the growth of thin films, covering an important gap in research. Part one covers electron diffraction techniques for in situ study of thin film growth, including chapters on topics such as reflection high-energy electron diffraction (RHEED) and inelastic scattering techniques. Part two focuses on photoemission techniques, with chapters covering ultraviolet photoemission spectroscopy (UPS), X-ray photoelectron spectroscopy (XPS) and in situ spectroscopic ellipsometry for characterization of thin film growth. Finally, part three discusses alternative in situ characterization techniques. Chapters focus on topics such as ion beam surface characterization, real time in situ surface monitoring of thin film growth, deposition vapour monitoring and the use of surface x-ray diffraction for studying epitaxial film growth. With its distinguished editors and international team of contributors, In situ characterization of thin film growth is a standard reference for materials scientists and engineers in the electronics and photonics industries, as well as all those with an academic research interest in this area. Chapters review electron diffraction techniques, including the methodology for observations and measurements Discusses the principles and applications of photoemission techniques Examines alternative in situ characterisation techniques
Book Synopsis Metal Oxide-Based Thin Film Structures by : Nini Pryds
Download or read book Metal Oxide-Based Thin Film Structures written by Nini Pryds and published by Elsevier. This book was released on 2017-09-07 with total page 562 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide-Based Thin Film Structures: Formation, Characterization and Application of Interface-Based Phenomena bridges the gap between thin film deposition and device development by exploring the synthesis, properties and applications of thin film interfaces. Part I deals with theoretical and experimental aspects of epitaxial growth, the structure and morphology of oxide-metal interfaces deposited with different deposition techniques and new developments in growth methods. Part II concerns analysis techniques for the electrical, optical, magnetic and structural properties of thin film interfaces. In Part III, the emphasis is on ionic and electronic transport at the interfaces of Metal-oxide thin films. Part IV discusses methods for tailoring metal oxide thin film interfaces for specific applications, including microelectronics, communication, optical electronics, catalysis, and energy generation and conservation. This book is an essential resource for anyone seeking to further their knowledge of metal oxide thin films and interfaces, including scientists and engineers working on electronic devices and energy systems and those engaged in research into electronic materials. Introduces the theoretical and experimental aspects of epitaxial growth for the benefit of readers new to the field Explores state-of-the-art analysis techniques and their application to interface properties in order to give a fuller understanding of the relationship between macroscopic properties and atomic-scale manipulation Discusses techniques for tailoring thin film interfaces for specific applications, including information, electronics and energy technologies, making this book essential reading for materials scientists and engineers alike
Book Synopsis Growth and Characterization of Organic/inorganic Thin Films for Photonic Device Applications by : Jon Wai Yu Sit
Download or read book Growth and Characterization of Organic/inorganic Thin Films for Photonic Device Applications written by Jon Wai Yu Sit and published by . This book was released on 2015 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis In Situ Real-time Studies of Organic Semiconductor Thin Film Growth by : Tushar Vrushank Desai
Download or read book In Situ Real-time Studies of Organic Semiconductor Thin Film Growth written by Tushar Vrushank Desai and published by . This book was released on 2012 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis discusses the thin film deposition of small molecule organic semiconductors. Small molecule organics are attracting significant interest primarily due to their ability to form well ordered thin films at low temperatures with reasonable electronic properties. Potential applications of organic based electronics include thin film transistors, display technologies, flexible integrated circuits and photovoltaics. The growth and morphology of these organic thin films is very sensitive to the nature (chemical and physical) of the underlying substrate. A significant challenge in fabricating organic thin film devices with superior electrical characteristics is that of controlling and more importantly understanding the properties at the interface between the organic semiconducting layer and the underlying substrate. In this thesis, the use of supersonic molecular beams as a means to deposit organic semiconductor thin films is discussed in conjunction with in situ real-time synchrotron scattering and ex situ atomic force microscopy as thin film characterization techniques. This thesis discusses the effects of the incident kinetic energy of the small molecule organic and the nature of dielectric (clean silicon dioxide, SiO2; or SiO2 modified with self-assembled monolayers, SAMs, of varying thickness and chemical functionality; or SiO2 modified with polymers of varying surface energy) on the fundamental thin film processes occurring at the organic semiconductor/substrate interface. These thin film processes include adsorption, nucleation and diffusion, and the filling up of individual monolayers during thin film growth. Experiments have provided significant insight into these fundamental thin film processes. The results indicate that the probability of adsorption is a strong function of the incident kinetic energy of the organic molecule and thickness of the underlying SAM. The submonolayer island shape and island density is also a strong function of the underlying substrate with the later implying a change in the diffusivity of the organic with the identity of the substrate. Finally, the results suggest that multilayer thin film morphology such as feature/grain size and the thin film roughness is also a function of the underlying substrate.
