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Catalytic And Asymmetric Organic Oxidations By Chiral Oxorutheniumiv And Cis Dioxorutheniumvi Complexes With Nitrogen Donor Ligands
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Book Synopsis Catalytic and Asymmetric Organic Oxidations by Chiral Oxoruthenium(iv) and Cis- Dioxoruthenium(vi) Complexes with Nitrogen Donor Ligands by : 馮偉康
Download or read book Catalytic and Asymmetric Organic Oxidations by Chiral Oxoruthenium(iv) and Cis- Dioxoruthenium(vi) Complexes with Nitrogen Donor Ligands written by 馮偉康 and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Catalytic and Asymmetric Organic Oxidations by Chiral Oxoruthenium(IV) and Cis- Dioxoruthenium(VI) Complexes with Nitrogen Donor Ligands by : Wai-hong Fung
Download or read book Catalytic and Asymmetric Organic Oxidations by Chiral Oxoruthenium(IV) and Cis- Dioxoruthenium(VI) Complexes with Nitrogen Donor Ligands written by Wai-hong Fung and published by . This book was released on 1998 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Metal-Catalyzed Oxidations of Organic Compounds by : Roger Sheldon
Download or read book Metal-Catalyzed Oxidations of Organic Compounds written by Roger Sheldon and published by Elsevier. This book was released on 2012-12-02 with total page 447 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.
Book Synopsis Asymmetric Organic Oxidation by Chiral Ruthenium Complexes Containing D2 and D4 Symmetric Porphyrinato Ligands by : Rui Zhang
Download or read book Asymmetric Organic Oxidation by Chiral Ruthenium Complexes Containing D2 and D4 Symmetric Porphyrinato Ligands written by Rui Zhang and published by Open Dissertation Press. This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Asymmetric Organic Oxidation by Chiral Ruthenium Complexes Containing D2 and D4 Symmetric Porphyrinato Ligands" by Rui, Zhang, 張瑞, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b4257624 Subjects: Ruthenium compounds - Oxidation Porphyrin and porphyrin compounds Ligands
Book Synopsis Asymmetric Oxidation Reactions by : Tsutomi Katsuki
Download or read book Asymmetric Oxidation Reactions written by Tsutomi Katsuki and published by Oxford University Press on Demand. This book was released on 2001 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: Asymmetric oxidation is a potent method for the stereo-controlled synthesis of functional highly compounds. Asymmetric Oxidation Reactions: A Practical Approach contains protocols for all the major methods of asymmetric oxidation reactions: the C-H bond, epoxidation of olefins, epoxidationusing peroxides, dihydroxylation, aminohydroxyaltion, aziridination, hydroxylation of enolates and enols, Baeyer-Villiger oxidations, oxidations of sulfides, selenides, and other heteroatoms, and oxidation using biocatalysts. Each section is written by experts and as well as the protocols providesthe reader with the features of the individual reactions, optimal reaction conditions, experimental precautions, and sample results. This book is therefore an indispensable laboratory companion to any chemist performing asymmetric oxidations.
Book Synopsis Metal-catalyzed Oxidations of Organic Compounds by : Roger A. Sheldon
Download or read book Metal-catalyzed Oxidations of Organic Compounds written by Roger A. Sheldon and published by . This book was released on 1981 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation-reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds.
Book Synopsis Synthesis and Reactivity of Cyclometallated Complexes Containing Nitrogen Donor Ligands by : Omar Khalid Al-Duaij
Download or read book Synthesis and Reactivity of Cyclometallated Complexes Containing Nitrogen Donor Ligands written by Omar Khalid Al-Duaij and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Asymetric Oxidation Reactions Catalyzed by Chiral Substituted Polymers by : Bo Hao
Download or read book Asymetric Oxidation Reactions Catalyzed by Chiral Substituted Polymers written by Bo Hao and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The discovery of new methodologies to advance the fields of synthetic organic, nanoclusters, and polymer chemistry is critical in the asymmetric synthesis of organic compounds. Particularly, catalytic asymmetric oxidation reactions are economic. The oxidation reactions provide chiral molecules and additional functionality onto the molecules for functional group manipulation. New kinds of polymers, namely chiral-substituted poly-N-vinylpyrrolidinones (CSPVPs), stabilize the bimetallic nanoclusters such as Pd/Au or Cu/Au and induce chirality. These chiral polymers wrap around the nanometer-sized (~3 nm) bimetallic nanoclusters and catalyze a number of enantioselective oxidation reactions using oxygen or hydrogen peroxide as the oxidant. Cycloalkanediols were asymmetrically oxidized by 1 atm of oxygen gas to yield the corresponding hydroxyl ketone under the catalysis of Pd/Au (3:1) - CSPVP nanoclusters. Alkenes were oxidized by Pd/Au (3:1)-CSPVP nanoclusters under 2 atmospheric of oxygen in water to give the syn-dihydroxylated products in high chemical and excellent optical yields. Various cycloalkanes underwent regio- and enantio-selective C-H oxidation with Cu/Au (3:1)-CSPVP and 30% hydrogen peroxide to produce the corresponding chiral oxo-molecules in very good to excellent chemical and optical yields. We further discovered an enantioselective desymmetrization of a,a -dialkenyl-alkanols and a,a -dialkenyl-amino acid ethyl esters to give chiral disubstituted lactones and lactams, respectively. A number of medium-sized natural products and drugs were also oxidized regioselectively to give the corresponding mono-oxygenated products. A broad-spectrum predictive C-H oxidation of complex molecules is possible. Chapter 1 mainly discussed the synthesis and characterization of the new classes of chiral substituted PVP and bimetallic nanoclusters. Chapter 2 focus on various kind of oxidation reactions by the catalysis of CSPVP stabilized bimetallic nanoclusters. Among various bioluminescence assays, firefly luciferase based bioluminescence assays are popular due to their high specific activity, low background noise and ease of use. However, it has been found that some aromatic carboxylic acid substantially inhibited the firefly luciferase reporter enzyme's activity. In order to study firefly luciferase inhibition and the proteins associated with inhibition mechanism, we designed two 6-(dimethylamino)-2-phenylisoindolin-1-one derivatives as probe molecules. The synthesis of one probe molecule is discussed in Chapter 3 and the further investigation of its inhibitory activity on firefly luciferase is being conducted by our collaborate.
Book Synopsis Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations by : B. Meunier
Download or read book Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations written by B. Meunier and published by Springer. This book was released on 2013-10-03 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species involved in catalytic oxidations. The series contains critical reviews of the present position and future trends, and short and concise reports written by the world’s renowned experts.
Book Synopsis Oxidation of Organic Compounds: Gas-phase oxidations, homogeneous and heterogeneous catalysis, applied oxidations and synthetic processes by :
Download or read book Oxidation of Organic Compounds: Gas-phase oxidations, homogeneous and heterogeneous catalysis, applied oxidations and synthetic processes written by and published by . This book was released on 1968 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Catalytic Oxidation in Organic Synthesis by : K. Muñiz
Download or read book Catalytic Oxidation in Organic Synthesis written by K. Muñiz and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Catalytic Oxidation of Organic Compounds in the Vapor Phase by : Leroy Frank Marek
Download or read book The Catalytic Oxidation of Organic Compounds in the Vapor Phase written by Leroy Frank Marek and published by . This book was released on 1932 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt:
