Carbene Chemistry

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Contemporary Carbene Chemistry

Author : Robert A. Moss
Publisher : John Wiley & Sons
ISBN 13 : 1118730267
Total Pages : 506 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Contemporary Carbene Chemistry by : Robert A. Moss

Download or read book Contemporary Carbene Chemistry written by Robert A. Moss and published by John Wiley & Sons. This book was released on 2013-10-17 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents the most innovative results in carbene chemistry, setting the foundation for new discoveries and applications The discovery of stable carbenes has reinvigorated carbene chemistry research, with investigators seeking to develop carbenes into new useful catalysts and ligands. Presenting the most innovative and promising areas of carbene research over the past decade, this book explores newly discovered structural, catalytic, and organometallic aspects of carbene chemistry, with an emphasis on new and emerging synthetic applications. Contemporary Carbene Chemistry features contributions from an international team of pioneering carbene chemistry researchers. Collectively, these authors have highlighted the most interesting and promising areas of investigation in the field. The book is divided into two parts: Part 1, Properties and Reactions of Carbenes, explores new findings on carbene stability, acid-base behavior, and catalysis. Carbenic structure and reactivity are examined in chapters dedicated to stable carbenes, carbodicarbenes, carbenes as guests in supramolecular hosts, tunneling in carbene and oxacarbene reactions, and ultrafast kinetics of carbenes and their excited state precursors. Theoretical concerns are addressed in chapters on computational methods and dynamics applied to carbene reactions. Part 2, Metal Carbenes, is dedicated to the synthetic dimensions of carbenes, particularly the reactions and catalytic properties of metal carbenes. The authors discuss lithium, rhodium, ruthenium, chromium, molybdenum, tungsten, cobalt, and gold. All the chapters conclude with a summary of the current situation, new challenges on the horizon, and promising new research directions. A list of key reviews and suggestions for further reading also accompanies every chapter. Each volume of the Wiley Series on Reactive Intermediates in Chemistry and Biology focuses on a specific reactive intermediate, offering a broad range of perspectives from leading experts that sets the stage for new applications and further discoveries.

Carbene Chemistry

Author : Wolfgang Kirmse
Publisher :
ISBN 13 :
Total Pages : 320 pages
Book Rating : 4.:/5 ( download)

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Book Synopsis Carbene Chemistry by : Wolfgang Kirmse

Download or read book Carbene Chemistry written by Wolfgang Kirmse and published by . This book was released on 1964 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal Carbenes in Organic Synthesis

Author : K H Dtz
Publisher : Springer Science & Business Media
ISBN 13 : 9783540218333
Total Pages : 396 pages
Book Rating : 4.2/5 (183 download)

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Book Synopsis Metal Carbenes in Organic Synthesis by : K H Dtz

Download or read book Metal Carbenes in Organic Synthesis written by K H Dtz and published by Springer Science & Business Media. This book was released on 2004-09-21 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts

The Organometallic Chemistry of N-heterocyclic Carbenes

Author : Han Vinh Huynh
Publisher : John Wiley & Sons
ISBN 13 : 1118698797
Total Pages : 352 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis The Organometallic Chemistry of N-heterocyclic Carbenes by : Han Vinh Huynh

Download or read book The Organometallic Chemistry of N-heterocyclic Carbenes written by Han Vinh Huynh and published by John Wiley & Sons. This book was released on 2017-02-03 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organometallic Chemistry of N-heterocyclic Carbenes describes various aspects of N-heterocyclic Carbenes (NHCs) and their transition metal complexes at an entry level suitable for advanced undergraduate students and above. The book starts with a historical overview on the quest for carbenes and their complexes. Subsequently, unique properties, reactivities and nomenclature of the four classical NHCs derived from imidazoline, imidazole, benzimidazole and 1,2,4-triazole are elaborated. General and historically relevant synthetic aspects for NHCs, their precursors and complexes are then explained. The book continues with coverage on the preparation and characteristics of selected NHC complexes containing the most common metals in this area, i.e. Ni, Pd, Pt, Ag, Cu, Au, Ru, Rh and Ir. The book concludes with an overview and outlook on the development of various non-classical NHCs beyond the four classical types. Topics covered include: Stabilization, dimerization and decomposition of NHCs Stereoelectronic properties of NHCs and their evaluation Diversity of NHCs Isomers of NHC complexes and their identification NMR spectroscopic signatures of NHC complexes normal, abnormal and mesoionic NHCs The Organometallic Chemistry of N-heterocyclic Carbenes is an essential resource for all students and researchers interested in this increasingly important and popular field of research.

Transition Metal-Catalyzed Carbene Transformations

Author : Jianbo Wang
Publisher : John Wiley & Sons
ISBN 13 : 3527347992
Total Pages : 450 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Transition Metal-Catalyzed Carbene Transformations by : Jianbo Wang

Download or read book Transition Metal-Catalyzed Carbene Transformations written by Jianbo Wang and published by John Wiley & Sons. This book was released on 2022-05-16 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.

Carbene Chemistry

Author : Wolfgang Kirmse
Publisher : Elsevier
ISBN 13 : 0323162487
Total Pages : 310 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Carbene Chemistry by : Wolfgang Kirmse

Download or read book Carbene Chemistry written by Wolfgang Kirmse and published by Elsevier. This book was released on 2012-12-02 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, Volume 1: Carbene Chemistry is a 12-chapter text that covers pertinent research studies on the carbene chemistry. The first ten chapters are devoted to comprehensive surveys of carbene chemistry. Each chapter tackles specific carbene compound, such as olefinic and acetylenic carbenes, aryl and diarylcarbenes, carboalkoxycarbenes, ketocarbenes, halocarbenes, heteroatom-containing carbenes, and dicarbenes. The formation, synthesis, and reactions of these compounds are discussed. The remaining two chapters the excess energy in reactions and spin states of carbenes. This book will be of value to organic chemists, organic chemistry researchers, teachers, and students.

Advances in Carbene Chemistry

Author : U.H. Brinker
Publisher : Elsevier
ISBN 13 : 9780080549613
Total Pages : 332 pages
Book Rating : 4.5/5 (496 download)

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Book Synopsis Advances in Carbene Chemistry by : U.H. Brinker

Download or read book Advances in Carbene Chemistry written by U.H. Brinker and published by Elsevier. This book was released on 2001-10-24 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our understanding of carbene chemistry has advanced dramatically, especially in the last decade, and new developments continue to emerge. Some of the recent exciting findings have been collected in the first and second volumes of Advances in Carbene Chemistry. With the third volume, the series continues to provide a periodic coverage of carbene chemistry in its broadest sense. Beginning as chemical curiosities, carbenes are now solidly established as reactive intermediates with fascinating and productive research areas of their own. Five decades of divalent carbon chemistry have provided us with a vast repertoire of new, unusual, and surprising reactions. Some of those reactions, once classified as exotic, have become standard methods in organic synthesis. These highly reactive carbene species have been harnessed and put to work to achieve difficult synthetic tasks other reactive intermediates cannot easily perform. The fruitful relationship between experiment and theory has pushed carbene chemistry further toward the direction of reaction control; that is, regio- and stereoselectivity in intra- and intermolecular addition and insertion reactions. The interplay between experiment and modern spectroscopy has led to the characterization of many carbenes that are crucial to both an understanding and further development of this field.

N-Heterocyclic Carbenes in Transition Metal Catalysis

Author : Frank Glorius
Publisher : Springer
ISBN 13 : 3540369309
Total Pages : 232 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis N-Heterocyclic Carbenes in Transition Metal Catalysis by : Frank Glorius

Download or read book N-Heterocyclic Carbenes in Transition Metal Catalysis written by Frank Glorius and published by Springer. This book was released on 2007-02-05 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.

Carbene Chemistry

Author : Guy Bertrand
Publisher : CRC Press
ISBN 13 : 0824743210
Total Pages : 278 pages
Book Rating : 4.8/5 (247 download)

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Book Synopsis Carbene Chemistry by : Guy Bertrand

Download or read book Carbene Chemistry written by Guy Bertrand and published by CRC Press. This book was released on 2002-05-14 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: Highlights recent discoveries in the development of rapid kinetic techniques that allow for direct visualization and state-of-the-art computational methods.

N-Heterocyclic Carbenes in Synthesis

Author : Steven P. Nolan
Publisher : John Wiley & Sons
ISBN 13 : 9783527314003
Total Pages : 330 pages
Book Rating : 4.3/5 (14 download)

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Book Synopsis N-Heterocyclic Carbenes in Synthesis by : Steven P. Nolan

Download or read book N-Heterocyclic Carbenes in Synthesis written by Steven P. Nolan and published by John Wiley & Sons. This book was released on 2006-10-27 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first handbook to focus solely on the application of N-heterocyclic carbenes in synthesis covers metathesis, organocatalysis, oxidation and asymmetric reactions, along with experimental procedures. Written by leading international experts this is a valuable and practical source for every organic chemist.

Carbene Chemistry

Author : Guy Bertrand
Publisher : CRC Press
ISBN 13 : 9780203910924
Total Pages : 322 pages
Book Rating : 4.9/5 (19 download)

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Book Synopsis Carbene Chemistry by : Guy Bertrand

Download or read book Carbene Chemistry written by Guy Bertrand and published by CRC Press. This book was released on 2002-05-14 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Highlights recent discoveries in the development of rapid kinetic techniques that allow for direct visualization and state-of-the-art computational methods.

N-Heterocyclic Carbenes

Author : Silvia Diez-Gonzalez
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626816
Total Pages : 636 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis N-Heterocyclic Carbenes by : Silvia Diez-Gonzalez

Download or read book N-Heterocyclic Carbenes written by Silvia Diez-Gonzalez and published by Royal Society of Chemistry. This book was released on 2016-11-04 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

N-Heterocyclic Carbenes in Organocatalysis

Author : Akkattu T. Biju
Publisher : John Wiley & Sons
ISBN 13 : 3527809058
Total Pages : 407 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis N-Heterocyclic Carbenes in Organocatalysis by : Akkattu T. Biju

Download or read book N-Heterocyclic Carbenes in Organocatalysis written by Akkattu T. Biju and published by John Wiley & Sons. This book was released on 2019-01-07 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Summarizing the emerging field of N-heterocyclic carbenes used in organocatalysis, this is an excellent overview of the synthesis and applications of NHCs focusing on carbon-carbon and carbon-heteroatom bond formation. Alongside comprehensive coverage of the synthesis, characteristics and applications, this handbook and ready reference also includes chapters on NHCs for polymerization reactions and natural product synthesis.

Carbene Chemistry

Author : Wolfgang Kirmse
Publisher : Elsevier
ISBN 13 : 0323161456
Total Pages : 634 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Carbene Chemistry by : Wolfgang Kirmse

Download or read book Carbene Chemistry written by Wolfgang Kirmse and published by Elsevier. This book was released on 2013-07-10 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbene Chemistry, Second Edition discusses the developments in various areas of carbene chemistry, including the correlation of spectroscopic studies of isolated carbenes with quantum chemical calculations; new carbene precursors; differentiation of carbenes and carbenoids; and mechanisms of single and triplet carbine reactions. This book is composed of two main parts encompassing 13 chapters. The first part covers the many reactions known to transfer a formally divalent carbon fragment from one molecule to another, with special emphasis on the mechanism and a critical evaluation of the evidence for carbene intermediates. The second part examines the multitude of product-forming reactions of carbenes and carbenoids with various substrates. This part also describes the structure-reactivity relationships for both carbenes and their substrates, followed by a discussion of the applications of carbene compounds in synthetic organic chemistry. This work will be of great value to organic chemists and researchers.

Advances in Metal Carbene Chemistry

Author : U. Schubert
Publisher : Springer Science & Business Media
ISBN 13 : 9400923171
Total Pages : 405 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Advances in Metal Carbene Chemistry by : U. Schubert

Download or read book Advances in Metal Carbene Chemistry written by U. Schubert and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 405 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are only few topics in organometallic chemistry, which have stimulated research activities in as many areas, as transition-metal carbene (alkylidene) complexes. About 25 years after the first planned synthesis of a carbene complex in E.O. Fischer's laboratory in Munich the NATO Advanced Research Workshop on Transition-Metal Carbene Complexes was the first meeting which,brought together scientists from different disciplines to discuss inorganic, organic, theoretical structural catalysis-related aspects of metal carbene chemistry. The 70th birthday of Professor E.O. Fischer was a good occasion for this enterprise. The organizers of the meeting (K.D. Dotz, Marburg; F.R. KreiBl, Munchen; U. Schubert, Wurzburg) were encouraged by the fact that most of the leading scientists in this area were able to participate in the workshop. The very high standard of the contributions is reflected in this book, which contains papers from the majority of the participants. The Proceedings show the state of the art in metal carbene chemistry and will hopefully be a landmark in the development of this area of chemistry. Generous financial support for the workshop and for the preparation of this book was provided by the Scientific Affairs Division of NATO and some companies. The organizers also acknowledge the efforts of the staff of the Bildungs zentrum der Hans-Seidel-Stiftung in Wild bad Kreuth for creating a pleasant and stimulating atmosphere during the conference.

N-Heterocyclic Carbenes

Author : Steven P. Nolan
Publisher : John Wiley & Sons
ISBN 13 : 3527671242
Total Pages : 568 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis N-Heterocyclic Carbenes by : Steven P. Nolan

Download or read book N-Heterocyclic Carbenes written by Steven P. Nolan and published by John Wiley & Sons. This book was released on 2014-07-07 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive reference and handbook covers in depth all major aspects of the use of N-heterocyclic carbene-complexes in organic synthesis: from the theoretical background to characterization, and from cross-coupling reactions to olefin metathesis. Edited by a leader and experienced scientist in the field of homogeneous catalysis and use of NHCs, this is an essential tool for every academic and industrial synthetic chemist.

Advances in Carbene Chemistry

Author : U.H. Brinker
Publisher : Elsevier
ISBN 13 : 9780080545912
Total Pages : 313 pages
Book Rating : 4.5/5 (459 download)

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Book Synopsis Advances in Carbene Chemistry by : U.H. Brinker

Download or read book Advances in Carbene Chemistry written by U.H. Brinker and published by Elsevier. This book was released on 1998-07-02 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: Beginning as chemical curiosities, carbenes are now solidly established as reactive intermediates with fascinating and productive research areas of their own. Five decades of divalent carbon chemistry have provided us with a vast repertoire of new, unusual and surprising reactions. Some of those reactions, once classified as exotic, have become standard methods in organic synthesis. These highly reactive carbene species have been harnessed and put to work to achieve difficult synthetic tasks that other reactive intermediates cannot easily perform. The fruitful relationship between experiment and theory has pushed carbene chemistry further toward the direction of reaction control; that is, regio- and stereoselectivity in intra- and intermolecular addition and insertion reactions. The interplay between experiment and modern spectroscopy has led to the characterisation of many carbenes that are crucial to both an understanding and a further development of this field. Understanding of carbene chemistry has advanced dramatically, especially in the last decade, and new developments continue to emerge. Some of the recent exciting findings have been collected in the first volume of Advances in Carbene Chemistry. With this second volume, the series will continue to provide a periodic coverage of carbene chemistry in its broadest sense - leading into the next century.