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Application Of Fluctuation Solution Theory To Strong Electrolyte Solutions
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Book Synopsis Application of Fluctuation Solution Theory to Strong Electrolyte Solutions by : Heriberto Cabezas
Download or read book Application of Fluctuation Solution Theory to Strong Electrolyte Solutions written by Heriberto Cabezas and published by . This book was released on 1985 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluctuation solution theory relates derivatives of the thermodynamic properties to spatial integrals of the direct correlation functions. This formalism has been used as the basis for a model of aqueous strong electrolyte solutions which gives both volumetric properties and activities. The main thrust of the work has been the construction of a microscopic model for the direct correlation functions. This model contains the correlations due to the hard core repulsion, long range field interactions, and short range forces. The hard core correlations are modeled with a hard sphere expression derived from the Percus-Yevick theory. The long range field correlations are accounted for by using asymptotic potentials of mean force and the hypernetted chain equation. The short range correlations which include hydration and hydrogen bonding are modeled with a density expansion of the direct correlation function. The model requires six parameters for each ion and two for water. The ionic parameters are valid for all solution and those for water are universal. The model has been used to calculate derivative properties for six 1:1 electrolytes in water at 25c, 1 ATM, the calculated properties have been compared to experimentally determined values in order to confirm the adequacy of the model.
Book Synopsis Fluctuation Solution Theory for Strong Electrolyte Solutions by : Yeqiong Hu
Download or read book Fluctuation Solution Theory for Strong Electrolyte Solutions written by Yeqiong Hu and published by . This book was released on 1997 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Fluctuation Theory of Solutions by : Paul E. Smith
Download or read book Fluctuation Theory of Solutions written by Paul E. Smith and published by CRC Press. This book was released on 2016-04-19 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are essentially two theories of solutions that can be considered exact: the McMillan-Mayer theory and Fluctuation Solution Theory (FST). The first is mostly limited to solutes at low concentrations, while FST has no such issue. It is an exact theory that can be applied to any stable solution regardless of the number of components and their co
Book Synopsis Handbook of Aqueous Electrolyte Thermodynamics by : Joseph F. Zemaitis, Jr.
Download or read book Handbook of Aqueous Electrolyte Thermodynamics written by Joseph F. Zemaitis, Jr. and published by John Wiley & Sons. This book was released on 1986-06-15 with total page 883 pages. Available in PDF, EPUB and Kindle. Book excerpt: Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.
Book Synopsis Molecular Thermodynamics Of Electrolyte Solutions (Second Edition) by : Lloyd L Lee
Download or read book Molecular Thermodynamics Of Electrolyte Solutions (Second Edition) written by Lloyd L Lee and published by World Scientific. This book was released on 2021-01-07 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications — natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.
Book Synopsis Activity Coefficients in Electrolyte Solutions by : Kenneth S. Pitzer
Download or read book Activity Coefficients in Electrolyte Solutions written by Kenneth S. Pitzer and published by CRC Press. This book was released on 2018-05-04 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book was first published in 1991. It considers the concepts and theories relating to mostly aqueous systems of activity coefficients.
Book Synopsis The Viscosity of Strong Electrolyte Solutions According to Electrostatis Theory by : Hans Falkenhagen
Download or read book The Viscosity of Strong Electrolyte Solutions According to Electrostatis Theory written by Hans Falkenhagen and published by . This book was released on 1932 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Equilibrium Properties of Aqueous Solutions of Single Strong Electrolytes by : Edward Armand Guggenheim
Download or read book Equilibrium Properties of Aqueous Solutions of Single Strong Electrolytes written by Edward Armand Guggenheim and published by Pergamon. This book was released on 1969 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Hydrodynamic Fluctuations in Fluids and Fluid Mixtures by : Jose M. Ortiz de Zarate
Download or read book Hydrodynamic Fluctuations in Fluids and Fluid Mixtures written by Jose M. Ortiz de Zarate and published by Elsevier. This book was released on 2006-04-19 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with density, temperature, velocity and concentration fluctuations in fluids and fluid mixtures. The book first reviews thermal fluctuations in equilibrium fluids on the basis of fluctuating hydrodynamics. It then shows how the method of fluctuating hydrodynamics can be extended to deal with hydrodynamic fluctuations when the system is in a stationary nonequilibrium state. In contrast to equilibrium fluids where the fluctuations are generally short ranged unless the system is close to a critical point, fluctuations in nonequilibrium fluids are always long-ranged encompassing the entire system. The book provides the first comprehensive treatment of fluctuations in fluids and fluid mixtures brought out of equilibrium by the imposition of a temperature and concentration gradient but that are still in a macroscopically quiescent state. By incorporating appropriate boundary conditions in the case of fluid layers, it is shown how fluctuating hydrodynamics affects the fluctuations close to the onset of convection. Experimental techniques of light scattering and shadowgraphy for measuring nonequilibrium fluctuations are elucidated and the experimental results thus far reported in the literature are reviewed. · Systematic exposition of fluctuating hydrodynamics and its applications· First book on nonequilibrium fluctuations in fluids· Fluctuating Boussinesq equations and nonequilibrium fluids· Fluid layers and onset of convection· Rayleigh scattering and Brillouin scattering in fluids· Shadowgraph technique for measuring fluctuations· Fluctuations near hydrodynamic instabilities
Book Synopsis From Crystal to Solution by : Gennadiĭ Alekseevich Krestov
Download or read book From Crystal to Solution written by Gennadiĭ Alekseevich Krestov and published by . This book was released on 1980 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: A look at past, present and future; Structure of liquid: properties of liquids; liquid water; non-aqueous and mixed solvents; Electrolytes in solution: ions as special particles; ions in solution; electrolytic dissociation; electrolytic activity and ionization of medium; association of ions in solutions; Solvation of ions; definition of solvation and its types; donor-acceptor interaction; connection with structure; quantitative characteristics; Properties of electrolyte solutions: chemical properties; structure of solutions; quantitative characteristics of structural changes in solvents; comparison of aqueous and non-aqueous solutions of electrolytes; Methods of studying electrolyte solutions; Theories of electrolyte solutions; Instead of conclusion.
Book Synopsis American Doctoral Dissertations by :
Download or read book American Doctoral Dissertations written by and published by . This book was released on 1997 with total page 806 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Cell Theory of Strong Electrolyte Solutions by : Frank Warren Smith
Download or read book Cell Theory of Strong Electrolyte Solutions written by Frank Warren Smith and published by . This book was released on 1963 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Dissertation Abstracts International by :
Download or read book Dissertation Abstracts International written by and published by . This book was released on 1998 with total page 862 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Fundamentals of Inhomogeneous Fluids by : Douglas Henderson
Download or read book Fundamentals of Inhomogeneous Fluids written by Douglas Henderson and published by CRC Press. This book was released on 2021-12-17 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: A monograph examining recent progress in the field of inhomogeneous fluids, focusing on the theoretical - as well as experimental - techniques used. It presents the comprehensive theory of first-order phase transitions, including melting, and contains numerous figures, tables and display equations.;The contributors treat such subjects as: exact sum rules for inhomogenous fluids, explaining density functional and integral equation methods; exact solutions for two-dimensional homogeneous and inhomogeneous plasmas; current advances in the theory of interfacial electrochemistry; wetting experiments and the theory of wetting; freezing, with an emphasis on quantum systems and homogeneous nucleation in liquid-vapour and solid-liquid transitions; self-organizing liquids as well as kinetic phenomena in inhomogeneous fluids, using a modified Enskog theory.;Featuring over 1000 bibliographic citations, this volume is aimed at physical, surface, colloid and surfactant chemists; also physicists, electrochemists and graduate-level students in these disciplines.
Book Synopsis High Temperatures - High Pressures by :
Download or read book High Temperatures - High Pressures written by and published by . This book was released on 1969 with total page 776 pages. Available in PDF, EPUB and Kindle. Book excerpt: An international refereed journal devoted to the experimental and theoretical study of the thermophysical properties of matter.
Book Synopsis Solution Properties for Aqueous Electrolyte Systems Based on Fluctuation Solution Theory by : J. Dale Massie
Download or read book Solution Properties for Aqueous Electrolyte Systems Based on Fluctuation Solution Theory written by J. Dale Massie and published by . This book was released on 1986 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Potential Distribution Theorem and Models of Molecular Solutions by : Tom L. Beck
Download or read book The Potential Distribution Theorem and Models of Molecular Solutions written by Tom L. Beck and published by Cambridge University Press. This book was released on 2006-08-31 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: An understanding of statistical thermodynamic molecular theory is fundamental to the appreciation of molecular solutions. This complex subject has been simplified by the authors with down-to-earth presentations of molecular theory. Using the potential distribution theorem (PDT) as the basis, the text provides a discussion of practical theories in conjunction with simulation results. The authors discuss the field in a concise and simple manner, illustrating the text with useful models of solution thermodynamics and numerous exercises. Modern quasi-chemical theories that permit statistical thermodynamic properties to be studied on the basis of electronic structure calculations are given extended development, as is the testing of those theoretical results with ab initio molecular dynamics simulations. The book is intended for students taking up research problems of molecular science in chemistry, chemical engineering, biochemistry, pharmaceutical chemistry, nanotechnology and biotechnology.
