Adsorption And Catalysis On Transition Metals And Their Oxides

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Adsorption and Catalysis on Transition Metals and Their Oxides

Author : Vsevolod F. Kiselev
Publisher : Springer Science & Business Media
ISBN 13 : 3642738877
Total Pages : 453 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Adsorption and Catalysis on Transition Metals and Their Oxides by : Vsevolod F. Kiselev

Download or read book Adsorption and Catalysis on Transition Metals and Their Oxides written by Vsevolod F. Kiselev and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with adsorption and catalysis on the surface of transition elements and their compounds, many of which are in teresting because of their particular electronic structure. The authors have worked through a vast body of experimental evi dence on the structure and properties of surfaces of transition metals and relevant oxides. Consideration is given mostly to simple (as opposed to mixed) oxides of transition elements, to common metals and to the adsorption of simple gases. A great deal of attention is paid to the nature of active surface sites responsible for chemisorption and catalytic transformations. The description relies mainly on the simplified ligand-field theory, which, however, proves quite satisfactory for predicting the adsorptive and catalytic activity of species. In many cases simple systems were explored with the aid of novel techniques, and it is only for such systems that the mechanism of the ele mentary act of adsorption and catalysis can be given adequate treatment. The present monograph has emerged from our earlier work in Russian, which appeared in the Khimiya Publishing House (Mos cow) in 1981. This English edition has, however, been revised completely to broaden its scope and to include more recent a chievements. For fruitful discussions the authors are grateful to A.A.

Adsorption and Catalysis on Transition Metals and Their Oxides

Author : Vsevolod F Kiselev
Publisher :
ISBN 13 : 9783642738883
Total Pages : 460 pages
Book Rating : 4.7/5 (388 download)

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Book Synopsis Adsorption and Catalysis on Transition Metals and Their Oxides by : Vsevolod F Kiselev

Download or read book Adsorption and Catalysis on Transition Metals and Their Oxides written by Vsevolod F Kiselev and published by . This book was released on 1989-05-11 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Transition Metal Oxides

Author : H.H. Kung
Publisher : Elsevier
ISBN 13 : 9780080887425
Total Pages : 281 pages
Book Rating : 4.8/5 (874 download)

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Book Synopsis Transition Metal Oxides by : H.H. Kung

Download or read book Transition Metal Oxides written by H.H. Kung and published by Elsevier. This book was released on 1989-04-01 with total page 281 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book the author presents an up-to-date summary of existing information on the structure, electronic properties, chemistry and catalytic properties of transition metal oxides. The subjects covered in the book can be divided into three sections. The first (chapters 1 to 3) covers the structural, physical, magnetic, and electronic properties of transition metal oxides. Although the emphasis is on surface properties, relevant bulk properties are also discussed. The second section (chapters 4 to 7) covers surface chemical properties. It includes topics that describe the importance of surface coordinative unsaturation in adsorption, the formation of surface acidity and the role of acidity in determining surface chemical properties, the nature and reactivities of adsorbed oxygen, and the surface chemistry in the reduction of oxides. The third section (chapters 8 to 14) is on the catalytic properties. Various catalytic reactions including decomposition, hydrogenation, isomerization, metathesis, selective oxidation, and reactions involving carbon oxides are discussed. Emphasis is placed more on reaction mechanisms and the role of catalysts than on kinetics and processes. Chapters on the preparation of oxide catalysts and on photo-assisted processes are also included. Whenever appropriate, relationships between various topics are indicated. Written for surface physicists, chemists, and catalytic engineers, the book will serve as a useful source of information for investigators and as a comprehensive overview of the subject for graduate students.

Transition Metal Oxides

Author : Harold H. Kung
Publisher :
ISBN 13 : 9780444418012
Total Pages : 285 pages
Book Rating : 4.4/5 (18 download)

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Book Synopsis Transition Metal Oxides by : Harold H. Kung

Download or read book Transition Metal Oxides written by Harold H. Kung and published by . This book was released on 1989 with total page 285 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal Oxide Catalysis, 2 Volume Set

Author : S. David Jackson
Publisher : John Wiley & Sons
ISBN 13 : 3527626123
Total Pages : 887 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Metal Oxide Catalysis, 2 Volume Set by : S. David Jackson

Download or read book Metal Oxide Catalysis, 2 Volume Set written by S. David Jackson and published by John Wiley & Sons. This book was released on 2008-12-23 with total page 887 pages. Available in PDF, EPUB and Kindle. Book excerpt: With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.

Metal Oxides

Author : J.L.G. Fierro
Publisher : CRC Press
ISBN 13 : 142002812X
Total Pages : 808 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Metal Oxides by : J.L.G. Fierro

Download or read book Metal Oxides written by J.L.G. Fierro and published by CRC Press. This book was released on 2005-08-24 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of metals has traditionally been more understood than that of its oxides. As catalytic applications continue to grow in a variety of disciplines, Metal Oxides: Chemistry and Applications offers a timely account of transition-metal oxides (TMO), one of the most important classes of metal oxides, in the context of catalysis. The first part of the book examines the crystal and electronic structure, stoichiometry and composition, redox properties, acid-base character, and cation valence states, as well as new approaches to the preparation of ordered TMO with extended structure of texturally defined systems. The second part compiles some practical aspects of TMO applications in materials science, chemical sensing, analytical chemistry, solid-state chemistry, microelectronics, nanotechnology, environmental decontamination, and fuel cells. The book examines many types of reactions - such as dehydration, reduction, selective oxidations, olefin metathesis, VOC removal, photo- and electrocatalysis, and water splitting - to elucidate how chemical composition and optical, magnetic, and structural properties of oxides affect their surface reactivity in catalysis. Drawing insight from leading international experts, Metal Oxides: Chemistry and Applications is a comprehensive and interdisciplinary reference for researchers that may also be used by newcomers as a guide to the field.

Surface Chemistry and Catalysis

Author : Albert F. Carley
Publisher : Springer Science & Business Media
ISBN 13 : 1475766378
Total Pages : 392 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Surface Chemistry and Catalysis by : Albert F. Carley

Download or read book Surface Chemistry and Catalysis written by Albert F. Carley and published by Springer Science & Business Media. This book was released on 2013-04-18 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 2001 Wyn Roberts celebrated both his 70th birthday and 50 years of working in surface science, to use the term "surface science" in its broadest meaning. This book aims to mark the anniversary with a contribution of lasting value, something more than the usual festschrift issue of a relevant journal. The book is divided into three sections: Surface Science, Model Catalysts and Catalysis, topics in which Wyn has always had interests. The authors for each chapter were chosen from some of the many eminent scientists who have worked with Wyn in various ways and are all internationally acknowledged as leaders in their field. The authors have produced authoritative reviews of their own specialties which together result in a book with an unrivalled combination of breadth and depth exploring the most recent developments in surface chemistry and catalysis.

Oxide Surfaces

Author :
Publisher : Elsevier
ISBN 13 : 9780080538310
Total Pages : 676 pages
Book Rating : 4.5/5 (383 download)

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Book Synopsis Oxide Surfaces by :

Download or read book Oxide Surfaces written by and published by Elsevier. This book was released on 2001-05-21 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is a multi-author survey (in 15 chapters) of the current state of knowledge and recent developments in our understanding of oxide surfaces. The author list includes most of the acknowledged world experts in this field. The material covered includes fundamental theory and experimental studies of the geometrical, vibrational and electronic structure of such surfaces, but with a special emphasis on the chemical properties and associated reactivity. The main focus is on metal oxides but coverage extends from 'simple' rocksalt materials such as MgO through to complex transition metal oxides with different valencies.

Chemisorption and Reactivity on Supported Clusters and Thin Films:

Author : R.M. Lambert
Publisher : Springer Science & Business Media
ISBN 13 : 9401589119
Total Pages : 534 pages
Book Rating : 4.4/5 (15 download)

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Book Synopsis Chemisorption and Reactivity on Supported Clusters and Thin Films: by : R.M. Lambert

Download or read book Chemisorption and Reactivity on Supported Clusters and Thin Films: written by R.M. Lambert and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis provides the backbone of the world's chemical and oil industries. The innate complexity of practical catalytic systems suggests that useful progress should be achievable by investigating key aspects of catalysis by experimental studies on idealised model systems. Thin films and supported clusters are two promising types of model system that can be used for this purpose, since they mimic important aspects of the properties of practical dispersed catalysts. Similarly, appropriate theoretical studies of chemisorption and surface reaction clusters or extended slab systems can provide valuable information on the factors that underlie bonding and catalytic activity. This volume describes such experimental and theoretical approaches to the surface chemistry and catalytic behaviour of metals, metal oxides and metal/metal oxide systems. An introduction to the principles and main themes of heterogeneous catalysis is followed by detailed accounts of the application of modern experimental and theoretical techniques to fundamental problems. The application of advanced experimental methods is complemented by a full description of theoretical procedures, including Hartree-Fock, density functional and similar techniques. The relative merits of the various approaches are considered and directions for future progress are indicated.

Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides

Author : Anatoli Davydov
Publisher :
ISBN 13 :
Total Pages : 272 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides by : Anatoli Davydov

Download or read book Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides written by Anatoli Davydov and published by . This book was released on 1990-10-11 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Included here is a summary of findings made by the author from infrared investigations of the surface chemistry of simple and complex oxide catalysts. The focus is on spectral characteristics of active sites on oxide surfaces, namely hydroxyl groups, coordinatively unsaturated cations, and surface oxygen. There is a detailed account of the method used for characterizing the oxidation state and coordination of cations on oxide surfaces by the adsorption of probe molecules. In addition, the role played by surface sites in surface-molecule adsorption is used to organize and classify data relating to the interaction of carbon, nitrogen, ammonia, and alkenes with surfaces of transition metal oxides and with supported or mixed oxides containing transition metal cations.

Adsorption and Catalysis on Oxide Surfaces

Author : M. Che
Publisher : Elsevier
ISBN 13 : 9780080960555
Total Pages : 441 pages
Book Rating : 4.9/5 (65 download)

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Book Synopsis Adsorption and Catalysis on Oxide Surfaces by : M. Che

Download or read book Adsorption and Catalysis on Oxide Surfaces written by M. Che and published by Elsevier. This book was released on 1985-07-01 with total page 441 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Symposium was held to honour the memory of the late Dr. A.J. Tench who made numerous important contributions to our knowledge of the structure, reactivity and adsorption properties of oxide surfaces. This volume contains an up-to-date picture of adsorption and catalysis on oxide surfaces, not in the form of a comprehensive review but in its living aspects of work in progress. It describes detailed studies on the determination of the coordination surface ions, particularly oxide ions, by photoluminescence and reflectance spectroscopy, on the identification of adsorbed species by magnetic optical or surface techniques and on catalysis, with emphasis on new concepts such as catalysis involving excited states or structure sensitive reactions. Professionals working in the industrial and academic laboratories will find the book particularly useful as it provides a state-of-the-art account of our understanding of the structure and adsorption characteristics of oxide surfaces. Contained in the book are first class research papers by leading exponents in this field. A very important issue is that the book highlights for the first time the importance of excited states and structure sensitivity in determining the behaviour of oxide surfaces.

Metal Oxides in Heterogeneous Catalysis

Author : Jacques C. Vedrine
Publisher : Elsevier
ISBN 13 : 0128116323
Total Pages : 618 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Metal Oxides in Heterogeneous Catalysis by : Jacques C. Vedrine

Download or read book Metal Oxides in Heterogeneous Catalysis written by Jacques C. Vedrine and published by Elsevier. This book was released on 2018-01-11 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. Presents case studies in each chapter that provide a focus on the industrial applications Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications

Heterogeneous Catalytic Redox Reactions

Author : Vladislav Sadykov
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110587777
Total Pages : 255 pages
Book Rating : 4.1/5 (15 download)

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Book Synopsis Heterogeneous Catalytic Redox Reactions by : Vladislav Sadykov

Download or read book Heterogeneous Catalytic Redox Reactions written by Vladislav Sadykov and published by Walter de Gruyter GmbH & Co KG. This book was released on 2019-10-21 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt: The current book brings together cutting-edge research in the area of heterogeneous catalytic redox processes. The first part of the book covers the catalytic properties of transition metal oxides and the techniques for catalysts preparation, such as mechanochemistry, plasmochemistry, hydrothermal treatment, etc. Further the authors focus on mechanisms of heterogeneous redox reactions followed by the overview of industrial applications.

Theoretical Aspects of Heterogeneous Catalysis

Author : M.A. Nascimento
Publisher : Springer Science & Business Media
ISBN 13 : 0306476673
Total Pages : 258 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Theoretical Aspects of Heterogeneous Catalysis by : M.A. Nascimento

Download or read book Theoretical Aspects of Heterogeneous Catalysis written by M.A. Nascimento and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis is a fascinating and complex subject of utmost importance in the present day. Its immense technological and economical importance and the inherent complexity of the catalytic phenomena have stimulated theoretical and experimental studies by a broad spectrum of scientists, including chemists, physicists, chemical engineers, and material scientists. Computational and theoretical techniques are now having a major impact in this field. This book aims to illustrate and discuss the subject of heterogeneous catalysis and to show the current capabilities of the theoretical and computational methods for studying the various steps (diffusion, adsorption, chemical reaction) of heterogeneous catalytic process involving zeolites, metal oxides, and transition metal surfaces. The book covers: the use of techniques of computational chemistry to simulate zeolites, metallic and bimetallic surfaces, and oxide-supported metals; the impact of simulation methods on the understanding of the diffusion and adsorption of molecules and cations within the pores of zeolites, and also on the adsorption of molecules on metal and metal-oxide surfaces; and the applications of quantum-mechanical methods to the study of the reaction mechanism and pathways of the adsorbed molecules. This book is recommended primarily to scientists and graduate students conducting research in the fields of heterogeneous catalysis and surface science. It will also be valuable to advanced undergraduate students wishing to become acquainted with the latest developments in these exciting fields of research, and to experimentalists seeking theoretical support for interpreting their results.

Surface Properties and Catalysis by Non-Metals

Author : J.P. Bonnelle
Publisher : Springer Science & Business Media
ISBN 13 : 9400971605
Total Pages : 571 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Surface Properties and Catalysis by Non-Metals by : J.P. Bonnelle

Download or read book Surface Properties and Catalysis by Non-Metals written by J.P. Bonnelle and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 571 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the field of heterogeneous catalysis. it is convenient to distinguish. in a perfectly unjustified and over··simplified way. bet:leen metal catalysts. 2nd the other catalysts. The fj.J"st are easy to define : they are those in which a reduced metal is the active phase. It is thus easy to circumscribe. by exclusion, the other class namely the "non-metals". We have adopted this definition for the sake of our colleagues working on catalysis by metals, and to avoid a lengthy title like "sm' face pl"operties and catalysts by transi tion metal oxides. sulftdes, carbides, nitriles, etc. Defined in this manner, non-metal catalysts represented, in 1980, 84 wt. % of the industrial heterogeneous catalysts. To be more specific, this proportion corresponds to catalysts which, under the working conditions in the industrial ?lant. contain their catalytically active metallic elements in a non-reduced state. It should however be recalled that most metal catalysts are supported on oxides, which, often, repl'esent over 90% (sometimes 99.4% in the case of the platinum reforming catalysts) of the total weight.

Catalysis by Unique Metal Ion Structures in Solid Matrices

Author : Gabriele Centi
Publisher : Springer Science & Business Media
ISBN 13 : 9401007829
Total Pages : 331 pages
Book Rating : 4.4/5 (1 download)

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Book Synopsis Catalysis by Unique Metal Ion Structures in Solid Matrices by : Gabriele Centi

Download or read book Catalysis by Unique Metal Ion Structures in Solid Matrices written by Gabriele Centi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 331 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also exciting opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices. The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.

Handbook of Nanophase Materials

Author : Avery Goldstein
Publisher : CRC Press
ISBN 13 : 9780824794699
Total Pages : 384 pages
Book Rating : 4.7/5 (946 download)

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Book Synopsis Handbook of Nanophase Materials by : Avery Goldstein

Download or read book Handbook of Nanophase Materials written by Avery Goldstein and published by CRC Press. This book was released on 1997-06-17 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Integrates current research on submicron-sized domain materials. Provides fundamental insight into particle size control and nanophase methodologies and materials--addressing specific problems in a host of research fields, including chemistry, physics, materials science, and engineering."