Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (953 download)

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Book Synopsis Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers by :

Download or read book Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall goal of the project was to bridge the gap between our knowledge of small-scale geochemical reaction rates and reaction rates meaningful for modeling transport at core scales. The working hypothesis was that reaction rates, determined from laboratory measurements based upon reactions typically conducted in well mixed batch reactors using pulverized reactive media may be significantly changed in in situ porous media flow due to rock microstructure heterogeneity. Specifically we hypothesized that, generally, reactive mineral surfaces are not uniformly accessible to reactive fluids due to the random deposition of mineral grains and to the variation in flow rates within a pore network. Expected bulk reaction rates would therefore have to be correctly up-scaled to reflect such heterogeneity. The specific objective was to develop a computational tool that integrates existing measurement capabilities with pore-scale network models of fluid flow and reactive transport. The existing measurement capabilities to be integrated consisted of (a) pore space morphology, (b) rock mineralogy, and (c) geochemical reaction rates. The objective was accomplished by: (1) characterizing sedimentary sandstone rock morphology using X-ray computed microtomography, (2) mapping rock mineralogy using back-scattered electron microscopy (BSE), X-ray dispersive spectroscopy (EDX) and CMT, (3) characterizing pore-accessible reactive mineral surface area, and (4) creating network models to model acidic CO2 saturated brine injection into the sandstone rock samples.

Geological Sequestration of Carbon Dioxide

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Publisher : Elsevier
ISBN 13 : 0080466885
Total Pages : 471 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Geological Sequestration of Carbon Dioxide by : Luigi Marini

Download or read book Geological Sequestration of Carbon Dioxide written by Luigi Marini and published by Elsevier. This book was released on 2006-10-12 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer.* Provides applications for investigating and predicting geological carbon dioxide sequestration* Reviews the geochemical literature in the field* Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration

Geological Storage of CO2 in Deep Saline Formations

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Publisher : Springer
ISBN 13 : 9402409963
Total Pages : 567 pages
Book Rating : 4.4/5 (24 download)

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Book Synopsis Geological Storage of CO2 in Deep Saline Formations by : Auli Niemi

Download or read book Geological Storage of CO2 in Deep Saline Formations written by Auli Niemi and published by Springer. This book was released on 2017-02-24 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers readers a comprehensive overview, and an in-depth understanding, of suitable methods for quantifying and characterizing saline aquifers for the geological storage of CO2. It begins with a general overview of the methodology and the processes that take place when CO2 is injected and stored in deep saline-water-containing formations. It subsequently presents mathematical and numerical models used for predicting the consequences of CO2 injection. This book provides descriptions of relevant experimental methods, from laboratory experiments to field scale site characterization and techniques for monitoring spreading of the injected CO2 within the formation. Experiences from a number of important field injection projects are reviewed, as are those from CO2 natural analog sites. Lastly, the book presents relevant risk management methods. Geological storage of CO2 is widely considered to be a key technology capable of substantially reducing the amount of CO2 released into the atmosphere, thereby reducing the negative impacts of such releases on the global climate. Around the world, projects are already in full swing, while others are now being initiated and executed to demonstrate the technology. Deep saline formations are the geological formations considered to hold the highest storage potential, due to their abundance worldwide. To date, however, these formations have been relatively poorly characterized, due to their low economic value. Accordingly, the processes involved in injecting and storing CO2 in such formations still need to be better quantified and methods for characterizing, modeling and monitoring this type of CO2 storage in such formations must be rapidly developed and refined.

Science of Carbon Storage in Deep Saline Formations

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Publisher : Elsevier
ISBN 13 : 9780128127520
Total Pages : 0 pages
Book Rating : 4.1/5 (275 download)

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Book Synopsis Science of Carbon Storage in Deep Saline Formations by : Pania Newell

Download or read book Science of Carbon Storage in Deep Saline Formations written by Pania Newell and published by Elsevier. This book was released on 2018-09-10 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Science of Carbon Storage in Deep Saline Formations: Process Coupling across Time and Spatial Scales summarizes state-of-the-art research, emphasizing how the coupling of physical and chemical processes as subsurface systems re-equilibrate during and after the injection of CO2. In addition, it addresses, in an easy-to-follow way, the lack of knowledge in understanding the coupled processes related to fluid flow, geomechanics and geochemistry over time and spatial scales. The book uniquely highlights process coupling and process interplay across time and spatial scales that are relevant to geological carbon storage.

Geologic Carbon Sequestration

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Publisher : Springer
ISBN 13 : 3319270192
Total Pages : 336 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Geologic Carbon Sequestration by : V. Vishal

Download or read book Geologic Carbon Sequestration written by V. Vishal and published by Springer. This book was released on 2016-05-11 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: This exclusive compilation written by eminent experts from more than ten countries, outlines the processes and methods for geologic sequestration in different sinks. It discusses and highlights the details of individual storage types, including recent advances in the science and technology of carbon storage. The topic is of immense interest to geoscientists, reservoir engineers, environmentalists and researchers from the scientific and industrial communities working on the methodologies for carbon dioxide storage. Increasing concentrations of anthropogenic carbon dioxide in the atmosphere are often held responsible for the rising temperature of the globe. Geologic sequestration prevents atmospheric release of the waste greenhouse gases by storing them underground for geologically significant periods of time. The book addresses the need for an understanding of carbon reservoir characteristics and behavior. Other book volumes on carbon capture, utilization and storage (CCUS) attempt to cover the entire process of CCUS, but the topic of geologic sequestration is not discussed in detail. This book focuses on the recent trends and up-to-date information on different storage rock types, ranging from deep saline aquifers to coal to basaltic formations.

Geochemical Modeling of CO2 Sequestration in Dolomitic Limestone Aquifers

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (74 download)

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Book Synopsis Geochemical Modeling of CO2 Sequestration in Dolomitic Limestone Aquifers by : Mark W. Thomas

Download or read book Geochemical Modeling of CO2 Sequestration in Dolomitic Limestone Aquifers written by Mark W. Thomas and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: ABSTRACT: Geologic sequestration of carbon dioxide (CO2) in a deep, saline aquifer is being proposed for a power-generating facility in Florida as a method to mitigate contribution to global climate change from greenhouse gas (GHG) emissions. The proposed repository is a brine-saturated, dolomitic-limestone aquifer with anhydrite inclusions contained within the Cedar Keys/Lawson formations of Central Florida. Thermodynamic modeling is used to investigate the geochemical equilibrium reactions for the minerals calcite, dolomite, and gypsum with 28 aqueous species for the purpose of determining the sensitivity of mineral precipitation and dissolution to the temperature and pressure of the aquifer and the salinity and initial pH of the brine. The use of different theories for estimating CO2 fugacity, solubility in brine, and chemical activity is demonstrated to have insignificant effects on the predicted results. Nine different combinations of thermodynamic models predict that the geochemical response to CO2 injection is calcite and dolomite dissolution and gypsum precipitation, with good agreement among the quantities estimated. In all cases, CO2 storage through solubility trapping is demonstrated to be a likely process, while storage through mineral trapping is predicted to not occur. Over the range of values examined, it is found that net mineral dissolution and precipitation is relatively sensitive to temperature and salinity, insensitive to CO2 injection pressure and initial pH, and significant changes to porosity will not occur.

Geological Carbon Storage

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Publisher : John Wiley & Sons
ISBN 13 : 1119118670
Total Pages : 372 pages
Book Rating : 4.1/5 (191 download)

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Book Synopsis Geological Carbon Storage by : Stéphanie Vialle

Download or read book Geological Carbon Storage written by Stéphanie Vialle and published by John Wiley & Sons. This book was released on 2018-11-15 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: Geological Carbon Storage Subsurface Seals and Caprock Integrity Seals and caprocks are an essential component of subsurface hydrogeological systems, guiding the movement and entrapment of hydrocarbon and other fluids. Geological Carbon Storage: Subsurface Seals and Caprock Integrity offers a survey of the wealth of recent scientific work on caprock integrity with a focus on the geological controls of permanent and safe carbon dioxide storage, and the commercial deployment of geological carbon storage. Volume highlights include: Low-permeability rock characterization from the pore scale to the core scale Flow and transport properties of low-permeability rocks Fundamentals of fracture generation, self-healing, and permeability Coupled geochemical, transport and geomechanical processes in caprock Analysis of caprock behavior from natural analogues Geochemical and geophysical monitoring techniques of caprock failure and integrity Potential environmental impacts of carbon dioxide migration on groundwater resources Carbon dioxide leakage mitigation and remediation techniques Geological Carbon Storage: Subsurface Seals and Caprock Integrity is an invaluable resource for geoscientists from academic and research institutions with interests in energy and environment-related problems, as well as professionals in the field.

Petrophysical Modeling and Simulation Study of Geological CO2 Sequestration

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ISBN 13 :
Total Pages : 452 pages
Book Rating : 4.:/5 (881 download)

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Book Synopsis Petrophysical Modeling and Simulation Study of Geological CO2 Sequestration by : Xianhui Kong

Download or read book Petrophysical Modeling and Simulation Study of Geological CO2 Sequestration written by Xianhui Kong and published by . This book was released on 2014 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Global warming and greenhouse gas (GHG) emissions have recently become the significant focus of engineering research. The geological sequestration of greenhouse gases such as carbon dioxide (CO2) is one approach that has been proposed to reduce the greenhouse gas emissions and slow down global warming. Geological sequestration involves the injection of produced CO2 into subsurface formations and trapping the gas through many geological mechanisms, such as structural trapping, capillary trapping, dissolution, and mineralization. While some progress in our understanding of fluid flow in porous media has been made, many petrophysical phenomena, such as multi-phase flow, capillarity, geochemical reactions, geomechanical effect, etc., that occur during geological CO2 sequestration remain inadequately studied and pose a challenge for continued study. It is critical to continue to research on these important issues. Numerical simulators are essential tools to develop a better understanding of the geologic characteristics of brine reservoirs and to build support for future CO2 storage projects. Modeling CO2 injection requires the implementation of multiphase flow model and an Equation of State (EOS) module to compute the dissolution of CO2 in brine and vice versa. In this study, we used the Integrated Parallel Accurate Reservoir Simulator (IPARS) developed at the Center for Subsurface Modeling at The University of Texas at Austin to model the injection process and storage of CO2 in saline aquifers. We developed and implemented new petrophysical models in IPARS, and applied these models to study the process of CO2 sequestration. The research presented in this dissertation is divided into three parts. The first part of the dissertation discusses petrophysical and computational models for the mechanical, geological, petrophysical phenomena occurring during CO2 injection and sequestration. The effectiveness of CO2 storage in saline aquifers is governed by the interplay of capillary, viscous, and buoyancy forces. Recent experimental data reveals the impact of pressure, temperature, and salinity on interfacial tension (IFT) between CO2 and brine. The dependence of CO2-brine relative permeability and capillary pressure on IFT is also clearly evident in published experimental results. Improved understanding of the mechanisms that control the migration and trapping of CO2 in the subsurface is crucial to design future storage projects for long-term, safe containment. We have developed numerical models for CO2 trapping and migration in aquifers, including a compositional flow model, a relative permeability model, a capillary model, an interfacial tension model, and others. The heterogeneities in porosity and permeability are also coupled to the petrophysical models. We have developed and implemented a general relative permeability model that combines the effects of pressure gradient, buoyancy, and capillary pressure in a compositional and parallel simulator. The significance of IFT variations on CO2 migration and trapping is assessed. The variation of residual saturation is modeled based on interfacial tension and trapping number, and a hysteretic trapping model is also presented. The second part of this dissertation is a model validation and sensitivity study using coreflood simulation data derived from laboratory study. The motivation of this study is to gain confidence in the results of the numerical simulator by validating the models and the numerical accuracies using laboratory and field pilot scale results. Published steady state, core-scale CO2/brine displacement results were selected as a reference basis for our numerical study. High-resolution compositional simulations of brine displacement with supercritical CO2 are presented using IPARS. A three-dimensional (3D) numerical model of the Berea sandstone core was constructed using heterogeneous permeability and porosity distributions based on geostatistical data. The measured capillary pressure curve was scaled using the Leverett J-function to include local heterogeneity in the sub-core scale. Simulation results indicate that accurate representation of capillary pressure at sub-core scales is critical. Water drying and the shift in relative permeability had a significant impact on the final CO2 distribution along the core. This study provided insights into the role of heterogeneity in the final CO2 distribution, where a slight variation in porosity gives rise to a large variation in the CO2 saturation distribution. The third part of this study is a simulation study using IPARS for Cranfield pilot CO2 sequestration field test, conducted by the Bureau of Economic Geology (BEG) at The University of Texas at Austin. In this CO2 sequestration project, a total of approximately 2.5 million tons supercritical CO2 was injected into a deep saline aquifer about ~10000 ft deep over 2 years, beginning December 1st 2009. In this chapter, we use the simulation capabilities of IPARS to numerically model the CO2 injection process in Cranfield. We conducted a corresponding history-matching study and got good agreement with field observation. Extensive sensitivity studies were also conducted for CO2 trapping, fluid phase behavior, relative permeability, wettability, gravity and buoyancy, and capillary effects on sequestration. Simulation results are consistent with the observed CO2 breakthrough time at the first observation well. Numerical results are also consistent with bottomhole injection flowing pressure for the first 350 days before the rate increase. The abnormal pressure response with rate increase on day 350 indicates possible geomechanical issues, which can be represented in simulation using an induced fracture near the injection well. The recorded injection well bottomhole pressure data were successfully matched after modeling the fracture in the simulation model. Results also illustrate the importance of using accurate trapping models to predict CO2 immobilization behavior. The impact of CO2/brine relative permeability curves and trapping model on bottom-hole injection pressure is also demonstrated.

Geochemistry of Geologic CO2 Sequestration

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 1501508075
Total Pages : 556 pages
Book Rating : 4.5/5 (15 download)

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Book Synopsis Geochemistry of Geologic CO2 Sequestration by : Donald J. DePaolo

Download or read book Geochemistry of Geologic CO2 Sequestration written by Donald J. DePaolo and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 77 of Reviews in Mineralogy and Geochemistry focuses on important aspects of the geochemistry of geological CO2 sequestration. It is in large part an outgrowth of research conducted by members of the U.S. Department of Energy funded Energy Frontier Research Center (EFRC) known as the Center for Nanoscale Control of Geologic CO2 (NCGC). Eight out of the 15 chapters have been led by team members from the NCGC representing six of the eight partner institutions making up this center - Lawrence Berkeley National Laboratory (lead institution, D. DePaolo - PI), Oak Ridge National Laboratory, The Ohio State University, the University of California Davis, Pacific Northwest National Laboratory, and Washington University, St. Louis.

Handbook of Clean Energy Systems, 6 Volume Set

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Publisher : John Wiley & Sons
ISBN 13 : 1118388585
Total Pages : 4038 pages
Book Rating : 4.1/5 (183 download)

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Book Synopsis Handbook of Clean Energy Systems, 6 Volume Set by : Jinyue Yan

Download or read book Handbook of Clean Energy Systems, 6 Volume Set written by Jinyue Yan and published by John Wiley & Sons. This book was released on 2015-06-22 with total page 4038 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Clean Energy Systems brings together an international team of experts to present a comprehensive overview of the latest research, developments and practical applications throughout all areas of clean energy systems. Consolidating information which is currently scattered across a wide variety of literature sources, the handbook covers a broad range of topics in this interdisciplinary research field including both fossil and renewable energy systems. The development of intelligent energy systems for efficient energy processes and mitigation technologies for the reduction of environmental pollutants is explored in depth, and environmental, social and economic impacts are also addressed. Topics covered include: Volume 1 - Renewable Energy: Biomass resources and biofuel production; Bioenergy Utilization; Solar Energy; Wind Energy; Geothermal Energy; Tidal Energy. Volume 2 - Clean Energy Conversion Technologies: Steam/Vapor Power Generation; Gas Turbines Power Generation; Reciprocating Engines; Fuel Cells; Cogeneration and Polygeneration. Volume 3 - Mitigation Technologies: Carbon Capture; Negative Emissions System; Carbon Transportation; Carbon Storage; Emission Mitigation Technologies; Efficiency Improvements and Waste Management; Waste to Energy. Volume 4 - Intelligent Energy Systems: Future Electricity Markets; Diagnostic and Control of Energy Systems; New Electric Transmission Systems; Smart Grid and Modern Electrical Systems; Energy Efficiency of Municipal Energy Systems; Energy Efficiency of Industrial Energy Systems; Consumer Behaviors; Load Control and Management; Electric Car and Hybrid Car; Energy Efficiency Improvement. Volume 5 - Energy Storage: Thermal Energy Storage; Chemical Storage; Mechanical Storage; Electrochemical Storage; Integrated Storage Systems. Volume 6 - Sustainability of Energy Systems: Sustainability Indicators, Evaluation Criteria, and Reporting; Regulation and Policy; Finance and Investment; Emission Trading; Modeling and Analysis of Energy Systems; Energy vs. Development; Low Carbon Economy; Energy Efficiencies and Emission Reduction. Key features: Comprising over 3,500 pages in 6 volumes, HCES presents a comprehensive overview of the latest research, developments and practical applications throughout all areas of clean energy systems, consolidating a wealth of information which is currently scattered across a wide variety of literature sources. In addition to renewable energy systems, HCES also covers processes for the efficient and clean conversion of traditional fuels such as coal, oil and gas, energy storage systems, mitigation technologies for the reduction of environmental pollutants, and the development of intelligent energy systems. Environmental, social and economic impacts of energy systems are also addressed in depth. Published in full colour throughout. Fully indexed with cross referencing within and between all six volumes. Edited by leading researchers from academia and industry who are internationally renowned and active in their respective fields. Published in print and online. The online version is a single publication (i.e. no updates), available for one-time purchase or through annual subscription.

Negative Emissions Technologies and Reliable Sequestration

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Publisher : National Academies Press
ISBN 13 : 0309484529
Total Pages : 511 pages
Book Rating : 4.3/5 (94 download)

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Book Synopsis Negative Emissions Technologies and Reliable Sequestration by : National Academies of Sciences, Engineering, and Medicine

Download or read book Negative Emissions Technologies and Reliable Sequestration written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-04-08 with total page 511 pages. Available in PDF, EPUB and Kindle. Book excerpt: To achieve goals for climate and economic growth, "negative emissions technologies" (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change. Unlike carbon capture and storage technologies that remove carbon dioxide emissions directly from large point sources such as coal power plants, NETs remove carbon dioxide directly from the atmosphere or enhance natural carbon sinks. Storing the carbon dioxide from NETs has the same impact on the atmosphere and climate as simultaneously preventing an equal amount of carbon dioxide from being emitted. Recent analyses found that deploying NETs may be less expensive and less disruptive than reducing some emissions, such as a substantial portion of agricultural and land-use emissions and some transportation emissions. In 2015, the National Academies published Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration, which described and initially assessed NETs and sequestration technologies. This report acknowledged the relative paucity of research on NETs and recommended development of a research agenda that covers all aspects of NETs from fundamental science to full-scale deployment. To address this need, Negative Emissions Technologies and Reliable Sequestration: A Research Agenda assesses the benefits, risks, and "sustainable scale potential" for NETs and sequestration. This report also defines the essential components of a research and development program, including its estimated costs and potential impact.

Experimental and Numarical Investigation of Carbon Dioxide Sequestration in Deep Saline Aquifers

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (611 download)

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Book Synopsis Experimental and Numarical Investigation of Carbon Dioxide Sequestration in Deep Saline Aquifers by :

Download or read book Experimental and Numarical Investigation of Carbon Dioxide Sequestration in Deep Saline Aquifers written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Started as an EOR technique to produce oil, injection of carbon dioxide which is essentially a greenhouse gas is becoming more and more important. Although there are a number of mathematical modeling studies, experimental studies are limited and most studies focus on injection into sandstone reservoirs as opposed to carbonate ones. This study presents the results of computerized tomography (CT) monitored laboratory experiments to characterize relevant chemical reactions associated with injection and storage of CO2 in carbonate formations. Porosity changes along the core plugs and the corresponding permeability changes are reported for varying CO2 injection rates, temperature and salt concentrations. CT monitored experiments are designed to model fast near well bore flow and slow reservoir flows. It was observed that either a permeability improvement or a permeability reduction can be obtained. The trend of change in rock properties is very case dependent because it is related to distribution of pores, brine composition and as well the thermodynamic conditions. As the salt concentration decreased the porosity and thus the permeability decrease was less pronounced. Calcite scaling is mainly influenced by orientation and horizontal flow resulted in larger calcite deposition compared to vertical flow. The duration of CO2 – rock contact and the amount of area contacted by CO2 seems to have a more pronounced effect compared to rate effect. The experiments were modeled using a multi-phase, non-isothermal commercial simulator where solution and deposition of calcite were considered by the means of chemical reactions. The calibrated model was then used to analyze field scale injections and to model the potential CO2 sequestration capacity of a hypothetical carbonate aquifer formation. It was observed that solubility and hydrodynamic storage of CO2 is larger compared to mineral trapping.

Predicting the Geochemical Effects of SO2 Impurities During Carbon Storage

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Publisher :
ISBN 13 :
Total Pages : 235 pages
Book Rating : 4.:/5 (112 download)

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Book Synopsis Predicting the Geochemical Effects of SO2 Impurities During Carbon Storage by : Anja Birte Frank

Download or read book Predicting the Geochemical Effects of SO2 Impurities During Carbon Storage written by Anja Birte Frank and published by . This book was released on 2015 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this study was to improve our ability to predict CO2-SO2 geologic storage. SO2 is an impurity of industrial CO2 gas streams which is expected to intensify brine acidification resulting in enhanced mineral reaction. Short-term H2SO4-brine-rock experiments were combined with reaction path modelling to identify reactions and evaluate the pH and temperature dependency of reaction rates. In addition, available reactive surface area was investigated to enhance our ability to upscale to reservoir scale. Kinetically controlled reaction path models that included CO2, SO2 and O2 were generated and then run at reservoir conditions for 100 y. The models predicted a rapid buffering of the SO2 induced acidification. Compared to pure CO2 storage the CO2-SO2-O2 reservoir models resulted in enhanced carbonate reaction extents and a greater porosity increase, which have significant ramifications for the safety of the seal and the storage capacity of the storage formation.

Mechanisms for CO2 Sequestration in Geological Formations and Enhanced Gas Recovery

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Publisher : Springer
ISBN 13 : 3319230875
Total Pages : 106 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Mechanisms for CO2 Sequestration in Geological Formations and Enhanced Gas Recovery by : Roozbeh Khosrokhavar

Download or read book Mechanisms for CO2 Sequestration in Geological Formations and Enhanced Gas Recovery written by Roozbeh Khosrokhavar and published by Springer. This book was released on 2015-10-28 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives background information why shale formations in the world are important both for storage capacity and enhanced gas recovery (EGR). Part of this book investigates the sequestration capacity in geological formations and the mechanisms for the enhanced storage rate of CO2 in an underlying saline aquifer. The growing concern about global warming has increased interest in geological storage of carbon dioxide (CO2). The main mechanism of the enhancement, viz., the occurrence of gravity fingers, which are the vehicles of enhanced transport in saline aquifers, can be visualized using the Schlieren technique. In addition high pressure experiments confirmed that the storage rate is indeed enhanced in porous media. The book is appropriate for graduate students, researchers and advanced professionals in petroleum and chemical engineering. It provides the interested reader with in-depth insights into the possibilities and challenges of CO2 storage and the EGR prospect.

Carbon Dioxide Capture for Storage in Deep Geologic Formations - Results from the CO2 Capture Project

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Publisher : Elsevier
ISBN 13 : 0081005016
Total Pages : 686 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Carbon Dioxide Capture for Storage in Deep Geologic Formations - Results from the CO2 Capture Project by : David C Thomas

Download or read book Carbon Dioxide Capture for Storage in Deep Geologic Formations - Results from the CO2 Capture Project written by David C Thomas and published by Elsevier. This book was released on 2015-01-03 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past decade, the prospect of climate change resulting from anthropogenic CO2 has become a matter of growing public concern. Not only is the reduction of CO2 emissions extremely important, but keeping the cost at a manageable level is a prime priority for companies and the public, alike. The CO2 capture project (CCP) came together with a common goal in mind: find a technological process to capture CO2 emissions that is relatively low-cost and able be to be expanded to industrial applications. The Carbon Dioxide Capture and Storage Project outlines the research and findings of all the participating companies and associations involved in the CCP. The final results of thousands of hours of research are outlined in the book, showing a successful achievement of the CCP's goals for lower cost CO2 capture technology and furthering the safe, reliable option of geological storage. The Carbon Dioxide Capture and Storage Project is a valuable reference for any scientists, industrialists, government agencies, and companies interested in a safer, more cost-efficient response to the CO2 crisis.

Geomechanical, Geochemical, and Hydrological Aspects of Co2 Injection Into Saline Reservoirs

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Publisher :
ISBN 13 :
Total Pages : 686 pages
Book Rating : 4.:/5 (129 download)

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Book Synopsis Geomechanical, Geochemical, and Hydrological Aspects of Co2 Injection Into Saline Reservoirs by : Maziar Foroutan

Download or read book Geomechanical, Geochemical, and Hydrological Aspects of Co2 Injection Into Saline Reservoirs written by Maziar Foroutan and published by . This book was released on 2021 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon dioxide Capturing, and Sequestration (CCS) is a promising technique that helps mitigate the amount of CO2 emitted into the atmosphere. CCS process mainly involves capturing CO2 at the industrial plant, followed by transportation and injection into a suitable geological storage, under supercritical conditions. Saline aquifers are among the best geological storage candidates due to their availability, high storage capacity and injectivity. Despite the CCUS technology promise, several public safety concerns remain to be address, including but not limited to reservoir/wellbore stability and integrity, CO2 leakage, ground deformation (uplift) and induced seismicity. The injected supercritical CO2 is trapped through different mechanisms in the host reservoir including (i) structural and stratigraphic trapping, (ii) residual trapping, (iii) solubility trapping, and (iv) mineral trapping. Dissolution of CO2 into the formation brine creates an acidic environment, which is highly reactive. The potential mineral dissolution in reservoir rocks can enhance the storage capacity and reservoir injectivity, while the secondary precipitation of minerals can decrease the storage capacity and injectivity. However, the geochemical processes triggered by CO2 injection can potentially degrade the mechanical properties of the reservoir rock, which can consequently disturb the wellbore-stability, reservoir integrity, and lead to significant reservoir compaction. Furthermore, injecting CO2 changes the stress-regime by increasing pore-pressure in the reservoir and its surroundings, which can potentially reactivate the existing faults, leading to induced seismicity. In this research, experiments were performed to evaluate the variation of porosity and pore-connectivity of intact sandstone specimens upon injecting CO2-enriched brine. In addition, the permeability evolution during the CO2-enriched brine injection process was evaluated under different reservoir condition. The mechanical impacts of injecting CO2-enriched brine were evaluated by comparing the mechanical properties (i.e., elastic, strength, seismic and time dependent properties) before and after injecting CO2-enriched brine. In addition, to evaluate the response of fractured reservoirs to CO2 injection, CO2-enriched brine was injected into a limestone and varyingly cemented (i.e., calcite and quartz cemented) sandstone specimens that were artificially fractured. The experimental results were used to numerically simulate CO2 injection into a core-scale porous medium to investigate the changes in CO2 concentration and mass transfer mechanism under different porosity, permeability, and injection pressure values. The experimental results of injecting CO2-enrihed brine to the intact (non-fractured) specimens revealed permeability enhancement and mechanical weakening caused by mineral dissolution. The extent of changes in permeability and mechanical properties of rock specimens varied under different reservoir conditions (i.e., pressure, salinity, and temperature). The mechanical weakening increased the possibility of induced seismicity, which consequently resulted in decreasing the allowable injection pressure of CO2. However, the permeability increase resulted in enhancing CO2 mass transfer and accelerating the solubility trapping in the brine aquifer.

The American Journal of Science

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Author :
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ISBN 13 :
Total Pages : 550 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis The American Journal of Science by : Mrs. Gambold

Download or read book The American Journal of Science written by Mrs. Gambold and published by . This book was released on 2007 with total page 550 pages. Available in PDF, EPUB and Kindle. Book excerpt: