Two-stage, Close Coupled Catalytic Liquefaction of Coal. [Catalysts

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ISBN 13 :
Total Pages : 28 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Two-stage, Close Coupled Catalytic Liquefaction of Coal. [Catalysts by :

Download or read book Two-stage, Close Coupled Catalytic Liquefaction of Coal. [Catalysts written by and published by . This book was released on 1991 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall purpose of the program is to achieve higher yields of better quality transportation and turbine fuels and to lower the capital and production costs in order to make the products from direct coal liquefaction competitive with other fossil fuel products.

Two-stage, Close Coupled Catalytic Liquefaction of Coal. [Catalyst Used

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ISBN 13 :
Total Pages : 50 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Two-stage, Close Coupled Catalytic Liquefaction of Coal. [Catalyst Used by :

Download or read book Two-stage, Close Coupled Catalytic Liquefaction of Coal. [Catalyst Used written by and published by . This book was released on 1991 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first calendar quarter of 1991 was a productive period with two bench-scale studies, microautoclave support studies, mini-Process Development Unit (PDU) preparations, and process modelling. Several catalyst presulfiding agents and CO2 effects upon liquefaction were evaluated in microautoclave scale tests. Dimethyl disulfide will be used for the PDU scale-up based on the results of these tests and prior data. Carbon dioxide appears to enhance coal conversion; however, gas and water yields are increased indicating possible water gas shift-hydrocarbon synthesis reactions. In the bench-scale studies, the rejuvenation of spent catalyst with acid and carbon burn-off produced catalytic activity akin to fresh and catalyst in a 12 day evaluation. A 14 day study of the addition of high concentrations of CO2 to a sub-bituminous coal liquefaction system demonstrated the occurrence of water gas shift hydrocarbon synthesis reactions and conversely higher coal conversions and distillate yields with high hydrogen consumptions. Preparations for a PDU Demonstration Run on Black Thunder Mine coal are underway. The British Coal Filtration Process will be used for solid separation. The results of microautoclave scale tests on Illinois, Ohio and Black Thunder Mine coals were reviewed and statistically analyzed to provide a sound basis for kinetic interpretation.

Two-stage, Close Coupled Catalytic Liquefaction of Coal

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ISBN 13 :
Total Pages : 37 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Two-stage, Close Coupled Catalytic Liquefaction of Coal by :

Download or read book Two-stage, Close Coupled Catalytic Liquefaction of Coal written by and published by . This book was released on 1990 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the first quarter of 1990, work was carried out in the microautoclave, microreactor, and Bench-Scale units. An economics analysis on sub-bituminous coal processing at two space velocities was also completed. Several supported catalysts and a sample of iron oxide were screened in the microautoclave unsulfided and sulfided with DMDS and TNPS. A second shipment of Black Thunder coal from Wilsonville, oil agglomerated cleaned Illinois {number sign}6 coal from Homer City, OTISCA cleaned coal a New Mexico coal were evaluated for relative conversions with and without catalyst. Results of Bench-Scale developments with cleaned, oil agglomerated, Illinois {number sign}6 coal from Homer City(CC-6), Dispersed Catalyst/Supported Catalyst Two-Stage and reversed sequential operation (CC-7), on Black Thunder Coal (CC-7), and preliminary observations on OTISCA cleaned coal are presented. The oil agglomerated cleaned coal gave higher conversion and distillate production than the OTISCA cleaned coal. The Dispersed/Supported Two-Stage operation yielded higher gas production than the reverse sequence but also showed the higher coal conversion. Economic analysis of sub-bituminous coal processing at two space velocities showed a 3% higher return on investment with a 50% increase in space velocity. 13 tabs.

Two-stage, Closed Coupled Catalytic Liquefaction of Coal. Seventeeth Quarterly Report, 1 October 1992--31 December 1992

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ISBN 13 :
Total Pages : 24 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Two-stage, Closed Coupled Catalytic Liquefaction of Coal. Seventeeth Quarterly Report, 1 October 1992--31 December 1992 by :

Download or read book Two-stage, Closed Coupled Catalytic Liquefaction of Coal. Seventeeth Quarterly Report, 1 October 1992--31 December 1992 written by and published by . This book was released on 1992 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall purpose of the program is to achieve higher yields of better quality transportation and turbine fuels and to lower the capital and production costs in order to make the products from direct coal liquefaction competitive with other fossil fuel products. This quarterly report covers work on Laboratory Testing and Bench Scale Studies with Black Thunder and Illinois No. 6 coals. The major activities during this period were preparation and testing of FeOOH-impregnated Black Thunder coal in Bench Scale Run (CC-15) and evaluation of A060 (AKZO) NiMo extrudates with Illinois No. 6 coal (CC-1 6). Using a procedure developed by Pittsburgh Energy Technology Center approximately 1100 lbs. of iron-impregnated coal was prepared. This FEOOH impregnated coal was evaluated in a 14 day Bench Run (CC-15) with and without FeOOH. Results were promising with distillate yields of 60--66 Wt% MAF coal versus 57.4 Wt% without iron catalyst. The process consisted of FEOOH impregnated coal preparation and use of a pretreatment reactor plus a back-mixed first stage followed by a supported catalyst second stage. Since Shell 317 bimodal NiMo catalyst is no longer manufactured, Bench run CC-1 6 was conducted to evaluate A060 AKZO experimental catalyst. This catalyst was prepared in quantity and successfully tested in ebullated beds at Wilsonville. Results show the overall performance to be as good as Shell 317 and that A060 is a good substitute catalyst for future experimentation.

Two-stage, Close Coupled Catalytic Liquefaction of Coal. Tenth Quarterly Report, 1 January 1991--31 March 1991

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ISBN 13 :
Total Pages : 50 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Two-stage, Close Coupled Catalytic Liquefaction of Coal. Tenth Quarterly Report, 1 January 1991--31 March 1991 by :

Download or read book Two-stage, Close Coupled Catalytic Liquefaction of Coal. Tenth Quarterly Report, 1 January 1991--31 March 1991 written by and published by . This book was released on 1991 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first calendar quarter of 1991 was a productive period with two bench-scale studies, microautoclave support studies, mini-Process Development Unit (PDU) preparations, and process modelling. Several catalyst presulfiding agents and CO2 effects upon liquefaction were evaluated in microautoclave scale tests. Dimethyl disulfide will be used for the PDU scale-up based on the results of these tests and prior data. Carbon dioxide appears to enhance coal conversion; however, gas and water yields are increased indicating possible water gas shift-hydrocarbon synthesis reactions. In the bench-scale studies, the rejuvenation of spent catalyst with acid and carbon burn-off produced catalytic activity akin to fresh and catalyst in a 12 day evaluation. A 14 day study of the addition of high concentrations of CO2 to a sub-bituminous coal liquefaction system demonstrated the occurrence of water gas shift hydrocarbon synthesis reactions and conversely higher coal conversions and distillate yields with high hydrogen consumptions. Preparations for a PDU Demonstration Run on Black Thunder Mine coal are underway. The British Coal Filtration Process will be used for solid separation. The results of microautoclave scale tests on Illinois, Ohio and Black Thunder Mine coals were reviewed and statistically analyzed to provide a sound basis for kinetic interpretation.

Catalysts and Process Developments for Two-stage Liquefaction. Final Technical Report, October 1, 1989--September 30, 1992

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ISBN 13 :
Total Pages : 433 pages
Book Rating : 4.:/5 (873 download)

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Book Synopsis Catalysts and Process Developments for Two-stage Liquefaction. Final Technical Report, October 1, 1989--September 30, 1992 by :

Download or read book Catalysts and Process Developments for Two-stage Liquefaction. Final Technical Report, October 1, 1989--September 30, 1992 written by and published by . This book was released on 1992 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research in this project centered upon developing and evaluating catalysts and process improvements for coal liquefaction in the two-stage, close-coupled catalytic process. The major results are summarized here and they are described in more detail under each Task. In tasks for coal pretreatment and beneficiation, it was shown for coal handling that drying of both lignite or subbituminous coals using warm air, vacuum oven or exposing to air for long time was detrimental to subsequent liquefaction. Both laboratory and bench-scale beneficiations indicated that in order to achieve increased liquefaction yield for Illinois No. 6 bituminous coal, size separation with in sink-float technique should be used. For subbituminous coal, the best beneficiation was aqueous SO2 treatment, which reduced mineral matter. In the case of lignite, the fines should be rejected prior to aqueous SO2 treatment and sink-float gravity separation. In liquefying coals with supported catalysts in both first and second stages, coal conversion was highest (93%) with Illinois No. 6 coal, which also had the highest total liquid yield of 80%, however, the product contained unacceptably high level of resid (30%). Both low rank coals gave lower conversion (85--87%) and liquid yields (57--59%), but lighter products (no resid). The analysis of spent first stage catalysts indicated significant sodium and calcium deposits causing severe deactivation. The second stage catalysts were in better condition showing high surface areas and low coke and metal deposits. The use of dispersed catalyst in the first stage would combat the severe deactivation.

Catalysts and Process Developments for Two-stage Liquefaction. Second Quarterly Progress Report, April 1, 1992--June 30, 1992

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ISBN 13 :
Total Pages : 43 pages
Book Rating : 4.:/5 (683 download)

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Book Synopsis Catalysts and Process Developments for Two-stage Liquefaction. Second Quarterly Progress Report, April 1, 1992--June 30, 1992 by :

Download or read book Catalysts and Process Developments for Two-stage Liquefaction. Second Quarterly Progress Report, April 1, 1992--June 30, 1992 written by and published by . This book was released on 1992 with total page 43 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research under way in this project centers upon developing and evaluation catalysts and process improvements for coal liquefaction in the two-stage close-coupled catalytic process. The project is being carried out under contract to the United States Department of Energy. As discussed in the previous quarterly report, the results showed that C/T liquefaction is not a good option for Black Thunder subbituminous coal. In this quarter, the liquefaction of Black Thunder coal was continued. The studies showed that the combination of Wender's sulfated iron oxide with molybdenum is the most effective catalyst for this liquefaction. Compared with other iron/molybdenum catalysts, distillate yields were increased and the catalyst deactivation was not as severe as for the supported (extruded) catalysts.

Two-stage, Closed Coupled Catalytic Liquefaction of Coal. Sixteenth Quarterly Report, 1 July 1992-30 September 1992

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (88 download)

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Book Synopsis Two-stage, Closed Coupled Catalytic Liquefaction of Coal. Sixteenth Quarterly Report, 1 July 1992-30 September 1992 by :

Download or read book Two-stage, Closed Coupled Catalytic Liquefaction of Coal. Sixteenth Quarterly Report, 1 July 1992-30 September 1992 written by and published by . This book was released on 1992 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalysts and Process Development for Two-stage Liquefaction. First Quarterly Report, January 1, 1992--March 31, 1992

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ISBN 13 :
Total Pages : 42 pages
Book Rating : 4.:/5 (683 download)

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Book Synopsis Catalysts and Process Development for Two-stage Liquefaction. First Quarterly Report, January 1, 1992--March 31, 1992 by :

Download or read book Catalysts and Process Development for Two-stage Liquefaction. First Quarterly Report, January 1, 1992--March 31, 1992 written by and published by . This book was released on 1992 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research under way in this project centers upon developing and evaluating catalysts and process improvements for coal liquefaction in the two-stage, close-coupled catalytic process. The project is being carried out under contract to the United States Department of Energy. As discussed in the previous quarterly report, promising results were obtained by liquefying Illinois No. 6 bituminous and Black Thunder subbituminous coals using oil-soluble catalysts Molyvan L and molybdenum octoate. In this quarter, the liquefaction of Black Thunder coal was continued. Runs were made in catalytic/thermal (C/T) mode with supported AMOCAT{trademark} 1C (NiMo) and AMOCAT{trademark} 1B (Mo) catalysts. Although the initial performance in these runs was good (90% conversion with no resid production), both catalysts deactivated rapidly. Spent catalysts showed severe coke deposition as well as formation of a calcium-rich shell on the catalyst surface. Overall, C/T liquefaction is not a good process option for Black Thunder coal.

Two-stage, Close Coupled Catalytic Liquefaction of Coal. Eleventh Quarterly Report, 1 April 1991--30 June 1991

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ISBN 13 :
Total Pages : 28 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Two-stage, Close Coupled Catalytic Liquefaction of Coal. Eleventh Quarterly Report, 1 April 1991--30 June 1991 by :

Download or read book Two-stage, Close Coupled Catalytic Liquefaction of Coal. Eleventh Quarterly Report, 1 April 1991--30 June 1991 written by and published by . This book was released on 1991 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall purpose of the program is to achieve higher yields of better quality transportation and turbine fuels and to lower the capital and production costs in order to make the products from direct coal liquefaction competitive with other fossil fuel products.

Two-stage, Close Coupled Catalytic Liquefaction of Coal. Fourteenth Quarterly Report, 1 January 1992--31 March 1992

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ISBN 13 :
Total Pages : 28 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Two-stage, Close Coupled Catalytic Liquefaction of Coal. Fourteenth Quarterly Report, 1 January 1992--31 March 1992 by :

Download or read book Two-stage, Close Coupled Catalytic Liquefaction of Coal. Fourteenth Quarterly Report, 1 January 1992--31 March 1992 written by and published by . This book was released on 1992 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt: This quarterly report covers activities of the Two-Stage, Close- Coupled Catalytic Liquefaction of Coal program during the period January 1,--March 31,1992, at Hydrocarbon Research, Inc. in Lawrenceville and Princeton, New Jersey. This DOE contract period is from October 1, 1988 to September 30, 1992. The overall purpose of the program is to achieve higher yields of better quality transportation and turbine fuels and to lower the capital and production costs in order to make the products from direct coal liquefaction competitive with other fossil fuel products. The quarterly report covers work on Laboratory Testing, PDU Activities and Administration.

Synthetic Fuels from Coal

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Publisher : Springer Science & Business Media
ISBN 13 : 9781853331039
Total Pages : 398 pages
Book Rating : 4.3/5 (31 download)

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Book Synopsis Synthetic Fuels from Coal by : I. Romey

Download or read book Synthetic Fuels from Coal written by I. Romey and published by Springer Science & Business Media. This book was released on 1987 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fossil Energy Update

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ISBN 13 :
Total Pages : 936 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Fossil Energy Update by :

Download or read book Fossil Energy Update written by and published by . This book was released on 1982 with total page 936 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Energy Research Abstracts

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ISBN 13 :
Total Pages : 782 pages
Book Rating : 4.3/5 (129 download)

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Book Synopsis Energy Research Abstracts by :

Download or read book Energy Research Abstracts written by and published by . This book was released on 1995 with total page 782 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies. Final Report, [October 1, 1988--July 31, 1993].

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ISBN 13 :
Total Pages : 402 pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies. Final Report, [October 1, 1988--July 31, 1993]. by :

Download or read book Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) Process Bench Studies. Final Report, [October 1, 1988--July 31, 1993]. written by and published by . This book was released on 1993 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the final report of a four year and ten month contract starting on October 1, 1988 to July 31, 1993 with the US Department of Energy to study and improve Close-Coupled Catalytic Two-Stage Direct Liquefaction of coal by producing high yields of distillate with improved quality at lower capital and production costs in comparison to existing technologies. Laboratory, Bench and PDU scale studies on sub-bituminous and bituminous coals are summarized and referenced in this volume. Details are presented in the three topical reports of this contract; CTSL Process Bench Studies and PDU Scale-Up with Sub-Bituminous Coal-DE-88818-TOP-1, CTSL Process Bench Studies with Bituminous Coal-DE-88818-TOP-2, and CTSL Process Laboratory Scale Studies, Modelling and Technical Assessment-DE-88818-TOP-3. Results are summarized on experiments and studies covering several process configurations, cleaned coals, solid separation methods, additives and catalysts both dispersed and supported. Laboratory microautoclave scale experiments, economic analysis and modelling studies are also included along with the PDU-Scale-Up of the CTSL processing of sub-bituminous Black Thunder Mine Wyoming coal. During this DOE/HRI effort, high distillate yields were maintained at higher throughput rates while quality was markedly improved using on-line hydrotreating and cleaned coals. Solid separations options of filtration and delayed coking were evaluated on a Bench-Scale with filtration successfully scaled to a PDU demonstration. Directions for future direct coal liquefaction related work are outlined herein based on the results from this and previous programs.

Disposable Catalysts in Two-stage Coal Liquefaction

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ISBN 13 :
Total Pages : 166 pages
Book Rating : 4.:/5 (123 download)

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Book Synopsis Disposable Catalysts in Two-stage Coal Liquefaction by : Surya B. Reddy Karri

Download or read book Disposable Catalysts in Two-stage Coal Liquefaction written by Surya B. Reddy Karri and published by . This book was released on 1984 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Integrated Two-stage Coal Liquefaction Batch Catalyst Operations

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Total Pages : pages
Book Rating : 4.:/5 (226 download)

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Book Synopsis Integrated Two-stage Coal Liquefaction Batch Catalyst Operations by :

Download or read book Integrated Two-stage Coal Liquefaction Batch Catalyst Operations written by and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: