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Transitions From Near Surface To Interior Redox Upon Lithiation In Conversion Electrode Materials
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Book Synopsis Transitions from Near-surface to Interior Redox Upon Lithiation in Conversion Electrode Materials by :
Download or read book Transitions from Near-surface to Interior Redox Upon Lithiation in Conversion Electrode Materials written by and published by . This book was released on 2015 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoparticle electrodes in lithium-ion batteries have both near-surface and interior contributions to their redox capacity, each with distinct rate capabilities. Using combined electron microscopy, synchrotron X-ray methods and ab initio calculations, we have investigated the lithiation pathways that occur in NiO electrodes. We find that the near-surface electroactive (Ni22!i0) sites saturated very quickly, and then encounter unexpected difficulty in propagating the phase transition into the electrode (referred to as a "shrinking-core" mode). However, the interior capacity for Ni22!i0 can be accessed efficiently following the nucleation of lithiation "fingers" which propagate into the sample bulk, but only after a certain incubation time. Our microstructural observations of the transition from a slow shrinking-core mode to a faster lithiation finger mode corroborate with synchrotron characterization of large-format batteries, and can be rationalized by stress effects on transport at high-rate discharge. The finite incubation time of the lithiation fingers sets the intrinsic limitation for the rate capability (and thus the power) of NiO for electrochemical energy storage devices. The present work unravels the link between the nanoscale reaction pathways and the C-rate-dependent capacity loss, and provides guidance for the further design of battery materials that favors high C-rate charging.
Book Synopsis Nanobatteries and Nanogenerators by : Huaihe Song
Download or read book Nanobatteries and Nanogenerators written by Huaihe Song and published by Elsevier. This book was released on 2020-11-21 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt: The term ‘nanobattery’ can refer not only to the nanosized battery, but also to the uses of nanotechnology in a macro-sized battery for enhancing its performance and lifetime. Nanobatteries can offer many advantages over the traditional battery, including higher power density, shorter charging time, and longer shelf life. Nano-generators refer to the uses of nanosized devices and materials to convert mechanical, thermal and light-based energies into electricity. Similar to with traditional battery, in nanobatteries, the chemical energy is converted into electricity. This book addresses the fundamental design concepts and promising applications of nanobatteries and nanogenerators. Particular application areas include healthcare, biomedical, smart nanodevices and nanosensors, which may require new electric power sources, including self-powered ability and nanostructured electric power sources. In this regard, nanobatteries and nanogenerators represent the next generation of electric power. This is an important reference source for materials scientists, engineers and energy scientists, who are looking to increase their understanding of how nanotechnology is being used to create new energy storage and generation solutions. Outlines the major design and fabrication principles and techniques for creating nano-sized batteries and generators Demonstrates how nanotechnology is being used to make batteries and generators more powerful and longer lasting Assesses the challenges of mass manufacturing nanobatteries and nanogenerators
Book Synopsis Electrode Materials for Energy Storage and Conversion by : Mesfin A. Kebede
Download or read book Electrode Materials for Energy Storage and Conversion written by Mesfin A. Kebede and published by CRC Press. This book was released on 2021-11-17 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview of the latest developments and materials used in electrochemical energy storage and conversion devices, including lithium-ion batteries, sodium-ion batteries, zinc-ion batteries, supercapacitors and conversion materials for solar and fuel cells. Chapters introduce the technologies behind each material, in addition to the fundamental principles of the devices, and their wider impact and contribution to the field. This book will be an ideal reference for researchers and individuals working in industries based on energy storage and conversion technologies across physics, chemistry and engineering. FEATURES Edited by established authorities, with chapter contributions from subject-area specialists Provides a comprehensive review of the field Up to date with the latest developments and research Editors Dr. Mesfin A. Kebede obtained his PhD in Metallurgical Engineering from Inha University, South Korea. He is now a principal research scientist at Energy Centre of Council for Scientific and Industrial Research (CSIR), South Africa. He was previously an assistant professor in the Department of Applied Physics and Materials Science at Hawassa University, Ethiopia. His extensive research experience covers the use of electrode materials for energy storage and energy conversion. Prof. Fabian I. Ezema is a professor at the University of Nigeria, Nsukka. He obtained his PhD in Physics and Astronomy from University of Nigeria, Nsukka. His research focuses on several areas of materials science with an emphasis on energy applications, specifically electrode materials for energy conversion and storage.
Book Synopsis Thin Films for Energy Harvesting, Conversion, and Storage by : Zhong Chen
Download or read book Thin Films for Energy Harvesting, Conversion, and Storage written by Zhong Chen and published by MDPI. This book was released on 2019-11-07 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt: Efficient clean energy harvesting, conversion, and storage technologies are of immense importance for the sustainable development of human society. To this end, scientists have made significant advances in recent years regarding new materials and devices for improving the energy conversion efficiency for photovoltaics, thermoelectric generation, photoelectrochemical/electrolytic hydrogen generation, and rechargeable metal ion batteries. The aim of this Special Issue is to provide a platform for research scientists and engineers in these areas to demonstrate and exchange their latest research findings. This thematic topic undoubtedly represents an extremely important technological direction, covering materials processing, characterization, simulation, and performance evaluation of thin films used in energy harvesting, conversion, and storage.
Book Synopsis Liquid Cell Electron Microscopy by : Frances M. Ross
Download or read book Liquid Cell Electron Microscopy written by Frances M. Ross and published by Cambridge University Press. This book was released on 2017 with total page 529 pages. Available in PDF, EPUB and Kindle. Book excerpt: 2.6.2 Electrodes for Electrochemistry
Book Synopsis Nanomaterials for Lithium-Ion Batteries by : Rachid Yazami
Download or read book Nanomaterials for Lithium-Ion Batteries written by Rachid Yazami and published by CRC Press. This book was released on 2013-10-08 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the most recent advances in the science and technology of nanostructured materials for lithium-ion application. With contributions from renowned scientists and technologists, the chapters discuss state-of-the-art research on nanostructured anode and cathode materials, some already used in commercial batteries and others still in de
Book Synopsis Principles and Applications of Lithium Secondary Batteries by : Jung-Ki Park
Download or read book Principles and Applications of Lithium Secondary Batteries written by Jung-Ki Park and published by John Wiley & Sons. This book was released on 2012-06-13 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium secondary batteries have been key to mobile electronics since 1990. Large-format batteries typically for electric vehicles and energy storage systems are attracting much attention due to current energy and environmental issues. Lithium batteries are expected to play a central role in boosting green technologies. Therefore, a large number of scientists and engineers are carrying out research and development on lithium secondary batteries. The book is written in a straightforward fashion suitable for undergraduate and graduate students, as well as scientists, and engineers starting out in the field. The chapters in this book have been thoroughly edited by a collective of experts to achieve a cohesive book with a consistent style, level, and philosophy. They cover a wide range of topics, including principles and technologies of key materials such as the cathode, anode, electrolyte, and separator. Battery technologies such as design, manufacturing processes, and evaluation methods as well as applications are addressed. In addition, analytical methods for determining electrochemical and other properties of batteries are also included. Hence, this book is a must-have for everyone interested in obtaining all the basic information on lithium secondary batteries.
Book Synopsis Lithium Batteries by : Gholam-Abbas Nazri
Download or read book Lithium Batteries written by Gholam-Abbas Nazri and published by Springer Science & Business Media. This book was released on 2009-01-14 with total page 725 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium Batteries: Science and Technology is an up-to-date and comprehensive compendium on advanced power sources and energy related topics. Each chapter is a detailed and thorough treatment of its subject. The volume includes several tutorials and contributes to an understanding of the many fields that impact the development of lithium batteries. Recent advances on various components are included and numerous examples of innovation are presented. Extensive references are given at the end of each chapter. All contributors are internationally recognized experts in their respective specialty. The fundamental knowledge necessary for designing new battery materials with desired physical and chemical properties including structural, electronic and reactivity are discussed. The molecular engineering of battery materials is treated by the most advanced theoretical and experimental methods.
Book Synopsis Studies on Anionic Redox in Li-Rich Cathode Materials of Li-Ion Batteries by : Biao Li
Download or read book Studies on Anionic Redox in Li-Rich Cathode Materials of Li-Ion Batteries written by Biao Li and published by Springer. This book was released on 2018-12-13 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents studies and discussions on anionic redox, which can be used to boost the capacities of cathode electrodes by providing extra electron transfer. This theoretically and practically significant book facilitates the implementation of anionic redox in electrodes for real-world use and accelerates the development of high-energy-density lithium-ion batteries. Lithium-ion batteries, as energy storage systems, are playing a more and more important role in powering modern society. However, their energy density is still limited by the low specific capacity of the cathode electrodes. Based on a profound understanding of band theory, the author has achieved considerable advances in tuning the redox process of lithium-rich electrodes to obtain enhanced electrochemical performance, identifying both the stability mechanism of anionic redox in lithium-rich cathode materials, and its activation mechanism in these electrode systems.
Book Synopsis Handbook of Advanced Ceramics and Composites by : Yashwant Mahajan
Download or read book Handbook of Advanced Ceramics and Composites written by Yashwant Mahajan and published by Springer. This book was released on 2020-11-26 with total page 1527 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook presents an authoritative account of the potential of advanced ceramics and composites in strategic applications, including defense, national security, aerospace, and energy security (especially nuclear energy). It highlights how their unique combination of superior properties such as low density, high strength, high elastic modulus, high hardness, high temperature capability, and excellent chemical and environmental stability are optimized in technologies within these fields. The handbook is organized according to application type. It allows readers to learn about strategies that have been used in different fields and to transfer them to their own. The book addresses a wide variety of ceramics and their composites, including PZT ceramics, carbon nanotubes, aerogels, silica radomes, relaxor ferroelectrics, and many others.
Book Synopsis Nanomaterials For Energy Conversion And Storage by : Dunwei Wang
Download or read book Nanomaterials For Energy Conversion And Storage written by Dunwei Wang and published by World Scientific. This book was released on 2017-11-10 with total page 836 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of nanomaterials in energy conversion and storage represents an opportunity to improve the performance, density and ease of transportation in renewable resources. This book looks at the most recent research on the topic, with particular focus on artificial photosynthesis and lithium-ion batteries as the most promising technologies to date. Research on the broad subject of energy conversion and storage calls for expertise from a wide range of backgrounds, from the most fundamental perspectives of the key catalytic processes at the molecular level to device scale engineering and optimization. Although the nature of the processes dictates that electrochemistry is a primary characterization tool, due attention is given to advanced techniques such as synchrotron studies in operando. These studies look at the gap between the performance of current technology and what is needed for the future, for example how to improve on the lithium-ion battery and to go beyond its capabilities.Suitable for students and practitioners in the chemical, electrochemical, and environmental sciences, Nanomaterials for Energy Conversion and Storage provides the information needed to find scalable, economically viable and safe solutions for sustainable energy.
Download or read book Na-ion Batteries written by and published by John Wiley & Sons. This book was released on 2021-05-11 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers both the fundamental and applied aspects of advanced Na-ion batteries (NIB) which have proven to be a potential challenger to Li-ion batteries. Both the chemistry and design of positive and negative electrode materials are examined. In NIB, the electrolyte is also a crucial part of the batteries and the recent research, showing a possible alternative to classical electrolytes – with the development of ionic liquid-based electrolytes – is also explored. Cycling performance in NIB is also strongly associated with the quality of the electrode-electrolyte interface, where electrolyte degradation takes place; thus, Na-ion Batteries details the recent achievements in furthering knowledge of this interface. Finally, as the ultimate goal is commercialization of this new electrical storage technology, the last chapters are dedicated to the industrial point of view, given by two startup companies, who developed two different NIB chemistries for complementary applications and markets.
Book Synopsis Electrochemical Energy Storage by : Jean-Marie Tarascon
Download or read book Electrochemical Energy Storage written by Jean-Marie Tarascon and published by John Wiley & Sons. This book was released on 2015-02-23 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt: The electrochemical storage of energy has become essential in assisting the development of electrical transport and use of renewable energies. French researchers have played a key role in this domain but Asia is currently the market leader. Not wanting to see history repeat itself, France created the research network on electrochemical energy storage (RS2E) in 2011. This book discusses the launch of RS2E, its stakeholders, objectives, and integrated structure that assures a continuum between basic research, technological research and industries. Here, the authors will cover the technological advances as well as the challenges that must still be resolved in the field of electrochemical storage, taking into account sustainable development and the limited time available to us.
Book Synopsis Lithium Ion Rechargeable Batteries by : Kazunori Ozawa
Download or read book Lithium Ion Rechargeable Batteries written by Kazunori Ozawa and published by John Wiley & Sons. This book was released on 2012-01-09 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: Starting out with an introduction to the fundamentals of lithium ion batteries, this book begins by describing in detail the new materials for all four major uses as cathodes, anodes, separators, and electrolytes. It then goes on to address such critical issues as self-discharge and passivation effects, highlighting lithium ion diffusion and its profound effect on a battery's power density, life cycle and safety issues. The monograph concludes with a detailed chapter on lithium ion battery use in hybrid electric vehicles. Invaluable reading for materials scientists, electrochemists, physicists, and those working in the automobile and electrotechnical industries, as well as those working in computer hardware and the semiconductor industry.
Book Synopsis Redox Flow Batteries by : Huamin Zhang
Download or read book Redox Flow Batteries written by Huamin Zhang and published by CRC Press. This book was released on 2017-11-22 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: Flow batteries have received attention in large-scale energy storage due to their flexible design, high safety, high energy efficiency, and environmental friendliness. In recent years, they have been rapidly developed and tested in a variety of scales that prove their feasibility and advantages of use. As energy becomes a global focus, it is important to consider flow battery systems. This book offers a detailed introduction to the function of different kinds of redox flow batteries, including vanadium flow batteries, as well as the electrochemical processes for their development, materials and components, applications, and near future prospects. Redox Flow Batteries: Fundamentals and Applications will give readers a full understanding of flow batteries from fundamentals to commercial applications.
Book Synopsis Lithium-ion Batteries by : Perla B. Balbuena
Download or read book Lithium-ion Batteries written by Perla B. Balbuena and published by World Scientific. This book was released on 2004 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.
Book Synopsis Electrodes for Li-ion Batteries by : Laure Monconduit
Download or read book Electrodes for Li-ion Batteries written by Laure Monconduit and published by John Wiley & Sons. This book was released on 2015-06-29 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt: The electrochemical energy storage is a means to conserve electrical energy in chemical form. This form of storage benefits from the fact that these two energies share the same vector, the electron. This advantage allows us to limit the losses related to the conversion of energy from one form to another. The RS2E focuses its research on rechargeable electrochemical devices (or electrochemical storage) batteries and supercapacitors. The materials used in the electrodes are key components of lithium-ion batteries. Their nature depend battery performance in terms of mass and volume capacity, energy density, power, durability, safety, etc. This book deals with current and future positive and negative electrode materials covering aspects related to research new and better materials for future applications (related to renewable energy storage and transportation in particular), bringing light on the mechanisms of operation, aging and failure.
