Transition Metal Clusters

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Transition Metal Carbonyl Cluster Chemistry

Author : Paul J. Dyson
Publisher : CRC Press
ISBN 13 : 1482283077
Total Pages : 180 pages
Book Rating : 4.4/5 (822 download)

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Book Synopsis Transition Metal Carbonyl Cluster Chemistry by : Paul J. Dyson

Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Cluster Chemistry

Author : Guillermo Gonzalez-Moraga
Publisher : Springer Science & Business Media
ISBN 13 : 3642859267
Total Pages : 310 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Cluster Chemistry by : Guillermo Gonzalez-Moraga

Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.

Transition Metal Clusters

Author : Brian F. Johnson
Publisher :
ISBN 13 : 9780783776514
Total Pages : 693 pages
Book Rating : 4.7/5 (765 download)

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Book Synopsis Transition Metal Clusters by : Brian F. Johnson

Download or read book Transition Metal Clusters written by Brian F. Johnson and published by . This book was released on 1980 with total page 693 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Progress in the Physics of Clusters

Author : Gennady N. Chuev
Publisher : World Scientific
ISBN 13 : 9789810236601
Total Pages : 524 pages
Book Rating : 4.2/5 (366 download)

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Book Synopsis Progress in the Physics of Clusters by : Gennady N. Chuev

Download or read book Progress in the Physics of Clusters written by Gennady N. Chuev and published by World Scientific. This book was released on 1999 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: The findings reported in this book on the methods of cluster measurements will lead to new avenues using nondestructive mass spectrometry and dipole mass isomers. Much attention is given to the physics and chemistry of fullerenes and nanotubes, including the problems surrounding the formation and growth of nanotubes, electron characteristics of fullerenes, the influence of solvents, simulation of the properties of carbon clusters, etc. Some unique experimental data on the conversion of aerosols into aerogels with the formation of fractal structures is provided. In addition, the book covers one of the most interesting subjects of modern physics -- fractal clusters.

Molecular Clusters

Author : Thomas Fehlner
Publisher : Cambridge University Press
ISBN 13 : 1107320836
Total Pages : 388 pages
Book Rating : 4.1/5 (73 download)

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Book Synopsis Molecular Clusters by : Thomas Fehlner

Download or read book Molecular Clusters written by Thomas Fehlner and published by Cambridge University Press. This book was released on 2007-07-05 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Clusters can be viewed as solids at the nano-scale, yet molecular cluster chemistry and solid state chemistry have traditionally been considered as separate topics. This treatment has made it conceptually difficult to appreciate commonalities of structure and bonding between the two. Using analogous models, this is the first book to form a connecting bridge. Although the focus is on clusters, sufficient attention is paid to solid-state compounds at each stage of the development to establish the interrelationship between the two topics. Comprehensive coverage of cluster types by composition, size and ligation, is provided, as is a synopsis of selected research. Written in an accessible style and highly illustrated to aid understanding, this book is suitable for researchers in inorganic chemistry, physical chemistry, materials science, and condensed matter physics.

Catalysis by Di- and Polynuclear Metal Cluster Complexes

Author : Richard D. Adams
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 586 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Catalysis by Di- and Polynuclear Metal Cluster Complexes by : Richard D. Adams

Download or read book Catalysis by Di- and Polynuclear Metal Cluster Complexes written by Richard D. Adams and published by Wiley-VCH. This book was released on 1998-03-16 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt: A pioneer work on catalysis of organic chemical reactions involving multinuclear metal complexes. Catalysis by Di- and Polynuclear Metal Cluster Complexes surveys the latest developments at the frontier of this exciting field, combining theory with new and original examples of catalytic processes produced by polynuclear metal complexes. An invaluable resource for inorganic and organometallic chemists in industry and R&D, it contains chapters from world experts and scholars on: Concepts and models for characterizing homogeneous reactions catalyzed by transition metal cluster complexes Activation of ruthenium clusters for use in catalysis Catalysis by mixed metal clusters containing gold phosphine groupings Catalysis by sulfido bridged dimolybdenum complexes Dimolybdenum and ditungsten complexes Synthesis of organic compounds catalyzed by transition metal clusters Catalysis with dirhodium (II) complexes Catalytic synthesis of polythioether macrocycles Catalysis of Rh, Rh-Co, and Ir-Co multinuclear complexes and its applications to organic syntheses Bimetallic hydroformylation catalysis Catalysis by colloids Catalysis with palladium clusters Heterometallic clusters for heterogeneous catalysis Supported clusters in catalysis.

The Chemistry of Metal Cluster Complexes

Author : Duward F. Shriver
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 456 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Chemistry of Metal Cluster Complexes by : Duward F. Shriver

Download or read book The Chemistry of Metal Cluster Complexes written by Duward F. Shriver and published by Wiley-VCH. This book was released on 1990 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR

Transition Metal Clusters

Author : Brian Frederick Gilbert Johnson
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 702 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Transition Metal Clusters by : Brian Frederick Gilbert Johnson

Download or read book Transition Metal Clusters written by Brian Frederick Gilbert Johnson and published by John Wiley & Sons. This book was released on 1980 with total page 702 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Clusters and Colloids

Author : Günter Schmid
Publisher : John Wiley & Sons
ISBN 13 : 3527616063
Total Pages : 570 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Clusters and Colloids by : Günter Schmid

Download or read book Clusters and Colloids written by Günter Schmid and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the rapidly developing field of cluster science. In an interdisciplinary approach, basic concepts as well as recent developments in research and practical applications are authoritatively discussed by leading authors. Topics covered include 'naked' metal clusters, clusters stabilized by ligands, clusters in solids, and colloids. The reader will find answers to questions like: * How many metal atoms must a particle have to exhibit metallic properties? * How can the large specific surface of clusters and colloids be employed in catalysts? * How can metal clusters be introduced into solid hosts? * Which effects are responsible for the transition from isolated to condensed clusters? The editor has succeeded in bringing the contributions of various authors together into a homogeneous, readable book, which will be useful for the academic and industrial reader alike.

Ligated Transition Metal Clusters in Solid-state Chemistry

Author : Jean-François Halet
Publisher : Springer Nature
ISBN 13 : 3030251241
Total Pages : 201 pages
Book Rating : 4.0/5 (32 download)

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Book Synopsis Ligated Transition Metal Clusters in Solid-state Chemistry by : Jean-François Halet

Download or read book Ligated Transition Metal Clusters in Solid-state Chemistry written by Jean-François Halet and published by Springer Nature. This book was released on 2019-08-29 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume dedicated to the memory of Marcel Sergent who was a leader in this field for many years, addresses past achievements and recent developments in this vibrant area of research. Large classes of ligated transition metal clusters are produced either exclusively or most reliably by means of high-temperature solid-state reactions. Among them, the Chevrel-Sergent phases and related materials have generated enormous interest since their discovery in 1971. Today, these materials and their numerous derivatives still constitute a vivid area of research finding some applications not only in superconductivity, but also in catalysis, optics or thermoelectricity to mention a few.

Metal Nanoparticles and Clusters

Author : Francis Leonard Deepak
Publisher : Springer
ISBN 13 : 3319680536
Total Pages : 426 pages
Book Rating : 4.3/5 (196 download)

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Book Synopsis Metal Nanoparticles and Clusters by : Francis Leonard Deepak

Download or read book Metal Nanoparticles and Clusters written by Francis Leonard Deepak and published by Springer. This book was released on 2017-11-17 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the continually expanding field of metal nanoparticles and clusters, in particular their size-dependent properties and quantum phenomena. The approaches to the organization of atoms that form clusters and nanoparticles have been advancing rapidly in recent times. These advancements are described through a combination of experimental and computational approaches and are covered in detail by the authors. Recent highlights of the various emerging properties and applications ranging from plasmonics to catalysis are showcased.

A Textbook of Inorganic Chemistry – Volume 1

Author : Mandeep Dalal
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 480 pages
Book Rating : 4.1/5 (938 download)

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Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal

Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Inorganic Syntheses, Volume 34

Author :
Publisher : John Wiley & Sons
ISBN 13 : 0471653675
Total Pages : 284 pages
Book Rating : 4.4/5 (716 download)

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Book Synopsis Inorganic Syntheses, Volume 34 by :

Download or read book Inorganic Syntheses, Volume 34 written by and published by John Wiley & Sons. This book was released on 2004-07-12 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series provides inorganic chemists with detailed and foolproof procedures for the preparation of important and timely compounds. Volume 34 continues to report such procedures with an up-to-date selection of contributions by internationally-recognized researchers, including the following:

Transition Metal Sulphides

Author : Th. Weber
Publisher : Springer Science & Business Media
ISBN 13 : 9401735778
Total Pages : 357 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Transition Metal Sulphides by : Th. Weber

Download or read book Transition Metal Sulphides written by Th. Weber and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrotreating catalysis with transition metal sulphides is one of the most important areas of industrial heterogeneous catalysis. The present book deals with the chemical and catalytic aspects of transition metal sulphides, focusing on their use in hydrotreating catalysis. The book¿s 12 chapters present reviews of solid-state, coordination and organometallic chemistry, surface science and spectroscopic studies, quantum chemical calculations, catalytic studies with model and real catalysts, as well as refinery processes. A presentation of state-of-the-art background to pertinent work in the field. Can be used as an introduction to the chemical and catalytic properties of transition metal sulphides as well as an advanced level reference.

Early Transition Metal Clusters with [pi]-donor Ligands

Author : Malcolm H. Chisholm
Publisher :
ISBN 13 :
Total Pages : 376 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Early Transition Metal Clusters with [pi]-donor Ligands by : Malcolm H. Chisholm

Download or read book Early Transition Metal Clusters with [pi]-donor Ligands written by Malcolm H. Chisholm and published by . This book was released on 1995 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal Clusters at Surfaces

Author : Karl-Heinz Meiwes-Broer
Publisher : Springer Science & Business Media
ISBN 13 : 9783540665625
Total Pages : 332 pages
Book Rating : 4.6/5 (656 download)

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Book Synopsis Metal Clusters at Surfaces by : Karl-Heinz Meiwes-Broer

Download or read book Metal Clusters at Surfaces written by Karl-Heinz Meiwes-Broer and published by Springer Science & Business Media. This book was released on 2000-04-05 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: Numerous experiments and calculations have shown that isolated metal clusters possess many interesting features, quite different from those known from surface and solid- state physics or from atomic and molecular physics. The technological exploitation of these new properties, e.g. in miniature electronic or mechanical components, requires the cluster to be brought into an environment such as an encapsulating matrix or a surface. Due to the interaction with the contact medium, the properties of the clusters may change or even disappear. Thus the physics of cluster-on-surface systems -- the main subject of this book -- is of fundamental importance. The book addresses a wide audience, from the newcomer to the expert. Starting from fundamental concepts of adsorbate-surface interactions, the modification of electronic properties through electron confinement, and concepts of cluster production, it elucidates the distinct properties of the new metallic nanostructures.

Modern Perspectives in Inorganic Crystal Chemistry

Author : Erwin Parthé
Publisher : Springer Science & Business Media
ISBN 13 : 9401127263
Total Pages : 283 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Modern Perspectives in Inorganic Crystal Chemistry by : Erwin Parthé

Download or read book Modern Perspectives in Inorganic Crystal Chemistry written by Erwin Parthé and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of crystal structures has had an ever increasing impact on many fields of science such as physics, chemistry, biology, materials science, medicine, pharmacy, metallurgy, mineralogy and geology. Particularly, with the advent of direct methods of structure determination, the data on crystal structures are accumulating at an unbelievable pace and it becomes more and more difficult to oversee this wealth of data. A crude rationalization of the structures of organic compounds and the atom coordinations can be made with the well-known Kekule model, however, no such generally applicable model exists for the structures of inorganiC and particularly intermetallic compounds. There is a need to rationalize the inorganic crystal structures, to find better ways of describing them, of denoting the geometrical relationships between them, of elucidating the electronic factors and of explaining the bonding between the atoms with the aim of not only having a better understanding of the known structures, but also of predicting structural features of new compounds.