Laser Spectroscopy of Highly Vibrationally Excited Molecules

Download Laser Spectroscopy of Highly Vibrationally Excited Molecules PDF Online Free

Author :
Publisher : CRC Press
ISBN 13 : 1000445127
Total Pages : 397 pages
Book Rating : 4.0/5 (4 download)

DOWNLOAD NOW!


Book Synopsis Laser Spectroscopy of Highly Vibrationally Excited Molecules by : Vladilen Stepanovich Letokhov

Download or read book Laser Spectroscopy of Highly Vibrationally Excited Molecules written by Vladilen Stepanovich Letokhov and published by CRC Press. This book was released on 2021-07-28 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt: Laser spectroscopy has been perfected over the last fifteen years to become a precise tool for the investigation of highly vibrationally excited molecules. Intense infrared laser radiation permits both the multiple-photon resonant excitation and the dissociation of polyatomic molecules. In this book, the latest results of some of the foremost Soviet researchers are published for the first time in the West. Laser Spectroscopy of Highly Vibrationally Excited Molecules contains a comprehensive study of both the experimental and theoretical aspects of the basic photophysical interactions that occur in these processes. The book first focuses on the nonlinear interaction between the resonant vibrational mode and the intense infrared field and then examines the nonlinear interaction between the vibrational modes themselves due to anharmonicity. These interrelated processes determine all the characteristics of polyatomic molecules in an infrared field. The book also discusses related phenomena such as spectra broadening, optical resonance, photon echoes, and dynamical chaos. It includes examples of multiple-photon resonant excitation such as the excitation of OsO4 by CO^O2 laser radiation, which is detected by the visible luminescence that results. This book will be of great interest to researchers and postgraduate students in infrared laser spectroscopy and the laser chemistry of molecules and applications of isotope separation.

Topics in Fluorescence Spectroscopy

Download Topics in Fluorescence Spectroscopy PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 0306470705
Total Pages : 555 pages
Book Rating : 4.3/5 (64 download)

DOWNLOAD NOW!


Book Synopsis Topics in Fluorescence Spectroscopy by : Joseph R. Lakowicz

Download or read book Topics in Fluorescence Spectroscopy written by Joseph R. Lakowicz and published by Springer Science & Business Media. This book was released on 2006-04-18 with total page 555 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluorescence spectroscopy continues its advance to more sophisticated methods and applications. As one looks over the previous decades, its appears that the first practical instruments for time-resolved measurements appeared in the 1970’s. The instrumentation and analysis methods for time-resolved fluorescence advanced rapidly throughout the 1980’s. Since 1990 we have witnessed a rapid migration of the principles of time-resolved fluorescence to cell biology and clinical appli- tions. Most recently, we have seen the introduction of multi-photon excitation, pump-probe and stimulated emission methods for studies of biological mac- molecules and for cellular imaging. These advanced topics are the subject of the present volume. Two-photon excitation was first predicted by Maria Goppert-Mayer in 1931, but was not experimentally observed until 1961. Observation of two-photon excitation required the introduction of lasers which provided adequate photon density for multi-photon absorption. Since the early observations of two-photon excitation in the 1960s, multi-photon spectroscopy has been limited to somewhat exotic applications of chemical physics, where it is used to study the electronic symmetry of small molecules. Placing one’s self back in 1980, it would be hard to imagine the use of multi-photon excitation in biophysics or cellular imaging.

Strategies for Planar Laser-induced Fluorescence Thermometry in Shock Tube Flows

Download Strategies for Planar Laser-induced Fluorescence Thermometry in Shock Tube Flows PDF Online Free

Author :
Publisher : Stanford University
ISBN 13 :
Total Pages : 151 pages
Book Rating : 4.F/5 ( download)

DOWNLOAD NOW!


Book Synopsis Strategies for Planar Laser-induced Fluorescence Thermometry in Shock Tube Flows by : Ji Hyung Yoo

Download or read book Strategies for Planar Laser-induced Fluorescence Thermometry in Shock Tube Flows written by Ji Hyung Yoo and published by Stanford University. This book was released on 2011 with total page 151 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis was motivated by the need to better understand the temperature distribution in shock tube flows, especially in the near-wall flow regions. Two main ideas in planar laser-induced fluorescence (PLIF) diagnostics are explored in this thesis. The first topic is the development of a single-shot PLIF diagnostic technique for quantitative temperature distribution measurement in shock tube flow fields. PLIF is a non-intrusive, laser-based diagnostic technique capable of instantaneously imaging key flow features, such as temperature, pressure, density, and species concentration, by measuring fluorescence signal intensity from laser-excited tracer species. This study performed a comprehensive comparison of florescence tracers and excitation wavelengths to determine the optimal combination for PLIF imaging in shock tube flow applications. Excitation of toluene at 248nm wavelength was determined to be the optimal strategy due to the resulting high temperature sensitivity and fluorescence signal level, compared to other ketone and aromatic tracers at other excitation wavelengths. Sub-atmospheric toluene fluorescence yield data was measured to augment the existing photophysical data necessary for this diagnostic technique. In addition, a new imaging test section was built to allow PLIF imaging in all regions of the shock tube test section, including immediately adjacent to the side and end walls. The signal-to-noise (SNR) and spatial resolution of the PLIF images were optimized using statistical analysis. Temperature field measurements were made with the PLIF diagnostic technique across normal incident and reflected shocks in the shock tube core flow. The resulting images show uniform spatial distribution, and good agreement with conditions calculated from the normal shock jump equations. Temperature measurement uncertainty is about 3.6% at 800K. The diagnostic was also applied to image flow over a wedge. The resulting images capture all the flow features predicted by numerical simulations. The second topic is the development of a quantitative near-wall diagnostic using tracer-based PLIF imaging. Side wall thermal boundary layers and end wall thermal layers are imaged to study the temperature distribution present under constant pressure conditions. The diagnostic technique validated in the shock tube core flow region was further optimized to improve near-wall image quality. The optimization process considered various wall materials, laser sheet orientations, camera collection angles, and optical components to find the configuration that provides the best images. The resulting images have increased resolution (15[Mu]m) and are able to resolve very thin non-uniform near-wall temperature layers (down to 60[Mu]m from the surface). The temperature field and thickness measurements of near-wall shock tube flows under various shock conditions and test gases showed good agreement with boundary layer theory. To conclude this thesis, new applications and future improvements to the developed PLIF diagnostic technique are discussed. These suggested refinements can provide an even more robust and versatile PLIF imaging technique capable of measuring a wider range of flow conditions near walls.

Encyclopedia of Chemical Physics and Physical Chemistry

Download Encyclopedia of Chemical Physics and Physical Chemistry PDF Online Free

Author :
Publisher : CRC Press
ISBN 13 : 1003803288
Total Pages : 986 pages
Book Rating : 4.0/5 (38 download)

DOWNLOAD NOW!


Book Synopsis Encyclopedia of Chemical Physics and Physical Chemistry by : John H. Moore

Download or read book Encyclopedia of Chemical Physics and Physical Chemistry written by John H. Moore and published by CRC Press. This book was released on 2023-07-03 with total page 986 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia of Physical Chemistry and Chemical Physics introduces possibly unfamiliar areas, explains important experimental and computational techniques, and describes modern endeavors. The encyclopedia quickly provides the basics, defines the scope of each subdiscipline, and indicates where to go for a more complete and detailed explanation. Particular attention has been paid to symbols and abbreviations to make this a user-friendly encyclopedia. Care has been taken to ensure that the reading level is suitable for the trained chemist or physicist. The encyclopedia is divided in three major sections: FUNDAMENTALS: the mechanics of atoms and molecules and their interactions, the macroscopic and statistical description of systems at equilibrium, and the basic ways of treating reacting systems. The contributions in this section assume a somewhat less sophisticated audience than the two subsequent sections. At least a portion of each article inevitably covers material that might also be found in a modern, undergraduate physical chemistry text. METHODS: the instrumentation and fundamental theory employed in the major spectroscopic techniques, the experimental means for characterizing materials, the instrumentation and basic theory employed in the study of chemical kinetics, and the computational techniques used to predict the static and dynamic properties of materials. APPLICATIONS: specific topics of current interest and intensive research. For the practicing physicist or chemist, this encyclopedia is the place to start when confronted with a new problem or when the techniques of an unfamiliar area might be exploited. For a graduate student in chemistry or physics, the encyclopedia gives a synopsis of the basics and an overview of the range of activities in which physical principles are applied to chemical problems. It will lead any of these groups to the salient points of a new field as rapidly as possible and gives pointers as to where to read about the topic in more detail.

Nonequilibrium Vibrational Kinetics

Download Nonequilibrium Vibrational Kinetics PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642486150
Total Pages : 354 pages
Book Rating : 4.6/5 (424 download)

DOWNLOAD NOW!


Book Synopsis Nonequilibrium Vibrational Kinetics by : Mario Capitelli

Download or read book Nonequilibrium Vibrational Kinetics written by Mario Capitelli and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is devoted to the systematic treatment of nonequi 1 ibrium vibrational kinetics in molecular systems. Particular emphasis is given to the vibrational excitation of diatomic molecules by low-energy electrons in a discharge and by IR photons in laser-pumped systems. The book follows the different steps of the introduction, redistribution, loss, and chemical conversion of the vibrational quanta, from the points of view of the overall kinetics and the dynamics of elementary processes. These two aspects are balanced in a multidisciplinary approach. The different chapters give the basic instruments (theoretical and experimental) which are needed to understand the ki netics of nonequilibrium systems. The book will introduce the reader to different areas such as plasmachemistry, laser chemistry, IR and Raman spectroscopy, and relaxation phenomena, emphasizing how the vibrational energy affects such research fields. The chapters dedicated to collisional dynamics involving vibrational excited molecules provide an introduc tion to the modern techniques uti 1 ized in the scattering theory of inelastic and reactive collisions. The extension of the vibrational kinetics to polyatomic mole cules, discussed in Chap. 10, is the natural bridge between coll ision and coll i sionless regimes. In conclusion, we hope that the approach followed in this book will stimulate the collaboration of researchers coming from different research fields, which are too often completely separate.

Theory of Chemical Reaction Dynamics

Download Theory of Chemical Reaction Dynamics PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 1402021658
Total Pages : 498 pages
Book Rating : 4.4/5 (2 download)

DOWNLOAD NOW!


Book Synopsis Theory of Chemical Reaction Dynamics by : Antonio Laganà

Download or read book Theory of Chemical Reaction Dynamics written by Antonio Laganà and published by Springer Science & Business Media. This book was released on 2006-03-28 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Research Workshop, held in Balatonföldvár, Hungary, 8-12 June 2003

The Formation and Decay of Excited Species

Download The Formation and Decay of Excited Species PDF Online Free

Author :
Publisher : Elsevier
ISBN 13 : 0080867987
Total Pages : 313 pages
Book Rating : 4.0/5 (88 download)

DOWNLOAD NOW!


Book Synopsis The Formation and Decay of Excited Species by : C.H. Bamford

Download or read book The Formation and Decay of Excited Species written by C.H. Bamford and published by Elsevier. This book was released on 1969 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Formation and Decay of Excited Species

Progress in Reaction Kinetics

Download Progress in Reaction Kinetics PDF Online Free

Author :
Publisher : Elsevier
ISBN 13 : 1483213722
Total Pages : 524 pages
Book Rating : 4.4/5 (832 download)

DOWNLOAD NOW!


Book Synopsis Progress in Reaction Kinetics by : G. Porter

Download or read book Progress in Reaction Kinetics written by G. Porter and published by Elsevier. This book was released on 2013-09-11 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Reaction Kinetics, Volume 3 presents articles about advances in reaction kinetics. The book begins with a theoretical review of bimolecular reactions, such as the relation between free energy and potential energy surfaces. The text describes reactions of hydrogen atoms in the gas phase; the hot atom chemistry of gas-phase systems; the inhibition of gaseous free radical chain reactions; and vibrational relaxation in gases. Articles about pulse radiolysis; the effects of dose-rate and linear energy transfer in radiation chemistry; and the electronic spectra and kinetics of aromatic free radicals are also considered. The book further tackles the kinetics of polymerization of vinyl monomers by lithium alkyls as well as radical polymerization in solutions. Chemists and professionals dealing with radiation, physical, and industrial chemistry will find the book invaluable.

Plasma Chemistry

Download Plasma Chemistry PDF Online Free

Author :
Publisher : Cambridge University Press
ISBN 13 : 1139471732
Total Pages : pages
Book Rating : 4.1/5 (394 download)

DOWNLOAD NOW!


Book Synopsis Plasma Chemistry by : Alexander Fridman

Download or read book Plasma Chemistry written by Alexander Fridman and published by Cambridge University Press. This book was released on 2008-05-05 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a fundamental introduction to all aspects of modern plasma chemistry, this book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics and electrodynamics, as well as all major electric discharges applied in plasma chemistry. Fridman considers most of the major applications of plasma chemistry, from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production and from plasma metallurgy to plasma medicine. It is helpful to engineers, scientists and students interested in plasma physics, plasma chemistry, plasma engineering and combustion, as well as chemical physics, lasers, energy systems and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics and numerical formulas for practical calculations related to specific plasma-chemical processes and applications. Problems and concept questions are provided, helpful in courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.

Plasma Physics and Engineering

Download Plasma Physics and Engineering PDF Online Free

Author :
Publisher : CRC Press
ISBN 13 : 1482293633
Total Pages : 882 pages
Book Rating : 4.4/5 (822 download)

DOWNLOAD NOW!


Book Synopsis Plasma Physics and Engineering by : Alexander Fridman

Download or read book Plasma Physics and Engineering written by Alexander Fridman and published by CRC Press. This book was released on 2004-04-15 with total page 882 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plasma engineering is a rapidly expanding area of science and technology with increasing numbers of engineers using plasma processes over a wide range of applications. A current partial list would include: electronics, energetics, fuel conversion, ozone generation, treatment of polymers and othermaterials, synthesis of new materials, production of

Time-Resolved Vibrational Spectroscopy V

Download Time-Resolved Vibrational Spectroscopy V PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642847714
Total Pages : 343 pages
Book Rating : 4.6/5 (428 download)

DOWNLOAD NOW!


Book Synopsis Time-Resolved Vibrational Spectroscopy V by : Hiroaki Takahashi

Download or read book Time-Resolved Vibrational Spectroscopy V written by Hiroaki Takahashi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 343 pages. Available in PDF, EPUB and Kindle. Book excerpt: The work contained in this volume is representative of the presentations made by the participants at the Fifth International Conference on Time-Resolved Vibra tional Spectroscopy, which was held at Waseda University, Tokyo, Japan, from June 3 to 7, 1991. The conference was the fifth in a biennial series initiated in 1982 by Prof. George H. Atkinson (University of Arizona) at Lake Placid, USA, and subsequently convened by Prof. Alfred Laubereau (University of Bayreuth, Germany) and Dr. Manfred Stockburger (Max-Planck Institut, G6ttingen, Ger many) at Bayreuth-BischofsgrUn, Germany, in 1985, by Prof. Joop D.W. Van Voorst (University of Amsterdam) at Amersfoort, The Netherlands, in 1987, and by Prof. Thomas G. Spiro (princeton University) at Princeton, USA, in 1989. The purpose of the conference is to bring together researchers from various disciplines and provide a forum for discussion of the latest advances in time resolved spectroscopies concerned with transient vibrational phenomena and their application to fundamental scientific and engineering studies. The 167 registered participants, including 46 students, from 14 different countries, represented a wide range of scientific disciplines, and clearly indicated that the field continues to expand into new areas of physics, chemistry, biology, and materials science. Their enthusiasm and the originality and quality of the contributions presented produced a very successful and enjoyable conference.

Unimolecular Kinetics

Download Unimolecular Kinetics PDF Online Free

Author :
Publisher : Elsevier
ISBN 13 : 012816218X
Total Pages : 544 pages
Book Rating : 4.1/5 (281 download)

DOWNLOAD NOW!


Book Synopsis Unimolecular Kinetics by :

Download or read book Unimolecular Kinetics written by and published by Elsevier. This book was released on 2019-05-30 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: Unimolecular Kinetics: Part 2: Collisional Energy Transfer and the Master Equation, Volume 43 in Elsevier's Comprehensive Molecular Kinetics series, addresses collision energy transfer and the effects it has on gas phase reactions, particularly at low gas density. Such systems include combustion, industrial gas phase processes and atmospheric/environmental processes. The book also discusses The Master Equation to give a good overview of the mechanics underpinning unimolecular kinetics. This new volume will be of interest to researchers investigating gas phase processes which involve unimolecular reactions and the related intermolecular reactions. - Discusses collision energy transfer and the effects it has on gas phase reactions - Introduces stochastic techniques to energy transfer methods, allowing for an extension of the unimolecular theory beyond simple molecular dissociation - Draws an important connection between detailed reaction dynamic studies and the rate of coefficient determination

Physics Briefs

Download Physics Briefs PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 816 pages
Book Rating : 4.3/5 (91 download)

DOWNLOAD NOW!


Book Synopsis Physics Briefs by :

Download or read book Physics Briefs written by and published by . This book was released on 1990 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Scientific and Technical Aerospace Reports

Download Scientific and Technical Aerospace Reports PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 1134 pages
Book Rating : 4.:/5 (31 download)

DOWNLOAD NOW!


Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1989 with total page 1134 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Radiationless Transitions

Download Radiationless Transitions PDF Online Free

Author :
Publisher : Elsevier
ISBN 13 : 0323150276
Total Pages : 440 pages
Book Rating : 4.3/5 (231 download)

DOWNLOAD NOW!


Book Synopsis Radiationless Transitions by : Sheng Lin

Download or read book Radiationless Transitions written by Sheng Lin and published by Elsevier. This book was released on 2012-12-02 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radiationless Transitions is a critical discussion of research studies on the theory and experiments in radiationless transitions. This book is composed of nine chapters, and begins with discussions on the theory and experiment of photophysical processes of single vibronic levels and/or single rovibronic levels. The subsequent chapters deal with the spectroscopic investigations of intramolecular vibrational relaxation; the dynamics of molecular excitation by light; and the photophysical processes of small molecules in condensed phase. The discussions then shift to the high pressure effects on molecular luminescence and the internal conversion involving localized excitations, presenting one qualitative and one quantitative example, as well as the intersystem crossing with localized excitations. A chapter explores the energy transfer processes that occur after a molecule in solution is excited by light, with an emphasis on solid solutions in which the large amplitude molecular motion is largely quenched. This chapter also looks into the liquid solutions in which the molecules can translate and rotate under the influence of fluctuating forces from the liquid. The concluding chapter focuses on ultrafast processes. Researchers in the fields of physics, chemistry, and biology will benefit from this book.

Nuclear Science Abstracts

Download Nuclear Science Abstracts PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 680 pages
Book Rating : 4.E/5 ( download)

DOWNLOAD NOW!


Book Synopsis Nuclear Science Abstracts by :

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1976 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Vibrational-Rotational Excitations in Nonlinear Molecular Systems

Download Vibrational-Rotational Excitations in Nonlinear Molecular Systems PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 1461513170
Total Pages : 361 pages
Book Rating : 4.4/5 (615 download)

DOWNLOAD NOW!


Book Synopsis Vibrational-Rotational Excitations in Nonlinear Molecular Systems by : Alexander A. Ovchinnikov

Download or read book Vibrational-Rotational Excitations in Nonlinear Molecular Systems written by Alexander A. Ovchinnikov and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: "If there would be no God ~ then what a staff-captain am I?" ~ said one of the characters in a novel by Dostoevskii. In a similar way we can exclaim: "If there would be no nonlinearity ~ than what physics would that be'?". Really, the most interesting and exciting effects are described by non linear equations, and vanish in the linear approximation. For example, the general theory of relativity by A.Einstein comes to mind first - one of the most beautiful physical theories, which is in fact essentially nonlinear. Next, the phase transitions crystal ~ liquid and liquid ~ gas are due to the anhar monicity of inter-particle interactions, to dissociation and infinite motion. Similarly, transitions into the superconducting state or the superftuid would be impossible with purely harmonic interaction potentials. Another bril liant achievement in nonlinear physics was the construction of a laser and the subsequent development of nonlinear optics. The latter describes the in teraction of the matter with light of super-high intensity, when multi-quanta intra-molecular transitions become essential. Last, we should note here the very beautiful mathematical theory ~ the theory of catastrophes. Its subject is the study of invariant general properties of multi-dimensional surfaces in the vicinity of bifurcation points with respect to continuous transformations.