The Synthesis and Reactions of Some New Cationic Alkyne Complexes of Tungsten(II).

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ISBN 13 :
Total Pages : 690 pages
Book Rating : 4.:/5 (218 download)

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Book Synopsis The Synthesis and Reactions of Some New Cationic Alkyne Complexes of Tungsten(II). by : Kevin R. Flower

Download or read book The Synthesis and Reactions of Some New Cationic Alkyne Complexes of Tungsten(II). written by Kevin R. Flower and published by . This book was released on 1990 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Reactivity of Tantalum and Tungsten Alkyne Complexes

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (139 download)

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Book Synopsis Synthesis and Reactivity of Tantalum and Tungsten Alkyne Complexes by : Pamela Andrea Wexler

Download or read book Synthesis and Reactivity of Tantalum and Tungsten Alkyne Complexes written by Pamela Andrea Wexler and published by . This book was released on 1990 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Reactions of Tungsten Complexes

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ISBN 13 :
Total Pages : 282 pages
Book Rating : 4.:/5 (389 download)

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Book Synopsis Synthesis and Reactions of Tungsten Complexes by : Dariusz Wodka

Download or read book Synthesis and Reactions of Tungsten Complexes written by Dariusz Wodka and published by . This book was released on 1997 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Reactions of Tungsten, Nickel, and Palladium Enolate Complexes

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ISBN 13 :
Total Pages : 396 pages
Book Rating : 4.:/5 (7 download)

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Book Synopsis Synthesis and Reactions of Tungsten, Nickel, and Palladium Enolate Complexes by : Elizabeth R. Burkhardt

Download or read book Synthesis and Reactions of Tungsten, Nickel, and Palladium Enolate Complexes written by Elizabeth R. Burkhardt and published by . This book was released on 1989 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt:

British Reports, Translations and Theses

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ISBN 13 :
Total Pages : 978 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis British Reports, Translations and Theses by : British Library. Document Supply Centre

Download or read book British Reports, Translations and Theses written by British Library. Document Supply Centre and published by . This book was released on 1991 with total page 978 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization

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Publisher : Cuvillier
ISBN 13 : 9783736976115
Total Pages : 0 pages
Book Rating : 4.9/5 (761 download)

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Book Synopsis Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization by : Janis Musso

Download or read book Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization written by Janis Musso and published by Cuvillier. This book was released on 2022-05-12 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, the synthesis of neutral and cationic group(VI) imido/oxo alkylidene N-heterocyclic carbene (NHC) complexes that tolerate protic functional groups and aldehydes was reported. Unprecedented turnover numbers of up to 1.2 million were found for their silica-supported representatives. Some group(VI) alkylidene NHC complexes even display stability towards moisture and air. Coordination of the NHC to tungsten imido bistriflate precursor complexes, however, can lead to undesired side reactions. This work consequently aimed at the development of novel, more efficient routes to neutral and cationic tungsten imido/oxo alkylidene NHC complexes. In addition, some molybdenum imido alkylidene NHC complexes were targeted. Thereby, the scope of synthetically accessible complexes was broadened and, subsequently, their reactivity in ring-opening metathesis polymerization (ROMP) was probed. Those complexes were used as thermally latent initiators for the ROMP of dicyclopentadiene. Precise determination of the onset temperature of polymerization was achieved via monitoring with differential scanning calorimetry. Furthermore, the selectivity of novel complexes was tested for the formation of stereoregular polymers through ROMP of enantiomerically pure norbornene derivatives, which allowed for the synthesis of up to 98% trans-isotactic or cis-syndiotactic polymers depending on the steric demand of the imido and the alkoxide ligand.

Dissertation Abstracts International

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ISBN 13 :
Total Pages : 810 pages
Book Rating : 4.F/5 ( download)

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Reactions of Tp'tungsten (II) Alkyne Complexes

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ISBN 13 :
Total Pages : 472 pages
Book Rating : 4.:/5 (232 download)

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Book Synopsis Reactions of Tp'tungsten (II) Alkyne Complexes by : Shaoguang Feng

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Synthesis and Reactions of Neutral Tungsten and Rhenium Formyl Complexes

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ISBN 13 :
Total Pages : 262 pages
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Book Synopsis Synthesis and Reactions of Neutral Tungsten and Rhenium Formyl Complexes by : William Edward Sattich

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Synthesis and Reactivity of Tungsten Germyl Silyl Complexes and a New Approach to Spin-on-glass Films of Silicon Dioxide

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ISBN 13 :
Total Pages : 174 pages
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Book Synopsis Synthesis and Reactivity of Tungsten Germyl Silyl Complexes and a New Approach to Spin-on-glass Films of Silicon Dioxide by : Lisa Kiernan Figge

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Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards

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ISBN 13 :
Total Pages : 444 pages
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New Alkyne Complexes of Tungsten II.

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ISBN 13 :
Total Pages : pages
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Book Synopsis New Alkyne Complexes of Tungsten II. by : Stephen David Ridyard

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Chiral Tungsten(II) Alkyne Complexes for Synthesis of Optically Active Alkynes and Cycloalkynes

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ISBN 13 :
Total Pages : 222 pages
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Book Synopsis Chiral Tungsten(II) Alkyne Complexes for Synthesis of Optically Active Alkynes and Cycloalkynes by : Michael Bryan Wells

Download or read book Chiral Tungsten(II) Alkyne Complexes for Synthesis of Optically Active Alkynes and Cycloalkynes written by Michael Bryan Wells and published by . This book was released on 1996 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Host Bibliographic Record for Boundwith Item Barcode 30112033097202 and Others

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ISBN 13 :
Total Pages : 592 pages
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Comprehensive Organic Synthesis

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Publisher : Newnes
ISBN 13 : 008097743X
Total Pages : 9815 pages
Book Rating : 4.0/5 (89 download)

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Download or read book Comprehensive Organic Synthesis written by and published by Newnes. This book was released on 2014-02-14 with total page 9815 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Polyhedron

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ISBN 13 :
Total Pages : 1054 pages
Book Rating : 4.3/5 (97 download)

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Download or read book Polyhedron written by and published by . This book was released on 1994 with total page 1054 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization

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Publisher : Cuvillier Verlag
ISBN 13 : 3736966113
Total Pages : 186 pages
Book Rating : 4.7/5 (369 download)

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Book Synopsis Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization by : Janis Musso

Download or read book Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization written by Janis Musso and published by Cuvillier Verlag. This book was released on 2022-05-12 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, the synthesis of neutral and cationic group(VI) imido/oxo alkylidene N-heterocyclic carbene (NHC) complexes that tolerate protic functional groups and aldehydes was reported. Unprecedented turnover numbers of up to 1.2 million were found for their silica-supported representatives. Some group(VI) alkylidene NHC complexes even display stability towards moisture and air. Coordination of the NHC to tungsten imido bistriflate precursor complexes, however, can lead to undesired side reactions. This work consequently aimed at the development of novel, more efficient routes to neutral and cationic tungsten imido/oxo alkylidene NHC complexes. In addition, some molybdenum imido alkylidene NHC complexes were targeted. Thereby, the scope of synthetically accessible complexes was broadened and, subsequently, their reactivity in ring-opening metathesis polymerization (ROMP) was probed. Those complexes were used as thermally latent initiators for the ROMP of dicyclopentadiene. Precise determination of the onset temperature of polymerization was achieved via monitoring with differential scanning calorimetry. Furthermore, the selectivity of novel complexes was tested for the formation of stereoregular polymers through ROMP of enantiomerically pure norbornene derivatives, which allowed for the synthesis of up to 98% trans-isotactic or cis-syndiotactic polymers depending on the steric demand of the imido and the alkoxide ligand.