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The Synthesis And Applications Of Low Valent Mu Biscarbene Complexes And High Valent Diimido Complexes Of Tungsten
Download The Synthesis And Applications Of Low Valent Mu Biscarbene Complexes And High Valent Diimido Complexes Of Tungsten full books in PDF, epub, and Kindle. Read online The Synthesis And Applications Of Low Valent Mu Biscarbene Complexes And High Valent Diimido Complexes Of Tungsten ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis Activation of Small Molecules by : William B. Tolman
Download or read book Activation of Small Molecules written by William B. Tolman and published by John Wiley & Sons. This book was released on 2006-12-13 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.
Book Synopsis Metal Catalyzed Cascade Reactions by : Thomas J.J. Müller
Download or read book Metal Catalyzed Cascade Reactions written by Thomas J.J. Müller and published by Springer. This book was released on 2006-06-27 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. This is a comprehensive overview of an exciting and highly dynamic, and innovative methodological concept.
Book Synopsis New Aspects of Zirconium Containing Organic Compounds by : Ilan Marek
Download or read book New Aspects of Zirconium Containing Organic Compounds written by Ilan Marek and published by Springer Science & Business Media. This book was released on 2005-02-18 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal carbene complexes have made their way from organometallic curiosities to valuable reagents and catalysts. They offer novel synthetic opportunities in carbon-carbon bond formation based on either carbene-centered reactions or on metal-templated processes which makes them indispensable in modern synthetic methodology. The most prominent metal carbenes are now either commercially available or easy to synthesize and handle with modern laboratory techniques. This volume organized in eight chapters written by the leading scientists in the field illustrates the theoretical background, non-classical nucleophilic and cycloaddition patterns, chromium-templated benzannulation and photo-induced reactions, rhodium-catalyzed carbene transfer as well as the principles and applications of olefin metathesis which has coined the progress in synthetic methodology over the past decade. Designed for researchers in academia and industry as well as graduate students it presents the state-of-the-art potential of carbene complexes in modern organic synthesis.
Book Synopsis High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes by : Carola S. Vogel
Download or read book High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes written by Carola S. Vogel and published by Springer Science & Business Media. This book was released on 2012-02-03 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.
Book Synopsis Catalytic Carbonylation Reactions by : Matthias Beller
Download or read book Catalytic Carbonylation Reactions written by Matthias Beller and published by Springer Science & Business Media. This book was released on 2006-09-14 with total page 289 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonylation reactions are of major importance in both organic and industrial chemistry. Due to the availability, price and reactivity pattern, carbon monoxide is becoming a more and more important building block for fine and bulk chemicals. The major reaction types of carbon monoxide are comprehensively discussed by leading experts from academia and industry. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples. This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis. Therefore, the reader will get a balanced view of this developing and complex subject.
Book Synopsis Palladium in Organic Synthesis by : Jiro Tsuji
Download or read book Palladium in Organic Synthesis written by Jiro Tsuji and published by Springer Science & Business Media. This book was released on 2005-07-06 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: with contributions by numerous experts
Book Synopsis Synthesis and Reactivity of Thioether-supported Organoiron and Low-valent Iron Complexes and Cyanide-bridged Binuclear Complexes by : Michael T. Mock
Download or read book Synthesis and Reactivity of Thioether-supported Organoiron and Low-valent Iron Complexes and Cyanide-bridged Binuclear Complexes written by Michael T. Mock and published by ProQuest. This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of FeCl 2 (THF) 1.5 lead to the synthesis of [PhTt tB u]FeCl that provided entry into new [PhTt tBu]FeX chemistry. [PhTt tBu]FeCl crystallizes as a five-coordinate chloride bridged dimer that is a high-spin ferrous complex with an S = 2 ground state. The metathetical reaction of [PhTt tBu]FeCl with the desired dialkylmagnesium reagent, R 2 Mg (R = Me, Et, Ph, Bn), in 1,4-dioxane/THF leads to the formation of high-spin, S = 2, electronically and coordinatively unsaturated four-coordinate organoiron(II) complexes of the type, [PhTt tBu]Fe(R) (R = Me, Et, Ph, Bn). Reaction of [PhTt tBu]Fe(R) (R = Me, Et, Ph) with CO yields the low-spin, S = 0, six-coordinate complexes [PhTt tBu]Fe(CO) 2 (R) (R = Me, Et, Ph). Carbonylation of [PhTt tBu]Fe(Bn) yields [PhTt tBu]Fe(CO) 2 (Bn) and the reduced monovalent species [PhTt tBu]Fe(CO) 2 . The reduction of [PhTt tBu]FeCl in the presence of a phosphine ligand, PMe 3 or PEt 3, yields the high-spin, S = 3/2, monovalent iron complexes, [PhTt tBu]Fe(PMe 3) or [PhTt tBu]Fe(PEt 3) in moderate yields. [PhTt tBu]Fe(PMe 3) reacts with CO producing the low-spin, S = 1/2, monovalent product [PhTt tBu]Fe(CO) 2 . X-ray crystallographic analysis confirms a five-coordinate, square pyramidal coordination geometry. [PhTt tBu]Fe(PMe 3) reacts with diphenylacetylene producing the high-spin, S = 3/2 product [PhTt tBu]Fe(PhC=CPh). X-ray crystallography confirms a five-coordinate, square pyramidal coordination geometry with PhC=CPh bound to the iron center in a symmetric, side-on eta 2 binding mode. [PhTt tBu]Fe(PMe 3) reacts with adamantyl azide producing the high-spin, S = 3/2 product, [kappa 2 -PhTt tBu]Fe(N 4 Ad 2). The dialkyltetraazadiene ligand exhibits nearly identical N-N bonds suggesting a delocalized ligand radical dialkyltetraazadiene resonance form. Efforts to model a catalytically inhibited form of COdH were performed by designing a simple Ni:Fe binuclear complex that provides the essential metal coordination spheres of the C-cluster active site. The scope of these studies was expanded to include a series of cyanide-bridged binuclear complexes, ('S 3 ')Ni-CN-M[Tp tBu] (M = Fe, Co, Ni, Zn). A similar coupling scheme was used to synthesize the copper(I) analogue, Et 4 N{('S 3 ')Ni-CN-Cu[Tp tBu]}. Two synthetic strategies were employed to investigate the formation of cyanide-bridged linkage isomers. The products of two different 13 CN labeled reactions intended to yield ('S 3 ')Ni-CN-Zn[Tp tBu] and ('S 3 ')Ni-NC-Zn[Tp tBu] were analyzed. Nearly identical infrared and 13 C NMR spectroscopic data provide additional evidence that ('S 3 ')Ni-CN-Zn[Tp tBu] is produced in both reactions.
Book Synopsis Synthesis and characterization of high-valent iron complexes of macrocyclic tetraamido-N ligands by : Kimberly L. Kostka
Download or read book Synthesis and characterization of high-valent iron complexes of macrocyclic tetraamido-N ligands written by Kimberly L. Kostka and published by . This book was released on 1993 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Ruthenium Catalysts and Fine Chemistry by : Christian Bruneau
Download or read book Ruthenium Catalysts and Fine Chemistry written by Christian Bruneau and published by Springer Science & Business Media. This book was released on 2004-06-30 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts
Author :Ahmed F. Abdel-Magid Publisher :Springer Science & Business Media ISBN 13 :9783540016038 Total Pages :316 pages Book Rating :4.0/5 (16 download)
Book Synopsis Organometallics in Process Chemistry by : Ahmed F. Abdel-Magid
Download or read book Organometallics in Process Chemistry written by Ahmed F. Abdel-Magid and published by Springer Science & Business Media. This book was released on 2004-06-15 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: The design of efficient syntheses of medicinal agents is one of the prime goals of the process chemist in the pharmaceutical industry. The expanding list of metal-mediated reactions has had a major impact on this endeavor over the last two decades. This volume will highlight some of the areas of organometallic chemistry that have played a particularly important role in development. The chapters are written by chemists who work in the process groups of major pharmaceutical companies and fine chemical manufacturers. Having demonstrated the power of organometallics in their processes the authors herein expand upon their experiences with examples from the literature as reported by process groups within the industry. The chapters are organized either by the application of a particular metal or reaction class. Removal of the residual metal(s) from the isolated active pharmaceutical ingredient (API) is key to the release of the material for human consumption, and hence, is reviewed here as well. This volume of Topics in Organometallic Chemistry is presented to offer a representative cross section of organometallic applications in the pharmaceutical industry as well as to give an appreciation for the creativity possible in process chemistry.
Book Synopsis Novel Chemistry of Low-valent Early Transition Metal Complexes by : Mikhail Victorovich Barybin
Download or read book Novel Chemistry of Low-valent Early Transition Metal Complexes written by Mikhail Victorovich Barybin and published by . This book was released on 1999 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Direct Synthesis of Metal Complexes by : B.I. Kharisov
Download or read book Direct Synthesis of Metal Complexes written by B.I. Kharisov and published by Elsevier. This book was released on 2018-04-19 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn't require organic solvents), with special attention paid to 'greener' methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. - Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more - Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water - Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
