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The Phase Rule And Phase Reaction
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Book Synopsis The Thermodynamics of Phase and Reaction Equilibria by : Ismail Tosun
Download or read book The Thermodynamics of Phase and Reaction Equilibria written by Ismail Tosun and published by Newnes. This book was released on 2012-10-17 with total page 736 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides you with a sound foundation for understanding abstract concepts (eg physical properties such as fugacity, etc or chemical processes, ie distillation, etc) of phase and reaction equilibria and shows you how to apply these concepts to solve practical problems using numerous and clear examples.
Book Synopsis Transport Phenomena in Multiphase Systems by : Amir Faghri
Download or read book Transport Phenomena in Multiphase Systems written by Amir Faghri and published by Academic Press. This book was released on 2006 with total page 1072 pages. Available in PDF, EPUB and Kindle. Book excerpt: Engineering students in a wide variety of engineering disciplines from mechanical and chemical to biomedical and materials engineering must master the principles of transport phenomena as an essential tool in analyzing and designing any system or systems wherein momentum, heat and mass are transferred. This textbook was developed to address that need, with a clear presentation of the fundamentals, ample problem sets to reinforce that knowledge, and tangible examples of how this knowledge is put to use in engineering design. Professional engineers, too, will find this book invaluable as reference for everything from heat exchanger design to chemical processing system design and more. * Develops an understanding of the thermal and physical behavior of multiphase systems with phase change, including microscale and porosity, for practical applications in heat transfer, bioengineering, materials science, nuclear engineering, environmental engineering, process engineering, biotechnology and nanotechnology * Brings all three forms of phase change, i.e., liquid vapor, solid liquid and solid vapor, into one volume and describes them from one perspective in the context of fundamental treatment * Presents the generalized integral and differential transport phenomena equations for multi-component multiphase systems in local instance as well as averaging formulations. The molecular approach is also discussed with the connection between microscopic and molecular approaches * Presents basic principles of analyzing transport phenomena in multiphase systems with emphasis on melting, solidification, sublimation, vapor deposition, condensation, evaporation, boiling and two-phase flow heat transfer at the micro and macro levels * Solid/liquid/vapor interfacial phenomena, including the concepts of surface tension, wetting phenomena, disjoining pressure, contact angle, thin films and capillary phenomena, including interfacial balances for mass, species, momentum, and energy for multi-component and multiphase interfaces are discussed * Ample examples and end-of-chapter problems, with Solutions Manual and PowerPoint presentation available to the instructors
Book Synopsis Phase Equilibria, Phase Diagrams and Phase Transformations by : Mats Hillert
Download or read book Phase Equilibria, Phase Diagrams and Phase Transformations written by Mats Hillert and published by Cambridge University Press. This book was released on 2007-11-22 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.
Book Synopsis Lectures in Classical Thermodynamics with an Introduction to Statistical Mechanics by : Daniel Blankschtein
Download or read book Lectures in Classical Thermodynamics with an Introduction to Statistical Mechanics written by Daniel Blankschtein and published by Springer Nature. This book was released on 2021-03-15 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook facilitates students’ ability to apply fundamental principles and concepts in classical thermodynamics to solve challenging problems relevant to industry and everyday life. It also introduces the reader to the fundamentals of statistical mechanics, including understanding how the microscopic properties of atoms and molecules, and their associated intermolecular interactions, can be accounted for to calculate various average properties of macroscopic systems. The author emphasizes application of the fundamental principles outlined above to the calculation of a variety of thermodynamic properties, to the estimation of conversion efficiencies for work production by heat interactions, and to the solution of practical thermodynamic problems related to the behavior of non-ideal pure fluids and fluid mixtures, including phase equilibria and chemical reaction equilibria. The book contains detailed solutions to many challenging sample problems in classical thermodynamics and statistical mechanics that will help the reader crystallize the material taught. Class-tested and perfected over 30 years of use by nine-time Best Teaching Award recipient Professor Daniel Blankschtein of the Department of Chemical Engineering at MIT, the book is ideal for students of Chemical and Mechanical Engineering, Chemistry, and Materials Science, who will benefit greatly from in-depth discussions and pedagogical explanations of key concepts. Distills critical concepts, methods, and applications from leading full-length textbooks, along with the author’s own deep understanding of the material taught, into a concise yet rigorous graduate and advanced undergraduate text; Enriches the standard curriculum with succinct, problem-based learning strategies derived from the content of 50 lectures given over the years in the Department of Chemical Engineering at MIT; Reinforces concepts covered with detailed solutions to illuminating and challenging homework problems.
Book Synopsis Gas-Phase Reactions by : V.N. Kondratiev
Download or read book Gas-Phase Reactions written by V.N. Kondratiev and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
Book Synopsis Encyclopedia of Glass Science, Technology, History, and Culture Two Volume Set by : Pascal Richet
Download or read book Encyclopedia of Glass Science, Technology, History, and Culture Two Volume Set written by Pascal Richet and published by John Wiley & Sons. This book was released on 2021-02-05 with total page 1568 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Encyclopedia begins with an introduction summarizing itsscope and content. Glassmaking; Structure of Glass, GlassPhysics,Transport Properties, Chemistry of Glass, Glass and Light,Inorganic Glass Families, Organic Glasses, Glass and theEnvironment, Historical and Economical Aspect of Glassmaking,History of Glass, Glass and Art, and outlinepossible newdevelopments and uses as presented by the best known people in thefield (C.A. Angell, for example). Sections and chapters arearranged in a logical order to ensure overall consistency and avoiduseless repetitions. All sections are introduced by a briefintroduction and attractive illustration. Newly investigatedtopics will be addresses, with the goal of ensuring that thisEncyclopedia remains a reference work for years to come.
Book Synopsis Methods for Phase Diagram Determination by : Ji-Cheng Zhao
Download or read book Methods for Phase Diagram Determination written by Ji-Cheng Zhao and published by Elsevier. This book was released on 2011-05-05 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase diagrams are "maps" materials scientists often use to design new materials. They define what compounds and solutions are formed and their respective compositions and amounts when several elements are mixed together under a certain temperature and pressure. This monograph is the most comprehensive reference book on experimental methods for phase diagram determination. It covers a wide range of methods that have been used to determine phase diagrams of metals, ceramics, slags, and hydrides.* Extensive discussion on methodologies of experimental measurements and data assessments * Written by experts around the world, covering both traditional and combinatorial methodologies* A must-read for experimental measurements of phase diagrams
Book Synopsis Phase Diagrams by : Flake C. Campbell
Download or read book Phase Diagrams written by Flake C. Campbell and published by ASM International. This book was released on 2012-01-01 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: This well-written text is for non-metallurgists and anyone seeking a quick refresher on an essential tool of modern metallurgy. The basic principles, construction, interpretation, and use of alloy phase diagrams are clearly described with ample illustrations for all important liquid and solid reactions. Gas-metal reactions, important in metals processing and in-service corrosion, also are discussed. Get the basics on how phase diagrams help predict and interpret the changes in the structure of alloys.
Book Synopsis Encyclopedia of Geochemistry by : William M. White
Download or read book Encyclopedia of Geochemistry written by William M. White and published by Springer. This book was released on 2018-07-24 with total page 1680 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.
Book Synopsis The Phase Rule and Its Applications by : Alexander Findlay
Download or read book The Phase Rule and Its Applications written by Alexander Findlay and published by . This book was released on 1915 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Phase Rule and Its Applications by : Alexander Findlay
Download or read book The Phase Rule and Its Applications written by Alexander Findlay and published by Good Press. This book was released on 2019-12-02 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The Phase Rule and Its Applications" by Alexander Findlay is an authoritative and comprehensive work that explores the fundamental principles and practical applications of the phase rule in chemistry. With clarity and precision, Findlay elucidates the significance of the phase rule in understanding the behavior of chemical systems, particularly in relation to changes in temperature, pressure, and composition. This essential reference provides valuable insights for researchers, scientists, and students alike, fostering a deeper understanding of the intricate processes governing matter and its transformations.
Book Synopsis Alloy Phase Equilibria by : Alan Prince
Download or read book Alloy Phase Equilibria written by Alan Prince and published by . This book was released on 1966 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Phase Rule written by and published by Krishna Prakashan Media. This book was released on with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Textbook of Physical Chemistry – Volume 1 by : Mandeep Dalal
Download or read book A Textbook of Physical Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2018-01-01 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Book Synopsis Phase Diagrams and Thermodynamic Modeling of Solutions by : Arthur D. Pelton
Download or read book Phase Diagrams and Thermodynamic Modeling of Solutions written by Arthur D. Pelton and published by Academic Press. This book was released on 2018-09-19 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models. - Presents a rigorous and complete development of thermodynamics for readers who already have a basic understanding of chemical thermodynamics - Provides an in-depth understanding of phase equilibria - Includes information that can be used as a text for graduate courses on thermodynamics and phase diagrams, or on solution modeling - Covers several types of phase diagrams (paraequilibrium, solidus projections, first-melting projections, Scheil diagrams, enthalpy diagrams), and more
Book Synopsis The Encyclopedia of Mineralogy by : Keith Frye
Download or read book The Encyclopedia of Mineralogy written by Keith Frye and published by Springer Science & Business Media. This book was released on 1981-12-31 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia of Mineralogy provides comprehensive, basic treatment of the science of mineralogy. More than 140 articles by internationally known scholars and research workers describe specific areas of mineralogical interest, and a glossary of 3000 entries defines all valid mineral species and many related mineral names. In addition to traditional topics - descriptions of major structural groups, methods of mineral analysis, and the paragenesis of mineral species - this volume embraces such subjects as asbestiform minerals, minerals found in caves and in living beings, and gems and gemology. It includes current data on the latest in our geological inventories - lunar minerals. It describes the properties, characteristics, and uses of industrial resources such as abrasive materials and Portland cement. A directory will guide traveling mineralogists to the major mineralogical museums of the world, with their special interests noted. Clear technical illustrations supplement the text throughout. To help the student and professional find particular information there are a comprehensive subject index, extensive cross-references of related topics (whether in this volume or others in the series), and reference lists to background information and detailed advanced treatment of all topics. The Encyclopedia of Mineralogy is a valuable reference and source for professionals in all geological sciences, for science teachers at all levels, for collectors and `rock hounds', and for all who are curious about the minerals on earth or those brought back from outer space.
Book Synopsis Phase Transitions in Polymers: The Role of Metastable States by : Stephen Z.D. Cheng
Download or read book Phase Transitions in Polymers: The Role of Metastable States written by Stephen Z.D. Cheng and published by Elsevier. This book was released on 2008-09-10 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: A classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are kinetically impeded on the pathway to thermodynamic equilibrium. This was illustrated in structural and morphological investigations of crystallization and mesophase transitions, liquid-liquid phase separation, vitrification and gel formation, as well as combinations of these transformation processes. The phase behaviours in polymers are thus dominated by interlinks of metastable states on different length scales. This concept successfully explains many experimental observations and provides a new way to connect different aspects of polymer physics.* Written by a leading scholar and industry expert* Presents new and cutting edge material encouraging innovation and future research* Connects hot topics and leading research in one concise volume
