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The Gas Phase Ligand Exchange Of Calcium Diketonate Complexes
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Book Synopsis The Gas-phase Ligand Exchange of Calcium Β-diketonate Complexes by : Brandi J. Gatte
Download or read book The Gas-phase Ligand Exchange of Calcium Β-diketonate Complexes written by Brandi J. Gatte and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gas-phase ligand exchange reactions of a series of metal beta-diketonate complexes were observed to occur within a triple quadrupole mass spectrometer. Calcium beta-diketonate complexes, when co-sublimed with other metal beta-diketonate complexes, were observed to undergo partial, mixed, and complete ligand exchange. Calcium-containing species were also found to cluster leading to multiple metal and ligand additions. The gas-phase reactions reported herein provide additional evidence into the gas-phase ligand exchange of beta-diketonates.
Book Synopsis The Gas Phase Ligand Exchange of Cadmium [beta]-diketonate Complexes by : Dominic Giovanni Silvestri
Download or read book The Gas Phase Ligand Exchange of Cadmium [beta]-diketonate Complexes written by Dominic Giovanni Silvestri and published by . This book was released on 2014 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: A series of gas-phase ligand exchange reactions involving Cadmium trifluorotrimethylacetylacetonate (Cd(tftm)2) were examined using a triple quadrupole mass spectrometer. Multiple co-sublimation experiments were explored with various metal [beta]-diketonates where several partial and complete ligand exchange processes were observed and are reported herein for the first time. In an attempt to elucidate possible mechanisms leading to the formation of the mixed ligand complex, select ion-neutral experiments were conducted within the collision cell of the triple quadrupole mass spectrometer.
Book Synopsis The Gas-phase Ligand Exchange of Trivalent Metal [beta]-diketonates by : James Kole Gasior
Download or read book The Gas-phase Ligand Exchange of Trivalent Metal [beta]-diketonates written by James Kole Gasior and published by . This book was released on 2017 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: The gas-phase ligand exchange reactions incorporating main group and transition metal [beta]-diketonate complexes were investigated using a Finnigan TSQ 7000 triple quadrupole electron impact mass spectrometer. Specifically, trivalent iron and aluminum complexes were reacted with a variety of other metal [beta]-diketonates during mass spectrometric analysis, and the ensuing gas-phase reactions were shown to generate a variety of products. Relative peak heights of parent ions in the resultant cosublimation spectra were compared to the reactants' baseline spectra to discern the relative reactivity of each parent ion, and subsequently, propose reaction mechanisms accounting for the production of mixed ligand products. To attain a more complete understanding of certain gas-phase reactions, tandem mass spectrometry was implemented to study selective reactions between specific parent ions and a neutral gas species. Analysis and interpretation of the resulting spectra allowed for the formulation of specific reaction mechanisms for each product detected. Finally, for the first time, the mechanism of partial ligand exchange was proposed and modeled using the PM3 semiempirical method to elucidate general features thought to be employed during the simultaneous mass analysis of homo-metal [beta]-diketonates.
Book Synopsis The Gas-phase Ligand Exchange of Select Alkaline Earth and Transition Metal ß-diketonate Complexes by : Kathleen Masena Fleming
Download or read book The Gas-phase Ligand Exchange of Select Alkaline Earth and Transition Metal ß-diketonate Complexes written by Kathleen Masena Fleming and published by . This book was released on 2016 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gas-phase ligand exchange reactions involving select alkaline earth and transition metal ß-diketonate complexes were evaluated using a triple quadrupole mass spectrometer. Once co-sublimation reactions confirmed ligand exchange, selective reactions were initiated to elucidate the mechanism of exchange. A series of co-sublimation and selective reactions involving several ß-diketonate complexes were investigated and are reported herein. The results from these gas-phase reactions have shed new light on the gas-phase ligand exchange of alkaline earth and transition metal ß-diketonate complexes.
Book Synopsis Ligand Exchange Reactions of Some Group IIIB −gb−s-diketonate Complexes by : Shedrach Oguzie Nweke
Download or read book Ligand Exchange Reactions of Some Group IIIB −gb−s-diketonate Complexes written by Shedrach Oguzie Nweke and published by . This book was released on 1968 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Gas-phase Ligand Exchange of Select Metal Bis-diisopropylacetylacetonate Complexes by : Victoria Marie Boulos
Download or read book The Gas-phase Ligand Exchange of Select Metal Bis-diisopropylacetylacetonate Complexes written by Victoria Marie Boulos and published by . This book was released on 2017 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: A series of gas-phase reactions were performed via co-sublimation within a triple quadrupole electron impact mass spectrometer. Novel alkaline earth and transition metal bis-diisopropylacetylacetonate coordination complexes were synthesized and observed to undergo gas-phase ligand exchange with select alkaline earth and transition metal bis-acetylacetonate and bis-trifluorotrimethylacetylacetonate complexes, and are reported herein for the first time. Also, novel alkaline earth and transition metal coordination compounds were characterized via x-ray crystallography. The results from these gas-phase experiments further establish the foundation of ligand exchange for this class of compounds.
Book Synopsis Vapor Phase Ligand Exchange by : Joseph Stauffer Jr.
Download or read book Vapor Phase Ligand Exchange written by Joseph Stauffer Jr. and published by . This book was released on 1966 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Gas Phase Multiply Charged Metal-ligand Complexes by : Georgina Danielle Claire Aitken
Download or read book Gas Phase Multiply Charged Metal-ligand Complexes written by Georgina Danielle Claire Aitken and published by . This book was released on 2008 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Ligand Exchange Equilibrium Studies of Some MO8 Anionic Beta-Diketonate Complexes of Yttrium (III), and Kinetic and Mechanistic Studies of Intermolecular Ligand Exchange in Some Organotin (IV) Acetylacetonate Complexes by 1H NMR Spectroscopy by : Rouben Ishayek
Download or read book Ligand Exchange Equilibrium Studies of Some MO8 Anionic Beta-Diketonate Complexes of Yttrium (III), and Kinetic and Mechanistic Studies of Intermolecular Ligand Exchange in Some Organotin (IV) Acetylacetonate Complexes by 1H NMR Spectroscopy written by Rouben Ishayek and published by . This book was released on 1973 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Gas-phase Studies of Multiply-charged Metal-ligand Complexes by : Bohan Wu
Download or read book Gas-phase Studies of Multiply-charged Metal-ligand Complexes written by Bohan Wu and published by . This book was released on 2007 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advances in Analytical Techniques and Methodology for Chemical Speciation Study by : Ottavia Giuffrè
Download or read book Advances in Analytical Techniques and Methodology for Chemical Speciation Study written by Ottavia Giuffrè and published by Frontiers Media SA. This book was released on 2021-07-05 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanisms of Inorganic and Organometallic Reactions Volume 7 by : M.V. Twigg
Download or read book Mechanisms of Inorganic and Organometallic Reactions Volume 7 written by M.V. Twigg and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of Mechanisms of Inorganic and Organometallic Reactions is to provide an ongoing critical review of the literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. The main focus is on reactions in solution, although solid state and gas phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen month literature period, and this, the seventh volume in the series, deals with papers published during July 1988 through December 1989. Where appropriate, there are references to earlier work, and also to specific sections in previous volumes. Coverage continues to span the whole area as comprehensively as possible in each volume, and although it is impossible be absolutely complete, every effort is made to include all the important for it to published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are only converted to common units when making comparisons. The basic format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic; this can now be done for more than a decade worth of research. In the last volume, ligand reactivity of both coordination and organometallic compounds were brought together in Chapter 12, and, in response to numerous positive comments from readers, this arrangement has been maintained. There have been some similar suggestions about oscillating reactions, and this topic may have a separate section in the next volume.
Download or read book Russian Chemical Reviews written by and published by . This book was released on 1993 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2668 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Coordination Chemistry by : Geoffrey Wilkinson
Download or read book Comprehensive Coordination Chemistry written by Geoffrey Wilkinson and published by Elsevier Science & Technology. This book was released on 1987 with total page 1626 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume three deals with the coordination chemistry of the elements in the common order based on the Periodic Table. The sequence of treatment of complexes of particular ligands for each metal follows the order given in the discussion of parent ligands.
Book Synopsis Mechanisms of Inorganic and Organometallic Reactions by : M. V. Twigg
Download or read book Mechanisms of Inorganic and Organometallic Reactions written by M. V. Twigg and published by . This book was released on 1983 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanisms of Inorganic and Organometallic Reactions by :
Download or read book Mechanisms of Inorganic and Organometallic Reactions written by and published by . This book was released on 1983 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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