The Conservation of Orbital Symmetry

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Publisher : Elsevier
ISBN 13 : 148328204X
Total Pages : 185 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis The Conservation of Orbital Symmetry by : R. B. Woodward

Download or read book The Conservation of Orbital Symmetry written by R. B. Woodward and published by Elsevier. This book was released on 2013-10-22 with total page 185 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Conservation of Orbital Symmetry examines the principle of conservation of orbital symmetry and its use. The central content of the principle was that reactions occur readily when there is congruence between orbital symmetry characteristics of reactants and products, and only with difficulty when that congruence does not obtain—or to put it more succinctly, orbital symmetry is conserved in concerted reaction. This principle is expected to endure, whatever the language in which it may be couched, or whatever greater precision may be developed in its application and extension. The book opens with a review of the elementary aspects of the molecular orbital theory of bonding. This is followed by separate chapters on correlation diagrams, the conservation of orbital symmetry, theory of electrocyclic reactions, theory of cycloadditions and cycloreversions, and theory of sigmatropic reactions. Subsequent chapters deal with group transfers and eliminations; secondary conformational effects in concerted cycloaddition reactions; and generalized selection rules for pericyclic reactions.

The Conservation of Orbital Symmetry

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Publisher :
ISBN 13 : 9781483232904
Total Pages : pages
Book Rating : 4.2/5 (329 download)

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Book Synopsis The Conservation of Orbital Symmetry by : R. B. Woodward

Download or read book The Conservation of Orbital Symmetry written by R. B. Woodward and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Conservation of Orbital Symmetry examines the principle of conservation of orbital symmetry and its use. The central content of the principle was that reactions occur readily when there is congruence between orbital symmetry characteristics of reactants and products, and only with difficulty when that congruence does not obtain-or to put it more succinctly, orbital symmetry is conserved in concerted reaction. This principle is expected to endure, whatever the language in which it may be couched, or whatever greater precision may be developed in its application and extension. The book ope ...

The Conservation of Orbital Symmetry

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Publisher :
ISBN 13 :
Total Pages : 177 pages
Book Rating : 4.:/5 (959 download)

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Book Synopsis The Conservation of Orbital Symmetry by : Roald Hoffmann

Download or read book The Conservation of Orbital Symmetry written by Roald Hoffmann and published by . This book was released on 2000 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt:

An Introduction to Conservation of Orbital Symmetry

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Author :
Publisher : Longman Publishing Group
ISBN 13 :
Total Pages : 96 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis An Introduction to Conservation of Orbital Symmetry by : Anthony J. Bellamy

Download or read book An Introduction to Conservation of Orbital Symmetry written by Anthony J. Bellamy and published by Longman Publishing Group. This book was released on 1974 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Orbital Symmetry and Reaction Mechanism

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Publisher : Springer Science & Business Media
ISBN 13 : 3642835686
Total Pages : 322 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Orbital Symmetry and Reaction Mechanism by : E.Amitai Halevi

Download or read book Orbital Symmetry and Reaction Mechanism written by E.Amitai Halevi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Criteria of orbital symmetry conservation had a profound influence on mechanistic thinking in organic chemistry and are still commonly applied today. The author presents a coherent set of operational rules for the analysis of scope and reliability. It is written from the viewpoint of Orbital Correspondence Analysis in Maximum Symmetry (OCAMS). Its advantage lies in its provision of a coherent overview of the relation between symmetry and mechanism. For reasons of consistency, the book remains within the framework of molecular orbital theory.

Orbital Symmetry

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Publisher : Elsevier
ISBN 13 : 148326775X
Total Pages : 201 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Orbital Symmetry by : Roland E. Lehr

Download or read book Orbital Symmetry written by Roland E. Lehr and published by Elsevier. This book was released on 2013-09-03 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: Orbital Symmetry: A Problem-Solving Approach was born of the necessity to present to students Woodward and Hoffmann's approach to pericyclic reactions. Hence the tone is introductory, and the book is addressed primarily to an audience of advanced undergraduate and beginning graduate students. The text seeks to familiarize the readers with several of the more often encountered methods of analyzing pericyclic reactions, and these methods should enable the analysis of virtually all of them. Problem solving is the foundation of the approach. Both the introductory and theory sections include problems to prepare the reader for the more extensive chapters of problems that follow. All problems (except those in Chapter VII) are answered in the text and are fully referenced where appropriate. Many of the problems require the use of molecular models if they are to be appreciated. Prentice-Hall's ""Framework Molecular Models"" and Benjamin's ""Maruzen Models"" are best suited for the construction of the highly strained molecules often encountered in the problems, and their use is recommended.

The Conservation of Orbital Symmetry

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Author :
Publisher :
ISBN 13 :
Total Pages : 177 pages
Book Rating : 4.:/5 (888 download)

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Book Synopsis The Conservation of Orbital Symmetry by : Roald Hoffmann (Chemiker)

Download or read book The Conservation of Orbital Symmetry written by Roald Hoffmann (Chemiker) and published by . This book was released on 1970 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Steric and Stereoelectronic Effects in Organic Chemistry

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Publisher : Springer Nature
ISBN 13 : 303075622X
Total Pages : 262 pages
Book Rating : 4.0/5 (37 download)

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Book Synopsis Steric and Stereoelectronic Effects in Organic Chemistry by : Veejendra K. Yadav

Download or read book Steric and Stereoelectronic Effects in Organic Chemistry written by Veejendra K. Yadav and published by Springer Nature. This book was released on 2021-07-01 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this second edition, the author has thoroughly updated each chapter and expanded the content with addition of three new chapters. This book comments on several key aspects of stereochemical control of organic reactions in measured detail to allow the reader easily grasp these concepts. In addition, emphasis is given to key information and important aspects of steric and stereoelectronic effects and their control on conformational profile and reactivity features. This book is not only an indispensable resource for advanced undergraduate and graduate students studying the stereochemical aspects of organic reactions, but also a good reference book for all organic chemists in both industry and academia.

Hückel Molecular Orbital Theory

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Publisher : Elsevier
ISBN 13 : 0323152996
Total Pages : 384 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Hückel Molecular Orbital Theory by : Keith Yates

Download or read book Hückel Molecular Orbital Theory written by Keith Yates and published by Elsevier. This book was released on 2012-12-02 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: Huckel Molecular Orbital Theory aims to be a simple, descriptive, and non-mathematical introduction to the Huckel molecular orbital theory and its applications in organic chemistry, thus the more basic text found in the book. The book, after an introduction to related concepts such as quantum mechanics and chemical bonding, discusses the Huckel molecular orbital theory and its basic assumptions; the variation principle and the basic Huckel method; and the use of symmetry properties in simplifying Huckel method orbital calculations. The book also covers other related topics such as the extensions and improvements of the simple Huckel method; the quantitative significance Huckel molecular orbital results; and the principle of conservation of orbital symmetry. The text is recommended for undergraduate students of organic chemistry who wish to be acquainted with the basics of the Huckel molecular orbital theory.

Organic Reactions and Orbital Symmetry

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Publisher : Cambridge University Press
ISBN 13 : 9780521220149
Total Pages : 324 pages
Book Rating : 4.2/5 (21 download)

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Book Synopsis Organic Reactions and Orbital Symmetry by : T. L. Gilchrist

Download or read book Organic Reactions and Orbital Symmetry written by T. L. Gilchrist and published by Cambridge University Press. This book was released on 1979-09-13 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: First published in 1979 as the second edition of a 1972 original, this textbook provides a systematic account of an important area of organic chemistry - that of cycloadditions and molecular rearrangements. The necessary theoretical background for understanding these reactions is presented in non-mathematical form and various alternative approaches to the theory are compared. The core of the book is a descriptive account of various types of cycloaddition and rearrangement reactions. The synthetic importance of these reactions is emphasised and, by providing the mechanistic background, the book demonstrates to the reader the relationship between the different types of reactions. This book will be of value to anyone with an interest in organic chemistry.

Orbital Interaction Theory of Organic Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 0471461849
Total Pages : 360 pages
Book Rating : 4.4/5 (714 download)

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Book Synopsis Orbital Interaction Theory of Organic Chemistry by : Arvi Rauk

Download or read book Orbital Interaction Theory of Organic Chemistry written by Arvi Rauk and published by John Wiley & Sons. This book was released on 2004-04-07 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: A practical introduction to orbital interaction theory and its applications in modern organic chemistry Orbital interaction theory is a conceptual construct that lies at the very heart of modern organic chemistry. Comprising a comprehensive set of principles for explaining chemical reactivity, orbital interaction theory originates in a rigorous theory of electronic structure that also provides the basis for the powerful computational models and techniques with which chemists seek to describe and exploit the structures and thermodynamic and kinetic stabilities of molecules. Orbital Interaction Theory of Organic Chemistry, Second Edition introduces students to the fascinating world of organic chemistry at the mechanistic level with a thoroughly self-contained, well-integrated exposition of orbital interaction theory and its applications in modern organic chemistry. Professor Rauk reviews the concepts of symmetry and orbital theory, and explains reactivity in common functional groups and reactive intermediates in terms of orbital interaction theory. Aided by numerous examples and worked problems, he guides readers through basic chemistry concepts, such as acid and base strength, nucleophilicity, electrophilicity, and thermal stability (in terms of orbital interactions), and describes various computational models for describing those interactions. Updated and expanded, this latest edition of Orbital Interaction Theory of Organic Chemistry includes a completely new chapter on organometallics, increased coverage of density functional theory, many new application examples, and worked problems. The text is complemented by an interactive computer program that displays orbitals graphically and is available through a link to a Web site. Orbital Interaction Theory of Organic Chemistry, Second Edition is an excellent text for advanced-level undergraduate and graduate students in organic chemistry. It is also a valuable working resource for professional chemists seeking guidance on interpreting the quantitative data produced by modern computational chemists.

Pericyclic Reactions

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Publisher : Springer Science & Business Media
ISBN 13 : 9400957181
Total Pages : 278 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Pericyclic Reactions by : G. Gill

Download or read book Pericyclic Reactions written by G. Gill and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: ??1???1??orbita1 theory has had some notable successes in the ana1ysis of individua1 organic reactions and in corre1ations between reaction series. Gen???ll? the theory has???? invoked to exp1ain known chemica1 phenomena, and rather infrequent1y [?? broad1y-based predictions. In 1965 Woodward and??????? published? series of papers?? the??1???1??orbita1 inter pretation of various types of concerted cyc10-addition reactions, which hitherto had???? rather????1? understood. Because these processes (now known as pericyclic reactions) had great synthetic importance, and because the Woodward-Hoffmann theory was stated so explicit1y as to allow [?? usefu1 and far-reaching predictions to?? made, the genera1 acceptance of the so-called Woodward-Hoffmann Ru1es was very rapid. Judging from the vast number of publications that have appeared,? great dea1 of experimentaleffort has???? channelled into this genera1 area since that time, the results of which provide? vindication of the ru1es. The theoretica1 basis of Woodward and Hoffmann's method has, however,???? the subject of criticism and controversy, and??????? of alternative theoretica1 methods have a1so appeared.???? university departments (inc1uding?ur own) have for some time covered pericyclic reactions in their undergraduate and graduate courses. Because aims, teaching methods, and persona1 preferences differ wide1y, each of the various theoretica1 methods have achieved some currency. We have sought to?1??? these methods in some sort of perspective. The book is intended to?? introductory, being aimed primarily at fina1 year undergraduates and first year postgraduates.

Symmetry and Spectroscopy

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Publisher : Courier Corporation
ISBN 13 : 9780486661445
Total Pages : 588 pages
Book Rating : 4.6/5 (614 download)

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Book Synopsis Symmetry and Spectroscopy by : Daniel C. Harris

Download or read book Symmetry and Spectroscopy written by Daniel C. Harris and published by Courier Corporation. This book was released on 1989-01-01 with total page 588 pages. Available in PDF, EPUB and Kindle. Book excerpt: Informal, effective undergraduate-level text introduces vibrational and electronic spectroscopy, presenting applications of group theory to the interpretation of UV, visible, and infrared spectra without assuming a high level of background knowledge. 200 problems with solutions. Numerous illustrations. "A uniform and consistent treatment of the subject matter." — Journal of Chemical Education.

Solids and Surfaces

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Publisher : John Wiley & Sons
ISBN 13 : 1119809924
Total Pages : 155 pages
Book Rating : 4.1/5 (198 download)

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Book Synopsis Solids and Surfaces by : Roald Hoffmann

Download or read book Solids and Surfaces written by Roald Hoffmann and published by John Wiley & Sons. This book was released on 2021-01-29 with total page 155 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dieses einzigartige Buch läßt Chemie und Physik im festen Zustand und auf Oberflächen 'zusammentreffen'. In einer lebhaften und anschaulichen Weise bringt es Chemikern die Sprache bei, mit der sie die Elektronenstruktur ausgedehnter Systeme verstehen lernen können. Gleichzeitig zeigt es, wie auch von Seiten der Chemie Modelle über den festen Zustand sowie über Bindungen und Reaktivität von Oberflächen erstellt werden können. Das Buch bedient sich zunächst der Sprache von Kristallorbitalen, Bandstrukturen und Zustandsdichten. Danach stellt es die Werkzeuge bereit, mit denen der Leser weg von den stark delokalisierten Orbitalen des Festkörpers gelangt, darunter der Zerfall von Zustandsdichten und die Population von Kristallorbital-Overlaps. Mit diesen Werkzeugen schafft es der Autor, detaillierte quantenmechanische Berechnungen mit der chemischen Betrachtungsweise mit Grenzorbitalen zu verknüpfen. Die beschriebenen Anwendungen umfassen eine allgemeine Vorstellung der Chemisorption, Bindungsbildung und -zerfall im festen Zustand, Bindungen im Metall, die Elektronenstruktur ausgewählter leitender und supraleitender Verbindungen sowie die für die Deformation ausgedehnter Systeme verantwortlichen Kräfte.

Orbital Symmetry Correlations in Organic Chemistry

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Publisher :
ISBN 13 : 9780442023188
Total Pages : 60 pages
Book Rating : 4.0/5 (231 download)

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Book Synopsis Orbital Symmetry Correlations in Organic Chemistry by : Norman Entwistle

Download or read book Orbital Symmetry Correlations in Organic Chemistry written by Norman Entwistle and published by . This book was released on 1972-01-01 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Orbital Symmetry Papers

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Publisher :
ISBN 13 :
Total Pages : 384 pages
Book Rating : 4.X/5 (4 download)

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Book Synopsis Orbital Symmetry Papers by : Howard E. Simmons

Download or read book Orbital Symmetry Papers written by Howard E. Simmons and published by . This book was released on 1974 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Applications of Orbital Symmetry

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (841 download)

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Book Synopsis Applications of Orbital Symmetry by : G.L. Goe

Download or read book Applications of Orbital Symmetry written by G.L. Goe and published by . This book was released on 1976 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: