The Anomeric Effect

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The Anomeric Effect

Author : Eusebio Juaristi
Publisher : CRC Press
ISBN 13 : 9780849389412
Total Pages : 248 pages
Book Rating : 4.3/5 (894 download)

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Book Synopsis The Anomeric Effect by : Eusebio Juaristi

Download or read book The Anomeric Effect written by Eusebio Juaristi and published by CRC Press. This book was released on 1994-10-12 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive review of the structural, conformational, and chemical manifestations of the anomeric effect. In order to present a cogent discussion of this most fundamental and relevant phenomenon, three chapters examine our present understanding of the origin of this conformational effect, based upon a wealth of theoretical and physical data. Equally important, however, are three additional chapters that deal with the general consequences of the stereoelectronic interactions that are associated with the basis of the anomeric effect. The remainder of the book is devoted to new areas of development in the topic-such as differentiation of the endo and exo anomeric interactions, specific analysis of the enthalpic component of anomeric effects, critical evaluation of the kinetics and reverse anomeric effects, discovery of a new substantial effect in second- and lower-row anomeric segments, and others.

The Anomeric Effect and Related Stereoelectronic Effects at Oxygen

Author : A. J. Kirby
Publisher : Springer Science & Business Media
ISBN 13 : 3642686761
Total Pages : 157 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis The Anomeric Effect and Related Stereoelectronic Effects at Oxygen by : A. J. Kirby

Download or read book The Anomeric Effect and Related Stereoelectronic Effects at Oxygen written by A. J. Kirby and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 157 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Anomeric Effect and Associated Stereoelectronic Effects

Author : Gregory Robert James Thatcher
Publisher : Washington, DC : American Chemical Society
ISBN 13 :
Total Pages : 716 pages
Book Rating : 4.:/5 (3 download)

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Book Synopsis The Anomeric Effect and Associated Stereoelectronic Effects by : Gregory Robert James Thatcher

Download or read book The Anomeric Effect and Associated Stereoelectronic Effects written by Gregory Robert James Thatcher and published by Washington, DC : American Chemical Society. This book was released on 1871 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: Discusses contemporary experimental and computational studies on the anomeric effect and related stereoelectronic effects and presents conflicting data and theories in this highly controversial area. Explores applications in carbohydrate chemistry, including enzymology, as well as organometallic chemistry and the chemistry of phosphates and sulfates. Includes examination of molecular modeling methods in compounds influenced by stereoelectronic effects.

Stereoelectronic Effects

Author : Anthony John Kirby
Publisher : Oxford University Press, USA
ISBN 13 :
Total Pages : 108 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Stereoelectronic Effects by : Anthony John Kirby

Download or read book Stereoelectronic Effects written by Anthony John Kirby and published by Oxford University Press, USA. This book was released on 1996 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereoelectronic effects control the way molecules are put together an d account for the "rules of engagement" which operate when molecules m eet and react. Understanding these effects is the key to understanding molecular behavior, since the same basic three-dimensional interactio ns are responsible for both structure and reactivity. This concise and very accessible volume provides a comprehensive, intentionally non-ma thematical coverage of stereochemistry, along with an in-depth discuss ion of the main classes of organic reactions, promoting a logical and simple way of thinking about chemistry.

Stereoelectronic Effects

Author : Igor V. Alabugin
Publisher : John Wiley & Sons
ISBN 13 : 1118906349
Total Pages : 404 pages
Book Rating : 4.1/5 (189 download)

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Book Synopsis Stereoelectronic Effects by : Igor V. Alabugin

Download or read book Stereoelectronic Effects written by Igor V. Alabugin and published by John Wiley & Sons. This book was released on 2016-10-17 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and reactivity of organic molecules An advanced textbook that provides an up-to-date overview of the field, starting from the fundamental principles Presents a large selection of modern examples of stereoelectronic effects in organic reactivity Shows practical applications of stereoelectronic effects in asymmetric catalysis, photochemical processes, bioorganic chemistry and biochemistry, inorganic and organometallic reactivity, supramolecular chemistry and materials science

Steric and Stereoelectronic Effects in Organic Chemistry

Author : Veejendra K. Yadav
Publisher : Springer Nature
ISBN 13 : 303075622X
Total Pages : 262 pages
Book Rating : 4.0/5 (37 download)

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Book Synopsis Steric and Stereoelectronic Effects in Organic Chemistry by : Veejendra K. Yadav

Download or read book Steric and Stereoelectronic Effects in Organic Chemistry written by Veejendra K. Yadav and published by Springer Nature. This book was released on 2021-07-01 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this second edition, the author has thoroughly updated each chapter and expanded the content with addition of three new chapters. This book comments on several key aspects of stereochemical control of organic reactions in measured detail to allow the reader easily grasp these concepts. In addition, emphasis is given to key information and important aspects of steric and stereoelectronic effects and their control on conformational profile and reactivity features. This book is not only an indispensable resource for advanced undergraduate and graduate students studying the stereochemical aspects of organic reactions, but also a good reference book for all organic chemists in both industry and academia.

Explorations with Sugars

Author : Raymond U. Lemieux
Publisher : Washington, DC : American Chemical Society
ISBN 13 :
Total Pages : 216 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Explorations with Sugars by : Raymond U. Lemieux

Download or read book Explorations with Sugars written by Raymond U. Lemieux and published by Washington, DC : American Chemical Society. This book was released on 1990 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: World-famous carbohydrate chemist Raymond Lemieux was the first to synthesize sucrose. He also developed the concept of the anomeric effect and has recently worked on antigens. His book is a collection of carbohydrate research history, plus an interesting and engaging insight into the man as scientist and family man.

Glycoscience

Author : Bertram O. Fraser-Reid
Publisher : Springer Science & Business Media
ISBN 13 : 3540361545
Total Pages : 2847 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis Glycoscience by : Bertram O. Fraser-Reid

Download or read book Glycoscience written by Bertram O. Fraser-Reid and published by Springer Science & Business Media. This book was released on 2008-04-14 with total page 2847 pages. Available in PDF, EPUB and Kindle. Book excerpt: As a reflection of the quantum leap that has been made in the study of glycostructures, the first edition of this book has been completely revised and updated. The editors give up-to-date information on glycostructures, their chemistry and chemical biology in the form of a completely comprehensive survey. Glycostructures play highly diverse and crucial roles in a myriad of organisms and important systems in biology, physiology, medicine, bioengineering and technology. Only in recent years have the tools been developed to partly understand the highly complex functions and the chemistry behind them. While many facts remain undiscovered, this MRW has been contributed to by a large number of the world’s leading researchers in the field.

The Carbohydrates Volume 1A

Author : W.W. Pigman
Publisher : Elsevier
ISBN 13 : 0323138330
Total Pages : 667 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis The Carbohydrates Volume 1A by : W.W. Pigman

Download or read book The Carbohydrates Volume 1A written by W.W. Pigman and published by Elsevier. This book was released on 2012-12-02 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Carbohydrates: Chemistry and Biochemistry, Second Edition, Volume IA deals with the chemical and biochemical aspects of carbohydrates such as monosaccharides, sugars, esters, halogen derivatives, phosphates, glycosides, glycosans, alditols, and cyclitols. Topics range from carbohydrate chemistry and stereochemistry to the synthesis of naturally occurring monosaccharides, mutarotations and actions of acids and bases, conformations of sugars, and reactivity of saccharide hydroxyl groups toward esterification. This book consists of 15 chapters that explore the effects of ionizing radiations and autoxidation reactions, physical methods and methods of separation, nucleosides and antibiotics, and the biosynthesis of sugars and complex saccharides. The rapidly growing fields of glycolipids and glycoproteins are also discussed. In addition, the reader is introduced to halogen derivatives such as glycosyl halides and nonanomeric halides, along with the hydrolysis and synthesis of phosphates and other inorganic esters, determination of the structure of glycosides, and the physical and chemical properties of acyclic derivatives. The two final chapters cover the official nomenclature rules for carbohydrates and for enzymes having carbohydrates as substrates. This book will be of interest to chemists and biochemists.

Molecular Structure

Author : Norman L. Allinger
Publisher : John Wiley & Sons
ISBN 13 : 1118043529
Total Pages : 356 pages
Book Rating : 4.1/5 (18 download)

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Book Synopsis Molecular Structure by : Norman L. Allinger

Download or read book Molecular Structure written by Norman L. Allinger and published by John Wiley & Sons. This book was released on 2010-12-15 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to analyzing the structures and properties of organic molecules Until recently, the study of organic molecules has traveled down two disparate intellectual paths—the experimental, or physical, method and the computational, or theoretical, method. Working somewhat independently of each other, these disciplines have guided research for decades, but they are now being combined efficiently into one unified strategy. Molecular Structure delivers the essential fundamentals on both the experimental and computational methods, then goes further to show how these approaches can join forces to produce more effective analysis of the structure and properties of organic compounds by: Looking at experimental structures: electron, neutron, X-ray diffraction, and microwave spectroscopy as well as computational structures: ab initio, semi-empirical molecular orbital, and molecular mechanics calculations Discussing various electronic effects, particularly stereoelectronic effects, including hyperconjugation, negative hyperconjugation, the Bohlmann and anomeric effects, and how and why these cause changes in structures and properties of molecules Illustrating complex carbohydrate effects such as the gauche effect, the delta-two effect, and the external anomeric torsional effect Covering hydrogen bonding, the CH bond, and how energies, especially heats of formation, can be affected Using molecular mechanics to tie all of these things together in the familiar language of the organic chemist, valence bond pictures Authored by a founding father of computational chemistry, Molecular Structure broadens the scope of the subject by serving as a pioneering guide for workers in the fields of organic, biological, and computational chemistry, as they explore new possibilities to advance their discoveries. This work will also be of interest to many of those in tangential or dependent fields, including medicinal and pharmaceutical chemistry and pharmacology.

Protecting Groups: Strategies and Applications in Carbohydrate Chemistry

Author : Sebastien Vidal
Publisher : John Wiley & Sons
ISBN 13 : 3527340106
Total Pages : 522 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Protecting Groups: Strategies and Applications in Carbohydrate Chemistry by : Sebastien Vidal

Download or read book Protecting Groups: Strategies and Applications in Carbohydrate Chemistry written by Sebastien Vidal and published by John Wiley & Sons. This book was released on 2019-04-29 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique overview of the most important protecting group strategies in carbohydrate chemistry Protecting Groups: Strategies and Applications in Carbohydrate Chemistry provides a detailed account of key strategies and methodologies for the protection of carbohydrates. Divided into two parts, the first focuses on groups that are used best to protect a specific position on a carbohydrate. In the second part, specific carbohydrate residues or compounds are discussed in the context of a specific protecting group strategy used to reach the desired regioisomer. This important book: -Features chapters on protecting groups at the primary and secondary positions of carbohydrates -Describes protecting group strategies towards sialic acid derivatives, glycofuranoses, sulfated glycosaminoglycans, and cyclodextrins -Provides information on automated glycan assembly -Includes a chapter on the industrial scale synthesis of heparin analogs Written by a team of leaders in the field, Protecting Groups: Strategies and Applications in Carbohydrate Chemistry is an indispensable guide for academics and industrial researchers interested in carbohydrate and natural product synthesis, pharmaceutical chemistry, and biochemistry.

Essentials of Glycobiology

Author : Ajit Varki
Publisher : CSHL Press
ISBN 13 : 9780879696818
Total Pages : 694 pages
Book Rating : 4.6/5 (968 download)

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Book Synopsis Essentials of Glycobiology by : Ajit Varki

Download or read book Essentials of Glycobiology written by Ajit Varki and published by CSHL Press. This book was released on 1999 with total page 694 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sugar chains (glycans) are often attached to proteins and lipids and have multiple roles in the organization and function of all organisms. "Essentials of Glycobiology" describes their biogenesis and function and offers a useful gateway to the understanding of glycans.

Organozinc Reagents in Organic Synthesis

Author : Ender Erdik
Publisher : CRC Press
ISBN 13 : 1000151719
Total Pages : 436 pages
Book Rating : 4.0/5 (1 download)

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Book Synopsis Organozinc Reagents in Organic Synthesis by : Ender Erdik

Download or read book Organozinc Reagents in Organic Synthesis written by Ender Erdik and published by CRC Press. This book was released on 2020-09-24 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organozinc reagents are used extensively in organic synthesis to find useful pathways to organic products. Illustrated and tabulated with over 950 equations, schemes, tables, and figures, Organozinc Reagents in Organic Synthesis provides an overall picture of the chemistry of organozinc compounds. Written by a professor of organic chemistry, the book familiarizes the reader with the reactions involving organozinc reagents that have general usefulness in synthesis. Emphasis is placed on preparation methods and reactivity of organozinc reagents. Reactions are summarized in equations and schemes, making it easy for you to see the characteristics of each type of reaction.

Aromaticity and Other Conjugation Effects

Author : Rolf Gleiter
Publisher : John Wiley & Sons
ISBN 13 : 352732934X
Total Pages : 486 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Aromaticity and Other Conjugation Effects by : Rolf Gleiter

Download or read book Aromaticity and Other Conjugation Effects written by Rolf Gleiter and published by John Wiley & Sons. This book was released on 2012-09-24 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors provide an excellent overview of conjugation effects in organic chemistry within and between Pi systems. Besides various aspects of aromaticity one finds detailed discussions of homo-, spiroand hyperconjugation as well as effects of through-space and throughbond interactions. These effects are presented on the basis of experimental results and are analyzed by the use of qualitative arguments of perturbation theory and from a comparison with results from high level ab initio calculations. This book is a must-have for bachelor students from the second year on, master and PhD students of chemistry. Also students in science such as physics, biology and medicine will benefit from the concepts described in the book. Furthermore, chemists in research and development will be grateful to find here an overview of conjugation effects allowing to understand the structures, the dynamics and the reactivity of molecules.

Stereoelectronic Effects in Organic Chemistry

Author : Pierre Deslongchamps
Publisher : Pergamon
ISBN 13 :
Total Pages : 396 pages
Book Rating : 4.X/5 (1 download)

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Book Synopsis Stereoelectronic Effects in Organic Chemistry by : Pierre Deslongchamps

Download or read book Stereoelectronic Effects in Organic Chemistry written by Pierre Deslongchamps and published by Pergamon. This book was released on 1983 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Conformation of Carbohydrates

Author : V. S. R. Rao
Publisher : CRC Press
ISBN 13 : 1000717542
Total Pages : 374 pages
Book Rating : 4.0/5 (7 download)

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Book Synopsis Conformation of Carbohydrates by : V. S. R. Rao

Download or read book Conformation of Carbohydrates written by V. S. R. Rao and published by CRC Press. This book was released on 2019-08-22 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text will give the reader a firm understanding of all aspects of carbohydrate conformation by describing and explaining the importance of interactions between carbohydrates and interactions of carbohydrates with proteins, nucleic acids or any other macromolecule., The authors have gathered a wealth of information on carbohydrate structures, different methods of conformational analysis, the role of carbohydrates as recognition molecules in biological systems and their industrial applications., Whether you are a student, teacher or a basic researcher, this text book is a ‘one-stop’ source of current information on carbohydrate conformation and the potential use of conformational properties in industry and also of their crucial role in important biological events such as cell-cell interaction, cell adhesion, cellular signaling mechanism.

Advanced Organic Chemistry

Author : Francis A. Carey
Publisher : Springer Science & Business Media
ISBN 13 : 0387448993
Total Pages : 1216 pages
Book Rating : 4.3/5 (874 download)

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Book Synopsis Advanced Organic Chemistry by : Francis A. Carey

Download or read book Advanced Organic Chemistry written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2007-06-27 with total page 1216 pages. Available in PDF, EPUB and Kindle. Book excerpt: The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.