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Tertiary Amine Complexes Of Cobalt Ii And Nickel Ii Trifluoromethanesulfonates
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Book Synopsis Tertiary Amine Complexes of Cobalt (II) and Nickel (II) Trifluoromethanesulfonates by : Michael Thelen Jansky
Download or read book Tertiary Amine Complexes of Cobalt (II) and Nickel (II) Trifluoromethanesulfonates written by Michael Thelen Jansky and published by . This book was released on 1978 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrated cobalt(II) and nickel(II) trifluoromethanesulfonates have been prepared by a previously reported procedure, and have been characterized for the first time as [Co(H2O)6] (CF3SO3)2H2O and [Ni(H2O)6] (CF3SO3)2. These formulations are based on analyses, near-infrared spectra, and on measurements of the ligand field electronic spectra and the magnetic susceptibilities. The metal ions are high-spin and octahedrally coordinated in both compounds. Methods have been developed for the preparation of the pure anhydrous cobalt(II) and the previously unknown nickel(II) trifluoromethanesulfonates from the hydrates. By determination of the d-d spectra and the magnetic moments, these are found to contain high-spin octahedrally coordinated metal cations, and therefore contain coordinated trifluoromethanesulfonate anions. The near-infrared spectral absorptions of these anions have been observed. The magnetic moment reported by previous workers for anhydrous cobalt(II) trifluoromethanesulfonate corresponds to the value found in this work for the hydrate. By vacuum line methods, pressure-composition data have been obtained for the triethylamine-cobalt(II) and nickel(II) trifluoromethanesulfonate systems. Breaks in the 25° isothermal phase diagrams show that very unstable adducts containing two molecules of triethylamine per metal ion are formed in each system. These could not be isolated. Various experimental methods for the preparation of quinuclidine complexes were investigated. The one found to be successful involved mixing, by Schlenk techniques, acetonitrile solutions of the anhydrous metal trifluoromethanesulfonate and of an excess of quinuclidine, evaporating the solvent, and removing the excess quinuclidine by sublimation. The solid complexes obtained in this way were characterized as [Co(QUIN)4] (CF3SO3)2 and [Ni(QUIN)2(CF3SO3)2] by their analyses, ligand field spectra, magnetic moments, and the near-infrared absorptions of the anions. As expected, quinuclidine is found to be a better ligand than its more sterically demanding analogue, triethylamine. The quinuclidine complexes of cobalt(II) and nickel(II) trifluoromethanesulfonates are much more stable. In the case of the cobalt complexes, the metal ion has a greater ligation number for quinuclidine than for triethylamine. In these solid salts and complexes, the trifluoromethanesulfonate ion shows a much greater tendency to coordinate than had been expected, based on a previous study using it in aqueous solution.
Book Synopsis Synthesis and Characterization of Cobalt (II), Nickel (II), and Copper (II) Complexes with 3, 3'-bis(p̲-X-benzoylacetoneiminato)bis(trimethylene)amine Ligands by : Yu-Ying Chen
Download or read book Synthesis and Characterization of Cobalt (II), Nickel (II), and Copper (II) Complexes with 3, 3'-bis(p̲-X-benzoylacetoneiminato)bis(trimethylene)amine Ligands written by Yu-Ying Chen and published by . This book was released on 1979 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Masters Theses in the Pure and Applied Sciences by : W. H. Shafer
Download or read book Masters Theses in the Pure and Applied Sciences written by W. H. Shafer and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 307 pages. Available in PDF, EPUB and Kindle. Book excerpt: Masters Theses in the Pure and Applied Sciences was first conceived, published, and dis seminated by the Center for Information and Numerical Data Analysis and Synthesis (CINDAS) * at Purdue University in 1957, starting its coverage of theses with the academic year 1955. Beginning with Volume 13, the printing and dissemination phases of the ac tivity were transferred to University Microfilms/Xerox of Ann Arbor, Michigan, with the thought that such an arrangement would be more beneficial to the academic and general scientific and technical community. After five years of this joint undertaking we had concluded that it was in the interest of all concerned if the printing and distribution of the volume were handled by an international publishing house to assure improved service and broader dissemination. Hence, starting with Volume 18, Masters Theses in the Pure and Applied Sciences has been disseminated on a worldwide basis by Plenum Publishing Corporation of New York, and in the same year the coverage was broadened to include Canadian universities. All back issues can also be ordered from Plenum. We have reported in Volume 24 (thesis year 1979) a total of 10,033 theses titles from 26 Canadian and 215 United States universities. We are sure that this broader base for theses titles reported will greatly enhance the value of this important annual reference work. While Volume 24 reports these submitted in 1979, on occasion, certain universities do report theses submitted in previous years but not reported at the time.
Book Synopsis Coordination Studies of Cobalt (II) and Nickel (II) Complexes of 1, 1, 3, 3-tetramethylurea and 1,1,3, 3-tetramethyl-2 Thiourea by : Thomas Morgan King
Download or read book Coordination Studies of Cobalt (II) and Nickel (II) Complexes of 1, 1, 3, 3-tetramethylurea and 1,1,3, 3-tetramethyl-2 Thiourea written by Thomas Morgan King and published by . This book was released on 1966 with total page 115 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis 1. Cyclic Diamine Complexes of Cobalt(II)-variations with Cobalt(II), Nickel(II) and Coper(II) by : Edward Danner Steffen
Download or read book 1. Cyclic Diamine Complexes of Cobalt(II)-variations with Cobalt(II), Nickel(II) and Coper(II) written by Edward Danner Steffen and published by . This book was released on 1972 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis An Experimental and Theoretical Study of Cobalt (II) and Nickel (II) Complexes with Acetonitrile as Ligands by : Peter Chuen Sun Kong
Download or read book An Experimental and Theoretical Study of Cobalt (II) and Nickel (II) Complexes with Acetonitrile as Ligands written by Peter Chuen Sun Kong and published by . This book was released on 1978 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Complexes of Cobalt (II) and Nickel (II) Salts with 2-, 3-, and 4-aminobenzonitrile by : Mbangni Mike Ndefru
Download or read book Complexes of Cobalt (II) and Nickel (II) Salts with 2-, 3-, and 4-aminobenzonitrile written by Mbangni Mike Ndefru and published by . This book was released on 1989 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elemental analysis and other analytical procedures were performed to establish the formulas of the compounds. Heat profiles of the samples were obtained by subjecting (using a differential scanning calorimeter) the samples to a thermal gradient.
Book Synopsis Cobalt (II) and Nickel (II) Complexes of [gamma]-thiobutyrolactam and N-methyl-[gamma]-thiobutyrolactam by : Michael Sulich
Download or read book Cobalt (II) and Nickel (II) Complexes of [gamma]-thiobutyrolactam and N-methyl-[gamma]-thiobutyrolactam written by Michael Sulich and published by . This book was released on 1967 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Lacunar 14-membered Cyclidene Complexes of Nickel(II) and Cobalt(II) by : Jihong Chen
Download or read book Synthesis and Characterization of Lacunar 14-membered Cyclidene Complexes of Nickel(II) and Cobalt(II) written by Jihong Chen and published by . This book was released on 1992 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Sterically Hindered Complexes of Cobalt (II) and Nickel (II). by : Zvi Dori
Download or read book Sterically Hindered Complexes of Cobalt (II) and Nickel (II). written by Zvi Dori and published by . This book was released on 1968 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Cobalt (II) and Nickel (II) Complexes of Saturated Diphosphines ... by : Arunachalam Tulsi Ram
Download or read book Cobalt (II) and Nickel (II) Complexes of Saturated Diphosphines ... written by Arunachalam Tulsi Ram and published by . This book was released on 1968 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Complexes of Iron(II), Cobalt(II), and Nickel(II) with Ligands Containing the Conjugated Methine Group by : Robert Carl Stoufer
Download or read book The Complexes of Iron(II), Cobalt(II), and Nickel(II) with Ligands Containing the Conjugated Methine Group written by Robert Carl Stoufer and published by . This book was released on 1959 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Nickel(II) and Cobalt(III) Complexes of Linear Tetradentate Ligands by : Ellen Hsia Hung
Download or read book The Nickel(II) and Cobalt(III) Complexes of Linear Tetradentate Ligands written by Ellen Hsia Hung and published by . This book was released on 1970 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Study of Some Nickel (II) and Cobalt (II) Coordination Complexes with Acetanilides by : Robert Wayne Gray
Download or read book A Study of Some Nickel (II) and Cobalt (II) Coordination Complexes with Acetanilides written by Robert Wayne Gray and published by . This book was released on 1968 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Cobalt(II), Nickel(II), and Copper(II) Complexes of Di- and Tetrapeptides Containing Tyrosine and Glycine Residues by :
Download or read book Cobalt(II), Nickel(II), and Copper(II) Complexes of Di- and Tetrapeptides Containing Tyrosine and Glycine Residues written by and published by . This book was released on 1979 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis O.S.U. Theses and Dissertations, 1978-1982 by : Oregon State University
Download or read book O.S.U. Theses and Dissertations, 1978-1982 written by Oregon State University and published by . This book was released on 1983 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Ligand Exchange and Substitution on Five-coordinate Complexes of Copper (II), Nickel (II) and Cobalt (II) by : Bruce Germein Doddridge
Download or read book Ligand Exchange and Substitution on Five-coordinate Complexes of Copper (II), Nickel (II) and Cobalt (II) written by Bruce Germein Doddridge and published by . This book was released on 1986 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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