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Author : T. Fuchigami
Publisher :
ISBN 13 : 9781607681359
Total Pages : 123 pages
Book Rating : 4.6/5 (813 download)
Download or read book Synthetic and Mechanistic Organic Electron Transfer Reactions written by T. Fuchigami and published by . This book was released on 2010 with total page 123 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : T. Fuchigami
Publisher : The Electrochemical Society
ISBN 13 : 1566777852
Total Pages : 133 pages
Book Rating : 4.5/5 (667 download)
Download or read book Synthetic and Mechanistic Organic Electron Transfer Reactions written by T. Fuchigami and published by The Electrochemical Society. This book was released on 2010-02 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt: The papers included in this issue of ECS Transactions were originally presented in the symposium ¿Synthetic and Mechanistic Organic Electron Transfer Reactions¿, held during the 216th meeting of The Electrochemical Society, in Vienna, Austria from October 4 to 9, 2009.
Author : Lennart Eberson
Publisher : Springer Science & Business Media
ISBN 13 : 3642725449
Total Pages : 245 pages
Book Rating : 4.6/5 (427 download)
Download or read book Electron Transfer Reactions in Organic Chemistry written by Lennart Eberson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.
Author : Lennart Eberson
Publisher :
ISBN 13 : 9783642725456
Total Pages : 252 pages
Book Rating : 4.7/5 (254 download)
Download or read book Electron Transfer Reactions in Organic Chemistry written by Lennart Eberson and published by . This book was released on 1987-08-20 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.
Author : Marye Anne Fox
Publisher : Elsevier Science Limited
ISBN 13 : 9780444871244
Total Pages : 754 pages
Book Rating : 4.8/5 (712 download)
Download or read book Photoinduced Electron Transfer written by Marye Anne Fox and published by Elsevier Science Limited. This book was released on 1988 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron transfer reactions are of great importance to nearly every subdiscipline of chemistry. The simple transfer of a single electron has been shown repeatedly to be a common activating mode for organic, inorganic, and biological molecules, and the very ubiquity of such reactions has guaranteed that their investigation would involve the most fundamental questions of modern chemistry. The fact that photoexcitation induces enhanced redox reactivity via electron transfer also provides a convenient method for experimentally testing theoretical predictions regarding structural and energetic effects. As can be seen from the very size of this work there is a great deal known about photoinduced electron transfer reactions and the editors have tried to capture the diversity and excitement inherent in this broad field. The reader will find contributions from theorists and experimentalists, from organic and inorganic chemists, from the perspective of the synthetic and mechanistic viewpoint. Some contributions are fundamental basic research, while others clearly show practical applications of these principles.These volumes are intended to serve a joint purpose: as a reference resource and an introductory overview to the diverse research accomplished via photoexcitation of electron donor-acceptor systems. The information is organized in four parts. The first deals with the theoretical and conceptual factors which influence electron transfer. The second covers experimental methodology and medium effects. The third and fourth deal with reactivity, with most organic transformation being addressed in Part C and most inorganic reactions covered in Part D. Each part thus provides an overview of typical reactions observed for these classes of compounds. Part D also provides examples of photoinduced electron transfer in current use in important applications. There is of course a significant interdependence between the four parts. Subject, chemical, and author citation indices appear at the end of each of Parts A, B and C, and comprehensive indices are included in Part D.
Author : Jun-Ichi Yoshida
Publisher : John Wiley & Sons
ISBN 13 : 352734487X
Total Pages : 260 pages
Book Rating : 4.5/5 (273 download)
Download or read book Organic Redox Chemistry written by Jun-Ichi Yoshida and published by John Wiley & Sons. This book was released on 2022-03-07 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Redox Chemistry Explore the most recent advancements and synthesis applications in redox chemistry Redox chemistry has emerged as a crucial research topic in synthetic method development. In Organic Redox Chemistry: Chemical, Photochemical and Electrochemical Syntheses, some key researchers in this field, including editors Dr. Frédéric W. Patureau and the late Dr. Jun-Ichi Yoshida, deliver an insightful exploration of this rapidly developing topic. This book highlights electron transfer processes in synthesis by using different techniques to initiate them, allowing for a multi-directional perspective in organic redox chemistry. Covering a wide array of the important and recent developments in the field, Organic Redox Chemistry will earn a place in the libraries of chemists seeking a one-stop resource that compares chemical, photochemical, and electrochemical methods in organic synthesis.
Author : Marye Anne Fox
Publisher : Elsevier Science Limited
ISBN 13 : 9780444871251
Total Pages : 790 pages
Book Rating : 4.8/5 (712 download)
Download or read book Photoinduced Electron Transfer written by Marye Anne Fox and published by Elsevier Science Limited. This book was released on 1988 with total page 790 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron transfer reactions are of great importance to nearly every subdiscipline of chemistry. The simple transfer of a single electron has been shown repeatedly to be a common activating mode for organic, inorganic, and biological molecules, and the very ubiquity of such reactions has guaranteed that their investigation would involve the most fundamental questions of modern chemistry. The fact that photoexcitation induces enhanced redox reactivity via electron transfer also provides a convenient method for experimentally testing theoretical predictions regarding structural and energetic effects. As can be seen from the very size of this work there is a great deal known about photoinduced electron transfer reactions and the editors have tried to capture the diversity and excitement inherent in this broad field. The reader will find contributions from theorists and experimentalists, from organic and inorganic chemists, from the perspective of the synthetic and mechanistic viewpoint. Some contributions are fundamental basic research, while others clearly show practical applications of these principles.These volumes are intended to serve a joint purpose: as a reference resource and an introductory overview to the diverse research accomplished via photoexcitation of electron donor-acceptor systems. The information is organized in four parts. The first deals with the theoretical and conceptual factors which influence electron transfer. The second covers experimental methodology and medium effects. The third and fourth deal with reactivity, with most organic transformation being addressed in Part C and most inorganic reactions covered in Part D. Each part thus provides an overview of typical reactions observed for these classes of compounds. Part D also provides examples of photoinduced electron transfer in current use in important applications. There is of course a significant interdependence between the four parts. Subject, chemical, and author citation indices appear at the end of each of Parts A, B and C, and comprehensive indices are included in Part D.
Author : J. Lessard
Publisher :
ISBN 13 :
Total Pages : 242 pages
Book Rating : 4.F/5 ( download)
Download or read book Analytical, Mechanistic, and Synthetic Organic Electrochemistry written by J. Lessard and published by . This book was released on 2004 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : W.M. Horspool
Publisher : Springer Science & Business Media
ISBN 13 : 1461326818
Total Pages : 542 pages
Book Rating : 4.4/5 (613 download)
Download or read book Synthetic Organic Photochemistry written by W.M. Horspool and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 542 pages. Available in PDF, EPUB and Kindle. Book excerpt: Of all major branches of organic chemistry, I think none has undergone such a rapid, even explosive, development during the past twenty-five years as organic photochemistry. Prior to about 1960, photochemistry was still widely regarded as a branch of physical chemistry which might perhaps have oc casional applications in the generation of free radicals. Strangely enough, this attitude to the subject had developed despite such early signs of promise as the photodimerization of anthracene first observed by Fritzsche in 1866, and some strikingly original pioneering work by Ciamician and Silber in the early years of this century. These latter workers first reported such varied photo reactions as the photoisomerization of carvenone to carvone camphor, the photodimerization of stilbene, and the photoisomerization of o-nitrobenzal dehyde to o-nitrosobenzoic acid; yet organic chemists continued for another fifty years or so to rely almost wholly on thermal rather than photochemical methods of activation in organic synthesis-truly a dark age. When my colleagues and I first began in the 1950s to study the synthetic possibilities of photoexcitation in the chemistry of benzene and its derivatives, virtually all the prior reports had indicated that benzene was stable to ultraviolet radiation. Yet I think it fair to say that more different types of photoreactions than thermal reactions of the benzene ring are now known. Comparable growth of knowledge has occurred in other branches of organic photochemistry, and photochemical techniques have in particular made possible or simplified the synthesis of numerous highly strained organic molecules.
Author : Uma Shanker
Publisher : Elsevier
ISBN 13 : 0128236221
Total Pages : 580 pages
Book Rating : 4.1/5 (282 download)
Download or read book Green Nanomaterials for Industrial Applications written by Uma Shanker and published by Elsevier. This book was released on 2021-09-29 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: Green Nanomaterials for Industrial Applications explores the applications of nanomaterials for a variety of industry sectors, along with their environmental impacts, lifecycle analysis, safety and sustainability. This book brings together the industrial applications of nanomaterials, covering new trends and challenges. Significant properties, safety and sustainability and environmental impacts of synthesis routes are also explored, as are major industrial applications, including agriculture, medicine, communications, construction, energy, and in the military. This book is an important information source for those in research and development who want to gain a greater understanding of how nanotechnology is being used to create cheaper, more efficient products. Green nanomaterials have significant advantages including low cost, high efficiency, neutral environmental impact, and stability. Green Nanomaterials for Industrial Applications provides comprehensive information about green nanomaterials, their types, and methods for generation, characterization as well as their properties. Furthermore, this book also provides coverage of industrial scale fabrication methods for green nanomaterials and their applications for various industrial sectors at both experimental and theoretical models scales. This book is an important reference source for materials scientists, engineers and environmental scientists who want to learn more about how sustainable nanomaterials are being used in a range of industrial applications. Explores industrial scale fabrication of green nanomaterials Assesses environmental, legal, health and safety aspects Discusses how green nanomaterials can be manufactured on an industrial scale
Author : Vincenzo Balzani
Publisher : Wiley-VCH
ISBN 13 : 9783527299126
Total Pages : 864 pages
Book Rating : 4.2/5 (991 download)
Download or read book Electron Transfer in Chemistry, Principles, Theories, Methods, and Techniques written by Vincenzo Balzani and published by Wiley-VCH. This book was released on 2001-05-02 with total page 864 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron transfer is the most important process to take place in natural and artificial chemical systems, playing a fundamental role, for example, in photosynthesis as well as in photography. Electron transfer reactions - oxidations and reductions - are involved in, among others, a variety of energy conversion processes, analytical methods, synthetic strategies, and information processing systems. This five-volume work is the only comprehensive yet up-to-date reference on electron transfer processes. Following a foreword by Nobel prize-winner R. A. Marcus, renowned experts from all over the world provide an interdisciplinary overview of every aspect of electron transfer including theoretical-physicochemical backgrounds, latest analytical techniques to identify, monitor and measure the rate of electron transfer, utilizing electron transfer reactions in organic synthesis and catalysis, electron transfer in the gas phase or in special heterogeneous systems such as zeolites or sensitized electrodes. Other central issues are the study of biological systems and the biomimetic electron transfer processes in artificial supramolecular systems. Finally, a complete volume is dedicated to the application of electron transfer in molecular-level electronics, imaging processes and energy conversion. Each chapter is complemented by numerous tables, formulae and illustrations providing an indispensable wealth of information. All references are cross-indexed throughout the work for easy access to this highly complex topic. Whether for quickly looking-up a keyword or as a thorough introduction to a special aspect, this is an essential handbook for everyone working in the field, from experts to postgraduates, from synthetic chemists, physicochemists or biochemists to research groups in material sciences.
Author : Howard Maskill
Publisher : John Wiley & Sons
ISBN 13 : 0470994169
Total Pages : 392 pages
Book Rating : 4.4/5 (79 download)
Download or read book The Investigation of Organic Reactions and Their Mechanisms written by Howard Maskill and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: A range of alternative mechanisms can usually be postulated for most organic chemical reactions, and identification of the most likely requires detailed investigation. Investigation of Organic Reactions and their Mechanisms will serve as a guide for the trained chemist who needs to characterise an organic chemical reaction and investigate its mechanism, but who is not an expert in physical organic chemistry. Such an investigation will lead to an understanding of which bonds are broken, which are made, and the order in which these processes happen. This information and knowledge of the associated kinetic and thermodynamic parameters are central to the development of safe, efficient, and profitable industrial chemical processes, and to extending the synthetic utility of new chemical reactions in chemical and pharmaceutical manufacturing, and academic environments. Written as a coherent account of the principal methods currently used in mechanistic investigations, at a level accessible to academic researchers and graduate chemists in industry, the book is highly practical in approach. The contributing authors, an international group of expert practitioners of the techniques covered, illustrate their contributions by examples from their own research and from the relevant wider chemical literature. The book covers basic aspects such as product analysis, kinetics, catalysis, and investigation of reactive intermediates. It also includes material on significant recent developments, e.g. computational chemistry, calorimetry, and electrochemistry, in addition to topics of high current industrial relevance, e.g. reactions in multiphase systems, and synthetically useful reactions involving free radicals and catalysis by organometallic compounds.
Author : Martin Oestreich
Publisher : John Wiley & Sons
ISBN 13 : 9780470716069
Total Pages : 608 pages
Book Rating : 4.7/5 (16 download)
Download or read book The Mizoroki-Heck Reaction written by Martin Oestreich and published by John Wiley & Sons. This book was released on 2009-02-11 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)
Author : Marye Anne Fox
Publisher :
ISBN 13 : 9780444871251
Total Pages : 820 pages
Book Rating : 4.8/5 (712 download)
Download or read book Photoinduced Electron Transfer written by Marye Anne Fox and published by . This book was released on 1988 with total page 820 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron transfer reactions are of great importance to nearly every subdiscipline of chemistry. The simple transfer of a single electron has been shown repeatedly to be a common activating mode for organic, inorganic, and biological molecules, and the very ubiquity of such reactions has guaranteed that their investigation would involve the most fundamental questions of modern chemistry. The fact that photoexcitation induces enhanced redox reactivity via electron transfer also provides a convenient method for experimentally testing theoretical predictions regarding structural and energetic effects. As can be seen from the very size of this work there is a great deal known about photoinduced electron transfer reactions and the editors have tried to capture the diversity and excitement inherent in this broad field. The reader will find contributions from theorists and experimentalists, from organic and inorganic chemists, from the perspective of the synthetic and mechanistic viewpoint. Some contributions are fundamental basic research, while others clearly show practical applications of these principles.These volumes are intended to serve a joint purpose: as a reference resource and an introductory overview to the diverse research accomplished via photoexcitation of electron donor-acceptor systems. The information is organized in four parts. The first deals with the theoretical and conceptual factors which influence electron transfer. The second covers experimental methodology and medium effects. The third and fourth deal with reactivity, with most organic transformation being addressed in Part C and most inorganic reactions covered in Part D. Each part thus provides an overview of typical reactions observed for these classes of compounds. Part D also provides examples of photoinduced electron transfer in current use in important applications. There is of course a significant interdependence between the four parts. Subject, chemical, and author citation indices appear at the end of each of Parts A, B and C, and comprehensive indices are included in Part D.
Author : J. Grimshaw
Publisher : Elsevier
ISBN 13 : 0080530729
Total Pages : 415 pages
Book Rating : 4.0/5 (85 download)
Download or read book Electrochemical Reactions and Mechanisms in Organic Chemistry written by J. Grimshaw and published by Elsevier. This book was released on 2000-12-01 with total page 415 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook. As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.
Author : David J Procter
Publisher : Royal Society of Chemistry
ISBN 13 : 184973075X
Total Pages : 214 pages
Book Rating : 4.8/5 (497 download)
Download or read book Organic Synthesis using Samarium Diiodide written by David J Procter and published by Royal Society of Chemistry. This book was released on 2009-11-10 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samarium diiodide is one of the most important reducing agents available to synthetic organic chemists. The lanthanide(II) reagent acts by single-electron transfer to organic substrates leading to the formation of both radical and/or anionic intermediates. The power of the reagent arises from its versatility - samarium diiodide can be used in processes ranging from functional group conversions to elaborate carbon-carbon bond-forming cyclization sequences that result in a dramatic increase in molecular complexity. In addition, reactions involving samarium diiodide often show high stereoselectivity as samarium ions can coordinate to Lewis basic sites on substrates and can direct the stereochemical course of reactions. The ability to fine-tune the reactivity of the reagent by the use of additives and co-solvents is an additional, attractive feature. Although samarium diiodide is used extensively by organic chemists, there is still a widely held view that the reagent can be difficult to prepare and use. In addition, samarium diiodide can mediate such a wide variety of organic chemistry that potential new users are often overawed by the extensive primary literature on the reagent. The objective of this book is to provide a concise, practical guide to the reagent. Rather than being a comprehensive review of the chemistry of samarium diiodide, this user-friendly book adopts an "an all you need to know" approach to the topic. The international authors are well-known for their work with the reagent and their expertise covers current developments in new reactivity and selectivity, applications in target synthesis, co-solvent and additive effects, coordination chemistry and mechanism. The book includes the best methods for preparing and handling the reagent, how solvents, co-solvents and additives alter reactivity, the basic mechanisms of reactions, common transformations using the reagent, and emerging areas in samarium diiodide chemistry. The authors have distilled the extensive primary literature to allow the reader to quickly grasp an understanding of the reagent and its utility. The illustrative practical procedures help the reader to prepare and use the reagent in the laboratory while references from the recent literature allow readers to pursue their interest in the popular reagent. The book also contains many illustrations and chemical schemes.
Author :
Publisher : Academic Press
ISBN 13 : 0080581579
Total Pages : 272 pages
Book Rating : 4.0/5 (85 download)
Download or read book Advances in Physical Organic Chemistry written by and published by Academic Press. This book was released on 1982-02-25 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Physical Organic Chemistry
