Synthesis, Characterization, and Ring Opening Metathesis Polymerization Activity of Pentamethylcyclopentadienyl Osmium Complexes

Download Synthesis, Characterization, and Ring Opening Metathesis Polymerization Activity of Pentamethylcyclopentadienyl Osmium Complexes PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 376 pages
Book Rating : 4.:/5 (435 download)

DOWNLOAD NOW!


Book Synopsis Synthesis, Characterization, and Ring Opening Metathesis Polymerization Activity of Pentamethylcyclopentadienyl Osmium Complexes by : Julia Lynn Brumaghim

Download or read book Synthesis, Characterization, and Ring Opening Metathesis Polymerization Activity of Pentamethylcyclopentadienyl Osmium Complexes written by Julia Lynn Brumaghim and published by . This book was released on 1999 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Ring Opening Metathesis Polymerisation and Related Chemistry

Download Ring Opening Metathesis Polymerisation and Related Chemistry PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 9401003734
Total Pages : 489 pages
Book Rating : 4.4/5 (1 download)

DOWNLOAD NOW!


Book Synopsis Ring Opening Metathesis Polymerisation and Related Chemistry by : Ezat Khosravi

Download or read book Ring Opening Metathesis Polymerisation and Related Chemistry written by Ezat Khosravi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the last ASI in Turkey in Sept. 1995, the olefin metathesis has made remarkable strong developments with an incredible speed in various directions. New catalyst systems have been developed which have resulted in the synthesis of novel materials. Other fascinating developments have been the new catalysts for stereoselective metathesis and catalysts with considerable functional group tolerance. These new catalysts in addition to Ring Opening Metathesis Polymerisation (ROMP) and Acyclic Diene Metathesis (ADMET) are now powerful tools for Ring Closing Metathesis (RCM) and have found many applications in the synthesis of natural products. A lot of information has been established about all aspects of the olefin metathesis and there is a vast literature concerning the process, covering the initiators, mechanistic features and applications of this reaction in organic and polymer synthesis. The NATO ASI on rd th ROMP and Related Chemistry took place in Polanica-Zdroj, Poland during 3 to 15 Sept. 2000, to highlight the developments in this area and to discuss the prospects and visions for the year 2000 and beyond. The aims of the ASI were: to provide a platform for dissemination of knowledge; to promote communication between people who have a serious interest in this field of chemistry; to help establishing international scientific contacts and to provide an opportunity for the scientists with an appropriate scientific background to learn of recent developments in this field of science. There were 15 lecturers and 67 participants in this NATO ASI.

Inorganic Chemistry Seminar Abstracts

Download Inorganic Chemistry Seminar Abstracts PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 272 pages
Book Rating : 4.:/5 (31 download)

DOWNLOAD NOW!


Book Synopsis Inorganic Chemistry Seminar Abstracts by :

Download or read book Inorganic Chemistry Seminar Abstracts written by and published by . This book was released on 1996 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization

Download Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization PDF Online Free

Author :
Publisher : Cuvillier Verlag
ISBN 13 : 3736966113
Total Pages : 186 pages
Book Rating : 4.7/5 (369 download)

DOWNLOAD NOW!


Book Synopsis Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization by : Janis Musso

Download or read book Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization written by Janis Musso and published by Cuvillier Verlag. This book was released on 2022-05-12 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, the synthesis of neutral and cationic group(VI) imido/oxo alkylidene N-heterocyclic carbene (NHC) complexes that tolerate protic functional groups and aldehydes was reported. Unprecedented turnover numbers of up to 1.2 million were found for their silica-supported representatives. Some group(VI) alkylidene NHC complexes even display stability towards moisture and air. Coordination of the NHC to tungsten imido bistriflate precursor complexes, however, can lead to undesired side reactions. This work consequently aimed at the development of novel, more efficient routes to neutral and cationic tungsten imido/oxo alkylidene NHC complexes. In addition, some molybdenum imido alkylidene NHC complexes were targeted. Thereby, the scope of synthetically accessible complexes was broadened and, subsequently, their reactivity in ring-opening metathesis polymerization (ROMP) was probed. Those complexes were used as thermally latent initiators for the ROMP of dicyclopentadiene. Precise determination of the onset temperature of polymerization was achieved via monitoring with differential scanning calorimetry. Furthermore, the selectivity of novel complexes was tested for the formation of stereoregular polymers through ROMP of enantiomerically pure norbornene derivatives, which allowed for the synthesis of up to 98% trans-isotactic or cis-syndiotactic polymers depending on the steric demand of the imido and the alkoxide ligand.

Advances in Ring Opening (Metathesis) Polymerization

Download Advances in Ring Opening (Metathesis) Polymerization PDF Online Free

Author :
Publisher : Wiley-VCH
ISBN 13 : 9783527301324
Total Pages : 0 pages
Book Rating : 4.3/5 (13 download)

DOWNLOAD NOW!


Book Synopsis Advances in Ring Opening (Metathesis) Polymerization by :

Download or read book Advances in Ring Opening (Metathesis) Polymerization written by and published by Wiley-VCH. This book was released on 2000-09-12 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume of Macromolecular Symposia contains contributions presented at the RO(M)P'99 International Symposium in Mons, Belgium. At this meeting, over one hundred chemists, physico-chemists, chemical engineers from the world of academia and industry, as well as students, discussed recent developments in mechanisms and kinetics in RO(M)P, synthesis and characterization of new macromolecular architectures, and new materials and applications via RO(M)P.

Synthesis of Molybdenum and Tungsten Oxo and Imido Alkylidene NHC Complexes and Their Use in Stereoselective Ring-Opening Metathesis Polymerization

Download Synthesis of Molybdenum and Tungsten Oxo and Imido Alkylidene NHC Complexes and Their Use in Stereoselective Ring-Opening Metathesis Polymerization PDF Online Free

Author :
Publisher : Cuvillier Verlag
ISBN 13 : 3736963947
Total Pages : 306 pages
Book Rating : 4.7/5 (369 download)

DOWNLOAD NOW!


Book Synopsis Synthesis of Molybdenum and Tungsten Oxo and Imido Alkylidene NHC Complexes and Their Use in Stereoselective Ring-Opening Metathesis Polymerization by : Mathis Benedikter

Download or read book Synthesis of Molybdenum and Tungsten Oxo and Imido Alkylidene NHC Complexes and Their Use in Stereoselective Ring-Opening Metathesis Polymerization written by Mathis Benedikter and published by Cuvillier Verlag. This book was released on 2021-04-08 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Rahmen der Dissertation wurden unterschiedliche Aspekte der Olefinmetathese mit Molybdän- und Wolframbasierten Katalysatoren untersucht. Zunächst wurde die Eignung von Molybdän Imido Alkyliden N-heterocyclischen Carben (NHC) Komplexen als Initiatoren für die ringöffnende Metathese-Polymerisation (ROMP) erforscht. Durch Einsatz von chiralen, enantiomerenreinen Norbornenderivaten als Monomer konnte gezeigt werden, dass mit diesen Komplexen selektiv trans-isotaktische Polymere hergestellt werden können. Die beobachtete Selektivität ist dabei stark abhängig von der Ligandensphäre. Des Weiteren konnte vollständig hydriertes, syndiotaktisches Polydicyclopentadien hergestellt und erstmals mittels Schmelzspinnen zu Fasern versponnen werden. Ein weiterer Schwerpunkt der Dissertation lag auf der Entwicklung neuer Katalysatoren für die Olefinmetathese. So wurde eine neue Syntheseroute zur Herstellung kationischer Wolfram Imido Alkyliden NHC Komplexen entwickelt. Durch Anpassung der Ligandensphäre konnten luftstabile kationische Molybdän und Wolfram Imido Alkyliden NHC Komplexe hergestellt werden, die hohe Produktivitäten in der Olefinmetathese von Substraten mit verschiedenen sauerstoff- und schwefelhaltigen funktionellen Gruppen zeigen. Schließlich konnte der erste Molybdän Oxo Alkyliden NHC Komplex hergestellt und charakterisiert werden.

Synthesis and Characterization of Ring-opening Metathesis Polymers with Pendant Carborane Groups

Download Synthesis and Characterization of Ring-opening Metathesis Polymers with Pendant Carborane Groups PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (655 download)

DOWNLOAD NOW!


Book Synopsis Synthesis and Characterization of Ring-opening Metathesis Polymers with Pendant Carborane Groups by :

Download or read book Synthesis and Characterization of Ring-opening Metathesis Polymers with Pendant Carborane Groups written by and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: By Alice Man.

Olefins Polymerization Reactivity of Niobium-Based Metal Complexes

Download Olefins Polymerization Reactivity of Niobium-Based Metal Complexes PDF Online Free

Author :
Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783846510292
Total Pages : 192 pages
Book Rating : 4.5/5 (12 download)

DOWNLOAD NOW!


Book Synopsis Olefins Polymerization Reactivity of Niobium-Based Metal Complexes by : Yogesh Raghunath Patil

Download or read book Olefins Polymerization Reactivity of Niobium-Based Metal Complexes written by Yogesh Raghunath Patil and published by LAP Lambert Academic Publishing. This book was released on 2011-09 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the synthesis and characterization of niobium-based metal complexes and their usefulness as catalysts for the polymerization of ethylene, norbornene, beta pinene and vinyl monomers. The polymerization of above described monomers was studied using niobium complexes based on N, N dialkylcarbamates, mixed chloro alkoxides, simple oxygen-containing ligands and the starting material for the preparation of such derivatives, i.e. NbCl5.Niobium N, N-dialkylcarbamates exhibited high activity for polymerization of ethylene when activated with TMA-depleted MAO and 1,2-dichloroethane as activator working at 1 bar ethylene pressure. These novel catalytic systems resulted very active in Ring-opening metathesis polymerization (ROMP) of norbornene (NBE)with the highest activity never reported up to now for any transition metal catalysts. The dinuclear niobium compounds and simple oxygen-containing derivatives of niobium pentachloride were tested for ethylene polymerization and produced satisfactory results.In this context, it was found that easily accessible NbCl5 works as an excellent catalyst for the polymerization of β-pinene styrene and butylvinyl ethers

Synthesis of Catalysts for Ring Opening Metathesis Polymerization

Download Synthesis of Catalysts for Ring Opening Metathesis Polymerization PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 382 pages
Book Rating : 4.:/5 (292 download)

DOWNLOAD NOW!


Book Synopsis Synthesis of Catalysts for Ring Opening Metathesis Polymerization by : Martha Dolan Morton

Download or read book Synthesis of Catalysts for Ring Opening Metathesis Polymerization written by Martha Dolan Morton and published by . This book was released on 1993 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Dissertation Abstracts International

Download Dissertation Abstracts International PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 956 pages
Book Rating : 4.F/5 ( download)

DOWNLOAD NOW!


Book Synopsis Dissertation Abstracts International by :

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2000 with total page 956 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis, Characterization, and Reactivity of Pentamethylcyclopentadienyl Complexes of Divalent Cobalt and Nickel

Download Synthesis, Characterization, and Reactivity of Pentamethylcyclopentadienyl Complexes of Divalent Cobalt and Nickel PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 490 pages
Book Rating : 4.:/5 (33 download)

DOWNLOAD NOW!


Book Synopsis Synthesis, Characterization, and Reactivity of Pentamethylcyclopentadienyl Complexes of Divalent Cobalt and Nickel by : Michael Edward Smith

Download or read book Synthesis, Characterization, and Reactivity of Pentamethylcyclopentadienyl Complexes of Divalent Cobalt and Nickel written by Michael Edward Smith and published by . This book was released on 1993 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt:

American Doctoral Dissertations

Download American Doctoral Dissertations PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 848 pages
Book Rating : 4.F/5 ( download)

DOWNLOAD NOW!


Book Synopsis American Doctoral Dissertations by :

Download or read book American Doctoral Dissertations written by and published by . This book was released on 1999 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis of New Molybdenum(VI) Alkylidene Complexes and Ring Opening Metathesis Polymers

Download Synthesis of New Molybdenum(VI) Alkylidene Complexes and Ring Opening Metathesis Polymers PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 336 pages
Book Rating : 4.:/5 (325 download)

DOWNLOAD NOW!


Book Synopsis Synthesis of New Molybdenum(VI) Alkylidene Complexes and Ring Opening Metathesis Polymers by : Jin-Kyu Lee

Download or read book Synthesis of New Molybdenum(VI) Alkylidene Complexes and Ring Opening Metathesis Polymers written by Jin-Kyu Lee and published by . This book was released on 1995 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Characterization of Dimethylbismuth and -indium Phenoxy-imine Complexes as Potential Catalysts for the Ring Opening Polymerization of Cyclic Esters

Download Synthesis and Characterization of Dimethylbismuth and -indium Phenoxy-imine Complexes as Potential Catalysts for the Ring Opening Polymerization of Cyclic Esters PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 156 pages
Book Rating : 4.:/5 (128 download)

DOWNLOAD NOW!


Book Synopsis Synthesis and Characterization of Dimethylbismuth and -indium Phenoxy-imine Complexes as Potential Catalysts for the Ring Opening Polymerization of Cyclic Esters by : Kathleen Morrison

Download or read book Synthesis and Characterization of Dimethylbismuth and -indium Phenoxy-imine Complexes as Potential Catalysts for the Ring Opening Polymerization of Cyclic Esters written by Kathleen Morrison and published by . This book was released on 2019 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Directory of Graduate Research

Download Directory of Graduate Research PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 1846 pages
Book Rating : 4.:/5 (318 download)

DOWNLOAD NOW!


Book Synopsis Directory of Graduate Research by :

Download or read book Directory of Graduate Research written by and published by . This book was released on 2001 with total page 1846 pages. Available in PDF, EPUB and Kindle. Book excerpt: Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.

Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities

Download Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 1646 pages
Book Rating : 4.0/5 ( download)

DOWNLOAD NOW!


Book Synopsis Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities by : American Chemical Society. Committee on Professional Training

Download or read book Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities written by American Chemical Society. Committee on Professional Training and published by . This book was released on 1991 with total page 1646 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymers for Biomedical Applications

Download Polymers for Biomedical Applications PDF Online Free

Author :
Publisher : American Chemical Society
ISBN 13 :
Total Pages : 442 pages
Book Rating : 4.3/5 (91 download)

DOWNLOAD NOW!


Book Synopsis Polymers for Biomedical Applications by : Anil Mahapatro

Download or read book Polymers for Biomedical Applications written by Anil Mahapatro and published by American Chemical Society. This book was released on 2008-04-17 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research on applications of polymers for biomedical applications has increased dramatically to find improved medical plastics for this rapidly evolving field. This book brings together various aspects of recent research and developments within academia and industry related to polymers for biomedical applications.