I. Synthesis, Characterization and Reactivity of Platinum(II) Metal Complexes of Phosphorus-containing Mesocycles. II. Bifunctional Phosphines as Reagents in Carbon Tetrachloride-promoted Chlorination Reactions

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ISBN 13 :
Total Pages : 504 pages
Book Rating : 4.:/5 (39 download)

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Book Synopsis I. Synthesis, Characterization and Reactivity of Platinum(II) Metal Complexes of Phosphorus-containing Mesocycles. II. Bifunctional Phosphines as Reagents in Carbon Tetrachloride-promoted Chlorination Reactions by : Susan Deborah Toto

Download or read book I. Synthesis, Characterization and Reactivity of Platinum(II) Metal Complexes of Phosphorus-containing Mesocycles. II. Bifunctional Phosphines as Reagents in Carbon Tetrachloride-promoted Chlorination Reactions written by Susan Deborah Toto and published by . This book was released on 1989 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis, Characterization, and Reactivity of Rhodium and Iridium Phosphine Complexes Containing Sulfur Ligands Resulting from Reactions with H2S

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ISBN 13 :
Total Pages : 586 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Synthesis, Characterization, and Reactivity of Rhodium and Iridium Phosphine Complexes Containing Sulfur Ligands Resulting from Reactions with H2S by : Ann Marie Mueting

Download or read book Synthesis, Characterization, and Reactivity of Rhodium and Iridium Phosphine Complexes Containing Sulfur Ligands Resulting from Reactions with H2S written by Ann Marie Mueting and published by . This book was released on 1985 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Copper(I) Chemistry of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles

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Publisher : Elsevier
ISBN 13 : 0128156945
Total Pages : 445 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Copper(I) Chemistry of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles by : Maravanji S. Balakrishna

Download or read book Copper(I) Chemistry of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles written by Maravanji S. Balakrishna and published by Elsevier. This book was released on 2019-04-25 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: Copper(I) Complexes of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles is a comprehensive guide to one of the most widely used and extensively studied metals: copper. The numerous practical applications of copper compounds are discussed, including homogeneous and heterogeneous catalysis and their use as fungicides, pesticides, pigments for paints, resins and glasses, and in high-temperature superconductors. The remarkable structural flexibility of simple copper(I) complexes, such as cuprous halides is covered, including numerous structural motifs that, when combined with different ligand systems, exhibit linear, trigonal planar or tetrahedral geometries. This work is an essential reference for inorganic and coordination chemists, as well as researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects. - Discusses the properties of copper and similarities to noble metals, such as their corrosion resistance, high thermal and electrical conductivity and rich coordination chemistry - Includes the copper(I) coordination chemistry of tertiary phosphines, bisphosphines and phosphines containing other donor atoms and their potential application in catalysis, biosystems and photochemical areas - Features a discussion of the rich photochemistry exhibited by some mixed-ligand copper(I) complexes (phosphines with heteroaromatic ligands) which can exhibit coprophilic interactions, photoluminescence and thermochromic properties

Organometallic Pincer Chemistry

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Publisher : Springer
ISBN 13 : 3642310818
Total Pages : 363 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Organometallic Pincer Chemistry by : Gerard van Koten

Download or read book Organometallic Pincer Chemistry written by Gerard van Koten and published by Springer. This book was released on 2012-09-17 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.

Synthesis and Original Reactivity of Copper and Gold Complexes

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Publisher : Springer
ISBN 13 : 9783319369495
Total Pages : 0 pages
Book Rating : 4.3/5 (694 download)

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Book Synopsis Synthesis and Original Reactivity of Copper and Gold Complexes by : Maximilian Joost

Download or read book Synthesis and Original Reactivity of Copper and Gold Complexes written by Maximilian Joost and published by Springer. This book was released on 2016-10-15 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first σ-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into σ-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and the corresponding mechanism identified. The intermolecular oxidative addition of σ-SiSi, σ-CC and σ-CX (X=halogen) bonds with molecular gold (I) complexes is studied in detail, effectively demonstrating that this reaction, usually considered to be impossible for gold, is actually highly favored, provided an adequate ligand is employed. The use of small-bite angle bis (phosphine) gold (I) complexes allows for the first time the oxidative addition of σ-CC and σ-CX bonds for gold (I). These results shed light on an unexpected reactivity pattern of gold complexes and may point the way to 2-electron redox transformations mediated by this metal, opening up new perspectives in gold catalysis.