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Author : Thomas Evan Vos
Publisher :
ISBN 13 :
Total Pages : 510 pages
Book Rating : 4.:/5 (89 download)
Download or read book Synthesis and Reactivity of Aminocyclopentadienyl Ruthenium Complexes written by Thomas Evan Vos and published by . This book was released on 2002 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Shun-Ichi Murahashi
Publisher : John Wiley & Sons
ISBN 13 : 3527605797
Total Pages : 398 pages
Book Rating : 4.5/5 (276 download)
Download or read book Ruthenium in Organic Synthesis written by Shun-Ichi Murahashi and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)
Author : Alvin A. Holder
Publisher : John Wiley & Sons
ISBN 13 : 3527339574
Total Pages : 344 pages
Book Rating : 4.5/5 (273 download)
Download or read book Ruthenium Complexes written by Alvin A. Holder and published by John Wiley & Sons. This book was released on 2018-02-27 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edited by a team of highly respected researchers combining their expertise in chemistry, physics, and medicine, this book focuses on the use of rutheniumcontaining complexes in artificial photosynthesis and medicine. Following a brief introduction to the basic coordination chemistry of ruthenium complexes and their synthesis in section one, as well as their photophysical and photochemical properties, the authors discuss in detail the major concepts of artificial photosynthesis and mechanisms of hydrogen production and water oxidation with ruthenium in section two. The third section of the text covers biological properties and important medical applications of ruthenium complexes as therapeutic agents or in diagnostic imaging. Aimed at stimulating research in this active field, this is an invaluable information source for researchers in academia, health research institutes and governmental departments working in the field of organometallic chemistry, green and sustainable chemistry as well as medicine/drug discovery, while equally serving as a useful reference also for scientists in industry.
Author : Munenori Numata
Publisher : Academic Press
ISBN 13 : 0128121270
Total Pages : 326 pages
Book Rating : 4.1/5 (281 download)
Download or read book Kinetic Control in Synthesis and Self-Assembly written by Munenori Numata and published by Academic Press. This book was released on 2018-11-23 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kinetic Control in Synthesis and Self-Assembly provides a unique overview of the fundamental principles, novel methods and practical applications for researchers across organic synthesis, supramolecular chemistry and materials sciences. The book examines naturally occurring molecular systems in which kinetic processes are more ubiquitous than thermodynamic processes, also exploring the control of reactions and molecular self-assemblies, through kinetic processes, in artificial systems. These methods currently play a crucial role for tuning materials functions. From organic synthesis, to supramolecular assemblies, and from restricted spaces, to material synthesis for hierarchical structures, the book offers valuable coverage for researchers across disciplines. Interesting topics include how to regulate kinetic pathways more precisely, essential molecular design for kinetic traps, and how molecular environments surrounding molecules (i.e., solvent, temperature, and pressure effects) influence kinetic control in reactions and self-assemblies. - Describes the nature and potential applications of kinetic processes compared to thermodynamic processes - Presents information useful to researchers active in molecular synthesis and self-assembly toward materials - Collates coverage of kinetic control for synthesis and self-assembly, treated separately in literature
Author : Atta-ur-Rahman
Publisher : Bentham Science Publishers
ISBN 13 : 1608054802
Total Pages : 404 pages
Book Rating : 4.6/5 (8 download)
Download or read book Advances in Organic Synthesis written by Atta-ur-Rahman and published by Bentham Science Publishers. This book was released on 2013-01-14 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challenging structures. It presents comprehensive articles written by eminent authorities on different synthetic approaches to selected target molecules and new methods developed to achieve specific synthetic transformations. Contributions are written by eminent scientists and each volume is edited by an authority in the field. Advances in Organic Synthesis is essential for all organic chemists in the academia and industry who wish to keep abreast of rapid and important developments in the field.
Author : E.P. Kündig
Publisher : Springer Science & Business Media
ISBN 13 : 9783540016045
Total Pages : 248 pages
Book Rating : 4.0/5 (16 download)
Download or read book Transition Metal Arene P-Complexes in Organic Synthesis and Catalysis written by E.P. Kündig and published by Springer Science & Business Media. This book was released on 2004-06-21 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of h6-bound areneï by p-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated arene complexes. The preparation of complexes is detailed, as are the scope, limitations and challenges of reactions in contemporary p-arene metal chemistry with special attention given to asymmetric transformations. The emphasis of the book is on transformations of interest to organic synthesis and on the use of the complexes as catalysts or as chiral ligands. The book is written for academic and industrial researchers in organic, organometallic, and inorganic chemistry as well as for advanced chemistry students
Author : D.F. Schriver
Publisher : Elsevier
ISBN 13 : 008096396X
Total Pages : 1071 pages
Book Rating : 4.0/5 (89 download)
Download or read book Comprehensive Organometallic Chemistry II, Volume 7 written by D.F. Schriver and published by Elsevier. This book was released on 2002-09-10 with total page 1071 pages. Available in PDF, EPUB and Kindle. Book excerpt: The section devoted to iron in this volume reflects the tremendous progress in the area. Specifically cluster chemistry, ligand transformations and detailed structural results are more prominent in COMC II. The organic chemistry of ruthenium and osmium is an area which has burgeoned during the period since the publication of COMC. This is especially true for the cluster chemistry of these elements, which have provided most of the advances in this important field. Consequently, this volume will include an update (1981-1993) of the chemistry of mono- and bi-nuclear complexes of ruthenium and osmium, with a rather more extensive treatment of tri- and tetra-nuclear complexes. This is because many of the early results in ruthenium and osmium cluster chemistry described in COMC are now much better understood and can thus be placed in a more general context. In the case of complexes containing clusters with five or more metal atoms, the coverage is essentially complete, again because this chemistry has developed during the 1980s.
Author : Y.Z. Voloshin
Publisher : Elsevier
ISBN 13 : 0080529178
Total Pages : 433 pages
Book Rating : 4.0/5 (85 download)
Download or read book Clathrochelates written by Y.Z. Voloshin and published by Elsevier. This book was released on 2002-09-19 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.
Author : Mark G. Moloney
Publisher : John Wiley & Sons
ISBN 13 : 1119532000
Total Pages : 692 pages
Book Rating : 4.1/5 (195 download)
Download or read book Organic Reaction Mechanisms 2018 written by Mark G. Moloney and published by John Wiley & Sons. This book was released on 2021-08-17 with total page 692 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Reaction Mechanisms 2018, the 54th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2018. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements Transition Metal Coupling Radical Reactions An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation.
Author : E W Abel
Publisher : Royal Society of Chemistry
ISBN 13 : 1847554148
Total Pages : 476 pages
Book Rating : 4.8/5 (475 download)
Download or read book Organometallic Chemistry written by E W Abel and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author : Ulrich S. Schubert
Publisher : Springer Nature
ISBN 13 : 3030755983
Total Pages : 462 pages
Book Rating : 4.0/5 (37 download)
Download or read book Ruthenium-Containing Polymers written by Ulrich S. Schubert and published by Springer Nature. This book was released on 2021-06-17 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the synthetic methodologies as well as the properties and potential usage of various ruthenium-containing materials. Starting from the first examples of 'ruthenopolymers' reported in the 1970s to the 3D architectures now synthesized, these materials have shown their importance far beyond fundamental polymer science. As well as highlighting the remarkable properties and versatile applications, this book also addresses a key question related to the applications of such heavy-metal-containing materials from the perspective of achieving a sustainable future. This book is of interest to both materials scientists and chemists in academia and industry.
Author : Iwao Omae
Publisher : Springer Science & Business Media
ISBN 13 : 4431546049
Total Pages : 214 pages
Book Rating : 4.4/5 (315 download)
Download or read book Cyclometalation Reactions written by Iwao Omae and published by Springer Science & Business Media. This book was released on 2014-01-23 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.
Author : Syed Shahabuddin
Publisher : CRC Press
ISBN 13 : 1003851568
Total Pages : 293 pages
Book Rating : 4.0/5 (38 download)
Download or read book Chemistry of Dehydrogenation Reactions and Its Applications written by Syed Shahabuddin and published by CRC Press. This book was released on 2024-02-21 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present book focuses on advancement in the application of heterogeneous catalytic materials for the dehydrogenative synthesis of valuable organic compounds from substrates such as alcohols and simple aliphatic compounds. Several heterogeneous transition metals-based catalytic materials are explored for the synthesis of valuable chemicals for industrial applications. The book provides insight into the application of state-of-the-art technology for energy utilization and clean chemical synthesis. Features: Offers a wide overview of dehydrogenation catalytic chemistry catalyzed by transition metals and their compounds. Helps design novel and more benign and uncomplicated protocols for the synthesis of valuable chemicals from readily available raw materials. Provides deeper insight into the aspect of dehydrogenation reactions for clean chemical synthesis via a cascade process. Summarizes new mechanistic details of dehydrogenation reactions, experimental side development and applications of dehydrogenation techniques. Explores alternative solutions for the assimilation and transportation of clean energy in the form of hydrogen energy utilization. This book is aimed at graduate students and researchers in chemical engineering, chemistry, catalysis, organic synthesis, pharmaceutical chemistry and petrochemistry.
Author : Basil J. Wakefield
Publisher : Academic Press
ISBN 13 : 0080538177
Total Pages : 269 pages
Book Rating : 4.0/5 (85 download)
Download or read book Organomagnesium Methods in Organic Chemistry written by Basil J. Wakefield and published by Academic Press. This book was released on 1995-03-16 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes. Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds; and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined. Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided. - Presents a general overview of the constitution and reactivity of organomagnesium compounds - Provides coverage on the detection and estimation of organomagnesium compounds - Emphasizes practical aspects as well as principles - Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes - Includes preparations by metallation and metal-halogen exchanges - Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes - Outlines information on synthetically useful reactions of organomagnesium compounds - Describes the formation of carbon-heteroatom bonds in organic compounds - Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds - Includes representative procedures and tables with references to well-described examples
Author : J. Derek Woollins
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 312 pages
Book Rating : 4.F/5 ( download)
Download or read book Inorganic Experiments written by J. Derek Woollins and published by Wiley-VCH. This book was released on 1994-09-13 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offers detailed descriptions of more than 60 experiments ranging from undergraduate to graduate level, covering organometallic, main group, solid state and coordination chemistry--Cover.
Author : Sanshiro Komiya
Publisher : John Wiley & Sons
ISBN 13 : 0471971952
Total Pages : 450 pages
Book Rating : 4.4/5 (719 download)
Download or read book Synthesis of Organometallic Compounds written by Sanshiro Komiya and published by John Wiley & Sons. This book was released on 1997-05-28 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic Chemistry: Inorganic Chemistry: A Textbook Series This series reflects the breadth of modern research in inorganic chemistry and fulfils the need for advanced texts. The series covers the whole range of inorganic and physical chemistry, solid state chemistry, coordination chemistry, main group chemistry and bioinorganic chemistry. Synthesis of Organometallic Compounds A Practical Guide Edited by Sanshiro Komiya Tokyo University of Agriculture and Technology, Japan. This book describes the concepts of organometallic chemistry and provides an overview of the chemistry of each metal including the synthesis and handling of its important organometallic compounds. Synthesis of Organometallic Compounds: A Practical Guide provides: an excellent introduction to organometallic synthesis detailed synthetic protocols for the most important organometallic syntheses an overview of the reactivity, applications and versatility of organometallic compounds a survey of metals and their organometallic derivatives The purpose of this book is to serve as a practical guide to understanding the general concepts of organometallics for graduate students and scientists who are not necessarily specialists in organometallic chemistry.
Author : Alan R. Katritzky
Publisher : Elsevier
ISBN 13 : 9780080423258
Total Pages : 1380 pages
Book Rating : 4.4/5 (232 download)
Download or read book Comprehensive Organic Functional Group Transformations written by Alan R. Katritzky and published by Elsevier. This book was released on 2003-03-21 with total page 1380 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this Volume, containing 24 chapters devoted to carbon attached by single bonds to two heteroatoms, the reader will find several chapters reviewing the synthesis of familiar functional groups, notably acetals, dithioacetals, aminals and the various mixed species. The derivatives with tetracoordinated (saturated) carbon are described in Part I and those, eg. ketene acetals, of tricoordinated carbon in Part II. However, the treatment is comprehensive and the authors have uncovered much fascinating chemistry concerning less familiar groups, including some like geminal halohydrins, halo amines and diols that are often unstable. Again, a surprisingly large number of compounds having two metals attached to the same carbon have been located in the literature, and the abundance of phosphorus derivatives, eg. those with geminal nitrogen functions, reflects their importance as biologically active species and as intermediates in synthesis. Part III consists of a single, short chapter describing dicoordinate carbon (carbenes) and examples of carbon cations, anions and radicals. Here the treatment is deliberately selective since throughout the work as a whole emphasis is placed on the synthesis of isolable species rather than the transient intermediates of organic reactions.
