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Synthesis And Reactions Of Organometallic Complexes Of Platinum And Palladium
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Book Synopsis Higher Oxidation State Organopalladium and Platinum Chemistry by : Allan J. Canty
Download or read book Higher Oxidation State Organopalladium and Platinum Chemistry written by Allan J. Canty and published by Springer Science & Business Media. This book was released on 2011-02-27 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kyle A. Grice, Margaret L. Scheuermann and Karen I. Goldberg: Five-Coordinate Platinum(IV) Complexes.- Jay A. Labinger and John E. Bercaw: The Role of Higher Oxidation State Species in Platinum-Mediated C-H Bond Activation and Functionalization.- Joy M. Racowski and Melanie S. Sanford: Carbon-Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes.- Helena C. Malinakova: Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles.- Allan J. Canty and Manab Sharma: h1-Alkynyl Chemistry for the Higher Oxidation States of Palladium and Platinum.- David C. Powers and Tobias Ritter: Palladium(III) in Synthesis and Catalysis.- Marc-Etienne Moret: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d10 and s2 Centers.
Download or read book Clathrochelates written by Y.Z. Voloshin and published by Elsevier. This book was released on 2002-09-19 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.
Book Synopsis Comprehensive Organometallic Chemistry II by : Richard J. Puddephatt
Download or read book Comprehensive Organometallic Chemistry II written by Richard J. Puddephatt and published by Elsevier. This book was released on 1995 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Compounds of Nickel, Palladium, Platinum, Copper, Silver and Gold by : R.J. Cross
Download or read book Organometallic Compounds of Nickel, Palladium, Platinum, Copper, Silver and Gold written by R.J. Cross and published by Springer. This book was released on 1985 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is one of the first volumes to be published in the series of Chapman and Hall Chemistry Sourcebooks which provides carefully tailored information to workers in specialized areas of chemistry. The information contained in this book is derived from the Dictionary of Organometallic Compounds, published in November 1984. The organic compounds of the six metals in this volume are of great interest both to inorganic and organic chemists. Organonickel and organopalladium compounds are frequently used as selective reagents in synthesis and as catalysts for organic reactions. Organoplatinum compounds, however, are generally slower to react and lend themselves to mechanistic studies. A vast range of such compounds has been prepared. Whilst organometallics of the gold triad are fewer, they display a range of interesting structures , and organocopper compounds are widely used synthetic reagents. It is therefore anticipated that this particular compendium will reach a wide readership. The databank on the properties of organometallic compounds, which is represented in its current form by the Dictionary of Organometallic Compounds and its subset publications such as this volume, will be kept continuously up-to-date. Supplements to the main Dictionary will appear annually and revised editions of this Sourcebook will be published from time to time as demands permits. RJ. Cross D.M.P. Mingos VII Introduction 1. Using the Sourcebook (2) Any compound with an established use, such as in catalysis, as a synthetic reagent or starting material.
Book Synopsis Handbook of Organopalladium Chemistry for Organic Synthesis by : Ei-ichi Negishi
Download or read book Handbook of Organopalladium Chemistry for Organic Synthesis written by Ei-ichi Negishi and published by John Wiley & Sons. This book was released on 2003-11-24 with total page 1657 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.
Book Synopsis Transition Metal Reagents and Catalysts by : Jiro Tsuji
Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by John Wiley & Sons. This book was released on 2002-08-16 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Book Synopsis Pincer and Pincer-Type Complexes by : Kálmán J. Szabó
Download or read book Pincer and Pincer-Type Complexes written by Kálmán J. Szabó and published by John Wiley & Sons. This book was released on 2014-06-10 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.
Book Synopsis Clusters and Colloids by : Günter Schmid
Download or read book Clusters and Colloids written by Günter Schmid and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the rapidly developing field of cluster science. In an interdisciplinary approach, basic concepts as well as recent developments in research and practical applications are authoritatively discussed by leading authors. Topics covered include 'naked' metal clusters, clusters stabilized by ligands, clusters in solids, and colloids. The reader will find answers to questions like: * How many metal atoms must a particle have to exhibit metallic properties? * How can the large specific surface of clusters and colloids be employed in catalysts? * How can metal clusters be introduced into solid hosts? * Which effects are responsible for the transition from isolated to condensed clusters? The editor has succeeded in bringing the contributions of various authors together into a homogeneous, readable book, which will be useful for the academic and industrial reader alike.
Book Synopsis Organometallic Reactions by : Ernest I. Becker
Download or read book Organometallic Reactions written by Ernest I. Becker and published by John Wiley & Sons. This book was released on 1971 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Mizoroki-Heck Reaction by : Martin Oestreich
Download or read book The Mizoroki-Heck Reaction written by Martin Oestreich and published by John Wiley & Sons. This book was released on 2009-02-11 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)
Book Synopsis Applied Homogeneous Catalysis with Organometallic Compounds by : Boy Cornils
Download or read book Applied Homogeneous Catalysis with Organometallic Compounds written by Boy Cornils and published by John Wiley & Sons. This book was released on 2017-12-26 with total page 1778 pages. Available in PDF, EPUB and Kindle. Book excerpt: The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.
Book Synopsis Cyclometalation Reactions by : Iwao Omae
Download or read book Cyclometalation Reactions written by Iwao Omae and published by Springer Science & Business Media. This book was released on 2014-01-23 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.
Book Synopsis Phosphorus Compounds by : Maurizio Peruzzini
Download or read book Phosphorus Compounds written by Maurizio Peruzzini and published by Springer Science & Business Media. This book was released on 2011-06-10 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Each chapter of Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences have been carefully selected by the editors in order to represent a state-of-the-art overview of how phosphorus chemistry can provide solutions in various fields of applications. The editors have assembled an international array of world-renowned scientists and each chapter is written by experts in the fields of synthetic chemistry, homogeneous catalysis, dendrimers, theoretical calculations, materials science, and medicinal chemistry with a special focus on the chemistry of phosphorus compounds. Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences is of interest to a general readership ranging from advanced university course students to experts in academia and industry.
Book Synopsis Organometallic Chemistry and Catalysis by : Karl Kirchner
Download or read book Organometallic Chemistry and Catalysis written by Karl Kirchner and published by Springer Science & Business Media. This book was released on 2001-02-01 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: From the beginning of chemistry as an exact (natural) science - almost 200 years ago - there was a more or less distinct differentiation between its various branches such as organic, inorganic, physical, analytical, or biochemistry. With the increasing insight into the connections and governing laws it soon became obvious, however, that such a clear separation could be regarded as more or less obsolete; within almost any field of chemical research one has to deal with most of the branches mentioned. Especially organic and inorganic chemistry are significant examples for this statement, overlapping considerably within the important field of organome tallic chemistry. This regime of chemistry started its advance with the discovery of dimethylzinc 150 years ago, had a highlight with the introduction of Grignard reagents around 1900, developed further with the start of lithium organyls in 1925 and literally exploded after the discovery of the first transition metal cyclopenta dienyl complex ferrocene half a century ago. The chronological sequence of the important steps, i. e. 1850 (Zn) - 1900 (Mg) - 1925 (Li) - 1950 (Fe), seems rather remarkable. The increasing group of metallocenes is not only of high theoretical and, due to the potential chirality of its members, stereochemical interest, but offers also a wide variety of extremely useful catalysts, especially for stereoselective reactions. The Austrian Chemical Society took this development into account by organizing the Twelfth International Conference on Organometallic Chemistry held in Vienna in 1985.
Book Synopsis Metal-based Anticancer Agents by : Angela Casini
Download or read book Metal-based Anticancer Agents written by Angela Casini and published by Royal Society of Chemistry. This book was released on 2019-04-05 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-based anticancer drugs are among the most successful therapeutic agents, as evidenced by the frequent prescription of selected platinum and arsenic compounds to patients. Metal-based Anticancer Agents covers the interdisciplinary world of inorganic drug discovery and development by introducing the most prominent compound classes based on different transition metals, discussing emerging concepts and enabling methods, as well as presenting key pre-clinical and clinical aspects. Recent progress on the unique features of next-generation targeted metal-based anticancer agents, including supramolecular coordination complexes used for both therapy and drug delivery, promise a bright future beyond the benefits of pure cytotoxic activity. With contributions from global leaders in the field, this book will serve as a useful reference to established researchers as well as a practical guide to those new to metallodrugs, and postgraduate students of medicinal chemistry and metallobiology.
Book Synopsis Advances in Organometallic Chemistry by :
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1999-10-14 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: A widely-acclaimed serial, Advances in Organometallic Chemistry contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.
Book Synopsis Organometallics as Catalysts in the Fine Chemical Industry by : Matthias Beller
Download or read book Organometallics as Catalysts in the Fine Chemical Industry written by Matthias Beller and published by Springer. This book was released on 2012-08-31 with total page 165 pages. Available in PDF, EPUB and Kindle. Book excerpt: Johannes G. de Vries: Pd-catalyzed coupling reactions.- Gregory T. Whiteker and Christopher J. Cobley: Applications of Rhodium-Catalyzed Hydroformylation in the Pharmaceutical, Agrochemical and Fragrance Industries.- Philippe Dupau: Ruthenium-catalyzed Selective Hydrogenation for Flavor and Fragrance Applications.- Hans-Ulrich Blaser, Benoît Pugin and Felix Spindler: Asymmetric Hydrogenation.- Ioannis Houpis: Case Study: Sequential Pd-catalyzed Cross-Coupling Reactions; Challenges on Scale-up.- Adriano F. Indolese: Pilot Plant Scale Synthesis of an Aryl-Indole - Scale up of a Suzuki Coupling.- Per Ryberg: Development of a Mild and Robust Method for Palladium Catalysed Cyanation on Large Scale.- Cheng-yi Chen: Application of Ring Closing Metathesis Strategy to the Synthesis of Vaniprevir (MK-7009), a 20-Membered Macrocyclic HCV Protease Inhibitor.
