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Author : Jeffrey Robert Cramm
Publisher :
ISBN 13 :
Total Pages : 318 pages
Book Rating : 4.:/5 (287 download)
Download or read book Studies in Matrix Isolation of Biradicals written by Jeffrey Robert Cramm and published by . This book was released on 1983 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Stephen Cradock
Publisher : CUP Archive
ISBN 13 : 9780521207591
Total Pages : 160 pages
Book Rating : 4.2/5 (75 download)
Download or read book Matrix Isolation written by Stephen Cradock and published by CUP Archive. This book was released on 1975-10-09 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: This 1975 book shows how and why matrix isolation developed and describes the necessary apparatus.
Author : M.S. Platz
Publisher : Springer Science & Business Media
ISBN 13 : 1489937072
Total Pages : 381 pages
Book Rating : 4.4/5 (899 download)
Download or read book Kinetics and Spectroscopy of Carbenes and Biradicals written by M.S. Platz and published by Springer Science & Business Media. This book was released on 2013-12-14 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of mechanistic organic chemistry is filled with claims of short-lived reactive intermediates connecting starting material to product. In many ways this book represents a personal odyssey of the editor in this area of chemistry. I well remember my introduction to organic chemistry as an undergraduate working in the laboratories of Shelton Bank at SUNY Albany in the early 1970s, and the excitement and frustration attending the piecing together of the details of a reaction mechanism by working backwards from the stable products of the reaction. In those days the reaction and the reactive intermediates flew by too rapidly to permit direct observation. Thus it came as something of a revelation to me as a graduate student at Yale that it was possible to slow down a reaction and actually "see" such ephemeral species as carbenes and biradicals by spectroscopic methods, by generating them photochemically at cryogenic temperatures. In this monograph several chap ters are devoted to low-temperature studies. Dougherty has described the matrix EPR spectra of biradicals, which were pure conjecture only ten years ago. Michl and Arnold have described the matrix spectroscopy of cyciobutadiene, a molecule that has fascinated organic chemists for over a hundred years. They have shown that by using a combination of matrix spec troscopic methods it is possible to learn nearly as much about the structure of cyciobutadiene, the prototypical antiaromatic biradicaloid, as about that of a common shelf-stable reagent.
Author : Robert Stephen Wyatt
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (122 download)
Download or read book Matrix Isolation Studies on Some High Temperature Systems written by Robert Stephen Wyatt and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Jacob Pacansky
Publisher :
ISBN 13 :
Total Pages : 238 pages
Book Rating : 4.:/5 (311 download)
Download or read book Matrix Isolation Studies of Small Molecules written by Jacob Pacansky and published by . This book was released on 1971 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Ian R. Dunkin
Publisher : Oxford University Press on Demand
ISBN 13 : 9780198558637
Total Pages : 242 pages
Book Rating : 4.5/5 (586 download)
Download or read book Matrix-isolation Techniques written by Ian R. Dunkin and published by Oxford University Press on Demand. This book was released on 1998 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: Matrix isolation is a technique for trapping reactive species at very low temperatures and studying them spectroscopically. This book offers detailed practical advice on how to carry out matrix-isolation experiments, and is a unique introduction to the subject. Chapter 1 introduces a briefhistorical survey of the development of the technique that incorporates a discussion of its strength and limitations. Chapter 2 provides a thorough description of the building of a matrix-isolation laboratory from scratch. All the necessary equipment is described in full and there are diagrammaticexamples throughout. In later chapters, ancillary equipment for generating reactive species, and an informative description of the various methods for forming low-temperature matrices are dealt with. There then follows a chapter on the specialized technique of matrix photochemistry with polarizedlight. The final chapter comprises an extensive collection of classic matrix experiments which have been selected due to their ease of application and which will thus serve as useful exercises for testing new pieces of equipment. This accessible text offers thorough coverage of the topic and willbe invaluable to postgraduate and industrial chemists as an introduction to matrix isolation techniques. Researchers in chemistry and related fields who are considering whether matrix isolation can play a part in their own research will also find this book useful.
Author : David Derek Price
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (536 download)
Download or read book Matrix isolation studies of some high temperature molecules written by David Derek Price and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Lester Andrews
Publisher :
ISBN 13 :
Total Pages : 448 pages
Book Rating : 4.3/5 (91 download)
Download or read book Chemistry and Physics of Matrix-isolated Species written by Lester Andrews and published by . This book was released on 1989 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Matrix-isolation spectroscopy, as a technique for studying unstable species, has had tremendous lasting powers. Since 1954, matrix-isolation has been able to assimilate new technology rather than being replaced by it. The matrix-isolation technique for producing and trapping new chemical species has been applied to an ever increasing range of chemical and physical problems since its inception. The last 12 years have seen a substantial number of new developments and applications of the matrix technique. The chapters in this book describe many of the contributions of matrix-isolation spectroscopy to chemistry and physics in the last decade, and as such predict the continued evolution of this technique over the next decade. Experimental techniques are generally closely related to the development of new apparatus, and each chapter has a section describing innovations in instrumentation such as the closed-cycle cryogenic cooler that has revolutionized the technique. In addition, each chapter describes many of the specialized methods used to prepare, trap and study particular new subject species. The volume will be an indispensable reference source for graduate students and other scientists new to this field, as well as chemists and physicists already involved in applied spectroscopy.
Author : A. C. Knipe
Publisher : John Wiley & Sons
ISBN 13 : 0470066822
Total Pages : 722 pages
Book Rating : 4.4/5 (7 download)
Download or read book Organic Reaction Mechanisms 1989 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2008-04-30 with total page 722 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1989 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1989. The 25th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
Author : Johannes W. Hofstraat
Publisher : John Wiley & Sons
ISBN 13 : 9780471245087
Total Pages : 580 pages
Book Rating : 4.2/5 (45 download)
Download or read book Shpol'skii Spectroscopy and Other Site-Selection Methods written by Johannes W. Hofstraat and published by John Wiley & Sons. This book was released on 2000-08-07 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent technological breakthroughs, most notably in the field of lasers as well as detection and data processing, have made it possible to apply high-resolution molecular spectroscopy to such areas as environmental science, bioanalysis, and chemical physics. This book describes recent advances and applications of high-resolution molecular spectroscopy in low temperature solid matrices.
Author : A. R. Butler
Publisher : John Wiley & Sons
ISBN 13 : 0470067071
Total Pages : 635 pages
Book Rating : 4.4/5 (7 download)
Download or read book Organic Reaction Mechanisms 1975 written by A. R. Butler and published by John Wiley & Sons. This book was released on 2008-05-27 with total page 635 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1975 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 19751. The 11th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
Author : National Science Foundation (U.S.)
Publisher :
ISBN 13 :
Total Pages : 160 pages
Book Rating : 4.:/5 (3 download)
Download or read book Annual Report for Fiscal Year ... written by National Science Foundation (U.S.) and published by . This book was released on 1978 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Vladimir Ya. Lee
Publisher : John Wiley & Sons
ISBN 13 : 1119956269
Total Pages : 390 pages
Book Rating : 4.1/5 (199 download)
Download or read book Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb written by Vladimir Ya. Lee and published by John Wiley & Sons. This book was released on 2011-07-22 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of : Si-, Ge-, Sn and Pb-centered cations, radicals and anions heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16] cyclic compounds (three-, four-, five-, and six-membered rings) heavy analogues of 1,3-dienes, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry
Author : A. C. Knipe
Publisher : John Wiley & Sons
ISBN 13 : 0470858591
Total Pages : 684 pages
Book Rating : 4.4/5 (78 download)
Download or read book Organic Reaction Mechanisms 1998 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2003-09-12 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: 34th volume in this highly successful series, Organic Reaction Mechanisms Provides the most recent developments in organic chemistry Compiled by well-respected editors with many years of relevant experience
Author : William M. Horspool
Publisher : CRC Press
ISBN 13 : 020349590X
Total Pages : 2898 pages
Book Rating : 4.2/5 (34 download)
Download or read book CRC Handbook of Organic Photochemistry and Photobiology, Volumes 1 & 2 written by William M. Horspool and published by CRC Press. This book was released on 2003-09-29 with total page 2898 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of this best-selling handbook is bigger, more comprehensive, and now completely current. In addition to thorough updates to the discussions featured in the first edition, this edition includes 66 new chapters that reflect recent developments, new applications, and emerging areas of interest. Within the handbook's 145 critically r
Author : Eric V. Anslyn
Publisher : University Science Books
ISBN 13 : 9781891389313
Total Pages : 1148 pages
Book Rating : 4.3/5 (893 download)
Download or read book Modern Physical Organic Chemistry written by Eric V. Anslyn and published by University Science Books. This book was released on 2006 with total page 1148 pages. Available in PDF, EPUB and Kindle. Book excerpt: In additionto covering thoroughly the core areas of physical organic chemistry -structure and mechanism - this book will escortthe practitioner of organic chemistry into a field that has been thoroughlyupdated.
Author : D. Bryce-Smith
Publisher : Royal Society of Chemistry
ISBN 13 : 0851861857
Total Pages : 560 pages
Book Rating : 4.8/5 (518 download)
Download or read book Photochemistry written by D. Bryce-Smith and published by Royal Society of Chemistry. This book was released on 1989 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: The breadth of scientific and technological interests in the general topic of photochemistry is truly enormous and includes, for example, such diverse areas as microelectronics, atmospheric chemistry, organic synthesis, non-conventional photoimaging, photosynthesis, solar energy conversion, polymer technologies, and spectroscopy. This Specialist Periodical Report on Photochemistry aims to provide an annual review of photo-induced processes that have relevance to the above wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology. In order to provide easy access to this vast and varied literature, each volume of Photochemistry comprises sections concerned with photophysical processes in condensed phases, organic aspects which are sub-divided by chromophore type, polymer photochemistry, and photochemical aspects of solar energy conversion. Volume 34 covers literature published from July 2001 to June 2002. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.
