Structure-property Relationships: Synthesis and Characterization of Perovskite-related Transition Metal Oxides

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ISBN 13 : 9781109913507
Total Pages : 207 pages
Book Rating : 4.9/5 (135 download)

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Book Synopsis Structure-property Relationships: Synthesis and Characterization of Perovskite-related Transition Metal Oxides by : Louis Whaley

Download or read book Structure-property Relationships: Synthesis and Characterization of Perovskite-related Transition Metal Oxides written by Louis Whaley and published by . This book was released on 2007 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fundamental structural component of perovskite-related phases is the octahedrally coordinated transition metal ion, symbolized as BO6 . Corner-sharing networks of BO6 octahedra are present in perovskites and related Ruddlesden-Popper Phases, ABO3 and AO(ABO 3)n, respectively. Face-sharing octahedra arranged into columns are characteristic of hexagonal, perovskite-related phases, and the relationship will be described in detail in Chapter 1. Edge sharing octahedra are characteristic of Keggin- and Lindquist-type polyoxometallates, which at first glance, seem unconnected from perovskites. However, Chapter 1 will show the deep connections among all of the phases mentioned above, by starting with perovskite phases.

Perovskite Materials

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Publisher : BoD – Books on Demand
ISBN 13 : 9535122452
Total Pages : 652 pages
Book Rating : 4.5/5 (351 download)

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Book Synopsis Perovskite Materials by : Likun Pan

Download or read book Perovskite Materials written by Likun Pan and published by BoD – Books on Demand. This book was released on 2016-02-03 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book summarizes the current state of the know-how in the field of perovskite materials: synthesis, characterization, properties, and applications. Most chapters include a review on the actual knowledge and cutting-edge research results. Thus, this book is an essential source of reference for scientists with research fields in energy, physics, chemistry and materials. It is also a suitable reading material for graduate students.

Fundamentals of Perovskite Oxides

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Publisher : CRC Press
ISBN 13 : 1000195686
Total Pages : 385 pages
Book Rating : 4.0/5 (1 download)

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Book Synopsis Fundamentals of Perovskite Oxides by : Gibin George

Download or read book Fundamentals of Perovskite Oxides written by Gibin George and published by CRC Press. This book was released on 2020-10-06 with total page 385 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook entitled Fundamentals of Perovskite Oxides: Synthesis, Structure, Properties and Applications summarizes the structure, synthesis routes, and potential applications of perovskite oxide materials. Since these perovskite-type ceramic materials offer opportunities in a wide range of fields of science and engineering, the chapters are broadly organized into four sections of perovskite-type oxide materials and technology. Covers recent developments in perovskite oxides Serves as a quick reference of perovskite oxides information Describes novel synthesis routes for nanostructured perovskites Discusses comprehensive details for various crystal structures, synthesis methods, properties, and applications Applies to academic education, scientific research, and industrial R&D for materials research in real-world applications like bioengineering, catalysis, energy conversion, energy storage, environmental engineering, and data storage and sensing This book serves as a handy and practical guideline suitable for students, engineers, and researchers working with advanced ceramic materials.

Structure Processing Properties Relationships in Stoichiometric and Nonstoichiometric Oxides

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Publisher : BoD – Books on Demand
ISBN 13 : 1789854512
Total Pages : 104 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Structure Processing Properties Relationships in Stoichiometric and Nonstoichiometric Oxides by : Speranta Tanasescu

Download or read book Structure Processing Properties Relationships in Stoichiometric and Nonstoichiometric Oxides written by Speranta Tanasescu and published by BoD – Books on Demand. This book was released on 2020-11-04 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: The interrelation among composition, microstructure, and properties of stoichiometric and nonstoichiometric compounds is a major field of research for both scientific and technological reasons. As such, this book focuses on metal oxides, which present a large diversity of electrical, magnetic, optical, optoelectronic, thermal, electrochemical, and catalytic properties, making them suitable for a wide range of applications. By bringing together scientific contributions with special emphasis on the interrelations between materials chemistry, processing, microstructures, and properties of stoichiometric and nonstoichiometric metal oxides, this book highlights the importance of tightly integrating high-throughput experiments (including both synthesis and characterization) and efficient and robust theory for the design of advanced materials.

Perovskite Metal Oxides

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Publisher : Elsevier
ISBN 13 : 0323995306
Total Pages : 730 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Perovskite Metal Oxides by : Srikanta Moharana

Download or read book Perovskite Metal Oxides written by Srikanta Moharana and published by Elsevier. This book was released on 2023-05-30 with total page 730 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perovskite Metal Oxides: Synthesis, Properties and Applications provides an overview on the topic, including the synthesis of various types of perovskites, their properties, characterization and application. The book reviews the applications of this category of materials for photovoltaics, electronics, biomedical, fuel cell, photocatalyst, sensor, energy storage and catalysis, along with processing techniques of perovskite metal oxides with a focus on low-cost and high-efficiency methods, including various properties and probable applications in academia and industry. Other sections discuss strategies to improve the functionality of perovskite metal oxide materials, including chemical methods and controlling the size, shape and structure of the materials. Finally, applications of perovskite metal oxides in energy conversion and storage, sensing and electronics are covered. Provides an overview of perovskite metal oxides, with an emphasis on synthesis, fabrication and characterization methods Discusses strategies to improve the functionality of perovskite metal oxide materials, including chemical methods and controlling the size, shape and structure of the materials Reviews applications of perovskite metal oxides in energy conversion and storage, sensing and electronics

Perovskites

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Publisher : John Wiley & Sons
ISBN 13 : 1118935632
Total Pages : 328 pages
Book Rating : 4.1/5 (189 download)

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Book Synopsis Perovskites by : Richard J. D. Tilley

Download or read book Perovskites written by Richard J. D. Tilley and published by John Wiley & Sons. This book was released on 2016-03-03 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Uniquely describes both the crystallography and properties of perovskite related materials. Practical applications in solar cells, microelectronics and telecommunications Interdisciplinary topic drawing on materials science, chemistry, physics, and geology Contains problems and answers to enhance knowledge retention

Synthesis and Crystal Growth of Novel Perovskite-based Transition Metal Oxides

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Publisher :
ISBN 13 :
Total Pages : 266 pages
Book Rating : 4.:/5 (556 download)

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Book Synopsis Synthesis and Crystal Growth of Novel Perovskite-based Transition Metal Oxides by : Guerman Popov

Download or read book Synthesis and Crystal Growth of Novel Perovskite-based Transition Metal Oxides written by Guerman Popov and published by . This book was released on 2003 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis Characterization and Magnetic Properties of Fe Doped ReCrO3 Re Pr Sm La Perovskites

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Publisher : Mohammed Abdul Malik
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.2/5 (249 download)

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Book Synopsis Synthesis Characterization and Magnetic Properties of Fe Doped ReCrO3 Re Pr Sm La Perovskites by : Bakshi Venugopal Rao

Download or read book Synthesis Characterization and Magnetic Properties of Fe Doped ReCrO3 Re Pr Sm La Perovskites written by Bakshi Venugopal Rao and published by Mohammed Abdul Malik. This book was released on 2024-03-11 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perovskite materials with a general formula ABO3 exhibit rich and varying physical properties including magnetic, semi-conducting, ferroelectric, multiferroic. Thus it is interesting and meaningful in both theory and experiments of these materials. In ABO3 structure, the zero occupancy of the transition metal B cations are chemically known to favour ferroelectricity. The availability of the transition metal d electrons in the perovskite oxides are necessary for magnetism to reduce the tendency for off centering ferroelectric distortions. Hence ferromagnetism and ferroelectricity seem to be mutually exclusive in perovskite structure oxides and the scarcity of ferromagnetic and ferroelectric materials has stimulated many theoretical and experimental works. A few metal oxides are known to exhibit ferroelectricity at relatively high temperatures and a magnetic transition at lower temperatures. Recently some researchers have found that rare earth chromites with formula ReCrO3 exhibit canted anti ferromagnetic [TN=113-140 K] and dielectric [TC=472-516K] transition characteristic which is a kind of possible multiferroic behavior. From the above discussion it is clear that the importance of the perovskite structure which has a stable and standard structure and also the transition metal oxides as a possible important application as a multiferroic materials. In particular, the rare earth transition metal oxides from the perovskite family are well known due to their striking properties which are related to exchange mechanisms and the competition between ferromagnetic and anti-ferromagnetic phases

Properties and Applications of Perovskite-Type Oxides

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Publisher : CRC Press
ISBN 13 : 9781439855225
Total Pages : 404 pages
Book Rating : 4.8/5 (552 download)

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Book Synopsis Properties and Applications of Perovskite-Type Oxides by : L.G. Tejuca

Download or read book Properties and Applications of Perovskite-Type Oxides written by L.G. Tejuca and published by CRC Press. This book was released on 2000-10-17 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference offers an overview of the bulk and surface properties of perovskite-like structures, and provides the latest discussions on the applications of these materials and processes. It also introduces ceramic methods for the processing of perovskite-derived high Tc cuprates.;Examining every available procedure for synthesizing high-surface-area perovskite oxides, this book: delineates processing techniques for preparing perovskite-derived high-critical-temperature superconductors; illustrates the relevance of physiochemical methods to investigate bulk and surface structures of perovskite compounds; explicates the importance of surface composition in the context of catalytic behaviour; summarizes methods of changing stoichiometry; shows how to design perovskite oxides for a given purpose; reviews key solid-state properties; and presents the major applications.

Perovskites and Related Mixed Oxides

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Publisher : John Wiley & Sons
ISBN 13 : 3527337636
Total Pages : 1050 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Perovskites and Related Mixed Oxides by : Pascal Granger

Download or read book Perovskites and Related Mixed Oxides written by Pascal Granger and published by John Wiley & Sons. This book was released on 2016-02-23 with total page 1050 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive handbook and ready reference details all the main achievements in the field of perovskite-based and related mixed-oxide materials. The authors discuss, in an unbiased manner, the potentials as well as the challenges related to their use, thus offering new perspectives for research and development on both an academic and industrial level. The first volume begins by summarizing the different synthesis routes from molten salts at high temperatures to colloidal crystal template methods, before going on to focus on the physical properties of the resulting materials and their related applications in the fields of electronics, energy harvesting, and storage as well as electromechanics and superconductivity. The second volume is dedicated to the catalytic applications of perovskites and related mixed oxides, including, but not limited to total oxidation of hydrocarbons, dry reforming of methane and denitrogenation. The concluding section deals with the development of chemical reactors and novel perovskite-based applications, such as fuel cells and high-performance ceramic membranes. Throughout, the contributions clearly point out the intimate links between structure, properties and applications of these materials, making this an invaluable tool for materials scientists and for catalytic and physical chemists.

Synthesis and Physical Property Characterization of Layered Transition Metal Pnictide-oxide Compounds

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Publisher :
ISBN 13 :
Total Pages : 298 pages
Book Rating : 4.:/5 (61 download)

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Book Synopsis Synthesis and Physical Property Characterization of Layered Transition Metal Pnictide-oxide Compounds by : Tadashi C. Ozawa

Download or read book Synthesis and Physical Property Characterization of Layered Transition Metal Pnictide-oxide Compounds written by Tadashi C. Ozawa and published by . This book was released on 2001 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Characterization of the Layered Transition Metal Oxides AxNbO2 (A

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Publisher :
ISBN 13 :
Total Pages : 404 pages
Book Rating : 4.:/5 (33 download)

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Book Synopsis Synthesis and Characterization of the Layered Transition Metal Oxides AxNbO2 (A by : Maria Anna Rzeznik

Download or read book Synthesis and Characterization of the Layered Transition Metal Oxides AxNbO2 (A written by Maria Anna Rzeznik and published by . This book was released on 1995 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt:

High-pressure Synthesis of the 4d and 5d Transition-metal Oxides with the Perovskite and the Perovskite-related Structure and Their Physical Properties

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ISBN 13 :
Total Pages : 412 pages
Book Rating : 4.:/5 (667 download)

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Book Synopsis High-pressure Synthesis of the 4d and 5d Transition-metal Oxides with the Perovskite and the Perovskite-related Structure and Their Physical Properties by : Jinguang Cheng

Download or read book High-pressure Synthesis of the 4d and 5d Transition-metal Oxides with the Perovskite and the Perovskite-related Structure and Their Physical Properties written by Jinguang Cheng and published by . This book was released on 2010 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Walker-type multianvil high-pressure facility is capable of high-pressure syntheses and measurements beyond 10 GPa and has been utilized in my research to synthesize the 4d Ruthenium and Rhodium and the 5d Iridium oxides with the perovskite-related structures. Under high-pressure and high-temperature conditions, these families of oxides can be enlarged to a great extent so that enables us not only to address the long-standing problem about ferromagnetism in the perovskite ruthenates but also explore new phenomena associated with the structural and electronic properties in the iridates and rhodates. In the perovskite ruthenates ARuO3 (A= Ca, Sr, and Ba), a systematic study of the variations of the ferromagnetic transition temperature T[subscript c] and the critical isothermal magnetization as a function of the average A-site cation size and the size variance as well as external high pressures reveals explicitly the crucial role of the local lattice strain and disorder on T[subscript c] and the nature of the localized-electron ferromagnetism. However, such a steric effect is dominated by the electronic effect in another perovskite ruthenate PbRuO3, which is a paramagnetic metal down to 1.8 K and undergoes a first-order structural transition to a low-temperature Imma phase at Tt [almost equal to] 90 K. Bandwidth broadening due to orbital hybridization between Pb-6s and Ru-4d plays an important role in suppressing the ferromagnetism in the Sr1-zPbzRuO3 system. The high-pressure sequence of the 9R-BaIrO3 was explored and three more polytypes, i.e. 5H, 6H and 3C, were identified under 10 GPa. With increasing fraction of the corner- to face-sharing IrO6/2 octahedra, the ground states of BaIrO3 evolve from a ferromagnetic insulator with T[subscript c] [almost equal to] 180 K in the 9R phase to a ferromagnetic metal with T[subscript c] [almost equal to] 50 K in the 5H phase, and finally to an exchange-enhanced paramagnetic metal near a quantum critical point in the 6H phase. In addition to the perovskite SrRhO3, a new 6H polytype was synthesized for the first time under high pressure and a pressure-temperature phase diagram was given for the 6H-perovskite transformation. Restoration of the Curie-Weiss behavior in the high-temperature magnetic susceptibility [chi](T) of the perovskite SrRhO3 resolves the puzzle about unusual dependence of [chi]−1 [symbol] T2 reported earlier and highlights the importance of spin-orbit coupling in the 4d and 5d transition-metal oxides.

Revolution of Perovskite

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Publisher : Springer Nature
ISBN 13 : 9811512671
Total Pages : 320 pages
Book Rating : 4.8/5 (115 download)

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Book Synopsis Revolution of Perovskite by : Narayanasamy Sabari Arul

Download or read book Revolution of Perovskite written by Narayanasamy Sabari Arul and published by Springer Nature. This book was released on 2020-01-03 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents advanced synthesis techniques for fabricating Perovskite materials with enhanced properties for applications such as energy storage devices, photovoltaics, electrocatalysis, electronic devices, photocatalysts, sensing, and biomedical instruments. The book attempts to fill a gap in the published literature and provide a detailed reference on Perovskite materials. This book will be of use to graduate students and academic and industrial researchers in the fields of solid-state chemistry, physics, materials science, and chemical engineering.

Tuning Structural and Physical Properties Via A-site Doping in Perovskite-type Transition Metal Oxides

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Publisher :
ISBN 13 : 9780438032682
Total Pages : 162 pages
Book Rating : 4.0/5 (326 download)

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Book Synopsis Tuning Structural and Physical Properties Via A-site Doping in Perovskite-type Transition Metal Oxides by : Hamoud H. Somaily

Download or read book Tuning Structural and Physical Properties Via A-site Doping in Perovskite-type Transition Metal Oxides written by Hamoud H. Somaily and published by . This book was released on 2018 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis investigates the structure-property relationship of two important classes of transition metal oxides (the perovskite-type A-site substituted titanates (Sr[sub 1-x-y]Ca[sub x]Nd[sub y])TiO[sub 3] and manganites (Sr[sub 1-x]Ba[sub x])MnO[sub 3]). A thorough evaluation is provided of their potential for prospective technological applications in heat recycling and information technology by examining the thermoelectric and multiferroic prop- erties, respectively. In the titanate compounds, we doped on the A-site with small rare earth ions in order to generate mixed valent transition metals to increase band filling while the Ca doping maintained fixed levels of distortions. In the case of the manganites, A-site Sr ions were substituted with large Ba ions for the purpose of increasing the materials strain and to promote ferroelectricity. Crystal structure was investigated using high-resolution neutron powder diffraction as a function of temperature and Nd/Ba doping. In the titanates, two series were synthesized and designed to have a nominally constant tolerance factor at room temperature. We determine the room temperature structures as tetragonal I4/mcm and orthorhombic Pbnm for the Sr-rich and Ca-rich series, respectively. Three low temperature orthorhombic structures, Pbnm, Ibmm and Pbcm were also observed for the Sr-rich series; whereas, the symmetry of the Ca-rich series remained unchanged throughout the full measured temperature range. Thermoelectricity in ternary (Sr[sub 1-x-y]Ca[sub x]Nd[sub y])TiO[sub 3] perovskites was investigated. The double substitution at the A-site maintained a fixed crystal distortion while Nd3+ doping modified the electronic properties of the materials via increased band filling. Unique compositions of cations allowed for increased A-site atomic mass disorder and the lattice thermal conductivity was significantly suppressed to values as low as ~ 1.5 W/K.m in some samples, approaching amorphous Silicon limit. Charge doping via balanced formation of Ti^3+ at the B-site has transformed materials into n-type semi-conductors. I examined the range of applicability of various conduction models, viz., variable range hopping, semiconductor-type conductivity across band gap, and small polaron hopping for the best description of the temperature variation of measured resistivity. We succeeded in achieving a relatively high figure of merit ZT=0.07 at ~ 400 K in the Sr-rich Sr[sub 0.76]Ca[sub 0.16]Nd[sub 0.08]TiO[sub 3] composition which is comparable to that of the best n-type TE SrTi[sub 0.80]Nb[sub 0.20]O[sub 3] oxide material reported to date. With an enhanced Seebeck coefficient at elevated temperatures and reduced thermal conductivity, we predict that Sr[sub 0.76]Ca[sub 0.16]Nd[sub 0.08]TiO[sub 3] and similar compositions have the potential to become some of the best materials in their class of thermoelectric oxides. We also report the structure-property phase diagram of unique single-ion type-1 multiferroic pseudocubic Sr1-xBaxMnO3 perovskites. Employing a specially designed multi-step reduction-oxidation synthesis technique, we have synthesized previously unknown Sr[sub 1-x]Ba[sub x]MnO[sub 3] compositions in their polycrystalline form with a significantly extended Ba solubility limit that is only rivaled by a very limited number of crystals and thin films grown under non-equilibrium conditions. Understanding the multiferroic interplay with structure in Sr[sub 1-x]Ba[sub x]MnO[sub 3] is of great importance as it opens the door wide to the development of newer materials from the parent (AA')(BB')O3 system with enhanced properties. To this end, using a combination of time-of-flight neutron and synchrotron x-ray scattering techniques, we determined the exact structures and quantified the Mn and oxygen polar distortions above and below the ferroelectric Curie temperature TC and the Neel temperature TN. In its ferroelectric state, the system crystalizes in the noncentrosymmetric tetragonal P4mm space group which gives rise to a large electric dipole moment PS, in the z-direction, of 18.4 and 29.5 microC/cm2 for x = 0.43 and 0.45, respectively. The two independently driven ferroelectric and magnetic order parameters are single-handedly accommodated by the Mn sublattice leading to a novel strain-assisted multiferroic behavior in agreement with many theoretical predictions. Our neutron diffraction results demonstrate the large and tunable suppression of the ferroelectric order at the onset of AFM ordering and confirm the coexistence and strong coupling of the two ferroic orders below T[sub N]. The refined magnetic moments confirm the strong covalent bonding between Mn and the oxygen anions which is necessary for stabilizing the ferroelectric phase.

Dissertation Abstracts International

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Publisher :
ISBN 13 :
Total Pages : 1006 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Dissertation Abstracts International by :

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2008 with total page 1006 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Structure, Properties, and Preparation of Perovskite-type Compounds

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Publisher : Pergamon
ISBN 13 :
Total Pages : 238 pages
Book Rating : 4.:/5 (38 download)

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Book Synopsis Structure, Properties, and Preparation of Perovskite-type Compounds by : Francis S. Galasso

Download or read book Structure, Properties, and Preparation of Perovskite-type Compounds written by Francis S. Galasso and published by Pergamon. This book was released on 1969 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structure, Properties and Preparation of Perovskite-Type Compounds, Volume 5 presents the various methods of preparing powders, single crystals, and thin films of perovskite-type compounds. This book discusses the structure of perovskite-type compounds and their properties. Organized into 11 chapters, this volume begins with an overview of the structure, properties, and preparation of perovskite-type compounds. This text then examines how X-ray diffraction can be used to determine unit cell data and to orient single crystals. Other chapters consider the effect of nuclear radiation on the prop ...