Structure Of The Double Layer And Electrode Processes Ii Effect Of The Nature Of The Electrode And Application Of The Thallium Amalgam Electrode

Author : Stal G. Mairanovskii
Publisher : Springer
ISBN 13 : 1489928316
Total Pages : 359 pages
Book Rating : 4.4/5 (899 download)

DOWNLOAD NOW!

Download or read book Catalytic and Kinetic Waves in Polarography written by Stal G. Mairanovskii and published by Springer. This book was released on 2013-11-11 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: As our knowledge of the mechanism of electrode processes increases, it becomes more and more apparent that the kinetic currents first observed by R. Brdicka and by K. Wiesner in the 1940's are very widely encountered. Very many electrode pro cesses contain a chemical stage. * This is true primarily of elec trode processes that involve organic compounds. Therefore, to understand the mechanism of electrode processes and, particular ly, to correctly interpret the results of polarographic investiga tions, it is important to know the characteristics and relationships controlling the chemical reactions taking place at the electrode surface. Generally, these reactions are substantially different from ordinary chemical reactions taking place in the bulk of the solution, since the reactions at the electrodes are often affected by the electric field of the electrode and the adsorption of the par ticipating compounds . The fact that hydrogen ions usuallY take part in the electro chemical reduction of organic compounds makes possible the use of electrochemical methods, particularly polarography, for the study of protolytic reactions. These reactions play an important role in organic chemistry: the majority of reactions of organic compounds in solutions go through a stage in which a hydrogen ion is removed or added (see, for example, [1, 2]). Therefore, the polarographic study of protolytic reactions can supply much important information to theoretical organic chemistry.