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Author : Emanuel Gullo
Publisher :
ISBN 13 :
Total Pages : 296 pages
Book Rating : 4.:/5 (591 download)
Download or read book Structure, Bonding and Reactivity of Metal-alkyl Complexes written by Emanuel Gullo and published by . This book was released on 2002 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Xiaohong Bei
Publisher :
ISBN 13 :
Total Pages : 276 pages
Book Rating : 4.:/5 (399 download)
Download or read book Synthesis, Structures, Bonding, and Reactivity of Group 4 Metal Alkyl Complexes Incorporating 8-quinolinolato Ligands written by Xiaohong Bei and published by . This book was released on 1997 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : J.M. Brown
Publisher : Springer
ISBN 13 : 9783662142233
Total Pages : 195 pages
Book Rating : 4.1/5 (422 download)
Download or read book Organometallic Bonding and Reactivity written by J.M. Brown and published by Springer. This book was released on 2013-10-03 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: General The making and breaking of carbon-metal bonds is fundamental to all the p- cesses of organometallic chemistry and moreover plays a significant role in - mogeneous as well as heterogeneous catalysis. This rather blunt statement - phasises the extent to which a proper understanding of the structure, energetics and reactivity of C-M bonds is at the core of the discipline. In order to accept it, a proper definition of the terms involved is required. Quite simply we define the metal-carbon bond in its broadest sense to embrace carbon linked to transiti- metals, lanthanides and actinides, and main group metals. We do not dist- guish between formally covalent single or multiple bonding on the one hand and q-bonding on the other. In the studies to be described in the following chapters, the emphasis will be on transition metal complexes and insofar as the fun- mentals come under scrutiny, simple metal alkyls or related species (metal al- nyl, alkynyl, aryl, or allyl) will play an emphatic part. The central role of metal alkyls and their congeners and especially the role of their metal carbon linkage in homogeneous catalysis may be appreciated by considering some key reaction steps leading to their formation or breakdown. There follows a few prominent examples of transition metal mediated stoichiometric or catalytic processes: - In homogeneous hydrogenation of double bonds, the stepwise reaction of an q2-coordinated alkene with dihydrogen gives first an alkyl metal hydride, and then the decoordinated alkane by elimination.
Author : Gerard Parkin
Publisher : Springer
ISBN 13 : 3642052436
Total Pages : 316 pages
Book Rating : 4.6/5 (42 download)
Download or read book Metal-Metal Bonding written by Gerard Parkin and published by Springer. This book was released on 2010-03-10 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: John Berry: Metal-Metal Bonds in Chains of Three or More Metal Atoms: From Homometallic to Heterometallic Chains.- Malcolm Chisholm: Electronically Coupled MM Quadruple Bonded Complexes of Molybdenum and Tungsten.- Philip Power: Transition Metal Complexes Stabilized by Bulky Terphenyl Ligands: Applications to Metal–Metal Bonded Compounds.- Gerard Parkin: Metal–Metal Bonding in Bridging Hydride and Alkyl Compounds.- Roland Fischer and Gernot Frenking: Structure and Bonding of Metal Rich Coordination Compounds Containing Low Valent Ga(I) and Zn(I) Ligands.- Mike Hill: Homocatenation of Metal and Metalloid Main Group Elements.- Constandinos A. Tsipis: Aromaticity/Antiaromaticity in "Bare" and ‘‘Ligand-Stabilized’’ Rings of Metal Atoms.- Alexander Boldyrev: All-Transition Metal Aromaticity and Antiaromaticity.
Author : Edwin C. Constable
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 332 pages
Book Rating : 4.3/5 (91 download)
Download or read book Metals and Ligand Reactivity written by Edwin C. Constable and published by Wiley-VCH. This book was released on 1996-01-18 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edwin C. Constable Metals and Ligand Reactivity An Introduction to the Organic Chemistry of Metal Complexes New, revised and expanded edition This book is a highly readable introduction to the reactions of coordinated ligands, which have become a useful tool in organic synthesis. Bridging the gap between the traditional fields, this text presents the basic concepts of ligand reactivity as well as synthetic applications of these reactions. Topics covered include Principles of metal-ligand interaction Reactions of coordinated ligands with nucleophiles and electrophiles Oxidation and reduction of coordinated ligands Cyclic and encapsulating ligands, template effects and supramolecular chemistry Carefully selected examples, lucidly designed figures and schemes as well as numerous study problems make this book an ideal guide for students and practitioners of organic synthesis. References to further reading are also included.
Author : Peter Maitlis
Publisher : Elsevier
ISBN 13 : 0323155324
Total Pages : 336 pages
Book Rating : 4.3/5 (231 download)
Download or read book Metal Complexes written by Peter Maitlis and published by Elsevier. This book was released on 2012-12-02 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organic Chemistry of Palladium, Volume 1: Metal Complexes deals with the number of organic reactions that can be catalyzed by palladium, particularly as regards the structures bonding, and reactions of the metal complexes. The book discusses monodentate ligands which are either neutral (carbonyls, isonitriles, carbenes) or anionic (methyl, phenyl, ethynyl, hydride). The text also examines the complexes formed by 1,3-. 1,4-, and 1,5-diolefins where four carbon atoms are bound to the metal. Palladium (II) can undergo a reaction with the 1,3-dienes and results in a ?-allylic complexes where only three carbon atoms are coordinated to the metal. (The bonding situation in complexes 1,4- and 1,5-dienes, where no great interaction between the olefins are similar to that in monoolefin complexes, is straightforward), Olefins can also react with palladium chloride in protic solvents to produce ketones (or aldehydes) or organic coupling products. Some experiments conducted by Huttel et al shows that some palladium was precipitated from the reactions giving lower yields, resulting in various aldehydes and ketones as by products. The book also discusses cyclopentadienyl and benzene complexes. The text can prove beneficial for researchers, investigators and scientists whose works involve organic chemistry, analytical chemistry, physical chemistry and inorganic chemistry.
Author : Didier Astruc
Publisher : Springer Science & Business Media
ISBN 13 : 3540461299
Total Pages : 598 pages
Book Rating : 4.5/5 (44 download)
Download or read book Organometallic Chemistry and Catalysis written by Didier Astruc and published by Springer Science & Business Media. This book was released on 2007-08-14 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.
Author : J.M. Brown
Publisher : Springer
ISBN 13 : 3540697071
Total Pages : 206 pages
Book Rating : 4.5/5 (46 download)
Download or read book Organometallic Bonding and Reactivity written by J.M. Brown and published by Springer. This book was released on 2003-07-01 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: The making and breaking of carbon-metal bonds is fundamental to all the processes of organometallic chemistry and metal mediated homogeneous or heterogeneous catalysis. The ever expanding scope of highly specific stoichiometric and catalytic transformations or organic substrates involving metals requires a thorough physical and theoretical understanding of fundamental principles of organometallic structure and reactivity. Diffraction experiments form the basis of tailoring the molecular architecture of organometallic compounds for specific functions. Mass spectrometric techniques possess the power to provide direct information on the energetics of transient species generated in the gas-phase. Computational chemistry with ab initio or density functional methods make a reliable numerical assessment of structures and (relative) energies increasingly feasible. Embedding methods, combining quantum chemistry with force field of semiempirical MO treatments, quantum dynamic studies and the computational modelling of solvent effects extend the utility of the basic methods. This volume in the series Topics in Organometallic Chemistry presents a survey by renowned experts of important experimental and theoretical developments to elucidate basic aspects of bonding, energetics, reaction mechanisms, molecular geometries and solid-state structures of organometallic compounds. Written by authors with frontier research expertise in their fields, both experimental and quantum chemical techniques, methodologies, results and interpretations are detailed in a manner suitable for the non-specialist, who seeks state-of-the-art information in the respective field.
Author : F. Albert Cotton
Publisher : Springer Science & Business Media
ISBN 13 : 0387258299
Total Pages : 840 pages
Book Rating : 4.3/5 (872 download)
Download or read book Multiple Bonds between Metal Atoms written by F. Albert Cotton and published by Springer Science & Business Media. This book was released on 2006-07-31 with total page 840 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides historical perspective as well as current data Abundantly illustrated with figures redrawn from literature data Covers all pertinent theory and physical chemistry Catalytic and chemotherapeutic applications are included
Author : Stephen T. Liddle
Publisher : John Wiley & Sons
ISBN 13 : 3527673385
Total Pages : 592 pages
Book Rating : 4.5/5 (276 download)
Download or read book Molecular Metal-Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2016-03-16 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.
Author : Robert H. Crabtree
Publisher : John Wiley & Sons
ISBN 13 : 0471718750
Total Pages : 600 pages
Book Rating : 4.4/5 (717 download)
Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by John Wiley & Sons. This book was released on 2005-06-14 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Author : Christoph Elschenbroich
Publisher : John Wiley & Sons
ISBN 13 : 3527805141
Total Pages : 817 pages
Book Rating : 4.5/5 (278 download)
Download or read book Organometallics written by Christoph Elschenbroich and published by John Wiley & Sons. This book was released on 2016-02-10 with total page 817 pages. Available in PDF, EPUB and Kindle. Book excerpt: THE textbook on organometallic chemistry. Comprehensive and up-to-date, the German original is already a classic, making this third completely revised and updated English edition a must for graduate students and lecturers in chemistry, inorganic chemists, chemists working with/on organometallics, bioinorganic chemists, complex chemists, and libraries. Over one third of the chapters have been expanded to incorporate developments since the previous editions, while the chapter on organometallic catalysis in synthesis and production appears for the first time in this form. From the reviews of the first English editions: 'The selection of material and the order of its presentation is first class ... Students and their instructors will find this book extraordinarily easy to use and extraordinarily useful.' -Chemistry in Britain 'Elschenbroich and Salzer have written the textbook of choice for graduate or senior-level courses that place an equal emphasis on main group element and transition metal organometallic chemistry. ... this book can be unequivocally recommended to any teacher or student of organometallic chemistry.' - Angewandte Chemie International Edition 'The breadth and depth of coverage are outstanding, and the excitement of synthetic organometallic chemistry comes across very strongly.' - Journal of the American Chemical Society
Author : Jiro Tsuji
Publisher : Springer
ISBN 13 :
Total Pages : 220 pages
Book Rating : 4.:/5 (44 download)
Download or read book Organic Synthesis by Means of Transition Metal Complexes written by Jiro Tsuji and published by Springer. This book was released on 1975-11 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1970 I wrote a review article for "Topics in Current Chemistry", surveying the general reaction patterns of transition-metal complexes from the standpoint of organic synthesis. The article seems to have evoked wide interest, and I therefore thought it appropriate to treat the subject more comprehensively in the form of a monograph. Organometallic chemistry is a rapidly growing field of intensive research. In this field, the application of organometallic compounds to organic synthesis is an important subject and many unique synthetic methods have been discovered, especially in the last decade. Syntheses using transition-metal com pounds are now in the foreground of organic chemistry. The purpose of this monograph is to give a bird's-eye view of this field to both organic and inorganic chemists through a mechanistic approach. A systematic unification of the voluminous data accumulated in this field is now urgently required. This subject is discussed by classifying various reactions into general patterns and by illustrating them with a limited number of pertinent examples.
Author : Mark Stradiotto
Publisher : John Wiley & Sons
ISBN 13 : 1118839811
Total Pages : 448 pages
Book Rating : 4.1/5 (188 download)
Download or read book Ligand Design in Metal Chemistry written by Mark Stradiotto and published by John Wiley & Sons. This book was released on 2016-09-01 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: The design of ancillary ligands used to modify the structural and reactivity properties of metal complexes has evolved into a rapidly expanding sub-discipline in inorganic and organometallic chemistry. Ancillary ligand design has figured directly in the discovery of new bonding motifs and stoichiometric reactivity, as well as in the development of new catalytic protocols that have had widespread positive impact on chemical synthesis on benchtop and industrial scales. Ligand Design in Metal Chemistry presents a collection of cutting-edge contributions from leaders in the field of ligand design, encompassing a broad spectrum of ancillary ligand classes and reactivity applications. Topics covered include: Key concepts in ligand design Redox non-innocent ligands Ligands for selective alkene metathesis Ligands in cross-coupling Ligand design in polymerization Ligand design in modern lanthanide chemistry Cooperative metal-ligand reactivity P,N Ligands for enantioselective hydrogenation Spiro-cyclic ligands in asymmetric catalysis This book will be a valuable reference for academic researchers and industry practitioners working in the field of ligand design, as well as those who work in the many areas in which the impact of ancillary ligand design has proven significant, for example synthetic organic chemistry, catalysis, medicinal chemistry, polymer science and materials chemistry.
Author : John F. Hartwig
Publisher :
ISBN 13 :
Total Pages : 1172 pages
Book Rating : 4.:/5 (318 download)
Download or read book Organotransition Metal Chemistry: From Bonding to Catalysis written by John F. Hartwig and published by . This book was released on 2010-02-10 with total page 1172 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.
Author : G. E. Coates
Publisher : Springer
ISBN 13 :
Total Pages : 284 pages
Book Rating : 4.F/5 ( download)
Download or read book Principles of Organometallic Chemistry written by G. E. Coates and published by Springer. This book was released on 1968-10 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of Organometallic Compounds (1960) was used not only by specialists but also as an undergraduate textbook. The third edition, recently published in two volumes, is about three times the length of the second and contains considerably more factual material than is appropriate for a student textbook. Therefore we believe that a shorter treatment would be welcome. In planning this book the authors have emphasized matters more of prin ciple than of detail, and have included in the first two chapters some general discussion of the properties and syntheses of organometallic compounds that is not to be found in the larger work. Some aspects of the organic chemistry of arsenic, and of silicon with particular reference to silicone polymers, are also included. Most university teachers of chemistry are becoming seriously concerned about the relentless increase in the amount and complexity of the material that is squeezed into undergraduate chemistry courses. With this in mind the authors have tried to cut detail to a minimum, but readers will find that the relative amount presented varies considerably between the various topics discussed. In general the treatment is more extensive than usual only if either or both of these conditions are met: (1), the subject has significant bearing on other major branches of chemistry including im portant industrial processes; (2), the topic is commonly misunderstood or found to be confusing.
Author : B. L. Shaw
Publisher : Elsevier
ISBN 13 : 1483181715
Total Pages : 231 pages
Book Rating : 4.4/5 (831 download)
Download or read book Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis written by B. L. Shaw and published by Elsevier. This book was released on 2016-06-06 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis covers compounds that possess carbon atoms bonded to metal and to other carbon atoms. The order in which the substances appear in the book is based on the number of carbon atoms it have. The first section is about the alkyl, aryl, ethynyl, acyl, and carbene complexes. The second section deals with olefin and chelating diolefin complexes and complexes formed from acetylene. The following section covers the p-allylic complexes. The structures, stability, and bonding of alkyl and aryl complexes are fully covered. The magnetic moments and electronic spectra are discussed in detail.The fourth section discusses the conjugated diolefinic complexes that contain butadiene or cyclobutadiene. The rest of the book focuses on cyclopentadienyls, arene complexes, tropylium complexes, and complexes formed from cyclo-octatetraene or azulene. The book will be a useful tool for chemists, chemical engineers, and students and researchers in the field of chemistry.
