Structure and Reactivity of Nanostructured Model Catalysts

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Publisher :
ISBN 13 :
Total Pages : 84 pages
Book Rating : 4.:/5 (82 download)

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Book Synopsis Structure and Reactivity of Nanostructured Model Catalysts by : Thorsten Staudt

Download or read book Structure and Reactivity of Nanostructured Model Catalysts written by Thorsten Staudt and published by . This book was released on 2012 with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nanostructured Catalysts

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Publisher : Royal Society of Chemistry
ISBN 13 : 1847559875
Total Pages : 453 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Nanostructured Catalysts by : Christian Hess

Download or read book Nanostructured Catalysts written by Christian Hess and published by Royal Society of Chemistry. This book was released on 2011-07-22 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book gives a comprehensive up-to-date summary of the existing information on the structural/electronic properties, chemistry and catalytic properties of vanadium and molybdenum containing catalysts. It discusses the importance of nanoscience for the controlled synthesis of catalysts with functional properties and introduces the necessary background regarding surface properties and preparation techniques, leading from a textbook level to the current state of knowledge. Then follows an extensive survey and analysis of the existing open and patent literature - an essential knowledge source for the development of the new generation of partial oxidation catalysts. Important examples from current research on partial oxidation reactions are reviewed from experts in the field. The next chapter discusses the importance of 2- and 3-dimensional model systems for a fundamental understanding of the structure of transition metal oxide catalysts and its correlation to reactivity. Finally, an outlook on research opportunities within the area of partial oxidation reactions is presented.

Nanostructured Catalysts

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Publisher : Springer Science & Business Media
ISBN 13 : 0387306412
Total Pages : 341 pages
Book Rating : 4.3/5 (873 download)

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Book Synopsis Nanostructured Catalysts by : Susannah L. Scott

Download or read book Nanostructured Catalysts written by Susannah L. Scott and published by Springer Science & Business Media. This book was released on 2008-04-06 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: With the recent advent of nanotechnology, research and development in the area of nanostructured materials has gained unprecedented prominence. Novel materials with potentially exciting new applications are being discovered at a much higher rate than ever before. Innovative tools to fabricate, manipulate, characterize and evaluate such materials are being developed and expanded. To keep pace with this extremely rapid growth, it is necessary to take a breath from time to time, to critically assess the current knowledge and provide thoughts for future developments. This book represents one of these moments, as a number of prominent scientists in nanostructured materials join forces to provide insightful reviews of their areas of expertise, thus offering an overall picture of the state-- the art of the field. Nanostructured materials designate an increasing number of materials with designed shapes, surfaces, structures, pore systems, etc. Nanostructured materials with modified surfaces include those whose surfaces have been altered via such techniques as grafting and tethering of organic or organometallic species, or through various deposition procedures including electro, electroless and vapor deposition, or simple adsorption. These materials find important applications in catalysis, separation and environmental remediation. Materials with patterned surfaces, which are essential for the optoelectronics industry, constitute another important class of surface-modified nanostructured materials. Other materials are considered nanostructured because of their composition and internal organization.

Nanostructured Catalysts

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Publisher : Nanoscience & Nanotechnology Series
ISBN 13 : 9780854041862
Total Pages : 438 pages
Book Rating : 4.0/5 (418 download)

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Book Synopsis Nanostructured Catalysts by : Christian Hess

Download or read book Nanostructured Catalysts written by Christian Hess and published by Nanoscience & Nanotechnology Series. This book was released on 2011 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book gives a comprehensive summary of the existing information on the structural/electronic properties, chemistry and catalytic properties of vanadium and molybdenum containing catalysts. As at least one of these two elements is essential to most partial oxidation catalysts the book is of great interest to advanced students of catalysis and researchers both in academia and industry. Despite major developments in the field, the last book with a similar scope was published in 1989 and therefore a new book is overdue. The book benefits largely from the fact that the subject is a major research focus at the Department of Inorganic Chemistry amongst other departments at the Fritz Haber Institute, a world leading institution for catalysis research, ensuring an up-to-date treatise. Such an integrated approach including the relation of in situ spectroscopic results from real catalysts to those of model catalytic systems has not been accomplished before. The introductory chapter discusses the importance of nanoscience for the controlled synthesis of catalysts with functional properties. The following two chapters introduce the necessary background regarding surface properties and preparation techniques, leading from a textbook level to the current state of knowledge. The following chapter starts with an extensive survey and analysis of the existing open and patent literature, which is an essential knowledge source for the development of the new generation of partial oxidation catalysts and will be of particular value to those developing new partial oxidation catalysts. In the remaining subchapters, important examples from current research on partial oxidation reactions are reviewed from experts in the field. The next chapter discusses the importance of 2- and 3-dimensional model systems for a fundamental understanding of the structure of transition metal oxide catalysts and its correlation to reactivity. These results are related to those of the real catalytic systems. The last chapter gives an outlook on research opportunities within the area of partial oxidation reactions.

Catalysis by Materials with Well-Defined Structures

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Publisher : Academic Press
ISBN 13 : 0128013400
Total Pages : 393 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Catalysis by Materials with Well-Defined Structures by : Zili Wu

Download or read book Catalysis by Materials with Well-Defined Structures written by Zili Wu and published by Academic Press. This book was released on 2015-03-26 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis by Materials with Well-Defined Structures examines the latest developments in the use of model systems in fundamental catalytic science. A team of prominent experts provides authoritative, first-hand information, helping readers better understand heterogeneous catalysis by utilizing model catalysts based on uniformly nanostructured materials. The text addresses topics and issues related to material synthesis, characterization, catalytic reactions, surface chemistry, mechanism, and theoretical modeling, and features a comprehensive review of recent advances in catalytic studies on nanomaterials with well-defined structures, including nanoshaped metals and metal oxides, nanoclusters, and single sites in the areas of heterogeneous thermal catalysis, photocatalysis, and electrocatalysis. Users will find this book to be an invaluable, authoritative source of information for both the surface scientist and the catalysis practitioner Outlines the importance of nanomaterials and their potential as catalysts Provides detailed information on synthesis and characterization of nanomaterials with well-defined structures, relating surface activity to catalytic activity Details how to establish the structure-catalysis relationship and how to reveal the surface chemistry and surface structure of catalysts Offers examples on various in situ characterization instrumental techniques Includes in-depth theoretical modeling utilizing advanced Density Functional Theory (DFT) methods

Bridging the Materials Gap in Catalysis: Reactivity Studies of Nanostructured Titania

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Publisher :
ISBN 13 :
Total Pages : 356 pages
Book Rating : 4.:/5 (98 download)

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Book Synopsis Bridging the Materials Gap in Catalysis: Reactivity Studies of Nanostructured Titania by : David A. Bennett

Download or read book Bridging the Materials Gap in Catalysis: Reactivity Studies of Nanostructured Titania written by David A. Bennett and published by . This book was released on 2016 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface science studies of defect-free, single-crystal model catalysts have provided vital knowledge in the form of structure-activity relationships and elementary reaction mechanisms. However, there is some difficultly in extending this understanding to more complex systems, since these model catalysts typically lack the range of features that occur on the high surface area catalysts used in industry. This project seeks to bridge the gap between these two classes of materials by studying thin films of well-defined TiO2 nanocrystals with tunable size and morphology using traditional surface science techniques. This enables the controlled introduction of features lacking in single-crystal model catalysts, allowing for the formulation of more complex structure-activity relationships. The thermal- and photocatalytic reactions of methanol to produce methane, formaldehyde, dimethyl ether, and methyl formate on these TiO 2 nanoparticles were investigated using temperature programmed desorption in ultra high vacuum. Results show clear effects of nanocrystal size and shape on the activity and selectivity of these reactions. This demonstrates the value of studying nanostructured metal-oxide catalysts to better understand the relationship between fundamental catalytic knowledge and the behavior of complex heterogeneous catalysts.

Nanocatalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 3540326464
Total Pages : 514 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis Nanocatalysis by : Ulrich Heiz

Download or read book Nanocatalysis written by Ulrich Heiz and published by Springer Science & Business Media. This book was released on 2007-01-10 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocatalysis, a subdiscipline of nanoscience, seeks to control chemical reactions by changing the size, dimensionality, chemical composition, and morphology of the reaction center and by changing the kinetics using nanopatterning of the reaction center. This book offers a detailed pedagogical and methodological overview of the field. Readers discover many examples of current research, helping them explore new and emerging applications.

International Assessment of Research and Development in Catalysis by Nanostructured Materials

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Publisher : World Scientific
ISBN 13 : 1848166893
Total Pages : 329 pages
Book Rating : 4.8/5 (481 download)

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Book Synopsis International Assessment of Research and Development in Catalysis by Nanostructured Materials by : Robert Davis

Download or read book International Assessment of Research and Development in Catalysis by Nanostructured Materials written by Robert Davis and published by World Scientific. This book was released on 2011 with total page 329 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalyst technologies account for over $1 trillion of revenue in the U.S. economy alone. The applications range from medicines and alternative energy fuel cell technologies to the development of new and innovative clothing fibers. In this book, a World Technology Evaluation Center (WTEC) panel of eight experts in the field assesses the current state of research and development in catalysis by nanostructured materials, its sources of funding, and discusses the state of the field with respect to productivity and leadership in various nations around the world. In addition to showing the numerous and highly advantageous practical applications of the field, the panel concludes that Western Europe is currently the most productive region, followed closely by the United States. Still, the research and development output of the People's Republic of China has recently surpassed that of Japan and is now poised to surpass that of the U.S. as well. As such, this assessment is a timely review of the field's progress, taking into account the increasing contributions from Asia, and will be essential reading for professionals, whether they are seeking an in-depth summary of the state of the art or a broad view of trends affecting the discipline.

Nanostructured Carbon Materials for Catalysis

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849739099
Total Pages : 570 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Nanostructured Carbon Materials for Catalysis by : Philippe Serp

Download or read book Nanostructured Carbon Materials for Catalysis written by Philippe Serp and published by Royal Society of Chemistry. This book was released on 2015 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: Looking at the structure, properties and synthesis of nanocarbons as catalysts, this is the first book to provide a comprehensive view of the subject.

Model Nanocatalysts with Tunable Reactivity

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Publisher :
ISBN 13 :
Total Pages : 155 pages
Book Rating : 4.:/5 (968 download)

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Book Synopsis Model Nanocatalysts with Tunable Reactivity by : Hemma Mistry

Download or read book Model Nanocatalysts with Tunable Reactivity written by Hemma Mistry and published by . This book was released on 2016 with total page 155 pages. Available in PDF, EPUB and Kindle. Book excerpt: One of the most pressing challenges of our time is meeting growing global energy demands while limiting human impact on the environment. To meet this challenge, new catalysts are needed to enable carbon neutral energy production processes and low cost synthesis of alternative fuels. In order to design new catalysts for such processes, fundamental understanding is needed on how the structural and chemical properties of nanostructured materials influences their surface chemistry. In this dissertation, I explore how the properties of nanoparticles, such as particle size, shape, composition, and chemical state, can be used to tune their reactivity. For this work, model nanoparticles were synthesized with well-defined structural and chemical properties, and a variety of surface science approaches were used for catalyst characterization. In particular, emphasis was placed on understanding the changes which may occur in the catalyst structure and chemical state during a reaction using advanced in situ techniques and correlating these changes to reactivity. After exploring how nanostructuring the catalyst surface can be used to tune reactivity and how dynamic changes can occur to nanocatalysts in reactive environments, these general principles are applied to a model reaction, the electroreduction of carbon dioxide, which is a promising process for synthesizing valuable products using renewable energy while consuming waste carbon dioxide. I explore the mechanisms behind how catalyst particle size, composition, and oxidation state can be used to improve activity and tune selectivity towards different carbon dioxide reduction products. Such fundamental mechanistic insights are critically needed to design efficient catalysts for this reaction.

Solution Combustion Synthesis Of Nanostructured Solid Catalysts For Sustainable Chemistry

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Publisher : World Scientific
ISBN 13 : 1786348713
Total Pages : 266 pages
Book Rating : 4.7/5 (863 download)

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Book Synopsis Solution Combustion Synthesis Of Nanostructured Solid Catalysts For Sustainable Chemistry by : Sergio Gonzalez-cortes

Download or read book Solution Combustion Synthesis Of Nanostructured Solid Catalysts For Sustainable Chemistry written by Sergio Gonzalez-cortes and published by World Scientific. This book was released on 2020-10-23 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: The term 'green chemistry' was coined by Anastas and Warner in the early 1990s and it is nowadays the mainstay of designing and implementing advanced chemical processes that decrease or eliminate the use and generation of hazardous substances whilst minimizing energy consumption.Solution Combustion Synthesis of Nanostructured Solid Catalysts for Sustainable Chemistry is an interdisciplinary collection of fundamental and applied cutting-edge studies which highlight general and specific aspects of the synthesis of nanostructured catalysts through Solution Combustion Synthesis (SCS), studying their applications from the perspective of green chemistry.This book intends to integrate the fundamental principles of the SCS process with its engineering aspects and covers the synthesis of a wide variety of catalytic materials. This reference book can be used as a permanent consulting material for students, researchers and the general readership for green chemistry, nanochemistry, materials science and chemical engineering.

Nanostructured Materials

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Publisher : Academic Press
ISBN 13 : 9780127444512
Total Pages : 244 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Nanostructured Materials by : Jackie Ying

Download or read book Nanostructured Materials written by Jackie Ying and published by Academic Press. This book was released on 2001-12-14 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thematic volume of Advances in Chemical Engineering presents the latest advances in the exciting interdisciplinary field of nanostructured materials. Written by chemical engineers, chemists, physicists, materials scientists, and bioengineers, this volume focuses on the molecular engineering of materials at the nanometer scale for unique size-dependent properties. It describes a "bottom-up" approach to designing nanostructured systems for a variety of chemical, physical, and biological applications.

Nanostructured Ceria Catalysts for Selective Oxidation

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Publisher :
ISBN 13 : 9784834401622
Total Pages : 0 pages
Book Rating : 4.4/5 (16 download)

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Book Synopsis Nanostructured Ceria Catalysts for Selective Oxidation by : Reddy Nallapa

Download or read book Nanostructured Ceria Catalysts for Selective Oxidation written by Reddy Nallapa and published by . This book was released on 2023-10-12 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured ceria catalysts have shown promising results in selective oxidation reactions due to their unique properties and structures. In this field, Nallapa Reddy has conducted research on designing and developing efficient and effective ceria-based catalysts for selective oxidation reactions. The use of nanostructured ceria catalysts has gained a lot of attention in recent years due to their high surface area, unique surface chemistry, and excellent redox properties, making them ideal for catalysis. The study of nanostructured ceria catalysts involves the synthesis, modification, and characterization of ceria-based catalysts at the nanoscale level. These catalysts can be tailored to specific chemical reactions and processes by controlling their chemical synthesis, modification, and processing parameters. Chemical reactions can be optimized to maximize yield, selectivity, and specificity by understanding the chemical properties, mechanisms, and intermediates of the reaction. Various characterization techniques such as X-ray diffraction, transmission electron microscopy, scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy are used to analyze the physical and chemical properties of the nanostructured ceria catalysts. The characterization results are crucial in understanding the structure-property relationship of the catalysts and to identify the optimal catalyst structure for a particular reaction. The potential applications of nanostructured ceria catalysts include catalytic oxidation reactions, redox reactions, and other chemical reactions in the field of chemical engineering. The surface properties of the catalysts can be modified to achieve the desired catalytic activity and selectivity for the specific reaction. These catalysts can be used for industrial applications in chemical synthesis, petrochemicals, and other chemical manufacturing processes. The development of nanostructured ceria catalysts has also contributed to the advancement of green chemistry by reducing the need for hazardous reagents and improving the efficiency of chemical reactions. However, the toxicity and biocompatibility of the catalysts need to be studied and considered to ensure their safe use in industrial applications and to prevent any negative impact on the environment. Overall, Nallapa Reddy's research on nanostructured ceria catalysts for selective oxidation reactions has contributed significantly to the field of catalysis and chemical engineering. The optimization of chemical reactions and the development of efficient and effective catalysts are crucial in achieving sustainable and efficient chemical manufacturing processes.

Model Systems in Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 0387980490
Total Pages : 531 pages
Book Rating : 4.3/5 (879 download)

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Book Synopsis Model Systems in Catalysis by : Robert Rioux

Download or read book Model Systems in Catalysis written by Robert Rioux and published by Springer Science & Business Media. This book was released on 2009-11-11 with total page 531 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an excellent compilation of cutting-edge research in heterogeneous catalysis and related disciplines – surface science, organometallic catalysis, and enzymatic catalysis. In 23 chapters by noted experts, the volume demonstrates varied approaches using model systems and their successes in understanding aspects of heterogeneous catalysis, both metal- and metal oxide-based catalysis in extended single crystal and nanostructured catalytic materials. To truly appreciate the astounding advances of modern heterogeneous catalysis, let us first consider the subject from a historical perspective. Heterogeneous catalysis had its beginnings in England and France with the work of scientists such as Humphrey Davy (1778–1829), Michael Faraday (1791–1867), and Paul Sabatier (1854–1941). Sabatier postulated that surface compounds, si- lar to those familiar in bulk to chemists, were the intermediate species leading to catalytic products. Sabatier proposed, for example, that NiH moieties on a Ni sur- 2 face were able to hydrogenate ethylene, whereas NiH was not. In the USA, Irving Langmuir concluded just the opposite, namely, that chemisorbed surface species are chemically bound to surfaces and are unlike known molecules. These chemisorbed species were the active participants in catalysis. The equilibrium between gas-phase molecules and adsorbed chemisorbed species (yielding an adsorption isotherm) produced a monolayer by simple site-filling kinetics.

Morphological, Compositional, and Shape Control of Materials for Catalysis

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Publisher : Elsevier
ISBN 13 : 0323446655
Total Pages : 712 pages
Book Rating : 4.3/5 (234 download)

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Book Synopsis Morphological, Compositional, and Shape Control of Materials for Catalysis by : Paolo Fornasiero

Download or read book Morphological, Compositional, and Shape Control of Materials for Catalysis written by Paolo Fornasiero and published by Elsevier. This book was released on 2017-05-23 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: Morphological, Compositional, and Shape Control of Materials for Catalysis, Volume 177, the latest in the Studies in Surface Science and Catalysis series, documents the fast-growing developments in the synthesis, characterization, and utilization of nanostructures for catalysis. The book provides essential background on using well-defined materials for catalysis and presents exciting new paradigms in the preparation and application of catalytic materials, with an emphasis on how structure determines catalytic properties. In addition, the book uniquely features discussions on the future of the field, with ample space for future directions detailed in each chapter. Presents the latest paradigms in the preparation and application of catalytic materials Provides essential background on using well-defined materials for catalysis Features discussion of future directions at the end of each chapter

Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry

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Publisher : Royal Society of Chemistry
ISBN 13 : 1788018052
Total Pages : 370 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry by : Rafael Luque

Download or read book Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry written by Rafael Luque and published by Royal Society of Chemistry. This book was released on 2019-05-10 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoparticles exhibit a range of different properties when compared to bulk materials. Their high surface-area to volume ratio makes them particularly attractive for use as catalysts and recent years have seen an explosion of research in this area. The ability to fine-tune the size and structure of nanoparticles means that it is possible to design catalytic materials for improved activity or specificity. As catalysis is one of the key technologies for more sustainable production of both chemicals and energy, the past few years have seen increasing numbers of nanomaterials reported for these applications. Depending on the application, a number of different catalyst synthesis and optimization protocols can be used. This book provides comprehensive links between the design and fabrication method for nanoparticles and their catalytic performance (activity, selectivity and stability) in various applications. Presenting an introduction to the concept of catalyst design and recent developments in the preparation and characterisation of nanomaterials, followed by several chapters on the design of catalysts for specific applications, this book is a valuable resource for researchers working on catalytic reactions, industrial processes and nanomaterial applications.

International Assessment Of Research And Development In Catalysis By Nanostructured Materials

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Author :
Publisher : World Scientific
ISBN 13 : 1908977809
Total Pages : 329 pages
Book Rating : 4.9/5 (89 download)

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Book Synopsis International Assessment Of Research And Development In Catalysis By Nanostructured Materials by : Robert Davis

Download or read book International Assessment Of Research And Development In Catalysis By Nanostructured Materials written by Robert Davis and published by World Scientific. This book was released on 2011-01-20 with total page 329 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalyst technologies account for over $1 trillion of revenue in the U.S. economy alone. The applications range from medicines and alternative energy fuel cell technologies to the development of new and innovative clothing fibers. In this book, a World Technology Evaluation Center (WTEC) panel of eight experts in the field assesses the current state of research and development in catalysis by nanostructured materials, its sources of funding, and discusses the state of the field with respect to productivity and leadership in various nations around the world. In addition to showing the numerous and highly advantageous practical applications of the field, the panel concludes that Western Europe is currently the most productive region, followed closely by the United States. Still, the research and development output of the People's Republic of China has recently surpassed that of Japan and is now poised to surpass that of the U.S. as well.As such, this assessment is a timely review of the field's progress, taking into account the increasing contributions from Asia, and will be essential reading for professionals, whether they are seeking an in-depth summary of the state of the art or a broad view of trends affecting the discipline./a