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Strained Sigma Bonds
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Book Synopsis Electron Flow in Organic Chemistry by : Paul H. Scudder
Download or read book Electron Flow in Organic Chemistry written by Paul H. Scudder and published by John Wiley & Sons. This book was released on 2013-02-19 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sets forth the analytical tools needed to solve key problems in organic chemistry With its acclaimed decision-based approach, Electron Flow in Organic Chemistry enables readers to develop the essential critical thinking skills needed to analyze and solve problems in organic chemistry, from the simple to complex. The author breaks down common mechanistic organic processes into their basic units to explain the core electron flow pathways that underlie these processes. Moreover, the text stresses the use of analytical tools such as flow charts, correlation matrices, and energy surfaces to enable readers new to organic chemistry to grasp the fundamentals at a much deeper level. This Second Edition of Electron Flow in Organic Chemistry has been thoroughly revised, reorganized, and streamlined in response to feedback from both students and instructors. Readers will find more flowcharts, correlation matrices, and algorithms that illustrate key decision-making processes step by step. There are new examples from the field of biochemistry, making the text more relevant to a broader range of readers in chemistry, biology, and medicine. This edition also offers three new chapters: Proton transfer and the principles of stability Important reaction archetypes Qualitative molecular orbital theory and pericyclic reactions The text's appendix features a variety of helpful tools, including a general bibliography, quick-reference charts and tables, pathway summaries, and a major decisions guide. With its emphasis on logical processes rather than memorization to solve mechanistic problems, this text gives readers a solid foundation to approach and solve any problem in organic chemistry.
Book Synopsis Strained Organic Molecules by : Arthur Greenberg
Download or read book Strained Organic Molecules written by Arthur Greenberg and published by Academic Press. This book was released on 2013-10-22 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: Strained Organic Molecule, Volume 38 considers the vast field of strained organic molecules. The book discusses energy and entropy; cyclopropane and cyclobutane; and unique strained groupings or building blocks. The text also describes the aesthetics, rearrangements, and topology of polycycles; kinetic and thermodynamic stability; and tetrahedral tetracoordinate carbon. The inverted tetrahedra, propellanes, buttaflanes, and paddlanes; planar methane and its derivatives; and five- and six-coordinaste carbon are also considered. Chemists will find the book invaluable.
Book Synopsis Strained Sigma Bonds by : Arasibo Campeche
Download or read book Strained Sigma Bonds written by Arasibo Campeche and published by Water Dragon Publishing. This book was released on 2024-05-22 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: Embark on adventures to discover stories about science, magic, the tarot, Haitian vodou, the clash of epistemologies, and addiction. These stories are about people trying to control their environment, their sense of self, even the smallest of things within their power… …and failing.
Book Synopsis Frontiers in Chemistry: Rising Stars 2022 by : Yunping Qiu
Download or read book Frontiers in Chemistry: Rising Stars 2022 written by Yunping Qiu and published by Frontiers Media SA. This book was released on 2024-02-01 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: We are delighted to present the 2022 Edition of our Frontiers in Chemistry “Rising Stars” article collection. This collection showcases the high-quality work of internationally recognized researchers in the early stages of their independent careers. All Rising Star researchers were individually nominated by our Guest Editors and Chief Editors in recognition of their potential to influence the future directions in their respective fields. This year, we have selected Guest Editors who were featured as our Rising Stars in our previous collection together with Editorial Board members. The work presented here highlights the diversity of research performed across the entire breadth of chemical science and presents advances in theory, experiment and methodology with applications to compelling problems.
Book Synopsis Hypercarbon Chemistry by : George A. Olah
Download or read book Hypercarbon Chemistry written by George A. Olah and published by John Wiley & Sons. This book was released on 2011-08-04 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: The essential new edition of the book that put hypercarbon chemistry on the map A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon. Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.
Book Synopsis Organotransition-Metal Chemistry by : Yoshio Ishii
Download or read book Organotransition-Metal Chemistry written by Yoshio Ishii and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthesis of Organotransition Metals.- Metallocarboranes: Past, Present, and Future.- Novel Rhodium and Palladium Complexes with Benzoyl and Thiobenzoyl Isocyanates as Ligands.- Polycyanovinyl Transition Metal Derivatives.- A New Preparation of Organocopper(I)-Isonitrile Complexes and Their Reactions.- An Unusual Behavior of?-Vinyl Alcohol Complexes of Transition Metals.- The Mode of Formation of Transition Metal to Carbon Bonds by Oxidative Addition.- Organoactinides: Coordination Patterns and Chemical Reactivity.- Recent Developments in Chemistry of Organolanthanides and Organoactinides.- C.
Book Synopsis Engineering, Medicine and Science at the Nano-Scale by : Stephen J. Fonash
Download or read book Engineering, Medicine and Science at the Nano-Scale written by Stephen J. Fonash and published by John Wiley & Sons. This book was released on 2018-08-17 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Students at universities the world over will benefit from the authors' concise treatment, arising out of lectures given for a graduate and advanced undergraduate course at Penn State University (USA) and University of Technology Delft (NL). The textbook begins by addressing, in general terms, the phenomena and peculiarities that occur at the nanoscale. In the following five chapters, readers are introduced in detail to nanoscale physics, chemistry, materials science, and biology, followed by chapters on synthesis and fabrication as well as characterization at the nanoscale. In the next four chapters a variety of exemplary applications taken from a wide range of sectors are also presented and discussed. Concerns for safety, environmental impact, workforce development, economic wellbeing, and societal change issues arising from nanotechnology are woven throughout the book and additionally form the focus of the last two chapters.
Book Synopsis The Art of Writing Reasonable Organic Reaction Mechanisms by : Robert B. Grossman
Download or read book The Art of Writing Reasonable Organic Reaction Mechanisms written by Robert B. Grossman and published by Springer Science & Business Media. This book was released on 2006-04-18 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.
Download or read book Research in Progress written by and published by . This book was released on 1971 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Original Reactivity of Copper and Gold Complexes by : Maximilian Joost
Download or read book Synthesis and Original Reactivity of Copper and Gold Complexes written by Maximilian Joost and published by Springer. This book was released on 2015-06-13 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first σ-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into σ-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and the corresponding mechanism identified. The intermolecular oxidative addition of σ-SiSi, σ-CC and σ-CX (X=halogen) bonds with molecular gold (I) complexes is studied in detail, effectively demonstrating that this reaction, usually considered to be impossible for gold, is actually highly favored, provided an adequate ligand is employed. The use of small-bite angle bis (phosphine) gold (I) complexes allows for the first time the oxidative addition of σ-CC and σ-CX bonds for gold (I). These results shed light on an unexpected reactivity pattern of gold complexes and may point the way to 2-electron redox transformations mediated by this metal, opening up new perspectives in gold catalysis.
Book Synopsis Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds by : Barry M. Trost
Download or read book Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds written by Barry M. Trost and published by Elsevier. This book was released on 1991 with total page 1328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Book Synopsis The Chemical Bond by : Gernot Frenking
Download or read book The Chemical Bond written by Gernot Frenking and published by John Wiley & Sons. This book was released on 2014-07-08 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the perfect complement to "Chemical Bonding - Across the Periodic Table" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community. The resulting book is a unique overview of the different approaches used for describing a chemical bond, including molecular-orbital based, valence-bond based, ELF, AIM and density-functional based methods. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemical models and faster computers.
Book Synopsis Bibliography of Mass Spectroscopy Literature for 1971 by :
Download or read book Bibliography of Mass Spectroscopy Literature for 1971 written by and published by . This book was released on 1973 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Aspects of Mechanism and Organometallic Chemistry by : J.H. Brewster
Download or read book Aspects of Mechanism and Organometallic Chemistry written by J.H. Brewster and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: In May of 1978, several hundred of the friends, colleagues and former students of Professor Herbert C. Brown gathered on the campus of Purdue University to note his formal retirement, to honor him for his past contributions to chemistry and to wish him continued success in research. It was a time of reunion and recollection, a time for looking back and giving recognition to a lifetime of accomplishment. There was the ceremony of a banquet, presided over with inimitable wit by Professor Derek Davenport, and the dedication of the Herbert C. Brown Archives, with addresses by Dr. Alfred Bader, of Aldrich Chemicals, and Dr. Alan Schriesheim, of Exxon. There was the publi cation of a book of the personal reminiscences of students and post doctoral colleagues - "Remembering HCB." But it was also a time for looking at the present and into the future with a set of scien tific lectures, mainly by former students or associates, who des cribed their current or projected research activities. That is what this book is about. The papers, some of which are expanded versions of the lectures, fall into two broad groups - some deal with the interplay of struc ture and mechanism, the others deal with the use of organometallics in synthesis. It is, perhaps, no accident that these are the two main areas of H. C. Brown's research interest.
Book Synopsis Additions to and Substitutions at C-C ?-Bonds by : M.F. Semmelhack
Download or read book Additions to and Substitutions at C-C ?-Bonds written by M.F. Semmelhack and published by Elsevier. This book was released on 1992-09-08 with total page 1322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Download or read book Computational Chemistry written by and published by Academic Press. This book was released on 2019-02-20 with total page 558 pages. Available in PDF, EPUB and Kindle. Book excerpt: Computational Chemistry, Volume 73, the latest release in the Advances in Inorganic Chemistry series, presents timely and informative summaries on current progress in a variety of subject areas. This acclaimed serial features reviews written by experts in the field, serving as an indispensable reference to advanced researchers that empowers readers to pursue new developments in each field. Users will find this to be a comprehensive overview of recent findings and trends from the last decade that covers various kinds of inorganic topics, from theoretical oriented supramolecular chemistry, to the quest for accurate calculations of spin states in transition metals. Features comprehensive reviews on the latest developments in computational studies in inorganic chemistry Includes contributions from leading experts in the field of inorganic reaction mechanisms Serves as an indispensable reference to advanced researchers in many related fields
Download or read book Organic Chemistry written by Pierre Vogel and published by John Wiley & Sons. This book was released on 2019-07-30 with total page 1382 pages. Available in PDF, EPUB and Kindle. Book excerpt: The know-how about reactivity, reaction mechanisms, thermodynamics and other basics in physical organic chemistry is the key for successful organic reactions. This textbook presents comprehensively this knowledge to the student and to the researcher, too. Includes Q&As.
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