Steam Reforming of Ethanol Over Sol-gel-synthesized Mixed Oxide Catalysts

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (611 download)

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Book Synopsis Steam Reforming of Ethanol Over Sol-gel-synthesized Mixed Oxide Catalysts by :

Download or read book Steam Reforming of Ethanol Over Sol-gel-synthesized Mixed Oxide Catalysts written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Depletion in the reserves of fossil fuels, inefficient energy production from these fuels and the negative effect of their usage on atmosphere, and thereby, on human health have accelerated researches on clean energy. Hydrogen produced from ethanol when used in fuel cells not only generates efficient energy but also creates a closed carbon cycle in nature. ZnO and Cu/ZnO catalysts are known with their superior performance in alcohol synthesis. From the principle of microkinetic reversibility they are expected to be superior catalysts for the steam reforming reaction of ethanol as well. ZnO catalysts can be modified by precious, Pd, or non-precious, Cu, metals to enhance hydrogen desorption capability, and dispersed on SiO2 for high surface areas via sol-gel technique. Steam reforming tests over ZnO catalysts revealed that they act only as ethanol dehydrogenation catalysts in the temperature range of 300-500C. Promotion with Pd or Cu decreased hydrogen selectivity due most probably to unreachable closed pores of the catalysts. Autothermal reforming tests over both ZnO/SiO2 and Co/SBA-15 catalysts, on the other hand, gave rise to the formation of several side products.

Sol-Gel Synthesis Strategies for Tailored Catalytic Materials

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Publisher : Springer Nature
ISBN 13 : 3031207238
Total Pages : 78 pages
Book Rating : 4.0/5 (312 download)

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Book Synopsis Sol-Gel Synthesis Strategies for Tailored Catalytic Materials by : Serena Esposito

Download or read book Sol-Gel Synthesis Strategies for Tailored Catalytic Materials written by Serena Esposito and published by Springer Nature. This book was released on 2023-01-30 with total page 78 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses the synthesis of catalytic materials with improved and tailored functionalities via the sol-gel method. Beginning with a general outline of traditional sol-gel chemistry, the book gradually explores surrounding topics, such as the formation of porous structures, while guiding the overall discussion toward the synthesis of heterogeneous catalysts and focusing throughout on the structure-activity relationship in catalytic materials. Featuring several case studies covering major current industrial applications, the book is an ideal guide for researchers looking to tailor catalytic materials for a specific catalytic process and thus exploiting the versatility of the “traditional” sol-gel method.

Hydrogen Production From Ethanol Over Silica Supported Cu And Zn Oxide Catalysts

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ISBN 13 :
Total Pages : 96 pages
Book Rating : 4.:/5 (417 download)

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Book Synopsis Hydrogen Production From Ethanol Over Silica Supported Cu And Zn Oxide Catalysts by : Habibe Işıl Tezel

Download or read book Hydrogen Production From Ethanol Over Silica Supported Cu And Zn Oxide Catalysts written by Habibe Işıl Tezel and published by . This book was released on 2006 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt: The majority of current energy needs are supplied by combustion of nonrenewable energy sources such as fossil fuels, which is associated with release of large quantities of greenhouse gases, especially carbon dioxide and other harmful emissions to the atmosphere. The gradual depletion of these fossil fuels reserves and efforts to combat pollution and greenhouse gas emissions have generated a considerable interest in using alternative sources of energy. Ethanol used in the hydrogen production process by steam reforming. The purpose of this work was to design a high performance catalyst for the production of hydrogen from steam reforming of ethanol. Ethanol steam reforming reaction is an endothermic reaction of ethanol with water to produce hydrogen and carbon dioxide. The different ZnO loading supported SiO2 catalyst and Cu promoted ZnO/SiO2 catalysts were prepared single step sol-gel method with different Cu loading. All catalysts were characterized by X-ray diffraction, BET surface area measurements and pore diameter analysis. BET surface area decreased and average pore diameter increased as the ZnO loading increased. Based on the XRD findings, it seems that zinc silicate crystallite phase is not formed under the preparation conditions used in this dissertation. The activity and selectivity tests of all catalysts were performed in a packed bed reactor with reaction temperature between 300 and 500oC. The performances of ZnO/SiO2 catalysts in ethanol steam reforming reaction were investigated as a function of ZnO loading. Cu catalysts are known as active catalysts for ethanol dehydrogenation. As the temperature was increased, the conversion increased and reached a maximum at 500oC for all Cu loadings.

Catalytic Steam Reforming of Ethanol Over Rh,Pd/Ceria

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ISBN 13 :
Total Pages : 178 pages
Book Rating : 4.:/5 (225 download)

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Book Synopsis Catalytic Steam Reforming of Ethanol Over Rh,Pd/Ceria by : Morgan Stephen Scott

Download or read book Catalytic Steam Reforming of Ethanol Over Rh,Pd/Ceria written by Morgan Stephen Scott and published by . This book was released on 2007 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen from ethanol features as one of the renewable, clean, alternative energies technology has increasingly become directed at. Catalytic steam reforming of ethanol produces up 75% hydrogen by volume. This work is devoted to the synthesis, characterisation and testing of a series of catalysts for ethanol steam reforming. These catalysts composed of two transition metals (Rhodium and Palladium) deposited over nanoparticles of cerium oxide as a support.

Solution Combustion Synthesis Of Nanostructured Solid Catalysts For Sustainable Chemistry

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Publisher : World Scientific
ISBN 13 : 1786348713
Total Pages : 266 pages
Book Rating : 4.7/5 (863 download)

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Book Synopsis Solution Combustion Synthesis Of Nanostructured Solid Catalysts For Sustainable Chemistry by : Sergio Gonzalez-cortes

Download or read book Solution Combustion Synthesis Of Nanostructured Solid Catalysts For Sustainable Chemistry written by Sergio Gonzalez-cortes and published by World Scientific. This book was released on 2020-10-23 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: The term 'green chemistry' was coined by Anastas and Warner in the early 1990s and it is nowadays the mainstay of designing and implementing advanced chemical processes that decrease or eliminate the use and generation of hazardous substances whilst minimizing energy consumption.Solution Combustion Synthesis of Nanostructured Solid Catalysts for Sustainable Chemistry is an interdisciplinary collection of fundamental and applied cutting-edge studies which highlight general and specific aspects of the synthesis of nanostructured catalysts through Solution Combustion Synthesis (SCS), studying their applications from the perspective of green chemistry.This book intends to integrate the fundamental principles of the SCS process with its engineering aspects and covers the synthesis of a wide variety of catalytic materials. This reference book can be used as a permanent consulting material for students, researchers and the general readership for green chemistry, nanochemistry, materials science and chemical engineering.

Surface Chemistry and Catalysis

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Publisher : MDPI
ISBN 13 : 303842286X
Total Pages : 301 pages
Book Rating : 4.0/5 (384 download)

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Book Synopsis Surface Chemistry and Catalysis by : Michalis Konsolakis

Download or read book Surface Chemistry and Catalysis written by Michalis Konsolakis and published by MDPI. This book was released on 2018-09-27 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "Surface Chemistry and Catalysis" that was published in Catalysts

Synthesis and Characterization of Nickel-based Mixed Oxides for Ethanol Steam Reforming

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Publisher :
ISBN 13 :
Total Pages : 139 pages
Book Rating : 4.:/5 (968 download)

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Book Synopsis Synthesis and Characterization of Nickel-based Mixed Oxides for Ethanol Steam Reforming by : Evgeny Bolshak

Download or read book Synthesis and Characterization of Nickel-based Mixed Oxides for Ethanol Steam Reforming written by Evgeny Bolshak and published by . This book was released on 2015 with total page 139 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Perovskites and Related Mixed Oxides

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Publisher : John Wiley & Sons
ISBN 13 : 3527337636
Total Pages : 1050 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Perovskites and Related Mixed Oxides by : Pascal Granger

Download or read book Perovskites and Related Mixed Oxides written by Pascal Granger and published by John Wiley & Sons. This book was released on 2016-02-23 with total page 1050 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive handbook and ready reference details all the main achievements in the field of perovskite-based and related mixed-oxide materials. The authors discuss, in an unbiased manner, the potentials as well as the challenges related to their use, thus offering new perspectives for research and development on both an academic and industrial level. The first volume begins by summarizing the different synthesis routes from molten salts at high temperatures to colloidal crystal template methods, before going on to focus on the physical properties of the resulting materials and their related applications in the fields of electronics, energy harvesting, and storage as well as electromechanics and superconductivity. The second volume is dedicated to the catalytic applications of perovskites and related mixed oxides, including, but not limited to total oxidation of hydrocarbons, dry reforming of methane and denitrogenation. The concluding section deals with the development of chemical reactors and novel perovskite-based applications, such as fuel cells and high-performance ceramic membranes. Throughout, the contributions clearly point out the intimate links between structure, properties and applications of these materials, making this an invaluable tool for materials scientists and for catalytic and physical chemists.

Industrial Arene Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527827986
Total Pages : 2751 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Industrial Arene Chemistry by : Jacques Mortier

Download or read book Industrial Arene Chemistry written by Jacques Mortier and published by John Wiley & Sons. This book was released on 2023-03-17 with total page 2751 pages. Available in PDF, EPUB and Kindle. Book excerpt: Industrial Arene Chemistry Explore the wide array of uses for aromatic hydrocarbons in this comprehensive reference Aromatics are a class of compounds—normally but not exclusively organic—which tend to be produced as by-products of various industrial processes. Their importance as petrochemical materials in themselves, along with the range of inter-relations between different aromatic chemicals, creates a complex and opportunity-filled market for aromatics. Industrial Arene Chemistry provides a thorough look at the conventional techniques required to use and produce these aromatic hydrocarbons. Beginning with an overview of the global aromatic market—including, but not limited to, manufacturers, markets of BTX, and downstream functional aromatics, aromatics derived from renewable sources, and economic forecasts—the book will also explore the impact shifting environmental factors will have on the future of aromatic chemistry. The text further explores BTX production processes differentiated according to the raw materials used. Importantly, this will establish the importance and growth of the biobased chemical industry. Industrial Arene Chemistry readers will also find: Case studies that describe major elements of specific technologies prototyped by contributors/companies as part of ongoing market development efforts Process chapters that include summaries of the conventional techniques and a more detailed discussion of recent high-impact studies Recent advances in conventional aromatic reactions, including alkylation, acylation and carboxylation, hydrogenation/reduction, oxidation, nitration/amination, sulfonation, and halogenation Industrial Arene Chemistry is a useful reference for chemists and chemical engineers who work with aromatics.

Preparation, Characterization, and Evaluation of Mg-Al Mixed Oxide Supported Nickel Catalysts for the Steam Reforming of Ethanol

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ISBN 13 :
Total Pages : 269 pages
Book Rating : 4.:/5 (827 download)

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Book Synopsis Preparation, Characterization, and Evaluation of Mg-Al Mixed Oxide Supported Nickel Catalysts for the Steam Reforming of Ethanol by : Luke James Ivor Coleman

Download or read book Preparation, Characterization, and Evaluation of Mg-Al Mixed Oxide Supported Nickel Catalysts for the Steam Reforming of Ethanol written by Luke James Ivor Coleman and published by . This book was released on 2008 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: The conversion of ethanol to hydrogen or syngas can be achieved by reacting ethanol with water via steam reforming, CH3CH2OH + (1-x)H2O = (4-x)H2 + (2-x)CO + xCO2 (R.1) CH3CH2OH + H2O = 4H2 + 2CO (R.2) CO + H2O = H2 + CO2 (R.3) Ideally, the ethanol steam reforming reaction can achieve a hydrogen yield of 6 moles of hydrogen per mole of ethanol when the value of x in (R.1) equals 2. High theoretical H2 yield makes ethanol steam reforming a very attractive route for H2 production. Thermodynamic equilibrium studies have shown that ethanol steam reforming produces mixtures of H2, CO, CO2, and CH4 below 950 K, while above 950 K the ethanol steam reforming reaction (R.1) adequately describes the product composition In this study a series of 10wt% Ni loaded Mg-Al mixed oxide supported catalysts were evaluated for the production of hydrogen via the steam reforming of ethanol.

Research Anthology on Synthesis, Characterization, and Applications of Nanomaterials

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Publisher : IGI Global
ISBN 13 : 1799887367
Total Pages : 1917 pages
Book Rating : 4.7/5 (998 download)

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Book Synopsis Research Anthology on Synthesis, Characterization, and Applications of Nanomaterials by : Management Association, Information Resources

Download or read book Research Anthology on Synthesis, Characterization, and Applications of Nanomaterials written by Management Association, Information Resources and published by IGI Global. This book was released on 2021-03-19 with total page 1917 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of nanotechnologies continues to grow, as nanomaterials have proven their versatility and use in many different fields and industries within the scientific profession. Using nanotechnology, materials can be made lighter, more durable, more reactive, and more efficient leading nanoscale materials to enhance many everyday products and processes. With many different sizes, shapes, and internal structures, the applications are endless. These uses range from pharmaceutics to materials such as cement or cloth, electronics, environmental sustainability, and more. Therefore, there has been a recent surge of research focused on the synthesis and characterizations of these nanomaterials to better understand how they can be used, their applications, and the many different types. The Research Anthology on Synthesis, Characterization, and Applications of Nanomaterials seeks to address not only how nanomaterials are created, used, or characterized, but also to apply this knowledge to the multidimensional industries, fields, and applications of nanomaterials and nanoscience. This includes topics such as both natural and manmade nanomaterials; the size, shape, reactivity, and other essential characteristics of nanomaterials; challenges and potential effects of using nanomaterials; and the advantages of nanomaterials with multidisciplinary uses. This book is ideally designed for researchers, engineers, practitioners, industrialists, educators, strategists, policymakers, scientists, and students working in fields that include materials engineering, engineering science, nanotechnology, biotechnology, microbiology, drug design and delivery, medicine, and more.

Advanced Solid Catalysts for Renewable Energy Production

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Publisher : IGI Global
ISBN 13 : 1522539042
Total Pages : 545 pages
Book Rating : 4.5/5 (225 download)

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Book Synopsis Advanced Solid Catalysts for Renewable Energy Production by : González-Cortés, Sergio

Download or read book Advanced Solid Catalysts for Renewable Energy Production written by González-Cortés, Sergio and published by IGI Global. This book was released on 2018-01-19 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years, the replacement of non-renewable crude oil by renewable sources has been addressed, particularly in developed countries. Its main driving force has been the increasing demand and limited reserves of fossil fuels, the greenhouse gas effect, and the need of securing energy supplies. Advanced Solid Catalysts for Renewable Energy Production provides emerging research on renewable energy production, catalysts, and environmental effects of increased productivity. While highlighting the challenges for future generations to develop in the sustainable energy age, readers will learn the importance of new approaches not only for synthesizing more active and selective (nano)catalysts, but also, for designing innovative catalytic processes that can eventually meet the growing energy efficiency demand and overcome the environmental issues. This book is an important resource for academicians, university researchers, technology developers, and graduate level students.

Handbook of Solid State Chemistry, 6 Volume Set

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Publisher : John Wiley & Sons
ISBN 13 : 3527325875
Total Pages : 3912 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Handbook of Solid State Chemistry, 6 Volume Set by : Richard Dronskowski

Download or read book Handbook of Solid State Chemistry, 6 Volume Set written by Richard Dronskowski and published by John Wiley & Sons. This book was released on 2017-10-23 with total page 3912 pages. Available in PDF, EPUB and Kindle. Book excerpt: This most comprehensive and unrivaled compendium in the field provides an up-to-date account of the chemistry of solids, nanoparticles and hybrid materials. Following a valuable introductory chapter reviewing important synthesis techniques, the handbook presents a series of contributions by about 150 international leading experts -- the "Who's Who" of solid state science. Clearly structured, in six volumes it collates the knowledge available on solid state chemistry, starting from the synthesis, and modern methods of structure determination. Understanding and measuring the physical properties of bulk solids and the theoretical basis of modern computational treatments of solids are given ample space, as are such modern trends as nanoparticles, surface properties and heterogeneous catalysis. Emphasis is placed throughout not only on the design and structure of solids but also on practical applications of these novel materials in real chemical situations.

Carbon Dioxide Utilization for Global Sustainability

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Publisher : Elsevier
ISBN 13 : 0080472176
Total Pages : 626 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Carbon Dioxide Utilization for Global Sustainability by : Sang-Eon Park

Download or read book Carbon Dioxide Utilization for Global Sustainability written by Sang-Eon Park and published by Elsevier. This book was released on 2004-10-27 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt: Addressing global environmental problems, such as global warming is essential to global sustainability. Continued research leads to advancement in standard methods and produces new data. Carbon Dioxide Utilization for Global Sustainability: Proceedings of the 7th ICCDU (International Conference on Carbon Dioxide Utilization) reflects the most recent research results, as well as stimulating scientific discussions with new challenges in advancing the development of carbon dioxide utilization. Drawing on a wealth of information, this well structured book will benefit students, researchers and consultants looking to catch up on current developments in environmental and chemical engineering. * Provides comprehensive data on CO2 utilisation* Contains up-to-date information, including recent research trends* Is written for students, researchers and consultants in environmental and chemical engineering

Advanced Nanomaterials for Catalysis and Energy

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Publisher : Elsevier
ISBN 13 : 012814808X
Total Pages : 590 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Advanced Nanomaterials for Catalysis and Energy by : Vladislav A. Sadykov

Download or read book Advanced Nanomaterials for Catalysis and Energy written by Vladislav A. Sadykov and published by Elsevier. This book was released on 2018-08-27 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Nanomaterials for Catalysis and Energy: Synthesis, Characterization and Applications outlines new approaches to the synthesis of nanomaterials (synthesis in flow conditions, laser electrodispersion of single metals or alloys on carbon or oxide supports, mechanochemistry, sol-gel routes, etc.) to provide systems with a narrow particle size distribution, controlled metal-support interaction and nanocomposites with uniform spatial distribution of domains of different phases, even in dense sintered materials. Methods for characterization of real structure and surface properties of nanomaterials are discussed, including synchrotron radiation diffraction and X-ray photoelectron spectroscopy studies, neutronography, transmission/scanning electron microscopy with elemental analysis, and more. The book covers the effect of nanosystems' composition, bulk and surface properties, metal-support interaction, particle size and morphology, deposition density, etc. on their functional properties (transport features, catalytic activity and reaction mechanism). Finally, it includes examples of various developed nanostructured solid electrolytes and mixed ionic-electronic conductors as materials in solid oxide fuel cells and asymmetric supported membranes for oxygen and hydrogen separation. Outlines synthetic and characterization methods for nanocatalysts Relates nanocatalysts' properties to their specific applications Proposes optimization methods aiming at specific applications

Hydrogen Production Through Sorption-enhanced Steam Reforming of Ethanol Using CaO-based Sorbent Mixed with Iron Oxide Catalyst

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis Hydrogen Production Through Sorption-enhanced Steam Reforming of Ethanol Using CaO-based Sorbent Mixed with Iron Oxide Catalyst by : Hind Omer Elsheikh Elfaki

Download or read book Hydrogen Production Through Sorption-enhanced Steam Reforming of Ethanol Using CaO-based Sorbent Mixed with Iron Oxide Catalyst written by Hind Omer Elsheikh Elfaki and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Superior Performance of Ni-W-Ce Mixed-metal Oxide Catalysts for Ethanol Steam Reforming

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Publisher :
ISBN 13 :
Total Pages : 10 pages
Book Rating : 4.:/5 (94 download)

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Book Synopsis Superior Performance of Ni-W-Ce Mixed-metal Oxide Catalysts for Ethanol Steam Reforming by :

Download or read book Superior Performance of Ni-W-Ce Mixed-metal Oxide Catalysts for Ethanol Steam Reforming written by and published by . This book was released on 2014 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this study, the ethanol steam reforming (ESR) reaction was examined over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO2 lattice, with the remaining Ni forming highly dispersed nano NiO (