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Speciation And Mobility Of Antimony And Arsenic In Mine Waste And The Aqueous Environment In The Region Of The Giant Mine Yellowknife Canada
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Book Synopsis Speciation and Mobility of Antimony and Arsenic in Mine Waste and the Aqueous Environment in the Region of the Giant Mine, Yellowknife, Canada by :
Download or read book Speciation and Mobility of Antimony and Arsenic in Mine Waste and the Aqueous Environment in the Region of the Giant Mine, Yellowknife, Canada written by and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Metabolism of Arsenite by : Joanne M. Santini
Download or read book The Metabolism of Arsenite written by Joanne M. Santini and published by CRC Press. This book was released on 2018-10-03 with total page 203 pages. Available in PDF, EPUB and Kindle. Book excerpt: Up to 200 million people in 70 countries are at risk from drinking water contaminated with arsenic, which is a major cause of chronic debilitating illnesses and fatal cancers. Until recently little was known about the mobility of arsenic, and how redox transformations determined its movement into or out of water supplies. Although human activities contribute to the release of arsenic from minerals, it is now clear that bacteria are responsible for most of the redox transformation of arsenic in the environment. Bacterial oxidation of arsenite (to the less mobile arsenate) has been known since 1918, but it was not until 2000 that a bacterium was shown to gain energy from this process. Since then a wide range of arsenite-oxidizing bacteria have been isolated, including aerobes and anaerobes; heterotrophs and autotrophs; thermophiles, mesophiles and psychrophiles. This book reviews recent advances in the study of such bacteria. After a section on background—geology and health issues—the main body of the book concerns the cellular machinery of arsenite oxidation. It concludes by examining possible applications. Topics treated are: The geology and cycling of arsenic Arsenic and disease Arsenite oxidation: physiology, enzymes, genes, and gene regulation. Community genomics and functioning, and the evolution of arsenite oxidation Microbial arsenite oxidation in bioremediation Biosensors for arsenic in drinking water and industrial effluents
Download or read book Arsenic written by Robert Bowell and published by Walter de Gruyter GmbH & Co KG. This book was released on 2014-11-21 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental Mineralogy and Bio-Geochemistry of Arsenic provides a comprehensive understanding of arsenic geochemistry in the near-surface environment. Topics covered include the mineralogy, thermodynamics, geochemistry, analysis, microbiology, and bioavailability of arsenic, with emphasis on implications for arsenic toxicity, geochemistry in natural ground waters, and mine-associated impacts and possible mitigation options. This volume is useful for those seeking to understand arsenic geochemistry and biological interactions in the near-surface environment, Clay Minerals does not use an online manuscript tracking/submission system. as well those working for mining companies, the chemicals industry, NGO’s or government bodies concerned with reducing the impact of arsenic on the environment.
Book Synopsis Mobility and Chemical Fate of Antimony and Arsenic in Historic Mining Environments of Kantishna Hills, Denali National Park and Preserve, Alaska by : Vanessa J. Ritchie
Download or read book Mobility and Chemical Fate of Antimony and Arsenic in Historic Mining Environments of Kantishna Hills, Denali National Park and Preserve, Alaska written by Vanessa J. Ritchie and published by . This book was released on 2011 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidative weathering processes of acid-forming sulfide minerals, such as pyrite (FeS2), and associated arsenopyrite (FeAsS) and stibnite (Sb2S3), can have a significant impact on water quality associated with current and legacy mining operations. Concentrations of toxic metals and metalloids, such as antimony (Sb) and arsenic (As), in acid mine drainage can exceed drinking water quality standards by orders of magnitude. This study provides a detailed hydrogeochemical assessment of the mobility and chemical fate of antimony and arsenic in streams draining from historic antimony mines within Denali National Park and Preserve, Alaska. Antimony and arsenic concentrations in stream water reach up to 720 parts per billion (ppb) and 239 ppb, respectively. Aqueous phase antimony and arsenic speciation was determined using liquid chromatography coupled to an inductively coupled plasma mass spectrometer. Antimony in all water samples is predominantly found as Sb5+ whereas arsenic was detected as mixtures of As3+ /As5+ . Elevated antimony concentrations extend over 8 km downstream from the source, whereas arsenic quickly attenuates within 1.5 km. High correlation between antimony/arsenic and iron concentrations in fine-fraction streambed sediment indicates that sorption and (co)precipitation with iron (hydr)oxides is an important pathway for the attenuation of antimony and arsenic in natural waters.
Book Synopsis The Influence of Bacteria on the Stability, Speciation and Mobility of Arsenic in Contaminated Sediments at Terra Mine, N.W.T., Canada by : Jessica Ann Drysdale
Download or read book The Influence of Bacteria on the Stability, Speciation and Mobility of Arsenic in Contaminated Sediments at Terra Mine, N.W.T., Canada written by Jessica Ann Drysdale and published by . This book was released on 2011 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: Terra mine is an abandoned copper and silver mine in the Northwest Territories, Canada, from which mine tailings were deposited into Ho-Hum Lake, adjacent to the mine's processing plant. The tailings contain elevated levels of arsenic (As), resulting in As levels exceeding Canadian sediment and water quality guidelines in the lake, and in downstream wetland water and sediment. This field and laboratory study focuses on the microbial ecology, and the reduction and oxidation of As, iron (Fe) and sulphur (S), in the wetland downstream from Ho-Hum Lake. This wetland is proposed as a passive remediation system for removal and storage of As. Using microcosm experiments, the stability of As-bearing sediments was compared in the upper, middle and lowestmost areas of the wetland over a 42-day period. Fresh sediments and sediments amended with a 10 mM acetate solution, both mixed with water, were compared. While no significant geochemical differences were found between acetate-amended and unamended microcosms, formation of inorganic As-S species was higher in amended microcosms, suggesting that micro-organisms were more active in the system because they were not carbon-limited. Formation of methylated-As species increased over time in all samples, including abiotic controls. Bacterial sulphate reduction occurred during the first 10 days of the experiment, perhaps resulting in precipitation of sulphide minerals. X-ray adsorption near edge spectroscopy was used to assess solid-state speciation of As in the sediments and indicated that pre-microcosm sediments from all sites showed high proportions of As(III)-S and As(III)-O speciation. Post-microcosm sediments revealed a 13% increase in the proportion of As(V)-O species, whereas abiotic controls showed only an 8% increase. DNA sequencing in post-microcosm sediments identified As, Fe and S reducing bacteria, and the geochemical patterns of As, Fe and S in the microcosms indicate the bacteria are likely active in the system. Microbial diversity and solid-state speciation of As in the sediments were assessed at varying depths at the microcosm sites, but correlation analysis revealed no significant relationship between As speciation and microbial diversity. A positive correlation between diversity and depth, and a negative relationship between As concentration and diversity, were found, perhaps indicating decreasing contamination with depth in the wetland.
Book Synopsis Patterns of Arsenic Speciation and Associated Potentially Toxic Elements at Sites Impacted by Mining and Mine Waste by : Keith William Torrance
Download or read book Patterns of Arsenic Speciation and Associated Potentially Toxic Elements at Sites Impacted by Mining and Mine Waste written by Keith William Torrance and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ability to find, mine, extract and smelt metallic ores has been central to technological development throughout history. Demand for metals is projected to increase in the coming decades and the supply of metals such as lithium, copper, indium, neodymium and tantalum have become strategically important in the manufacture of energy-efficient 'green' products and renewable energy generators. However, mining is accompanied by an environmental cost; mining accounts for almost 34% of total worldwide solid waste generated. Historically poor disposal practices in the industry have created a legacy of tailings piles, polluted rivers and health impacts that have the potential to impact surface water quality for centuries after the cessation of mining, primarily through the continued interaction of meteoric and groundwater with mine waste and mill tailings dumped on-site. Arsenic is a toxic metalloid that is commonly present in trace to minor amounts in ores of gold, mercury, lead and zinc as the mineral arsenopyrite (FeAsS) or as substitutions within other sulphide minerals. Consequently, arsenic (As), a known carcinogen, is a contaminant of concern in many mining districts and a useful indicator of water quality. Arsenic exists in natural waters as both As(III) and As(V) oxyanions, whose relative abundance is controlled by pH and redox conditions. The toxicity and mobility of dissolved As in water draining mine tailings is directly related to the inorganic arsenic species present. However, at many sites arsenic contamination of surface water is accompanied by other toxic metals, which are released with arsenic from the weathering and dissolution of sulphide minerals. To investigate the effect of other metal species, on arsenic speciation, field measurements of As(III) /As(V) ratios in surface water were made at selected historical mining sites with elevated levels of dissolved arsenic and of one or more toxic metals. Data are presented from nine contaminated mine sites in Scotland, Alaska and Colombia, representing different types of ore deposits and ore processing sites that have elevated As signatures. At these sites, antimony, mercury or cadmium is present as a secondary contaminant in surface water at levels near or above the USEPA MCL. In addition to arsenic species separation, major and trace elements, vii anions and stable isotopes were determined at each sample point, along with a full suite of in-situ water parameters. Local site variables, including bedrock geology, ore mineralogy, groundwater geochemistry and soil chemistry, contribute to the complexity of As speciation at each study location. It was determined that As(III) is the dominant species in water draining mine adits and tailing piles, instead of the more thermodynamically favoured As(V) species. As(III) is more mobile than As(V) and persists up to 300 metres downstream, before transformation to the more oxidised form. Better understanding of As mobility has the potential to improve remediation strategies at other contaminated mine sites.
Book Synopsis Arsenic in Ground Water by : Alan H. Welch
Download or read book Arsenic in Ground Water written by Alan H. Welch and published by Springer Science & Business Media. This book was released on 2003 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book consolidates much of what is known about the geochemistry of arsenic and provides new information on relationships between high concentrations of arsenic in ground water and geochemical environments. The subject matter of this book ranges in scope from molecular-scale geochemical processes that affect the mobility of arsenic in ground water, to arsenic contaminated ground water at the national scale. Chapters were contributed by an international group of research scientists from a broad range of backgrounds.
Book Synopsis Communicating Danger by : John Kurt Sandlos
Download or read book Communicating Danger written by John Kurt Sandlos and published by . This book was released on 2014 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The Giant Mine Remediation Plan proposes to freeze 237,000 tons of toxic arsenic trioxide dust where it is currently stored underground. It is likely that water pumping, monitoring, and maintenance at the site will be necessary for a very long time to prevent the arsenic from seeping into the local environment. The recent environmental assessment of the project requires ongoing research into a permanent solution to the arsenic problem at Giant Mine within a 100 year time frame. Despite this, a century is a very long time (people have forgotten about toxic sites over shorter periods), and there is no guarantee that technology can be developed to safely remove all arsenic from the site. A system to communicate with future generations about the arsenic hazards will reduce the risk people will forget about the site. ... At Giant Mine, a messaging system might involve simple warning signs and text messages imploring people not to damage the thermosyphons, with more detailed technical information on how to replace this equipment when necessary and maintain other facilities such as the water treatment plant. Unlike nuclear waste, it is possible that the arsenic threat might be removed within a relative short period of time (a matter of decades rather than the centuries it takes for nuclear waste to decay), so the emphasis might be on 'relaying' information on how to maintain the site to people roughly a century from now"--
Book Synopsis Arsenic in Ground Water of the Willamette Basin, Oregon by : Stephen R. Hinkle
Download or read book Arsenic in Ground Water of the Willamette Basin, Oregon written by Stephen R. Hinkle and published by . This book was released on 1999 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Arsenic speciation and mobility in mine wastes from a copper-arsenic mine in Devon, UK by : B. Palumbo-Roe
Download or read book Arsenic speciation and mobility in mine wastes from a copper-arsenic mine in Devon, UK written by B. Palumbo-Roe and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Impacts of Legacy Mining Operation on Inorganic Arsenic Bioaccumulation and Exposure in Yellowknife, Northwest Territories, Canada by : Claudia Tanamal
Download or read book The Impacts of Legacy Mining Operation on Inorganic Arsenic Bioaccumulation and Exposure in Yellowknife, Northwest Territories, Canada written by Claudia Tanamal and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Arsenic transfers and toxicology are important topics of research and a public health concern because arsenicosis affects millions of people worldwide every year. One of the most significant sources of arsenic in the environment is industrial wastes, such as by-products of mining operation. In Yellowknife, Northwest Territories, Canada, there were two large gold mines-Giant Mine and Con Mine, along with dozens of small-scale mines. The combined by-product of emission from these roasters might have contributed to high concentrations of arsenic found in the city. This thesis presents the results of two related studies to address the environmental health concern: (1) to investigate the arsenic transfers and arsenic species accumulation in freshwater food webs near large legacy mining operations in Yellowknife, and (2) to assess the long-term health risk of inorganic arsenic exposure from the consumption of fish in Yellowknife among the general residents and the Yellowknives Dene First Nation. We found that inorganic arsenic is biominified in food webs (i.e. inorganic arsenic concentrations diminish at higher trophic positions relative to lower trophic positions). Higher-trophic organisms have low inorganic arsenic concentrations in tissue due to biotransformation of inorganic arsenic to non-toxic organic arsenobetaine, and effective elimination of arsenic from their tissue. The trophic positions of freshwater organisms can be used to predict the range of arsenic concentrations and its species composition, accounting for more than 80% of variance. Dietary study results show that the Yellowknives Dene First Nation consumed significantly more fish in their diets (adults: 19 g/day, children: 9 g/day) compared to the general residents of Yellowknife (adults: 9 g/day, children: 5 g/day). Our probabilistic risk assessments showed no significant long-term non-carcinogenic and carcinogenic health risks of inorganic arsenic exposure from fish consumption for the majority of Yellowknife residents, but elevated cancer risks among the adult heavy fish consumers in Yellowknife. However, our data suggested that the residents of Yellowknife were not exposed to higher cancer risks from inorganic exposure compared to the general population in Canada. Therefore, due to fish health benefits and the values associated with its consumption, fish should continue to be a major source of sustenance in Yellowknife.
Book Synopsis Control of Arsenic Level in Gold Mine Waste Waters by : L. M. de Smecht
Download or read book Control of Arsenic Level in Gold Mine Waste Waters written by L. M. de Smecht and published by . This book was released on 1975 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt: Study of its chemistry of arsenic, the removal from waste waters using the Giant Yellowknife Mines as a case study, and the leaching of arsenic-bearing minerals.
Book Synopsis Polar Lakes and Rivers by : Warwick F. Vincent
Download or read book Polar Lakes and Rivers written by Warwick F. Vincent and published by Oxford University Press. This book was released on 2008-09-11 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an overview of the ecology of high latitude lakes, rivers and glacial environments in both the North and South polar regions. It describes each ecosystem type, the remarkable aquatic life that thrives in these extreme habitats, and the similarities and differences between Arctic and Antarctic waters.
Book Synopsis Heavy Metals in Soils by : B. J. Alloway
Download or read book Heavy Metals in Soils written by B. J. Alloway and published by Springer Science & Business Media. This book was released on 1995 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heavy metals in soils continue to receive increasing attention due to the growing scientific and public awareness of environmental issues and the development of analytical techniques to measure their concentrations accurately. Building on the success and acclaim of the first edition, this book continues to provide an up-to-date, balanced and comprehensive review of the subject in two sections: the first providing an introduction to the metals chemistry, sources and methods used for their analysis; and the second containing chapters dealing with individual elements in detail.
Book Synopsis Distinguishing Between Natural and Anthropogenic Sources of Arsenic in Soils from the Giant Mine, Northwest Territories and the North Brookfield Mine, Nova Scotia by :
Download or read book Distinguishing Between Natural and Anthropogenic Sources of Arsenic in Soils from the Giant Mine, Northwest Territories and the North Brookfield Mine, Nova Scotia written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Anthropogenic and geogenic sources of arsenic (As) have been identified in mining-impacted soils from the Giant mine (1948-1999), NT and the North Brookfield mine (1886-1906), NS. Both used roasting to extract gold from the arsenopyrite ore, decomposing it to As-bearing iron oxides (roaster oxides or RO) containing As, and releasing As3+-bearing arsenic trioxide (As2O3). Arsenic trioxide is considered highly soluble with the dissolved As3+ species being more mobile and toxic than other oxidation states. Soil profiles from the Giant mine show elevated As and antimony (Sb) at the surface (As=140-3300ppm) and decreasing concentrations with depth (As=22-600ppm). Surface soils contain anthropogenically-derived As2O3 identified using synchrotron methods (æXRD, æXANES) and environmental SEM. The persistence of As2O3 is attributed to Sb in As2O3 grains, dry climate and high organics in the soils. Anthropogenically-derived RO of maghemite (containing both As3+ and As5+) and natural arsenopyrite were observed. Sequential selective extractions (SSE) from surface soils show between 20% and 75% of As extracted in the crystalline iron-oxide phase is attributed to As2O3 and RO, while at depth As is bound by organics in the weaker leaches. North Brookfield mine soils show lower total As (2ppm to 45ppm) except near the roaster (4300ppm). No As2O3 was identified, probably due to the smaller scale and age of the mine, lower organic content and the lack of Sb. As-bearing phases include RO of hematite (As5+), As-rich rims on titanium-oxides, and As associated with clays and goethite. Adjacent to the roaster, SSE show As was also in the amorphous iron-oxide phase, also shown by As in arsenopyrite weathering rims. There are many differences between the North Brookfield and Giant mine soils including roasting techniques which produced different RO mineralogy, the scale of mining, climate, soil type, and the presence of As2O3. Currently, the Giant property is not publically accessible but m.
Book Synopsis Environmental Arsenic in a Changing World by : Yongguan Zhu
Download or read book Environmental Arsenic in a Changing World written by Yongguan Zhu and published by CRC Press. This book was released on 2019-08-23 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Congress "Arsenic in the Environment" offers an international, multi- and interdisciplinary discussion platform for research and innovation aimed towards a holistic solution to the problem posed by the environmental toxin arsenic, with significant societal impact. The Congress has focused on cutting edge and breakthrough research in physical, chemical, toxicological, medical, agricultural and other specific issues on arsenic across a broader environmental realm. The Biennial Congress "Arsenic in the Environment" was first organized in Mexico City (As2006) followed by As2008 in Valencia (Spain), As2010 in Tainan (Chinese Taiwan), As2012 in Cairns (Australia), As2014 in Buenos Aires (Argentina) and As2016 in Stockholm (Sweden). The 7th International Congress As2018 was held July 1-6, 2018, in Beijing, P. R. China and was entitled Environmental Arsenic in a Changing World. The Congress addressed the broader context of arsenic research aligned on the following themes: Theme 1: Arsenic Behaviour in Changing Environmental Media Theme 2: Arsenic in a Changing Agricultural Ecosystem Theme 3: Health Impacts of Environmental Arsenic Theme 4: Technologies for Arsenic Immobilization and Clean Water Blueprints Theme 5: Sustainable Mitigation and Management Arsenic in drinking water (mainly groundwater) has emerged as an issue of global health concern. During last decade, the presence of arsenic in rice, possibly also other food of plant origins, has attained increasing attention. This is particularly true in the Asian countries, where the use of high arsenic groundwater as source of irrigation water and drinking water has been flagged as severe health concern. This has been accentuated by elevating arsenic concentrations in deep groundwater recharged from shallow high arsenic groundwater, which may have further detrimental effects on public health. Notably, China has been in the forefront of research on arsenic biogeochemical cycling, health effects of arsenic, technologies for arsenic removal, and sustainable mitigation measures. The Congress has attracted professionals involved in different segments of interdisciplinary research on arsenic in an open forum, and strengthened relations between academia, research institutions, government and non-governmental agencies, industries, and civil society organizations to share an optimal ambience for exchange of knowledge.
Book Synopsis Chemical Speciation of Arsenic and Antimony in Natural Water Systems and Its Applications to Environmental Problems by : Wai Man Mok
Download or read book Chemical Speciation of Arsenic and Antimony in Natural Water Systems and Its Applications to Environmental Problems written by Wai Man Mok and published by . This book was released on 1988 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: