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Solute Solute Interactions In Non Aqueous Solvents
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Book Synopsis Highlights in Solute-Solvent Interactions by : Wolfgang Linert
Download or read book Highlights in Solute-Solvent Interactions written by Wolfgang Linert and published by Springer Science & Business Media. This book was released on 2001-12-11 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance.
Book Synopsis The Chemistry of Nonaqueous Solvents VA by : J.J. Lagowski
Download or read book The Chemistry of Nonaqueous Solvents VA written by J.J. Lagowski and published by Elsevier. This book was released on 2012-12-02 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Nonaqueous Solvents, Volume V-A: Principles and Basic Solvents provides the theoretical aspects of nonaqueous solution chemistry independent of solvent and information on individual solvent systems. This volume contains chapters on solvation and complex formation in protic and aprotic solvents; solvent basicity; ion-selective electrodes in nonaqueous solvents; nonaqueous solvents in organic electroanalytical chemistry; and anhydrous hydrazine and water-hydrazine mixtures. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.
Book Synopsis Chemistry in Aqueous and Non-aqueous Solvents by : Y. Mido
Download or read book Chemistry in Aqueous and Non-aqueous Solvents written by Y. Mido and published by Discovery Publishing House. This book was released on 2001 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Aqueous Solution Chemistry, Acids and Bases, Solute-Solvent Interactions, Chemistry in Protonic Solvents Liquid Ammonia, Liquid Hydrogen, Fluoride, Sulphuric, Acid, Liquid, Hydrogen, Cyanide, Acetic Acid and Liquid Hydrogen Sulphide, Non- Protonic Solvents Liquid Dinitrogen Tetroxide, Liquid Sulphur, Dioxide and Liquid Halides.
Book Synopsis Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents by : K. Burger
Download or read book Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents written by K. Burger and published by Elsevier. This book was released on 2012-12-02 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.
Book Synopsis Modern Physical Organic Chemistry by : Eric V. Anslyn
Download or read book Modern Physical Organic Chemistry written by Eric V. Anslyn and published by University Science Books. This book was released on 2006 with total page 1148 pages. Available in PDF, EPUB and Kindle. Book excerpt: In additionto covering thoroughly the core areas of physical organic chemistry -structure and mechanism - this book will escortthe practitioner of organic chemistry into a field that has been thoroughlyupdated.
Book Synopsis Lecture Notes on Solution Chemistry by : Viktor Gutmann
Download or read book Lecture Notes on Solution Chemistry written by Viktor Gutmann and published by World Scientific. This book was released on 1995 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book emphasises those features in solution chemistry which are difficult to measure, but essential for the understanding of both the qualitative and the quantitative aspects. Attention is paid to the mutual influences between solute and solvent, even at extremely small concentrations of the former. The described extension of the molecular concept leads to a broad view ? not by a change in paradigm ? but by finding the rules for the organizations both at the molecular and the supermolecular level of liquid and solid solutions.
Book Synopsis Fourth International Conference on Non-Aqueous Solutions by : V. Gutmann
Download or read book Fourth International Conference on Non-Aqueous Solutions written by V. Gutmann and published by Elsevier. This book was released on 2013-10-22 with total page 127 pages. Available in PDF, EPUB and Kindle. Book excerpt: Non-Aqueous Solutions is a collection of papers presented at the Fourth International Conference on the same subject. One paper presents the application of far- and mid-infra-red, Raman, alkali metal n.m.r. and 35C1 n.m.r. techniques to the study of electrolyte solutions in non-aqueous solvents. The paper notes that spectroscopic techniques can be very useful in the elucidation of the structure of electrolyte solutions. Both the vibrational spectroscopy and particularly the alkali metal n.m.r. are very sensitive probes of the immediate chemical environment of ions in solutions. Another paper points out that the energy change associated with the solvation of ions can be represented as the sum of two energy terms; firstly, from the dielectric polarization of the solvent molecules in the continuous dielectric medium; and secondly, due to specific ion-solvent interactions in the inner solvation shells of the ions. The energy contribution of the latter is minimal but can show comparatively large differences in various types of solvents. Another paper describes the chemistry of solutions in highly associated strong protonic acid solvents, including sulphuric acid, oleums, fluorosulfuric acid, and hydrogen fluoride. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the collection truly beneficial.
Book Synopsis The Chemistry of Nonaqueous Solvents III by : J.J. Lagowski
Download or read book The Chemistry of Nonaqueous Solvents III written by J.J. Lagowski and published by Elsevier. This book was released on 2012-12-02 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Nonaqueous Solvents, Volume III: Inert, Aprotic, and Acidic Solvents is a compilation of critical surveys of specific solvent systems. The compendium contains discussions on the solution chemistry of sulfur dioxide and acyl halides; the solvent properties of hydrogen sulfide and carboxylic acids; and the Bronsted acid-base behavior in inert organic solvents. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.
Book Synopsis Non-Aqueous Solvents in Inorganic Chemistry by : A. K. Holliday
Download or read book Non-Aqueous Solvents in Inorganic Chemistry written by A. K. Holliday and published by Elsevier. This book was released on 2013-10-22 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: Non-Aqueous Solvents in Inorganic Chemistry gives a concise treatment of the important inorganic non-aqueous solvents, emphasizing why they do in fact exhibit solvent power, how they are prepared and handled experimentally, how they can be used as media for the synthesis or analysis of inorganic and organometallic compounds, and how far the various acid-base concepts can be useful in accounting for many (but not all) of the reactions observed. This book is intended primarily for the undergraduate reader—both for the intending Chemistry Honours or R.I.C. graduate and the non-specialist student of chemistry. The subject matter is presented in a simple and readable form, without the inclusion of elaborate tables of properties and with the minimum of detail necessary for comprehension. Therefore, those working for the A- and S-level chemistry examinations for the G.C.E. could read much of the book with profit; and the research student who aspires to work in the field of non-aqueous solvents will, it is hoped, find this book a useful introduction to a fascinating branch of inorganic chemistry.
Book Synopsis Interfacial Aspects of Phase Transformations by : B. Mutaftschiev
Download or read book Interfacial Aspects of Phase Transformations written by B. Mutaftschiev and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 710 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Study Institute, Erice, Sicily, Italy, August 29-September 9, 1981
Book Synopsis The Chemistry of Non-aqueous Solvents: Principles and techniques by : J. J. Lagowski
Download or read book The Chemistry of Non-aqueous Solvents: Principles and techniques written by J. J. Lagowski and published by . This book was released on 1966 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Chemistry of Non-aqueous Solvents by : J. J. Lagowski
Download or read book The Chemistry of Non-aqueous Solvents written by J. J. Lagowski and published by . This book was released on 1978 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Solute-solvent Interactions by : Johannes Francois Coetzee
Download or read book Solute-solvent Interactions written by Johannes Francois Coetzee and published by . This book was released on 1969 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Hydrophobic Interactions by : Arieh Y. Ben-Naim
Download or read book Hydrophobic Interactions written by Arieh Y. Ben-Naim and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: My personal involvement with the problem of hydrophobic interactions (HI) began about ten years ago. At that time I was asked to write a review article on the properties of aqueous solutions of nonpolar solutes. While surveying the literature on this subject I found numerous discussions of the concept of HI. My interest in these interactions increased especially after reading the now classical review of W. Kauzmann (1959), in which the importance of the HI to biochemical processes is stressed. Yet, in spite of having read quite extensively on the various aspects of the subject, I acquired only a very vague idea of what people actually had in mind when referring to HI. In fact, it became quite clear that the term HI was applied by different authors to describe and interpret quite different phenomena occurring in aqueous solutions. Thus, even the most fundamental question of the very definition of the concept of HI remained unanswered. But other questions followed, e. g. : Are HI really a well established experimental fact? Is there any relation between HI and the peculiar properties of water? Is the phenomenon really unique to aqueous solutions? Finally, perhaps the most crucial question I sought to answer was whether or not there exists hard evidence that HI are really important -as often claimed-in biological processes.
Book Synopsis Handbook of Raman Spectroscopy by : Ian R. Lewis
Download or read book Handbook of Raman Spectroscopy written by Ian R. Lewis and published by CRC Press. This book was released on 2001-08-08 with total page 1076 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work covers principles of Raman theory, analysis, instrumentation, and measurement, specifying up-to-the-minute benefits of Raman spectroscopy in a variety of industrial and academic fields, and how to cultivate growth in new disciplines. It contains case studies that illustrate current techniques in data extraction and analysis, as well as over 500 drawings and photographs that clarify and reinforce critical text material. The authors discuss Raman spectra of gases; Raman spectroscopy applied to crystals, applications to gemology, in vivo Raman spectroscopy, applications in forensic science, and collectivity of vibrational modes, among many other topics.
Download or read book Water written by Felix Franks and published by Royal Society of Chemistry. This book was released on 2000 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: An understanding of the behavioural properties of water is fundamental to gaining an appreciation of many scientific processes and principles. Science students and teachers will therefore find Water not only interesting reading but also of considerable relevance to their studies.
Download or read book Food Freezing written by William B. Bald and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: Food Freezing: Today and Tomorrow represents the contributions of the invited speakers to an advanced study seminar held by the Institute for Applied Biology of the University of York during April 1990. The main objective of the seminar was to bring together food scientists and engineers to discuss their mutual problems and to seek new directions for possible solutions.
