Rheology of Drag Reducing Surfactant Systems

Download Rheology of Drag Reducing Surfactant Systems PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (622 download)

DOWNLOAD NOW!


Book Synopsis Rheology of Drag Reducing Surfactant Systems by : Katie Severson

Download or read book Rheology of Drag Reducing Surfactant Systems written by Katie Severson and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: This paper explores the rheological behavior of drag reducing surfactant systems. It concentrates on the relationships between shear viscosity, shear rate, first normal stress difference, and shear stress.

Turbulent Drag Reduction by Surfactant Additives

Download Turbulent Drag Reduction by Surfactant Additives PDF Online Free

Author :
Publisher : John Wiley & Sons
ISBN 13 : 1118181115
Total Pages : 233 pages
Book Rating : 4.1/5 (181 download)

DOWNLOAD NOW!


Book Synopsis Turbulent Drag Reduction by Surfactant Additives by : Feng-Chen Li

Download or read book Turbulent Drag Reduction by Surfactant Additives written by Feng-Chen Li and published by John Wiley & Sons. This book was released on 2012-01-10 with total page 233 pages. Available in PDF, EPUB and Kindle. Book excerpt: Turbulent drag reduction by additives has long been a hot research topic. This phenomenon is inherently associated with multifold expertise. Solutions of drag-reducing additives are usually viscoelastic fluids having complicated rheological properties. Exploring the characteristics of drag-reduced turbulent flows calls for uniquely designed experimental and numerical simulation techniques and elaborate theoretical considerations. Pertinently understanding the turbulent drag reduction mechanism necessities mastering the fundamentals of turbulence and establishing a proper relationship between turbulence and the rheological properties induced by additives. Promoting the applications of the drag reduction phenomenon requires the knowledge from different fields such as chemical engineering, mechanical engineering, municipal engineering, and so on. This book gives a thorough elucidation of the turbulence characteristics and rheological behaviors, theories, special techniques and application issues for drag-reducing flows by surfactant additives based on the state-of-the-art of scientific research results through the latest experimental studies, numerical simulations and theoretical analyses. Covers turbulent drag reduction, heat transfer reduction, complex rheology and the real-world applications of drag reduction Introduces advanced testing techniques, such as PIV, LDA, and their applications in current experiments, illustrated with multiple diagrams and equations Real-world examples of the topic’s increasingly important industrial applications enable readers to implement cost- and energy-saving measures Explains the tools before presenting the research results, to give readers coverage of the subject from both theoretical and experimental viewpoints Consolidates interdisciplinary information on turbulent drag reduction by additives Turbulent Drag Reduction by Surfactant Additives is geared for researchers, graduate students, and engineers in the fields of Fluid Mechanics, Mechanical Engineering, Turbulence, Chemical Engineering, Municipal Engineering. Researchers and practitioners involved in the fields of Flow Control, Chemistry, Computational Fluid Dynamics, Experimental Fluid Dynamics, and Rheology will also find this book to be a much-needed reference on the topic.

Characterization of Drag Reducing Surfactant Systems by Rheology and Flow Birefringence Measurements

Download Characterization of Drag Reducing Surfactant Systems by Rheology and Flow Birefringence Measurements PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 864 pages
Book Rating : 4.:/5 (376 download)

DOWNLOAD NOW!


Book Synopsis Characterization of Drag Reducing Surfactant Systems by Rheology and Flow Birefringence Measurements by : Bin Lu

Download or read book Characterization of Drag Reducing Surfactant Systems by Rheology and Flow Birefringence Measurements written by Bin Lu and published by . This book was released on 1997 with total page 864 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Studies on the Nanostructure, Rheology and Drag Reduction Characteristics of Drag Reducing Cationic Surfactant Solutions

Download Studies on the Nanostructure, Rheology and Drag Reduction Characteristics of Drag Reducing Cationic Surfactant Solutions PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 413 pages
Book Rating : 4.:/5 (496 download)

DOWNLOAD NOW!


Book Synopsis Studies on the Nanostructure, Rheology and Drag Reduction Characteristics of Drag Reducing Cationic Surfactant Solutions by : Wu Ge

Download or read book Studies on the Nanostructure, Rheology and Drag Reduction Characteristics of Drag Reducing Cationic Surfactant Solutions written by Wu Ge and published by . This book was released on 2008 with total page 413 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: At concentrations above CMC (critical micellization concentration) or temperatures above CMT (critical micellization temperature) surfactant molecules dissolved in aqueous solution self-assemble into colloidal aggregates such as micelles or vesicles. These colloidal aggregates vary in shape and size depending on a number of system conditions such as surfactant molecular structure, surfactant concentration, salt concentration, temperature, etc. Among the variety of micellar structures in solution, wormlike micelles resembling the long chain molecules of high polymers may reduce friction energy loss in turbulent flow by up to 90% at relatively low surfactant concentrations under appropriate flow and temperature conditions. This phenomenon is termed drag reduction (by surfactant additives) and it has significant potential impacts on fluid transport and on the environment. Among surfactant drag reducing additives, cationic surfactants with organic counterions have received the most attention in the past two decades mainly because of their excellent drag reducing ability, broad availability, low concentration requirements and general insensitivity to ionic metal impurities. Typical cationic surfactants studied for drag reduction are quaternary ammonium salts with one long alkyl chain (carbon number from 14 to 22) and methyl or hydroxyethyl groups in the other positions. They are, however, mildly toxic with poor biodegradability, so there is a need to develop more environmentally friendly surfactant drag reducing additives. Other types of surfactants such as anionics, zwitterionics and nonionics have also been studied. To obtain desired drag reducing properties, previous research has been focused on utilizing synergistic effects that may arise when two surfactant species are mixed. Mixed surfactant systems studied for drag reduction included cationic surfactants of mixed alkyl chain lengths, cationic/anionic, nonionic/nonionic, nonionic/anionic and zwitterionic/anionic surfactant mixtures in aqueous solutions and in water/co-solvent systems. Organic counterions added to dilute cationic surfactant aqueous solutions are effective in inducing and stabilizing wormlike micelle formation at relatively low counterion to surfactant molar ratios, thereby promoting their drag reducing effectiveness. The interactions of the cationic surfactant and organic counterion can be enhanced by tuning either or both of them, structurally and/or by concentration and molar ratio, to tailor-make highly efficient drag reducing systems suitable for different applications. Understanding the important role of organic counterions in the dynamics of the formation of cationic surfactant wormlike micelles and their networks is important. In this work, investigations have been conducted in how changes in the organic counterion chemical structure of a series of p-halobenzoates and counterion to surfactant ratio affect zeta potential, nanostructure, drag reduction and rheological properties. Also, certain mixed aromatic counterion systems were studied which showed excellent synergistic effects on promoting wormlike micellar branched networks and enhancing drag reducing effectiveness. In this work, an enclosed rotating disk apparatus was designed and constructed for screening novel surfactant species synthesized in chemistry laboratories. After correlating its drag reducing results with those obtained through the conventional pipe flow test system, this small scale apparatus is capable of testing materials for drag reduction effectiveness independently. A long range goal of this research is to develop effective low concentration surfactant systems with good drag reduction effectiveness. Guided by the correlations and understandings obtained in the past research, in this work, a number of new surfactants or counterions were selected or synthesized for exploratory drag reduction tests.

Investigation of Relationships Among Microstructure, Rheology, Drag Reduction and Heat Transfer of Drag Reducing Surfactant Solutions

Download Investigation of Relationships Among Microstructure, Rheology, Drag Reduction and Heat Transfer of Drag Reducing Surfactant Solutions PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (549 download)

DOWNLOAD NOW!


Book Synopsis Investigation of Relationships Among Microstructure, Rheology, Drag Reduction and Heat Transfer of Drag Reducing Surfactant Solutions by : Yunying Qi

Download or read book Investigation of Relationships Among Microstructure, Rheology, Drag Reduction and Heat Transfer of Drag Reducing Surfactant Solutions written by Yunying Qi and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: Drag reducing (DR) surfactant solutions can reduce pumping energy requirements in district heating and cooling (DHC) systems by 30-60%. To enhance the heat transfer ability of DR surfactant solutions, three methods were investigated. Fluted tube-in-tube heat exchangers and installing destructive devices at heat exchanger entrances were found to be very effective with moderate pressure drop penalties. The former is good for new DHC systems while the latter is ideal for existing DHC systems. Ultrasonic energy break up surfactant microstructures and enhance their heat transfer ability was effective for viscoelastic drag reducing surfactant solutions. The destructive devices and ultrasonic energy temporarily destroy the surfactant microstructure which enhances heat transfer. The microstructure recovers quickly and the solution regains its DR ability downstream of the exchanger. Unsaturated hydrocarbon chains with cis and trans configurations with different counterion/surfactant ratios influence the effective DR temperature range of cationic surfactant solutions, their shear degradation, their rheological behavior and their microstructures. Shearing effects on the microstructures of different DR surfactant solutions were studied using SANS. Surfactant microstructures aligned along the flow direction under shear. However, the critical shear rate for the initiation of alignment depends on surfactant microstructure. Differences and their relation to rheological properties and DR abilities are discussed. Shear induced structures (SIS) are accompanied by first normal stress difference (N1). Non-viscoelastic DR systems do not show SIS and N1. Threadlike micelle structures appear to be present in all DR surfactant solutions under shear, however. While some DR surfactant solutions have low extensional/shear viscosity ratios at extensional rates

Drag Reduction of Turbulent Flows by Additives

Download Drag Reduction of Turbulent Flows by Additives PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 9401712956
Total Pages : 243 pages
Book Rating : 4.4/5 (17 download)

DOWNLOAD NOW!


Book Synopsis Drag Reduction of Turbulent Flows by Additives by : A. Gyr

Download or read book Drag Reduction of Turbulent Flows by Additives written by A. Gyr and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 243 pages. Available in PDF, EPUB and Kindle. Book excerpt: Drag Reduction of Turbulent Flows by Additives is the first treatment of the subject in book form. The treatment is extremely broad, ranging from physicochemical to hydromechanical aspects. The book shows how fibres, polymer molecules or surfactants at very dilute concentrations can reduce the drag of turbulent flow, leading to energy savings. The dilute solutions are considered in terms of the physical chemistry and rheology, and the properties of turbulent flows are presented in sufficient detail to explain the various interaction mechanisms. Audience: Those active in fundamental research on turbulence and those seeking to apply the effects described. Fluid mechanical engineers, rheologists, those interested in energy saving methods, or in any other application in which the flow rate in turbulent flow should be increased.

Rheology of Drag Reducing Fluids

Download Rheology of Drag Reducing Fluids PDF Online Free

Author :
Publisher : Springer Nature
ISBN 13 : 303040045X
Total Pages : 196 pages
Book Rating : 4.0/5 (34 download)

DOWNLOAD NOW!


Book Synopsis Rheology of Drag Reducing Fluids by : Aroon Shenoy

Download or read book Rheology of Drag Reducing Fluids written by Aroon Shenoy and published by Springer Nature. This book was released on 2020-03-25 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt: ​This book explains theoretical derivations and presents expressions for fluid and convective turbulent flow of mildly elastic fluids in various internal and external flow situations involving different types of geometries, such as the smooth/rough circular pipes, annular ducts, curved tubes, vertical flat plates, and channels. Understanding the methodology of the analyses facilitates appreciation for the rationale used for deriving expressions of parameters relevant to the turbulent flow of mildly elastic fluids. This knowledge serves as a driving force for developing new ideas, investigating new situations, and extending theoretical analyses to other unexplored areas of the rheology of mildly elastic drag reducing fluids.The book suits a range of functions--it can be used to teach elective upper-level undergraduate or graduate courses for chemical engineers, material scientists, mechanical engineers, and polymer scientists; guide researchers unexposed to this alluring and interesting area of drag reduction; and serve as a reference to all who want to explore and expand the areas dealt with in this book.

Correlations Among Surfactant Drag Reduction Additive Chemical Structures, Rheological Properties and Microstructures in Water and Water/co-solvent Systems

Download Correlations Among Surfactant Drag Reduction Additive Chemical Structures, Rheological Properties and Microstructures in Water and Water/co-solvent Systems PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (645 download)

DOWNLOAD NOW!


Book Synopsis Correlations Among Surfactant Drag Reduction Additive Chemical Structures, Rheological Properties and Microstructures in Water and Water/co-solvent Systems by : Ying Zhang

Download or read book Correlations Among Surfactant Drag Reduction Additive Chemical Structures, Rheological Properties and Microstructures in Water and Water/co-solvent Systems written by Ying Zhang and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: Under appropriate conditions, surfactants in water are known to self-assemble into threadlike micelles which reduce the drag of the solution in turbulent flow compared to that of the water solvent at the same flow rate. The phenomenon is called turbulent drag reduction (DR). Using surfactant DR additives (DRA) can save up to 70% pumping energy in turbulent pipe flow water circulating systems, such as district cooling/heating systems, in which a large amount of water is temperature controlled in a central station and recirculated within a district to heat/cool the buildings therein. A new approach to energy saving in district cooling systems is to replace water with 20% ethylene glycol (EG) in water as the cooling medium, which can be cooled down to -5°C (compared to 5°C for water). The coolant typically warms up to 15°C and is then returned to the central station for recooling. The temperature difference for the 20%EG/W medium is 20°C ( -5°C to 15°C), twice as much as the 10°C for water (5°C to 15°C), increasing its cooling capacity and reducing the amount of recirculating coolant and pumping energy needed by about 50%. Pumping energy could be reduced by an additional 50% if effective surfactant DRAs can be used in such mixed solvents. However, co-solvents such as EG are known to inhibit micelle formation which may decrease the effectiveness of DRAs compared to pure water systems. This study investigated and developed effective surfactant DRAs in several water/co-solvent systems at low temperatures. DR, rheological, cryogenic transmission electron microscopy (cryo-TEM) and 1H NMR experiments are being carried out to develop correlations among DR, rheological properties and micelle microstructures. In addition to the practical application in district cooling systems using EG-water mixed solvent or other co-solvent systems, the results of this study provide more fundamental understanding of the effects of solvent properties on threadlike micelle microstructure, drag reduction and system rheology, which are poorly understood now.

Interactions Between Drag Reducing Polymers and Surfactants

Download Interactions Between Drag Reducing Polymers and Surfactants PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 133 pages
Book Rating : 4.:/5 (613 download)

DOWNLOAD NOW!


Book Synopsis Interactions Between Drag Reducing Polymers and Surfactants by : Ketan Prajapati

Download or read book Interactions Between Drag Reducing Polymers and Surfactants written by Ketan Prajapati and published by . This book was released on 2009 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt: Drag reduction in turbulent pipe flow using polymeric and surfactant additives is well known. Although extensive research work has been carried out on the drag reduction behavior of polymers and surfactants in isolation, little progress has been made on the synergistic effects of combined polymers and surfactants. In this work the interactions between drag-reducing polymers and surfactants were studied. The drag-reducing polymers studied were nonionic polyethylene oxide (referred to as PEO) and anionic copolymer of acrylamide and sodium acrylate (referred to as CPAM). The drag-reducing surfactants studied were nonionic ethoxylated alcohol - Alfonic 1412-7 (referred to as EA), cationic surfactant - Octadecyltrimethylammonium chloride in pure powder form (referred to as OTAC-p) and commercial grade cationic surfactant - Octadecyltrimethylammonium chloride in isopropanol solvent - Arquad 18-50 (referred to as OTAC-s). The interactions between polymers and surfactant were reflected in the measurements of the physical properties such as electrical conductivity, surface tension, viscosity and turbidity. The critical micelle concentration (cmc) of the mixed polymer / surfactant system was found to be different from that of the surfactant alone. The viscosity of a polymer solution was significantly affected by the addition of surfactant. Weak interactions were observed for the mixed systems of nonionic polymer - nonionic surfactant and anionic polymer - nonionic surfactant. Due to the wrapping of polymer chains around the developing micelles, a minimum in the viscosity is observed in these two cases. In the case of nonionic polymer / cationic surfactant system, the change in the viscosity was found to depend on the polymer concentration (C) and the critical entanglement concentration (C*). When the polymer concentration (C) was less than C* (C C*), the plot of the viscosity versus surfactant concentration exhibited a minimum. When C C*, a maximum in the viscosity versus surfactant concentration plot was observed. The interactions between nonionic polymer and cationic surfactant were observed to increase with the increase in temperature. A large drop in the viscosity occurred in the case of anionic-polymer / cationic-surfactant system when surfactant was added to the polymer solution. The observed changes in the viscosity are explained in terms of the changes in the extension of polymeric chains resulting from polymer-surfactant interactions. The anionic CPAM chains collapsed upon the addition of cationic OTAC-p, due to charge neutralization. The presence of counterion sodium salicylate (NaSal) stabilized the cationic surfactant monomers in the solution, resulting in micelle formation at a surfactant concentration well below the concentration where complete charge neutralization of anionic polymer occurred. Preliminary results are reported on the pipeline drag reduction behavior of mixed polymer-surfactant system. The results obtained using combinations of CPAM / OTAC-p in pipeline flow are found to be in harmony with the interaction study. Due to the shrinkage of CPAM chains upon the addition of OTAC-p, the drag reducing ability of CPAM is compromised.

Drag Reduction on Non-ionic Surfactants in Aqueous Systems

Download Drag Reduction on Non-ionic Surfactants in Aqueous Systems PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 126 pages
Book Rating : 4.:/5 (62 download)

DOWNLOAD NOW!


Book Synopsis Drag Reduction on Non-ionic Surfactants in Aqueous Systems by : Jen-Lin Chang

Download or read book Drag Reduction on Non-ionic Surfactants in Aqueous Systems written by Jen-Lin Chang and published by . This book was released on 1972 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The use of polyoxyethylene alcohol non-ionic surfactants as drag reducing additives in aqueous systems was investigated. Significant drag reduction was obtained with suitable combinations of one percent Alfonic 1214 and salts at 30°C such that the surfactant was near or above its upper critical solubility temperature. Maximum drag reduction was observed at the cloud point. Relative viscosity values also peaked at this point. No upper critical shear stress was attained up to wall shear stresses of 2,000 dynes/cm2 with one percent Alfonic 1214 solutions at their cloud points. At a fixed temperature, the salt concentration required to reach the cloud point is sensitive to the nature of the anion, but is less sensitive to the nature of the cation. Some sensitivity to pH was also observed. The cloud point is not sensitive to the concentration of the surfactant at concentrations below one percent. At 0.5 percent Alfonic 1214, upper critical shear stresses were observed even with solutions at their cloud points. The mechanical degradation is only temporary, however, and drag reduction ability is regained when the shear stress is lowered"--Abstract, leaf ii.

Turbulent Drag Reduction by Polymers, Surfactants and Their Mixtures in Pipeline Flow

Download Turbulent Drag Reduction by Polymers, Surfactants and Their Mixtures in Pipeline Flow PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 259 pages
Book Rating : 4.:/5 (86 download)

DOWNLOAD NOW!


Book Synopsis Turbulent Drag Reduction by Polymers, Surfactants and Their Mixtures in Pipeline Flow by : Ali Asghar Mohsenipour

Download or read book Turbulent Drag Reduction by Polymers, Surfactants and Their Mixtures in Pipeline Flow written by Ali Asghar Mohsenipour and published by . This book was released on 2011 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lthough extensive research work has been carried out on the drag reduction behavior of polymers and surfactants alone, little progress has been made on the synergistic effects of combined polymers and surfactants. A number of studies have demonstrated that certain types of polymers and surfactants interact with each other to form surfactant-polymer complexes. The formation of such complexes can cause changes in the solution properties and may result in better drag reduction characteristics as compared with pure additives. A series of drag-reducing surfactants and polymers were screened for the synergistic studies. The following two widely used polymeric drag reducing agents (DRA) were chosen: a copolymer of acrylamide and sodium acrylate (referred to as PAM) and polyethylene oxide (PEO). Among the different types of surfactants screened, a cationic surfactant octadecyltrimethylammonium chloride (OTAC) and an anionic surfactant Sodium dodecyl sulfate (SDS) were selected for the synergistic study. In the case of the cationic surfactant OTAC, sodium salicylate (NaSal) was used as a counterion. No counterion was used with anionic surfactant SDS. The physical properties such as viscosity, surface tension and electrical conductivity were measured in order to detect any interaction between the polymer and the surfactant. The drag reduction (DR) ability of both pure and mixed additives was investigated in a pipeline flow loop. The effects of different parameters such as additive concentration, type of water (deionized (DI) or tap), temperature, tube diameter, and mechanical degradation were investigated. The addition of OTAC to PAM solution has a significant effect on the properties of the system. The critical micelle concentration (CMC) of the mixed surfactant-polymer system is found to be different from that of the surfactant alone. The anionic PAM chains collapse upon the addition of cationic OTAC and a substantial decrease in the viscosity occurs. The pipeline flow behaviour of PAM/OTAC mixtures is found to be consistent with the bench scale results. The drag reduction ability of PAM is reduced upon the addition of OTAC. At low concentrations of PAM, the effect of OTAC on the drag reduction behavior is more pronounced. The drag reduction behavior of polymer solutions is strongly influenced by the nature of water (de-ionized or tap). The addition of OTAC to PEO solution exhibited a week interaction based on the viscosity and surface tension measurements. However, the pipeline results showed a considerable synergistic effect, that is, the mixed system gave a significantly higher drag reduction (lower friction factors) as compared with the pure additives (pure polymer or pure surfactant). The synergistic effect in the mixed system was stronger at low polymer concentrations and high surfactant concentrations. Also the resistance against mechanical degradation of the additive was improved upon the addition of OTAC to PEO. The mixed PEO/SDS system exhibited a strong interaction between the polymers (PEO) and the surfactant (SDS), Using electrical conductivity and surface tension measurements, the critical aggregation concentration (CAC) and the polymer saturation point (PSP) were determined. As the PEO concentration is increased, the CAC decreases and the PSP increase. The addition of SDS to the PEO solution exhibits a remarkable increase in the relative viscosity compared to the pure PEO solution. This increase is attributed to the changes in the hydrodynamic radius of the polymer coil. The pipeline flow exhibited a considerable increase in DR for the mixed system as compared to the pure PEO solution. The addition of surfactant always improves the extent of DR up to the PSP. Also the mixed PEO/ SDS system shows better resistance against shear degradation of the additive.

Investigations on Drag Reduction by Interactions Between Polymer and Surfactant and Polymer and Polymer

Download Investigations on Drag Reduction by Interactions Between Polymer and Surfactant and Polymer and Polymer PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 254 pages
Book Rating : 4.:/5 (973 download)

DOWNLOAD NOW!


Book Synopsis Investigations on Drag Reduction by Interactions Between Polymer and Surfactant and Polymer and Polymer by : Jia Yang

Download or read book Investigations on Drag Reduction by Interactions Between Polymer and Surfactant and Polymer and Polymer written by Jia Yang and published by . This book was released on 2015 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: A large amount of studies have been carried out on pipeline flow with several kinds of drag reducing agents, especially polymers and surfactants. Drag reducing agents, by definition, are additives which help suppress or eliminate turbulence in a pipeline. The mechanism and methodology of polymer only or surfactant only as drag reducing additives have been fully discovered. Whether mixed drag reducers such as polymer-surfactant or polymer-polymer systems would be effective is still not clear. In our study, polymer-surfactant and polymer-polymer mixed additives are used in order to explore the synergistic effects and interactions in pipeline flow loops. The experimental work was divided into two sections: bench-scale experiments and pilot-scale experiments. In bench-scale experiments, the properties of prepared fluids such as, surface tension, conductivity and shear viscosity were measured. Several comparison methods and calculations were applied to give better understandings of the properties resulting from mixing of polymer with surfactant and polymer with polymer. After analysis of the properties, several combinations of concentrations were selected and solutions were prepared in the main tank of pilot plant and pumped into the pipeline set-up to test the pipeline flow behaviors. Turbulence structure/Reynolds number, pipe diameter, polymer-surfactant concentration were all considered as influencing factors. Critical micelle concentration, critical aggregation concentration, polymer saturation point, the onset of drag reduction, and the interactions between the mixed additives were discussed. A comparison between pipeline results and the predictions of Blasius Equation or Dodge-Metzner Equation were also discussed.. For polymer-surfactant studies, a commonly used polymer additive - carboxylmethylcellulose (referred to as CMC which is anionic) was selected as the drag reducing agent. The performance of this polymer was investigated in the presence of six surfactants respectively - Alcohol ethoxylate (referred to as Alfonic 1412-9 and Alfonic 1412-3 which are nonionic), Aromox DMC (nonionic surfactant), Stepanol WA-100 and Stepwet DF-95 (which mainly consist sodium lauryl sulfates, anionic surfactant) and Amphosol (which is zwitterionic).The experiments were first conducted with pure CMC solution with different concentrations (100ppm, 500ppm, 700ppm and 1000ppm) as a standard. The 500ppm CMC solution was selected as the best polymer concentration with highest drag reduction efficiency. For polymer-surfactant combinations, CMC-Alfonic 1412-9, CMC-Alfonic1412-3, CMC-Stepanol and CMC-Stepwet systems were found to have significant interactions. High surfactant concentration resulted in reduction in %DR. The addition of Aromox increased the drag reduction ability and onset point when concentration was higher than the polymer saturation points. Also, both hydrophobic and electrostatic interactions were thought to have an effect on critical micelle concentration, which led to the fluctuations in the %DR. For polymer-polymer studies, PAM-PEO system at two different polymer concentrations were investigated. Overall, Pure PAM solution had much higher drag reduction ability than pure PEO solutions. Mixing them together, strong interactions occurred when PEO fraction was high (over 50%) which affected %DR and shear viscosity substantially. Power-law constants n and k were also taken into account and found to exhibit opposite trends with the increase of PEO fraction.

Journal of Rheology

Download Journal of Rheology PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 830 pages
Book Rating : 4.:/5 (318 download)

DOWNLOAD NOW!


Book Synopsis Journal of Rheology by :

Download or read book Journal of Rheology written by and published by . This book was released on 2007 with total page 830 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Sufactants- Suspended Solid Drag Reduction Systems in Pipelines

Download Sufactants- Suspended Solid Drag Reduction Systems in Pipelines PDF Online Free

Author :
Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783845443911
Total Pages : 124 pages
Book Rating : 4.4/5 (439 download)

DOWNLOAD NOW!


Book Synopsis Sufactants- Suspended Solid Drag Reduction Systems in Pipelines by : Hayder A. Abdulbari Al-Khfaji

Download or read book Sufactants- Suspended Solid Drag Reduction Systems in Pipelines written by Hayder A. Abdulbari Al-Khfaji and published by LAP Lambert Academic Publishing. This book was released on 2011-09 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: The concept of drag reduction allows the pipelines to be operated at a lower pressure drop, thus reducing energy consumption and costs while transporting fluids through onshore and offshore pipelines, channels, cooling and heating devices, etc. The objective of drag reduction study is to find a suitable means to reduce the physical force or drag that resists the movement of fluids through transporting media. Drag is identified through pressure drop measurement in piping system. The addition of a small amount of certain chemical additives in transporting system could reduce the drag. These chemicals additives are known as drag reducing agents (DRA). Surfactants, fibers and polymers are among the well-known additives which are used as a DRA. The mechanism of drag reduction depends on the form or type of DRA and thus the effect on drag varies with the choice of DRA. The present book analyzed the effect of anionic surfactants and suspended fibers on drag reduction based on solution concentration, combination of two different materials, fluid Reynolds number, pipe scales, surfactant molecular number and surfactant compound structure.

Modern Characterization Methods of Surfactant Systems

Download Modern Characterization Methods of Surfactant Systems PDF Online Free

Author :
Publisher : CRC Press
ISBN 13 : 9780824719784
Total Pages : 622 pages
Book Rating : 4.7/5 (197 download)

DOWNLOAD NOW!


Book Synopsis Modern Characterization Methods of Surfactant Systems by : Bernard Binks

Download or read book Modern Characterization Methods of Surfactant Systems written by Bernard Binks and published by CRC Press. This book was released on 1999-04-16 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt: Describes recent techniques applied to characterize surfactant systems, such as surfactant-stabilized colloids, micelles, microemulsions, emulsions and foams in both aqueous and nonaqueous fluids. The text probes adsorption and wetting phenomena at interfaces, including solid-liquid, liquid-vapour and liquid-liquid. It provides helpful examples and case studies illustrating how these techniques may be used in complementary ways.

Polymer Physics

Download Polymer Physics PDF Online Free

Author :
Publisher : John Wiley & Sons
ISBN 13 : 1118062957
Total Pages : 677 pages
Book Rating : 4.1/5 (18 download)

DOWNLOAD NOW!


Book Synopsis Polymer Physics by : Leszek A. Utracki

Download or read book Polymer Physics written by Leszek A. Utracki and published by John Wiley & Sons. This book was released on 2011-02-14 with total page 677 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a comprehensive review of the state-of-the-art advanced research in the field, Polymer Physics explores the interrelationships among polymer structure, morphology, and physical and mechanical behavior. Featuring contributions from renowned experts, the book covers the basics of important areas in polymer physics while projecting into the future, making it a valuable resource for students and chemists, chemical engineers, materials scientists, and polymer scientists as well as professionals in related industries.

An Experimental Investigation of Drag Reduction by Surfactant Solutions and of Its Implementation in Hydronic Systems

Download An Experimental Investigation of Drag Reduction by Surfactant Solutions and of Its Implementation in Hydronic Systems PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 778 pages
Book Rating : 4.:/5 (344 download)

DOWNLOAD NOW!


Book Synopsis An Experimental Investigation of Drag Reduction by Surfactant Solutions and of Its Implementation in Hydronic Systems by : Kazimir Gasljevic

Download or read book An Experimental Investigation of Drag Reduction by Surfactant Solutions and of Its Implementation in Hydronic Systems written by Kazimir Gasljevic and published by . This book was released on 1995 with total page 778 pages. Available in PDF, EPUB and Kindle. Book excerpt: