Regio and Chemo Selective Hydrogenation by Palladium Nanoparticles Embedded in Polyelectrolyte Films

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Publisher :
ISBN 13 :
Total Pages : 342 pages
Book Rating : 4.3/5 (129 download)

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Book Synopsis Regio and Chemo Selective Hydrogenation by Palladium Nanoparticles Embedded in Polyelectrolyte Films by : Somnath Bhattacharjee

Download or read book Regio and Chemo Selective Hydrogenation by Palladium Nanoparticles Embedded in Polyelectrolyte Films written by Somnath Bhattacharjee and published by . This book was released on 2008 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Unsupported Thiolate-capped Palladium Nanoparticles as Selective Hydrogenation Catalysts

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Publisher :
ISBN 13 : 9781085564441
Total Pages : 45 pages
Book Rating : 4.5/5 (644 download)

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Book Synopsis Unsupported Thiolate-capped Palladium Nanoparticles as Selective Hydrogenation Catalysts by : Jie S. Zhu

Download or read book Unsupported Thiolate-capped Palladium Nanoparticles as Selective Hydrogenation Catalysts written by Jie S. Zhu and published by . This book was released on 2019 with total page 45 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: The reactions of palladium are invaluable to modern academic and industrial research, and nanotechnology is the foundation on which the next generation of materials is built upon. Unsupported thiolate-capped palladium nanoparticles were found to be highly substrate selective for alkene hydrogenation and isomerization. A modified Brust-Schiffrin reaction enabled the facile and convenient synthesis of a diverse set of ultra-small thiolate-capped nanoparticles. The physical properties of these nanoparticles were highly tunable due to the widespread availability of ligand precursors. Mechanistic evidence and insights reveal that steric and electronic effects from the ligand environment on the nanoparticle surface controlled reactivity by influencing alkene adsorption via [pi] bond coordination or di-[sigma] bond formation. Only alkenes close enough to the metal surface of the nanoparticles underwent reaction. Dienes with good overlapping p orbitals could overcome these steric effects on the deactivated palladium nanoparticle surfaces. A mechanistic model was built from these completed studies, and this model can be used to predict the selectivity of hydrogenation or isomerization in multiple classes of alkenes with varied substitution patterns. These palladium nanoparticles were also found to be capable of chemoselective alkene hydrogenation in the presence of functional groups that are known to be labile towards reduction by palladium.

Thiolate-capped Palladium Nanoparticles for Selective Catalytic Hydrogenation of Alkenes in the Presence of Another Reactive Functional Group

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ISBN 13 : 9781085570886
Total Pages : 47 pages
Book Rating : 4.5/5 (78 download)

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Book Synopsis Thiolate-capped Palladium Nanoparticles for Selective Catalytic Hydrogenation of Alkenes in the Presence of Another Reactive Functional Group by : Mohammed Mahdaly

Download or read book Thiolate-capped Palladium Nanoparticles for Selective Catalytic Hydrogenation of Alkenes in the Presence of Another Reactive Functional Group written by Mohammed Mahdaly and published by . This book was released on 2019 with total page 47 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents the preparation and catalysis of octanethiolate-capped palladium nanoparticles (C8 PdNP) and phenylethanethiolate-capped palladium nanoparticles (PhC2 PdNP) for chemoselective catalytic hydrogenation reactions of alkene groups in the presence of other reducible functionalities. Kinetic studies are performed and analyzed by 1H NMR spectroscopy to obtain clearer understandings of the catalytic activity. The noncovalent interactions between surface phenyl ligands and aromatic substrates are found to hinder the hydrogenation activity of PhC2 PdNP. In comparison, the C8 PdNP is discovered to be highly active and selective for hydrogenating alkene and alkyne groups without the reduction of other reactive functional groups such as nitro, halo, carbonyls, etc. under the mild reaction condition (room temperature and atmospheric pressure).

Polymeric Gels

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Publisher : Woodhead Publishing
ISBN 13 : 0081021801
Total Pages : 570 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Polymeric Gels by : Kunal Pal

Download or read book Polymeric Gels written by Kunal Pal and published by Woodhead Publishing. This book was released on 2018-06-15 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymeric Gels: Characterization, Properties and Biomedical Applications covers the fundamentals and applications of polymeric gels. Particular emphasis is given to their synthesis, properties and characteristics, with topics such as natural, synthetic, and smart polymeric gels, medical applications, and advancements in conductive and magnetic gels presented. The book covers the basics and applications of hydrogels, providing readers with a comprehensive guide on the types of polymeric gels used in the field of biomedical engineering. Provides guidance for decisions on the suitability and appropriateness of a synthetic route and characterization technique for particular polymeric networks Analyzes and compares experimental data Presents in-depth information on the physical properties of polymeric gels using mathematical models Uses an interdisciplinary approach to discuss potential new applications for both established polymeric gels and recent advances

Thin Film Processes

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Publisher : BoD – Books on Demand
ISBN 13 : 9535130676
Total Pages : 222 pages
Book Rating : 4.5/5 (351 download)

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Book Synopsis Thin Film Processes by : Jagannathan Thirumalai

Download or read book Thin Film Processes written by Jagannathan Thirumalai and published by BoD – Books on Demand. This book was released on 2017-04-12 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book Thin Film Processes - Artifacts on Surface Phenomena and Technological Facets presents topics on global advancements in theoretical and experimental facts, instrumentation and practical applications of thin-film material perspectives and its applications. The aspect of this book is associated with the thin-film physics, the methods of deposition, optimization parameters and its wide technological applications. This book is divided into three main sections: Thin Film Deposition Methods: A Synthesis Perspective; Optimization Parameters in the Thin Film Science and Application of Thin Films: A Synergistic Outlook. Collected chapters provide applicable knowledge for a wide range of readers: common men, students and researchers. It was constructed by experts in diverse fields of thin-film science and technology from over 15 research institutes across the globe.

Nanoparticles in Catalysis

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Publisher : Springer Nature
ISBN 13 : 3030566307
Total Pages : 314 pages
Book Rating : 4.0/5 (35 download)

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Book Synopsis Nanoparticles in Catalysis by : Shū Kobayashi

Download or read book Nanoparticles in Catalysis written by Shū Kobayashi and published by Springer Nature. This book was released on 2020-11-06 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume discusses the great potential of metal nanoparticle catalysts for complicated molecular synthesis and reviews the current progress of this field. The development of highly active and stable heterogeneous catalysts is a crucial subject in modern science. However, development of heterogeneous catalysts for fine chemical synthesis has lagged far behind those for bulk chemical process. In recent years metal nanoparticle catalysts have been of great interest in this area due to their unique activity, ease of heterogenization, and robustness. Therefore, metal nanoparticle catalysts are an excellent candidate for the above-mentioned active and robust heterogeneous catalysts and this book provides an overview of this area. The present volume summarizes recent progress on nanoparticle catalysis for various organic transformations from simple redox reactions to complex asymmetric C–C bond forming reactions and also presents seminal studies on new technologies. It comprehensively summarizes advances in metal nanoparticle catalysis across several aspects including reaction manners, mechanistic investigations and new synthetic methodologies to encourage the use of metal nanoparticle catalysts for future organic synthesis. This volume will be of interest to students, researchers and professionals focused on the next-generation of fine chemical synthesis.

Metal Nanoparticles in Microbiology

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Publisher : Springer Science & Business Media
ISBN 13 : 3642183123
Total Pages : 306 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Metal Nanoparticles in Microbiology by : Mahendra Rai

Download or read book Metal Nanoparticles in Microbiology written by Mahendra Rai and published by Springer Science & Business Media. This book was released on 2011-04-02 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: Following an introduction to biogenic metal nanoparticles, this book presents how they can be biosynthesized using bacteria, fungi and yeast, as well as their potential applications in biomedicine. It is shown that the synthesis of nanoparticles using microbes is eco-friendly and results in reproducible metal nanoparticles of well-defined sizes, shapes and structures. This biotechnological approach based on the process of biomineralization exploits the effectiveness and flexibility of biological systems. Chapters include practical protocols for microbial synthesis of nanoparticles and microbial screening methods for isolating a specific nanoparticle producer as well as reviews on process optimization, industrial scale production, biomolecule-nanoparticle interactions, magnetosomes, silver nanoparticles and their numerous applications in medicine, and the application of gold nanoparticles in developing sensitive biosensors.

Thin Films and Coatings

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Publisher : CRC Press
ISBN 13 : 1482222914
Total Pages : 610 pages
Book Rating : 4.4/5 (822 download)

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Book Synopsis Thin Films and Coatings by : Sam Zhang

Download or read book Thin Films and Coatings written by Sam Zhang and published by CRC Press. This book was released on 2015-07-29 with total page 610 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thin Films and Coatings: Toughening and Toughness Characterization captures the latest developments in the toughening of hard coatings and in the measurement of the toughness of thin films and coatings. Featuring chapters contributed by experts from Australia, China, Czech Republic, Poland, Singapore, Spain, and the United Kingdom, this book: Presents the current status of hard-yet-tough ceramic coatings Reviews various toughness evaluation methods for films and hard coatings Explores the toughness and toughening mechanisms of porous thin films and laser-treated surfaces Examines adhesions of the film/substrate interface and the characterization of coating adhesion strength Discusses nanoindentation determination of fracture toughness, resistance to cracking, and sliding contact fracture phenomena Toughening and toughness measurement (of films and coatings) are two related, yet separate, fields of great importance in today’s nanotechnology world. Thin Films and Coatings: Toughening and Toughness Characterization is a timely reference written in such a way that novices will find it a stepping stone to the field and veterans will find it a rich source of information for their research.

Nanotechnology in Catalysis 3

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Publisher : Springer Science & Business Media
ISBN 13 : 0387346880
Total Pages : 342 pages
Book Rating : 4.3/5 (873 download)

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Book Synopsis Nanotechnology in Catalysis 3 by : Bing Zhou

Download or read book Nanotechnology in Catalysis 3 written by Bing Zhou and published by Springer Science & Business Media. This book was released on 2007-09-05 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume continues the tradition formed in Nanotechnology in Catalysis 1 and 2. As with those books, this one is based upon an ACS symposium. Some of the most illustrious names in heterogeneous catalysis are among the contributors. The book covers: Design, synthesis, and control of catalysts at nanoscale; understanding of catalytic reaction at nanometer scale; characterization of nanomaterials as catalysts; nanoparticle metal or metal oxides catalysts; nanomaterials as catalyst supports; new catalytic applications of nanomaterials.

Combinatorial Methods for Chemical and Biological Sensors

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Publisher : Springer Science & Business Media
ISBN 13 : 0387737138
Total Pages : 495 pages
Book Rating : 4.3/5 (877 download)

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Book Synopsis Combinatorial Methods for Chemical and Biological Sensors by : Radislav A. Potyrailo

Download or read book Combinatorial Methods for Chemical and Biological Sensors written by Radislav A. Potyrailo and published by Springer Science & Business Media. This book was released on 2009-03-21 with total page 495 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical sensors are in high demand for applications as varied as water pollution detection, medical diagnostics, and battlefield air analysis. Designing the next generation of sensors requires an interdisciplinary approach. The book provides a critical analysis of new opportunities in sensor materials research that have been opened up with the use of combinatorial and high-throughput technologies, with emphasis on experimental techniques. For a view of component selection with a more computational perspective, readers may refer to the complementary volume of Integrated Analytical Systems edited by M. Ryan et al., entitled “Computational Methods for Sensor Material Selection”.

Sustainable Preparation of Metal Nanoparticles

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849734283
Total Pages : 243 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Sustainable Preparation of Metal Nanoparticles by : Rafael Luque

Download or read book Sustainable Preparation of Metal Nanoparticles written by Rafael Luque and published by Royal Society of Chemistry. This book was released on 2013 with total page 243 pages. Available in PDF, EPUB and Kindle. Book excerpt: This timely publication bridges and presents the latest trends and updates in three hot topics of current and future society: nanomaterials, energy and environment. It provides the state-of-the-art as well as current challenges and advances in the sustainable preparation of metal nanoparticles and their applications. The book fills a critical gap in a multidisciplinary area of high economic, social and environmental importance. Currently, there are no books published that deal with these ever increasing important topics, as most books in this area focus on a particular topic (eg. nanomaterials or catalysis or energy or environment). This is the first multidisciplinary edited book covering the very basics to the more advanced, trendy developments, containing a unique blend of nano, green, renewable and bio.

Laser-induced Graphene

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Publisher :
ISBN 13 : 9789814877275
Total Pages : 88 pages
Book Rating : 4.8/5 (772 download)

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Book Synopsis Laser-induced Graphene by : Ruquan Ye

Download or read book Laser-induced Graphene written by Ruquan Ye and published by . This book was released on 2020-11-30 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt: LIG is a revolutionary technique that uses a common CO2 infrared laser scriber, like the one used in any machine shop, for the direct conversion of polymers into porous graphene under ambient conditions. This technique combines the preparation and patterning of 3D graphene in a single step, without the use of wet chemicals. The ease in the structural engineering and excellent mechanical properties of the 3D graphene obtained have made LIG a versatile technique for applications across many fields. This book compiles cutting-edge research on LIG by different research groups all over the world. It discusses the strategies that have been developed to synthesize and engineer graphene, including controlling its properties such as porosity, composition, and surface characteristics. The authors are pioneers in the discovery and development of LIG and the book will appeal to anyone involved in nanotechnology, chemistry, environmental sciences, and device development, especially those with an interest in the synthesis and applications of graphene-based materials.

Electrospun Nanofibers

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Publisher : Woodhead Publishing
ISBN 13 : 0081009119
Total Pages : 650 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Electrospun Nanofibers by : Mehdi Afshari

Download or read book Electrospun Nanofibers written by Mehdi Afshari and published by Woodhead Publishing. This book was released on 2016-09-13 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrospun Nanofibers covers advances in the electrospinning process including characterization, testing and modeling of electrospun nanofibers, and electrospinning for particular fiber types and applications. Electrospun Nanofibers offers systematic and comprehensive coverage for academic researchers, industry professionals, and postgraduate students working in the field of fiber science. Electrospinning is the most commercially successful process for the production of nanofibers and rising demand is driving research and development in this field. Rapid progress is being made both in terms of the electrospinning process and in the production of nanofibers with superior chemical and physical properties. Electrospinning is becoming more efficient and more specialized in order to produce particular fiber types such as bicomponent and composite fibers, patterned and 3D nanofibers, carbon nanofibers and nanotubes, and nanofibers derived from chitosan. Provides systematic and comprehensive coverage of the manufacture, properties, and applications of nanofibers Covers recent developments in nanofibers materials including electrospinning of bicomponent, chitosan, carbon, and conductive fibers Brings together expertise from academia and industry to provide comprehensive, up-to-date information on nanofiber research and development Offers systematic and comprehensive coverage for academic researchers, industry professionals, and postgraduate students working in the field of fiber science

Physics, Chemistry And Application Of Nanostructures: Reviews And Short Notes To Nanomeeting-2017

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Publisher : World Scientific
ISBN 13 : 9813224541
Total Pages : 531 pages
Book Rating : 4.8/5 (132 download)

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Book Synopsis Physics, Chemistry And Application Of Nanostructures: Reviews And Short Notes To Nanomeeting-2017 by : Victor E Borisenko

Download or read book Physics, Chemistry And Application Of Nanostructures: Reviews And Short Notes To Nanomeeting-2017 written by Victor E Borisenko and published by World Scientific. This book was released on 2017-04-27 with total page 531 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents invited reviews and original short notes of recent results obtained in studies concerning the fabrication and application of nanostructures, which hold great promise for the new generation of electronic, optoelectronic and energy conversion devices. They present achievements discussed at Special Sessions 'Frontiers of Molecular Diagnostics with Nanostructures' and 'Nanoelectromagnetics' organized within Nanomeeting-2017.Discussing exciting and relatively new topics such as fast-progressing nanoelectronics and optoelectronics, molecular electronics and spintronics, nanoelectromagnetics, nanophotonics, nanosensorics and nanoenergetics as well as nanotechnology and quantum processing of information, this book gives readers a more complete understanding of the practical applications of nanotechnology and nanostructures.

Frontiers in Materials: Rising Stars

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Publisher : Frontiers Media SA
ISBN 13 : 2889635813
Total Pages : 687 pages
Book Rating : 4.8/5 (896 download)

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Book Synopsis Frontiers in Materials: Rising Stars by : Nicola Maria Pugno

Download or read book Frontiers in Materials: Rising Stars written by Nicola Maria Pugno and published by Frontiers Media SA. This book was released on 2020-04-17 with total page 687 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Frontiers in Materials Editorial Office team are delighted to present the inaugural “Frontiers in Materials: Rising Stars” article collection, showcasing the high-quality work of internationally recognized researchers in the early stages of their independent careers. All Rising Star researchers featured within this collection were individually nominated by the Journal’s Chief Editors in recognition of their potential to influence the future directions in their respective fields. The work presented here highlights the diversity of research performed across the entire breadth of the materials science and engineering field, and presents advances in theory, experiment and methodology with applications to compelling problems. This Editorial features the corresponding author(s) of each paper published within this important collection, ordered by section alphabetically, highlighting them as the great researchers of the future. The Frontiers in Materials Editorial Office team would like to thank each researcher who contributed their work to this collection. We would also like to personally thank our Chief Editors for their exemplary leadership of this article collection; their strong support and passion for this important, community-driven collection has ensured its success and global impact. Laurent Mathey, PhD Journal Development Manager

Inorganic Nanoparticles

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Publisher : CRC Press
ISBN 13 : 1351833960
Total Pages : 885 pages
Book Rating : 4.3/5 (518 download)

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Book Synopsis Inorganic Nanoparticles by : Claudia Altavilla

Download or read book Inorganic Nanoparticles written by Claudia Altavilla and published by CRC Press. This book was released on 2017-12-19 with total page 885 pages. Available in PDF, EPUB and Kindle. Book excerpt: Among the various nanomaterials, inorganic nanoparticles are extremely important in modern technologies. They can be easily and cheaply synthesized and mass produced, and for this reason, they can also be more readily integrated into applications. Inorganic Nanoparticles: Synthesis, Applications, and Perspectives presents an overview of these special materials and explores the myriad ways in which they are used. It addresses a wide range of topics, including: Application of nanoparticles in magnetic storage media Use of metal and oxide nanoparticles to improve performance of oxide thin films as conducting media in commercial gas and vapor sensors Advances in semiconductors for light-emitting devices and other areas related to the energy sector, such as solar energy and energy storage devices (fuel cells, rechargeable batteries, etc.) The expanding role of nanosized particles in the field of catalysis, art conservation, and biomedicine The book’s contributors address the growing global interest in the application of inorganic nanoparticles in various technological sectors. Discussing advances in materials, device fabrication, and large-scale production—all of which are urgently required to reduce global energy demands—they cover innovations in areas such as solid-state lighting, detailing how it still offers higher efficiency but higher costs, compared to conventional lighting. They also address the impact of nanotechnology in the biomedical field, focusing on topics such as quantum dots for bioimaging, nanoparticle-based cancer therapy, drug delivery, antibacterial agents, and more. Fills the informational gap on the wide range of applications for inorganic nanoparticles in areas including biomedicine, electronics, storage media, conservation of cultural heritage, optics, textiles, and cosmetics Assembling work from an array of experts at the top of their respective fields, this book delivers a useful analysis of the vast scope of existing and potential applications for inorganic nanoparticles. Versatile as either a professional research resource or textbook, this effective tool elucidates fundamentals and current advances associated with design, characterization, and application development of this promising and ever-evolving device.

Catalytic Hydrogenation

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Publisher : Elsevier
ISBN 13 : 0080960618
Total Pages : 705 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Catalytic Hydrogenation by : L. Cervený

Download or read book Catalytic Hydrogenation written by L. Cervený and published by Elsevier. This book was released on 1986-08-01 with total page 705 pages. Available in PDF, EPUB and Kindle. Book excerpt: The collection of contributions in this volume presents the most up-to-date findings in catalytic hydrogenation. The individual chapters have been written by 36 top specialists each of whom has achieved a remarkable depth of coverage when dealing with his particular topic. In addition to detailed treatment of the most recent problems connected with catalytic hydrogenations, the book also contains a number of previously unpublished results obtained either by the authors themselves or within the organizations to which they are affiliated.Because of its topical and original character, the book provides a wealth of information which will be invaluable not only to researchers and technicians dealing with hydrogenation, but also to all those concerned with homogeneous and heterogeneous catalysis, organic technology, petrochemistry and chemical engineering.