Reactions of Ions with Atomic and Molecular Free Radicals. Progress Report, May 1, 1976--April 30, 1977. [0. 002 to 20 EV, Mechanisms, Adiabaticity].

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis Reactions of Ions with Atomic and Molecular Free Radicals. Progress Report, May 1, 1976--April 30, 1977. [0. 002 to 20 EV, Mechanisms, Adiabaticity]. by :

Download or read book Reactions of Ions with Atomic and Molecular Free Radicals. Progress Report, May 1, 1976--April 30, 1977. [0. 002 to 20 EV, Mechanisms, Adiabaticity]. written by and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A program of research undertaken to study the dynamics of the reactions of ions with atomic and molecular free radicals. The objectives of this research are to obtain fundamental information on reaction mechanisms in reactions of species with open-shell electronic configurations, and to investigate the importance of electronic nonadiabaticity in chemical reactions. During the past contract year the systems D/sub 2//sup +/ + F .-->. FD/sup +/ + D and D/sub 2//sup +/ + C .-->. CD/sup +/ + D were studied over the range of initial kinetic energy from 0.002 eV to 20 eV. In both reactions the product ion is scattered preferentially in the direction of the incident atom. The FD/sup +/ product ion is formed in the ground /sup 2/PI state. The unusually large internal excitation energy of CD/sup +/, however, suggests that it is formed in an excited electronic state, possibly /sup 1/PI. The data for the D/sub 2//sup +/ + C reaction can be reconciled with the assumption of electronic adiabaticity, while that for D/sub 2//sup +/ + F probably cannot.

Energy Research Abstracts

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ISBN 13 :
Total Pages : 500 pages
Book Rating : 4.3/5 (129 download)

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Download or read book Energy Research Abstracts written by and published by . This book was released on 1980 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Reactions of Ions with Atomic and Molecular Free Radicals. Progress Report, May 1, 1978--April 30, 1979. [Summaries of Research Activities at Univ. of Minnesota].

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Book Synopsis Reactions of Ions with Atomic and Molecular Free Radicals. Progress Report, May 1, 1978--April 30, 1979. [Summaries of Research Activities at Univ. of Minnesota]. by :

Download or read book Reactions of Ions with Atomic and Molecular Free Radicals. Progress Report, May 1, 1978--April 30, 1979. [Summaries of Research Activities at Univ. of Minnesota]. written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A program of research was undertaken to study the dynamics of the reactions of ions with atomic and molecular free radicals, using a merged molecular beam technique. The objectives of this research are to obtain fundamental information on reaction mechanisms in reactions of species having open-shell electronic configurations, and to investigate the importance of electronic nonadiabaticity in chemical reactions. During the present contract year work was done on completing studies of the reaction D2 + F(2P) .-->. FD+ + D and of the complementary reactions D2+ + HF .-->. FD22 + H, D2+ + HF .-->. FHD+ + D, and D2+ + HF .-->. FD+ + HD. Also some experiments were carried out on the reaction C+ + D2 .-->. CD+ + D to complement our previous work on the opposite initial charge state of the system, D2+ + C .-->. CD+ + D. Finally, as an aid in interpreting our merged-beam data at kinetic energies as low as 0.002 eV. A theoretical analysis was performed of the differential cross sections for ion-dipole capture collisions followed by direct-mode reactions. The results indicate that shifts in the product angular distribution with a change in the reactant kinetic energy do not necessarily imply a change in the short-range reaction mechanism. A list of publications is included.

INIS Atomindex

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ISBN 13 :
Total Pages : 868 pages
Book Rating : 4.3/5 (91 download)

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Download or read book INIS Atomindex written by and published by . This book was released on 1977 with total page 868 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Energetics and Dynamics of Free Radicals, Ions, and Clusters. Progress Report

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ISBN 13 :
Total Pages : 12 pages
Book Rating : 4.:/5 (682 download)

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Book Synopsis The Energetics and Dynamics of Free Radicals, Ions, and Clusters. Progress Report by :

Download or read book The Energetics and Dynamics of Free Radicals, Ions, and Clusters. Progress Report written by and published by . This book was released on 1994 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: The structure and energetics of free radicals, ions, and clusters have been investigated by photoelectron photoion coincidence (PEPICO) and analyzed with the aid of ab initio molecular orbital and statistical theory (RRKM) calculations. The two major themes are the quantitative analysis of unimolecular reactions with no adjustable parameters, and the study of cluster ion dissociation processes. Molecules (or free radicals) were prepared in a molecular beam so that they are translationally and vibrationally cold. The translational temperature was calculated from the measured time of flight (TOF) peak width, while the vibrational temperature was determined from the shift in the dissociation onset. Free radicals are produced by pyrolysis in the nozzle, and subsequent cooling of the free radicals is demonstrated. Ion dissociation rates in the range from 104 to 107 sec−1 are measured from the asymmetric TOF distribution. This method was used to measure the dissociation rates of a number of cold and warm ions, among them HCl (DCl) loss from C2H5Cl (C2D5Cl), a reaction that proceeds via tunneling. The analysis of the butene ion dissociation provided information about the role of angular momentum in dissociation reactions. This dissociative ionization of ethylene clusters demonstrated that ethylene dimer ions rearranged to butene ions prior to dissociation. Finally, a new value for the t-butyl ion heat of formation, which corrects a 15 kJ/mol error in the previous value, was obtained from the 0 K breakdown diagram of t-butyl iodide.

Chemical Kinetics and Reaction Dynamics

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Publisher : Springer Science & Business Media
ISBN 13 : 1402045476
Total Pages : 256 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Chemical Kinetics and Reaction Dynamics by : Santosh K. Upadhyay

Download or read book Chemical Kinetics and Reaction Dynamics written by Santosh K. Upadhyay and published by Springer Science & Business Media. This book was released on 2007-04-29 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.

Vibrational and Electronic Energy Levels of Polyatomic Transient Molecules

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Publisher : Amer Inst of Physics
ISBN 13 : 9781563963162
Total Pages : 461 pages
Book Rating : 4.9/5 (631 download)

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Book Synopsis Vibrational and Electronic Energy Levels of Polyatomic Transient Molecules by : Marilyn E. Jacox

Download or read book Vibrational and Electronic Energy Levels of Polyatomic Transient Molecules written by Marilyn E. Jacox and published by Amer Inst of Physics. This book was released on 1994-01-01 with total page 461 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemical Kinetics

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Publisher : Elsevier
ISBN 13 : 0080469345
Total Pages : 563 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Chemical Kinetics by : Luis Arnaut

Download or read book Chemical Kinetics written by Luis Arnaut and published by Elsevier. This book was released on 2006-12-21 with total page 563 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses. * Looking at atoms and molecules, and how molecular structures change with time. * Providing practical examples and detailed theoretical calculations* Of special interest to Industrial Chemistry and Biochemistry

Oxide Surfaces

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Publisher : Elsevier
ISBN 13 : 0080538312
Total Pages : 677 pages
Book Rating : 4.0/5 (85 download)

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Download or read book Oxide Surfaces written by and published by Elsevier. This book was released on 2001-05-21 with total page 677 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is a multi-author survey (in 15 chapters) of the current state of knowledge and recent developments in our understanding of oxide surfaces. The author list includes most of the acknowledged world experts in this field. The material covered includes fundamental theory and experimental studies of the geometrical, vibrational and electronic structure of such surfaces, but with a special emphasis on the chemical properties and associated reactivity. The main focus is on metal oxides but coverage extends from 'simple' rocksalt materials such as MgO through to complex transition metal oxides with different valencies.

Dissociative Recombination

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Publisher : Springer Science & Business Media
ISBN 13 : 146152976X
Total Pages : 277 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis Dissociative Recombination by : Bertrand R. Rowe

Download or read book Dissociative Recombination written by Bertrand R. Rowe and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of a NATO ARW held in Saint Jacut de la Mer, Brittany, France, May 3-8, 1992

Advanced Oxidation Processes for Water and Wastewater Treatment

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Publisher : IWA Publishing
ISBN 13 : 1843390175
Total Pages : 370 pages
Book Rating : 4.8/5 (433 download)

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Book Synopsis Advanced Oxidation Processes for Water and Wastewater Treatment by : Simon Parsons

Download or read book Advanced Oxidation Processes for Water and Wastewater Treatment written by Simon Parsons and published by IWA Publishing. This book was released on 2004-03-01 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: The suitability of Advanced Oxidation Processes (AOPs) for pollutant degradation was recognised in the early 1970s and much research and development work has been undertaken to commercialise some of these processes. AOPs have shown great potential in treating pollutants at both low and high concentrations and have found applications as diverse as ground water treatment, municipal wastewater sludge destruction and VOCs control. Advanced Oxidation Processes for Water and Wastewater Treatment is an overview of the advanced oxidation processes currently used or proposed for the remediation of water, wastewater, odours and sludge. The book contains two opening chapters which present introductions to advanced oxidation processes and a background to UV photolysis, seven chapters focusing on individual advanced oxidation processes and, finally, three chapters concentrating on selected applications of advanced oxidation processes. Advanced Oxidation Processes for Water and Wastewater Treatment will be invaluable to readers interested in water and wastewater treatment processes, including professionals and suppliers, as well as students and academics studying in this area. Dr Simon Parsons is a Senior Lecturer in Water Sciences at Cranfield University with ten years' experience of industrial and academic research and development.

Specific Ion Effects

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Publisher : World Scientific
ISBN 13 : 9814271586
Total Pages : 347 pages
Book Rating : 4.8/5 (142 download)

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Book Synopsis Specific Ion Effects by : Werner Kunz

Download or read book Specific Ion Effects written by Werner Kunz and published by World Scientific. This book was released on 2010 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specific ion effects are important in numerous fields of science and technology. This book summarizes the main ideas that came up over the years. It presents the efforts of theoreticians and supports it by the experimental results stemming from various techniques.

Modification of Polymers

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Publisher : Springer Science & Business Media
ISBN 13 : 1461337488
Total Pages : 414 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Modification of Polymers by : Charles E. Carraher

Download or read book Modification of Polymers written by Charles E. Carraher and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: The sheer volume of topics which could have been included under our general title prompted us to make some rather arbitrary decisions about content. Modification by irradiation is not included because the activity in this area is being treated elsewhere. We have chosen to emphasize chemical routes to modification and have striven to pre sent as balanced a representation of current activity as time and page count permit. Industrial applications, both real and potential, are included. Where appropriate, we have encouraged the contributors to include review material to help provide the reader with adequate context. The initial chapter is a review from a historical perspective of polymer modification and contains an extensive bibliography. The remainder of the book is divided into four general areas: Reactions and Preparation of Copolymers Reactions and Preparation of Block and Graft Copolymers Modification Through Condensation Reactions Applications The chemical modification of homopolymers such as polyvinylchlo ride, polyethylene, poly(chloroalkylene sulfides), polysulfones, poly chloromethylstyrene, polyisobutylene, polysodium acrylate, polyvinyl alcohol, polyvinyl chloroformate, sulfonated polystyrene; block and graft copolymers such as poly(styrene-block-ethylene-co-butylene block-styrene), poly(I,4-polybutadiene-block ethylene oxide), star chlorine-telechelic polyisobutylene, poly(isobutylene-co-2,3-dimethyl- 1,3-butadiene), poly(styrene-co-N-butylmethacrylate); cellulose, dex tran and inulin, is described.

Atomic and Plasma-material Interaction Data for Fusion

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (249 download)

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Download or read book Atomic and Plasma-material Interaction Data for Fusion written by and published by . This book was released on 1991 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Atomic and Molecular Processes

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Publisher : Elsevier
ISBN 13 : 1483276023
Total Pages : 921 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Atomic and Molecular Processes by : D.R. Bates

Download or read book Atomic and Molecular Processes written by D.R. Bates and published by Elsevier. This book was released on 2016-06-03 with total page 921 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomic and Molecular Processes focuses on radiative and collisional processes involving atoms or molecules, including photoionization, elastic and inelastic scattering of electrons, energy loss by slow electrons, excitation, ionization, detachment, charge transfer, elastic scattering, and chemical reactions. The selection first offers information on forbidden and allowed transitions, including forbidden transitions in diatomic molecular spectra; forbidden transitions in crystals; calculations of atomic line strengths; and measurements of atomic transition probabilities. The book also ponders on photoionization processes, photodetachment, and high temperature shock waves. The manuscript elaborates on electronic and ionic recombination, elastic scattering of electrons, and the motions of slow electrons in gases. The book also evaluates the theory of excitation and ionization by electron impact; measurement of collisional excitation and ionization cross sections; and spectral line broadening in plasmas. The selection is a dependable reference for readers interested in atomic and molecular processes.

Atomic Radiation and Polymers

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Publisher : Elsevier
ISBN 13 : 1483181308
Total Pages : 579 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Atomic Radiation and Polymers by : A. Charlesby

Download or read book Atomic Radiation and Polymers written by A. Charlesby and published by Elsevier. This book was released on 2016-06-06 with total page 579 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomic Radiation and Polymers examines the effects of radiation on polymer materials. The title deals with chemical changes that took place when polymers are exposed to radiation, and how these changes affect the physical properties of the polymers. The text first covers the interaction of radiation and matter, along with radiation sources and dosimetry. Next, the selection deals with the general properties of long chain polymers. The text also details the organic molecules and irradiated polymers. Chapters 22 to 24 tackle the radiation-induced changes in nuclear chain reaction, while Chapter 25 discusses the irradiation of polymers in solution where both direct and indirect effects occur. The next series of chapters details the theoretical aspects of reactions between the initial acts of ionization or excitation. The last two chapters cover the conductivity change at low radiation intensities, along with the data on radiation damage at very high intensities. The book will be of great interest to researchers and practitioners from the field of nuclear science and polymer technology.

Reaction Dynamics Involving Ions, Radicals, Neutral and Excited Species

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Publisher : Frontiers Media SA
ISBN 13 : 2889634302
Total Pages : 345 pages
Book Rating : 4.8/5 (896 download)

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Book Synopsis Reaction Dynamics Involving Ions, Radicals, Neutral and Excited Species by : Stefano Falcinelli

Download or read book Reaction Dynamics Involving Ions, Radicals, Neutral and Excited Species written by Stefano Falcinelli and published by Frontiers Media SA. This book was released on 2020-01-22 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: