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Reactions Of Aminoboron Compounds With Palladium And Platinum Complexes
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Book Synopsis Reactions of Aminoboron Compounds with Palladium and Platinum Complexes by : Christopher Martin Vogels
Download or read book Reactions of Aminoboron Compounds with Palladium and Platinum Complexes written by Christopher Martin Vogels and published by . This book was released on 1999 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reaction of Aminoboron Compounds with Palladium and Platinum Complexes by : Christopher M. Vogels
Download or read book Reaction of Aminoboron Compounds with Palladium and Platinum Complexes written by Christopher M. Vogels and published by . This book was released on 1999 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Chemistry of Platinum and Palladium: with Particular Reference to Complexes of the Elements by : F. R. Hartley
Download or read book The Chemistry of Platinum and Palladium: with Particular Reference to Complexes of the Elements written by F. R. Hartley and published by . This book was released on 1973 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Higher Oxidation State Organopalladium and Platinum Chemistry by : Allan J. Canty
Download or read book Higher Oxidation State Organopalladium and Platinum Chemistry written by Allan J. Canty and published by Springer. This book was released on 2011-02-25 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kyle A. Grice, Margaret L. Scheuermann and Karen I. Goldberg: Five-Coordinate Platinum(IV) Complexes.- Jay A. Labinger and John E. Bercaw: The Role of Higher Oxidation State Species in Platinum-Mediated C-H Bond Activation and Functionalization.- Joy M. Racowski and Melanie S. Sanford: Carbon-Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes.- Helena C. Malinakova: Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles.- Allan J. Canty and Manab Sharma: h1-Alkynyl Chemistry for the Higher Oxidation States of Palladium and Platinum.- David C. Powers and Tobias Ritter: Palladium(III) in Synthesis and Catalysis.- Marc-Etienne Moret: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d10 and s2 Centers.
Download or read book Metal Complexes written by Peter Maitlis and published by Elsevier. This book was released on 2012-12-02 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organic Chemistry of Palladium, Volume 1: Metal Complexes deals with the number of organic reactions that can be catalyzed by palladium, particularly as regards the structures bonding, and reactions of the metal complexes. The book discusses monodentate ligands which are either neutral (carbonyls, isonitriles, carbenes) or anionic (methyl, phenyl, ethynyl, hydride). The text also examines the complexes formed by 1,3-. 1,4-, and 1,5-diolefins where four carbon atoms are bound to the metal. Palladium (II) can undergo a reaction with the 1,3-dienes and results in a ?-allylic complexes where only three carbon atoms are coordinated to the metal. (The bonding situation in complexes 1,4- and 1,5-dienes, where no great interaction between the olefins are similar to that in monoolefin complexes, is straightforward), Olefins can also react with palladium chloride in protic solvents to produce ketones (or aldehydes) or organic coupling products. Some experiments conducted by Huttel et al shows that some palladium was precipitated from the reactions giving lower yields, resulting in various aldehydes and ketones as by products. The book also discusses cyclopentadienyl and benzene complexes. The text can prove beneficial for researchers, investigators and scientists whose works involve organic chemistry, analytical chemistry, physical chemistry and inorganic chemistry.
Book Synopsis Synthesis of Platinum and Palladium Compounds by Elimination Reactions by : Ian Linsay Grayson
Download or read book Synthesis of Platinum and Palladium Compounds by Elimination Reactions written by Ian Linsay Grayson and published by . This book was released on 1982 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Investigations of the Reactivity of Palladium and Platinum Complexes with Molecular Oxygen and Characterization of a Gold(III)-alkene Complex by : Margaret Louise Scheuermann
Download or read book Investigations of the Reactivity of Palladium and Platinum Complexes with Molecular Oxygen and Characterization of a Gold(III)-alkene Complex written by Margaret Louise Scheuermann and published by . This book was released on 2013 with total page 119 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the reactivity of metal complexes with molecular oxygen will facilitate the development of catalysts that can enable the widespread use of molecular oxygen as an oxidant for organic synthesis. This thesis presents two new classes of reactions between metal complexes and molecular oxygen. Neutral five-coordinate Pt complexes were tested for reactivity in the presence of molecular oxygen. In arene solution, the complexes (t̳B̳u̳̳M̳e̳2̳ nacnac)PtMe3 (1, t̳̳B̳u̳M̳e̳2̳ nacnac- = [((4-tBu-2,6-Me2C6H2)NC(CH3))2CH]-), (M̳e̳3̳ Me-nacnac)PtMe3 (2, M̳e̳3̳ Me-nacnac- = [((2,4,6-Me3C6H2)NC(CH3))2CCH3]-), and (t̳B̳u̳2̳ PyPyr)PtMe3 (3, t̳B̳u̳2̳ PyPyr- = 3,5-di-tert-butyl-2-(2-pyridyl)pyrrolide) reacted immediately with oxygen to form peroxo species in which two oxygen atoms bridge between the metal center and a carbon atom in the ligand backbone. In contrast, no reaction between ( i̳P̳r̳2̳ AnIm)PtMe3 (4a, i̳P̳r̳2̳ AnIm− = [o- C66H4-{N(C6H3 i Pr2)}(CH=NC6H3 i Pr2)]−) or (M̳e̳3̳ AnIm)PtMe3 (4b, M̳e̳̳3̳ AnIm− = [o-C6H4- {N(C6H2Me3)}(CH=NC6H2Me3)]−) and oxygen was observed. As activation of oxygen by five- coordinate PtIV species was found to involve cooperation between the metal center and the ligand, the ability of the ligand to participate in the oxygen binding appears to be a vital component. Oxygen atom transfer reactions of the novel peroxo species are also presented. In a separate study, an unusual reaction involving the activation of both molecular oxygen and a C-H bond at the same metal center was investigated. Pd(P(Ar)(tBu)2)2 (15, Ar = naphthyl) was found to react with molecular oxygen at room temperature in arene solvent to form a hydroxide dimer in which one equivalent of phosphine per Pd was lost and the remaining phosphine was cyclometalated through the naphthyl ring. At low temperature, two intermediates were observed. The nature of these intermediates suggests a mechanism involving initial reaction of Pd(P(Ar) (tBu)2)2 with O2 followed by the C-H activation step. In a final chapter unrelated to oxygen reactivity, the generation and characterization of a gold III̳-alkene complex by NMR and X-ray crystallography is presented. Such species have been proposed as intermediates in catalytic reactions but until recently none had been observed.
Book Synopsis Rearrangements and Other Reactions of Some Allylic-palladium And-platinum Compounds by : Derek John Mabbott
Download or read book Rearrangements and Other Reactions of Some Allylic-palladium And-platinum Compounds written by Derek John Mabbott and published by . This book was released on 1976 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactions of Palladium and Platinum Complexes of the Type [M2X2(PR3)4][BF4]2 by : David John Hawke
Download or read book Synthesis and Reactions of Palladium and Platinum Complexes of the Type [M2X2(PR3)4][BF4]2 written by David John Hawke and published by . This book was released on 1971 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Some Reactions of Zerovalent Platinum and Palladium Complexes by : Nuhad Salibi Akl
Download or read book Some Reactions of Zerovalent Platinum and Palladium Complexes written by Nuhad Salibi Akl and published by . This book was released on 1971 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactions of Palladium and Platinum Complexes of the Type [MF(PR3)3] [X] and [M2(OH)2(PR3)4] [X]2 by : John James McFarland
Download or read book Synthesis and Reactions of Palladium and Platinum Complexes of the Type [MF(PR3)3] [X] and [M2(OH)2(PR3)4] [X]2 written by John James McFarland and published by . This book was released on 1974 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactions of Diene Complexes of Palladium (II) and Platinum (II) by : Joseph Thomas Michalowski
Download or read book Reactions of Diene Complexes of Palladium (II) and Platinum (II) written by Joseph Thomas Michalowski and published by . This book was released on 1973 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Complexes written by Peter Maitlis and published by Academic Press. This book was released on 1971-01-28 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organic Chemistry of Palladium, Volume 1: Metal Complexes deals with the number of organic reactions that can be catalyzed by palladium, particularly as regards the structures bonding, and reactions of the metal complexes. The book discusses monodentate ligands which are either neutral (carbonyls, isonitriles, carbenes) or anionic (methyl, phenyl, ethynyl, hydride). The text also examines the complexes formed by 1,3-. 1,4-, and 1,5-diolefins where four carbon atoms are bound to the metal. Palladium (II) can undergo a reaction with the 1,3-dienes and results in a ?-allylic complexes where only three carbon atoms are coordinated to the metal. (The bonding situation in complexes 1,4- and 1,5-dienes, where no great interaction between the olefins are similar to that in monoolefin complexes, is straightforward), Olefins can also react with palladium chloride in protic solvents to produce ketones (or aldehydes) or organic coupling products. Some experiments conducted by Huttel et al shows that some palladium was precipitated from the reactions giving lower yields, resulting in various aldehydes and ketones as by products. The book also discusses cyclopentadienyl and benzene complexes. The text can prove beneficial for researchers, investigators and scientists whose works involve organic chemistry, analytical chemistry, physical chemistry and inorganic chemistry.
Book Synopsis Pd Palladium by : William P. Griffith
Download or read book Pd Palladium written by William P. Griffith and published by Springer. This book was released on 2014-03-12 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt: With platinum and rhodium, palladium is one of the most important members of the platinum metal group. The last Gmelin treatment of it was in 1942, and knowledge of its properties and chemistry has made enormous strides since then. This volume is primarily concerned with binary compounds and with the coordination complexes derived from them. Although it is a member of the nickel-palladium-platinum triad, it more closely resernblas platinum in its binary and coordination chemistry, though being a second-row transition element it displays less tendency than does platinum to assume higher oxidation states. ln heterogeneous and homogeneous catalysis, referred to at appropriate points, palladium and its complexes are of great importance in bulk and fine chemieals production, effecting a wide variety of organic transformations. The arrangement of material in this volume follows the traditional Gmelin arrangement. Within each category of compounds or complexes the material is arranged, as usual, in order of ascending metal oxidation states (e. g., palladium(ll) precedes palladium(IV)). The chemistry of the palladium-hydrogen system is so large that it merits a separate volume, so this book starts with the binary oxides and oxopalladates followed by hydroxides, hydroxo complexes and aquo complexes. Then nitrides and nitrates are treated. They are followed by the large chapters on halides and their complexes (172 pages). The largest single chapter in this volume (11 0 pages) deals with chlorides, chloropalladates and other chloro complexes.
Book Synopsis Pd Palladium by : William P. Griffith
Download or read book Pd Palladium written by William P. Griffith and published by Springer. This book was released on 2013-10-03 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: With platinum and rhodium, palladium is one of the most important members of the platinum metal group. The last Gmelin treatment of it was in 1942, and knowledge of its properties and chemistry has made enormous strides since then. This volume is primarily concerned with binary compounds and with the coordination complexes derived from them. Although it is a member of the nickel-palladium-platinum triad, it more closely resernblas platinum in its binary and coordination chemistry, though being a second-row transition element it displays less tendency than does platinum to assume higher oxidation states. ln heterogeneous and homogeneous catalysis, referred to at appropriate points, palladium and its complexes are of great importance in bulk and fine chemieals production, effecting a wide variety of organic transformations. The arrangement of material in this volume follows the traditional Gmelin arrangement. Within each category of compounds or complexes the material is arranged, as usual, in order of ascending metal oxidation states (e. g., palladium(ll) precedes palladium(IV)). The chemistry of the palladium-hydrogen system is so large that it merits a separate volume, so this book starts with the binary oxides and oxopalladates followed by hydroxides, hydroxo complexes and aquo complexes. Then nitrides and nitrates are treated. They are followed by the large chapters on halides and their complexes (172 pages). The largest single chapter in this volume (11 0 pages) deals with chlorides, chloropalladates and other chloro complexes.
Book Synopsis Synthesis and Reactions of Organometallic Complexes of Platinum and Palladium by : Edward David Dobrzynski
Download or read book Synthesis and Reactions of Organometallic Complexes of Platinum and Palladium written by Edward David Dobrzynski and published by . This book was released on 1974 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Structural Aspects and Reactions of Palladium(II) and Platinum(II) Complexes Containing Polyfunctional Ligands by : Hubertus Antoni Ankersmit
Download or read book Structural Aspects and Reactions of Palladium(II) and Platinum(II) Complexes Containing Polyfunctional Ligands written by Hubertus Antoni Ankersmit and published by . This book was released on 1996 with total page 125 pages. Available in PDF, EPUB and Kindle. Book excerpt: