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Reaction Diffusion And Solid State Chemical Kinetics
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Book Synopsis Reaction Diffusion and Solid State Chemical Kinetics by : V.I. Dybkov
Download or read book Reaction Diffusion and Solid State Chemical Kinetics written by V.I. Dybkov and published by Trans Tech Publications Ltd. This book was released on 2010-03-18 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume is indexed by Thomson Reuters BCI (WoS). This monograph deals with a physico-chemical approach to the problem of the solid-state growth of chemical compound layers and reaction-diffusion in binary heterogeneous systems formed by two solids; as well as a solid with a liquid or a gas. It is explained why the number of compound layers growing at the interface between the original phases is usually much lower than the number of chemical compounds in the phase diagram of a given binary system. For example, of the eight intermetallic compounds which exist in the aluminium-zirconium binary system, only ZrAl3 was found to grow as a separate layer at the AlZr interface under isothermal conditions. The physico-chemical approach predicts that, in most cases, the number of compound layers should not exceed two; with the main factor, resulting in the appearance of additional layers, being crack formation due to thermal expansion and volume effects.
Book Synopsis Reactions in the Solid State by : Michael E. Brown
Download or read book Reactions in the Solid State written by Michael E. Brown and published by Elsevier. This book was released on 1980-01-01 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt: The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.
Book Synopsis Principles of Solid State Chemistry by : Petr Petrovich Budnikov
Download or read book Principles of Solid State Chemistry written by Petr Petrovich Budnikov and published by . This book was released on 1968 with total page 478 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Solid State Reactions by : Hermann Schmalzried
Download or read book Solid State Reactions written by Hermann Schmalzried and published by . This book was released on 1981 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Kinetics of Solids by : Hermann Schmalzried
Download or read book Chemical Kinetics of Solids written by Hermann Schmalzried and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many different chemical processes take place inside solids or at solid surfaces and interfaces. However, their quantitative description sometimes seems difficult to understand. This book by Professor Schmalzried, author of the eminently successful Solid State Reactions; bridges the gap between the 'physical' and 'chemical' approaches to this subject because it is written in a language which both sides understand. For the first time, a comprehensive coverage of the rapidly developing field of Solid State Kinetics is available. The topics covered in this book go far beyond diffusional transport. Homogeneous and heterogeneous solid-state reactions, phase transitions or the influence of external fields are also treated in detail. With this background, the author explains e.g. charge transport mechanisms in ionic conductors, principles of sensor technology, or oxidation processes clearly and comprehensibly. This book is a must for every solid-state chemist and an indispensable tool for academic and industrial readers alike. From reviews: 'a first-rate reference work that a must for any science library' (J. Am Chem. Soc.) 'can be recommended without restrictions ...' (Z. Phys. Chem.)
Book Synopsis An Introduction to Solid State Diffusion by : Richard J. Borg
Download or read book An Introduction to Solid State Diffusion written by Richard J. Borg and published by Elsevier. This book was released on 2012-12-02 with total page 377 pages. Available in PDF, EPUB and Kindle. Book excerpt: The energetics and mechanisms of diffusion control the kinetics of such diverse phenomena as the fabrication of semiconductors and superconductors, the tempering of steel, geological metamorphism, the precipitation hardening of nonferrous alloys and corrosion of metals and alloys. This work explains the fundamentals of diffusion in the solid state at a level suitable for upper-level undergraduate and beginning graduate students in materials science, metallurgy, mineralogy, and solid state physics and chemistry. A knowledge of physical chemistry such as is generally provided by a one-year undergraduate course is a prerequisite, though no detailed knowledge of solid state physics or crystallography is required.
Book Synopsis Reactions in the Solid State by : Michael E. Brown
Download or read book Reactions in the Solid State written by Michael E. Brown and published by Elsevier Science. This book was released on 1980-01-15 with total page 339 pages. Available in PDF, EPUB and Kindle. Book excerpt: The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.
Book Synopsis Treatise on Solid State Chemistry by : N. Hannay
Download or read book Treatise on Solid State Chemistry written by N. Hannay and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 731 pages. Available in PDF, EPUB and Kindle. Book excerpt: The last quarter-century has been marked by the extremely rapid growth of the solid-state sciences. They include what is now the largest subfield of physics, and the materials engineering sciences have likewise flourished. And, playing an active role throughout this vast area of science and engineer ing have been very large numbers of chemists. Yet, even though the role of chemistry in the solid-state sciences has been a vital one and the solid-state sciences have, in turn, made enormous contributions to chemical thought, solid-state chemistry has not been recognized by the general body of chemists as a major subfield of chemistry. Solid-state chemistry is not even well defined as to content. Some, for example, would have it include only the quantum chemistry of solids and would reject thermodynamics and phase equilibria; this is nonsense. Solid-state chemistry has many facets, and one of the purposes of this Treatise is to help define the field. Perhaps the most general characteristic of solid-state chemistry, and one which helps differentiate it from solid-state physics, is its focus on the chemical composition and atomic configuration of real solids and on the relationship of composition and structure to the chemical and physical properties of the solid. Real solids are usually extremely complex and exhibit almost infinite variety in their compositional and structural features.
Book Synopsis Fluid-Solid Reactions by : H. Y. Sohn
Download or read book Fluid-Solid Reactions written by H. Y. Sohn and published by Elsevier. This book was released on 2020-08-12 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluid-Solid Reactions, Second Edition takes a detailed and thorough look at the scope of fluid-solid reaction systems, focusing on the four phenomena: external mass transfer, pore diffusion, chemical reaction, and adsorption/desorption. This completely revised new edition builds on the classic original edition through the introduction of cutting-edge new theories and applications, including the formulation and application of a new and convenient law that governs fluid-solid reaction kinetics. This book will be of primary interest to practicing engineers engaged in process research, development, and design in the many fields where fluid-solid reactions are critical to workflow and research. Fluid-solid reactions play a major role in the technology of most industrialized nations. These reactions encompass a very broad field, including the extraction of metals from their ores, the combustion of solid fuels, coal gasification, and the incineration of solid refuse. Features 50% new and revised content, arming researchers with the latest developments in the field Details a new unified approach to modeling the rates of fluid-solid reaction systems Authored by one of the world’s foremost experts on fluid-solid reactions and their applications in the field
Book Synopsis Handbook of Solid State Diffusion: Volume 1 by : Aloke Paul
Download or read book Handbook of Solid State Diffusion: Volume 1 written by Aloke Paul and published by Elsevier. This book was released on 2017-04-11 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Solid State Diffusion, Volume 1: Diffusion Fundamentals and Techniques covers the basic fundamentals, techniques, applications, and latest developments in the area of solid-state diffusion, offering a pedagogical understanding for students, academicians, and development engineers. Both experimental techniques and computational methods find equal importance in the first of this two-volume set. Volume 1 covers the fundamentals and techniques of solid-state diffusion, beginning with a comprehensive discussion of defects, then different analyzing methods, and finally concluding with an exploration of the different types of modeling techniques. Presents a handbook with a short mathematical background and detailed examples of concrete applications of the sophisticated methods of analysis Enables readers to learn the basic concepts of experimental approaches and the computational methods involved in solid-state diffusion Covers bulk, thin film, and nanomaterials Introduces the problems and analysis in important materials systems in various applications Collates contributions from academic and industrial problems from leading scientists involved in developing key concepts across the globe
Book Synopsis Lectures on Kinetic Processes in Materials by : Han-Ill Yoo
Download or read book Lectures on Kinetic Processes in Materials written by Han-Ill Yoo and published by Springer Nature. This book was released on 2020-05-09 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides beginning graduate or senior-level undergraduate students in materials disciplines with a primer of the fundamental and quantitative ideas on kinetic processes in solid materials. Kinetics is concerned with the rate of change of the state of existence of a material system under thermodynamic driving forces. Kinetic processes in materials typically involve chemical reactions and solid state diffusion in parallel or in tandem. Thus, mathematics of diffusion in continuum is first dealt with in some depth, followed by the atomic theory of diffusion and a brief review of chemical reaction kinetics. Chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions are examined. Through this course of learning, a student will become able to predict quantitatively how fast a kinetic process takes place, to understand the inner workings of the process, and to design the optimal process of material state change. Provides students with the tools to predict quantitatively how fast a kinetic process takes place and solve other diffusion related problems; Learns fundamental and quantitative ideas on kinetic processes in solid materials; Examines chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions, among others; Contains end-of chapter exercise problems to help reinforce students' grasp of the concepts presented within each chapter.
Book Synopsis Kinetics of Chemical Reactions by : Guy B. Marin
Download or read book Kinetics of Chemical Reactions written by Guy B. Marin and published by John Wiley & Sons. This book was released on 2019-04-29 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second, extended and updated edition presents the current state of kinetics of chemical reactions, combining basic knowledge with results recently obtained at the frontier of science. Special attention is paid to the problem of the chemical reaction complexity with theoretical and methodological concepts illustrated throughout by numerous examples taken from heterogeneous catalysis combustion and enzyme processes. Of great interest to graduate students in both chemistry and chemical engineering.
Book Synopsis Chemistry in Motion by : Bartosz A. Grzybowski
Download or read book Chemistry in Motion written by Bartosz A. Grzybowski and published by John Wiley & Sons. This book was released on 2009-04-03 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: Change and motion define and constantly reshape the world around us, on scales from the molecular to the global. In particular, the subtle interplay between chemical reactions and molecular transport gives rise to an astounding richness of natural phenomena, and often manifests itself in the emergence of intricate spatial or temporal patterns. The underlying theme of this book is that by “setting chemistry in motion” in a proper way, it is not only possible to discover a variety of new phenomena, in which chemical reactions are coupled with diffusion, but also to build micro-/nanoarchitectures and systems of practical importance. Although reaction and diffusion (RD) processes are essential for the functioning of biological systems, there have been only a few examples of their application in modern micro- and nanotechnology. Part of the problem has been that RD phenomena are hard to bring under experimental control, especially when the system’s dimensions are small. Ultimately this book will guide the reader through all the aspects of these systems – from understanding the basics to practical hints and then to applications and interpretation of results. Topics covered include: An overview and outlook of both biological and man-made reaction-diffusion systems. The fundamentals and mathematics of diffusion and chemical reactions. Reaction-diffusion equations and the methods of solving them. Spatial control of reaction-diffusion at small scales. Micro- and nanofabrication by reaction-diffusion. Chemical clocks and periodic precipitation structures. Reaction-diffusion in soft materials and at solid interfaces. Microstructuring of solids using RD. Reaction-diffusion for chemical amplification and sensing. RD in three dimensions and at the nanoscale, including nanosynthesis. This book is aimed at all those who are interested in chemical processes at small scales, especially physical chemists, chemical engineers, and material scientists. The book can also be used for one-semester, graduate elective courses in chemical engineering, materials science, or chemistry classes.
Book Synopsis Diffusion-Limited Reactions by : S.A. Rice
Download or read book Diffusion-Limited Reactions written by S.A. Rice and published by Elsevier. This book was released on 1985-03-01 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: Diffusion-Limited Reactions
Book Synopsis Chemical Kinetics and Reaction Dynamics by : Santosh K. Upadhyay
Download or read book Chemical Kinetics and Reaction Dynamics written by Santosh K. Upadhyay and published by Springer Science & Business Media. This book was released on 2007-04-29 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.
Book Synopsis Modern Aspects of Diffusion-Controlled Reactions by : E. Kotomin
Download or read book Modern Aspects of Diffusion-Controlled Reactions written by E. Kotomin and published by Elsevier. This book was released on 1996-10-24 with total page 611 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered abnormal from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions. The book demonstrates that incorporation of the reaction-induced spatial correlations of similar reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the correlation lengths and critical exponents similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data.
Book Synopsis An Introduction to Solid State Diffusion by : Richard John Borg
Download or read book An Introduction to Solid State Diffusion written by Richard John Borg and published by . This book was released on 1988 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: The energetics and mechanisms of diffusion control the kinetics of such diverse phenomena as the fabrication of semiconductors and superconductors, the tempering of steel, geological metamorphism, the precipitation hardening of nonferrous alloys and corrosion of metals and alloys. This work explains the fundamentals of diffusion in the solid state at a level suitable for upper-level undergraduate and beginning graduate students in materials science, metallurgy, mineralogy, and solid state physics and chemistry. A knowledge of physical chemistry such as is generally provided by a one-year undergraduate course is a prerequisite, though no detailed knowledge of solid state physics or crystallography is required.
