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Quantifying The Reactive Uptake Of Oh By Organic Aerosols In Acontinuous Flow Stirred Tank Reactor
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Book Synopsis Quantifying the Reactive Uptake of OH by Organic Aerosols in AContinuous Flow Stirred Tank Reactor by :
Download or read book Quantifying the Reactive Uptake of OH by Organic Aerosols in AContinuous Flow Stirred Tank Reactor written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Here we report a new method for measuring the heterogeneous chemistry of submicron organic aerosol particles using a continuous flow stirred tank reactor. This approach is designed to quantify the real time heterogeneous kinetics, using a relative rate method, under conditions of low oxidant concentration and long reaction times that more closely mimic the real atmosphere. A general analytical expression, which couples the aerosol chemistry with the flow dynamics in the chamber is developed and applied to the heterogeneous oxidation of squalane particles by hydroxyl radicals (OH) in the presence of O2. The particle phase reaction is monitored via photoionization aerosol mass spectrometry and yields a reactive uptake coefficient of 0.51+-0.10, using OH concentrations of 1-7x108 molec cdot cm-3 and reaction times of 1.5+-3 hours. This uptake coefficient is larger than that found for the reaction carried out under high OH concentrations (~;;1x1010 molec cdot cm-3) and short reaction times in a flow tube reactor. This difference suggests that oxidant concentration and reaction time are not interchangeable quantities in reactions of organic aerosols with radicals. In general, this approach provides a new way to examine how the chemical aging of organic particles measured at short reaction times and high oxidant concentrations in flow tubes might differ from the long reaction times and low oxidant levels found in the real atmosphere.
Book Synopsis Photoionization and Photo-Induced Processes in Mass Spectrometry by : Ralf Zimmermann
Download or read book Photoionization and Photo-Induced Processes in Mass Spectrometry written by Ralf Zimmermann and published by John Wiley & Sons. This book was released on 2021-07-06 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides comprehensive coverage of laser-induced ionization processes for mass spectrometry analysis Drawing on the expertise of the leading academic and industrial research groups involved in the development of photoionization methods for mass spectrometry, this reference for analytical scientists covers both the theory and current applications of photo-induced ionization processes. It places widely used techniques such as MALDI side by side with more specialist approaches such as REMPI and RIMS, and discusses leading edge developments in ultrashort laser pulse desorption, to give readers a complete picture of the state of the technology. Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications starts with a complete overview of the fundamentals of the technique, covering the basics of the gas phase ionization as well as those of laser desorption and ablation, pulse photoionization, and single particle ionization. Numerous application examples from different analytical fields are described that showcase the power and the wide scope of photo ionization in mass spectrometry. -The first general reference book on photoionization techniques for mass spectrometry -Examines technologies and applications of gas phase resonance-enhanced multiphoton ionization mass spectrometry (REMPI-MS) and gas phase resonance ionization mass spectrometry (RIMS) -Provides complete coverage of popular techniques like MALDI -Discusses the current and potential applications of each technology, focusing on process and environmental analysis Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications is an excellent book for spectroscopists, analytical chemists, photochemists, physical chemists, and laser specialists.
Book Synopsis Physical Chemistry of Gas-Liquid Interfaces by : Jennifer A. Faust
Download or read book Physical Chemistry of Gas-Liquid Interfaces written by Jennifer A. Faust and published by Elsevier. This book was released on 2018-05-31 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical Chemistry of Gas-Liquid Interfaces, the first volume in the Developments in Physical & Theoretical Chemistry series, addresses the physical chemistry of gas transport and reactions across liquid surfaces. Gas–liquid interfaces are all around us, especially within atmospheric systems such as sea spry aerosols, cloud droplets, and the surface of the ocean. Because the reaction environment at liquid surfaces is completely unlike bulk gas or bulk liquid, chemists must readjust their conceptual framework when entering this field. This book provides the necessary background in thermodynamics and computational and experimental techniques for scientists to obtain a thorough understanding of the physical chemistry of liquid surfaces in complex, real-world environments. - 2019 PROSE Awards - Winner: Category: Chemistry and Physics: Association of American Publishers - Provides an interdisciplinary view of the chemical dynamics of liquid surfaces, making the content of specific use to physical chemists and atmospheric scientists - Features 100 figures and illustrations to underscore key concepts and aid in retention for young scientists in industry and graduate students in the classroom - Helps scientists who are transitioning to this field by offering the appropriate thermodynamic background and surveying the current state of research
Book Synopsis OH-initiated Heterogeneous Oxidation of Atmospheric Organic Aerosols by : Ingrid Jennifer George
Download or read book OH-initiated Heterogeneous Oxidation of Atmospheric Organic Aerosols written by Ingrid Jennifer George and published by . This book was released on 2009 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemical aging of organic aerosols by OH-initiated heterogeneous oxidation was investigated using both model organic and ambient aerosol particles. Organic aerosol particles were exposed to OH radicals in an aerosol flow tube and the modification of their chemical composition and particle properties was studied. Overall, this work has shown that OH-initiated heterogeneous oxidation enhanced the degree of oxidation and the Cloud Condensation Nucleus (CCN) activity of organic aerosol particles for equivalent OH exposure timescales of a few days to a week.The modification of the hygroscopicity of model primary and secondary organic aerosols from chemical aging was investigated by measuring the CCN activity of organic aerosols exposed to OH radicals. Primary organic aerosols, initially CCN inactive, became as CCN active as secondary organic aerosols due to heterogeneous reaction, where surface tension reduction played a major role. The CCN activity for model secondary organic aerosols was also enhanced due to OH oxidation, but changes were less dramatic than for the model primary organic aerosols.Aerosol Mass Spectrometer (AMS) measurements showed that the heterogeneous uptake kinetics of OH radicals onto model primary organic aerosols was efficient. The heterogeneous reaction of organic aerosols with OH led to the production of high molecular weight particle-phase species with the addition of multiple oxygenated functional groups. These results were consistent with the observed increase in particle density with OH exposure. With the exception of solid organic aerosols, the particle volume and mass of organic particles were reduced by less than 20% from OH oxidation at high OH exposures due to volatilization of particle-phase reaction products.The degree of oxidation of the organic fraction of urban ambient aerosols was significantly enhanced for an equivalent atmospheric OH exposure time of 4 days for a daily average atmospheric OH concentration of 2x10 6 cm-3. Ambient aerosol particles sampled from a sparsely populated, forested region were initially more oxygenated than the urban aerosol particles and did not become more oxidized from reaction with OH radicals.
Book Synopsis Development of a New Technique to Study the Kinetics of Hydroxyl Radical Uptake on Micron-sized Organic Aerosols by : Lucas Jonathan Neil
Download or read book Development of a New Technique to Study the Kinetics of Hydroxyl Radical Uptake on Micron-sized Organic Aerosols written by Lucas Jonathan Neil and published by . This book was released on 2010 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: The importance of the hydroxyl radical (OH) to tropospheric chemistry is well known. The radicals' ability to react with most atmospheric trace gases allows it to act as the main removal mechanism for these gases. Due to the highly reactive nature of OH, the oxidizing capacity of the atmosphere is often defined simply by its concentration. Owing to its significant role, knowledge of all OH chemistry, homogeneous and heterogeneous, is important to understanding the chemistry of the troposphere. In order to accurately predict future levels of OH and other trace gases, a thorough understanding of all processes and variables involved in the emission and sequestering of these compounds is essential. The gas-phase chemistry of OH is well known and has been extensively characterized. The one process that scientists are still trying to fully understand is its involvement in heterogeneous chemistry. Some studies have suggested that the inclusion of OH heterogeneous chemistry is important to fully model tropospheric chemistry, while other studies have suggested that it can be neglected entirely. It is therefore important to study and understand the conditions in which heterogeneous chemistry is significant. In order to do this accurately, scientists must first understand the process and magnitude of the uptake of OH onto atmospherically relevant surfaces. The main objective of this work was the development of a new analytical tool for the study of heterogeneous hydroxyl radical reactions. To this end, experiments were conducted to determine the most efficient approach to couple a low pressure aerosol flow tube (LP-AFT) to a chemical ionisation mass spectrometer (CIMS). The use of CIMS allowed for the accurate detection and quantification of hydroxyl radicals. Through iterative experimentation the system was designed and became operational. Experimental work focused on laboratory studies of reaction kinetics, with data reported in this work representing the reactions of OH with model atmospheric aerosols. The uptake of OH on organic aerosols was examined using the newly developed LP-AFT-CIMS system at standard temperature. Liquid oleic acid particles were used to mimic atmospherically relevant particles. The uptake coefficient, [gamma], on oleic acid particles was determined to be 0.49 ± 0.08 for a log-normally distributed aerosol at ~400nm. This value is in very good agreement with currently published data. However, the overall error of this method (~16%) is observed to be lower than other currently available methods, which have errors ranging from 20 - 30%. It is postulated that the mass accommodation coefficient, [alpha], for OH radicals on organic surfaces approaches this value under standard atmospheric conditions. It's also suggested that under the correct conditions the heterogeneous loss of OH could contribute to the overall budget of the OH radical. Further atmospheric implications of this reaction are discussed.
Book Synopsis Sea Salt Aerosol Production by : Ernie R. Lewis
Download or read book Sea Salt Aerosol Production written by Ernie R. Lewis and published by American Geophysical Union. This book was released on 2004-01-09 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: Published by the American Geophysical Union as part of the Geophysical Monograph Series, Volume 152. Sea salt aerosol (SSA) exerts a major influence over a broad reach of geophysics. It is important to the physics and chemistry of the marine atmosphere and to marine geochemistry and biogeochemistry generally. It affects visibility, remote sensing, atmospheric chemistry, and air quality. Sea salt aerosol particles interact with other atmospheric gaseous and aerosol constituents by acting as sinks for condensable gases and suppressing new particle formation, thus influencing the size distribution of these other aerosols and more broadly influencing the geochemical cycles of substances with which they interact. As the key aerosol constituent over much of Earth's surface at present, and all the more so in pre-industrial times, SSA is central to description of Earth's aerosol burden.
Book Synopsis Ocean-Atmosphere Interactions of Gases and Particles by : Peter S. Liss
Download or read book Ocean-Atmosphere Interactions of Gases and Particles written by Peter S. Liss and published by Springer. This book was released on 2013-12-18 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: The oceans and atmosphere interact through various processes, including the transfer of momentum, heat, gases and particles. In this book leading international experts come together to provide a state-of-the-art account of these exchanges and their role in the Earth-system, with particular focus on gases and particles. Chapters in the book cover: i) the ocean-atmosphere exchange of short-lived trace gases; ii) mechanisms and models of interfacial exchange (including transfer velocity parameterisations); iii) ocean-atmosphere exchange of the greenhouse gases carbon dioxide, methane and nitrous oxide; iv) ocean atmosphere exchange of particles and v) current and future data collection and synthesis efforts. The scope of the book extends to the biogeochemical responses to emitted / deposited material and interactions and feedbacks in the wider Earth-system context. This work constitutes a highly detailed synthesis and reference; of interest to higher-level university students (Masters, PhD) and researchers in ocean-atmosphere interactions and related fields (Earth-system science, marine / atmospheric biogeochemistry / climate). Production of this book was supported and funded by the EU COST Action 735 and coordinated by the International SOLAS (Surface Ocean- Lower Atmosphere Study) project office.
Book Synopsis Phosphorus: Polluter and Resource of the Future by : Christian Schaum
Download or read book Phosphorus: Polluter and Resource of the Future written by Christian Schaum and published by IWA Publishing. This book was released on 2018-03-15 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive book provides an up-to-date and international approach that addresses the Motivations, Technologies and Assessment of the Elimination and Recovery of Phosphorus from Wastewater. This book is part of the Integrated Environmental Technology Series.
Book Synopsis Aerosol Science and Technology by : David S. Ensor
Download or read book Aerosol Science and Technology written by David S. Ensor and published by RTI Press. This book was released on 2011-10-06 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosol Science and Technology: History and Reviews captures an exciting slice of history in the evolution of aerosol science. It presents in-depth biographies of four leading international aerosol researchers and highlights pivotal research institutions in New York, Minnesota, and Austria. One collection of chapters reflects on the legacy of the Pasadena smog experiment, while another presents a fascinating overview of military applications and nuclear aerosols. Finally, prominent researchers offer detailed reviews of aerosol measurement, processes, experiments, and technology that changed the face of aerosol science. This volume is the third in a series and is supported by the American Association for Aerosol Research (AAAR) History Working Group, whose goal is to produce archival books from its symposiums on the history of aerosol science to ensure a lasting record. It is based on papers presented at the Third Aerosol History Symposium on September 8 and 9, 2006, in St. Paul, Minnesota, USA.
Book Synopsis Chemical Reactor Omnibook- soft cover by : Octave Levenspiel
Download or read book Chemical Reactor Omnibook- soft cover written by Octave Levenspiel and published by Lulu.com. This book was released on 2013 with total page 731 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Omnibook aims to present the main ideas of reactor design in a simple and direct way. it includes key formulas, brief explanations, practice exercises, problems from experience and it skims over the field touching on all sorts of reaction systems. Most important of all it tries to show the reader how to approach the problems of reactor design and what questions to ask. In effect it tries to show that a common strategy threads its way through all reactor problems, a strategy which involves three factors: identifying the flow patter, knowing the kinetics, and developing the proper performance equation. It is this common strategy which is the heart of Chemical Reaction Engineering and identifies it as a distinct field of study.
Book Synopsis Standard Methods for the Examination of Water and Wastewater by : American Public Health Association
Download or read book Standard Methods for the Examination of Water and Wastewater written by American Public Health Association and published by . This book was released on 1981 with total page 1254 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Heterogeneous and Liquid Phase Processes by : Peter Warneck
Download or read book Heterogeneous and Liquid Phase Processes written by Peter Warneck and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: The "European Experiment on the Transport and Transformation of Environmentally Relevant Trace Constituents over Europe" (EUROTRAC) was established in 1986 to tackle the scientific problem and combine the expertise, knowledge and resources in Europe, in order to apply them over a large region covering the greater part of the continent. EUROTRAC is a coordinated multidisciplinary scientific research project involving field measurements, laboratory studies, instrument development and development of comprehensive computer models for the simulation of the physical and chemical processes in the lower atmosphere.
Book Synopsis Air Emissions from Animal Feeding Operations by : National Research Council
Download or read book Air Emissions from Animal Feeding Operations written by National Research Council and published by National Academies Press. This book was released on 2003-04-07 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: Air Emissions from Animal Feeding Operations: Current Knowledge, Future Needs discusses the need for the U.S. Environmental Protection Agency to implement a new method for estimating the amount of ammonia, nitrous oxide, methane, and other pollutants emitted from livestock and poultry farms, and for determining how these emissions are dispersed in the atmosphere. The committee calls for the EPA and the U.S. Department of Agriculture to establish a joint council to coordinate and oversee short - and long-term research to estimate emissions from animal feeding operations accurately and to develop mitigation strategies. Their recommendation was for the joint council to focus its efforts first on those pollutants that pose the greatest risk to the environment and public health.
Book Synopsis Innovative Wastewater Treatment & Resource Recovery Technologies: Impacts on Energy, Economy and Environment by : Juan M. Lema
Download or read book Innovative Wastewater Treatment & Resource Recovery Technologies: Impacts on Energy, Economy and Environment written by Juan M. Lema and published by IWA Publishing. This book was released on 2017-06-15 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces the 3R concept applied to wastewater treatment and resource recovery under a double perspective. Firstly, it deals with innovative technologies leading to: Reducing energy requirements, space and impacts; Reusing water and sludge of sufficient quality; and Recovering resources such as energy, nutrients, metals and chemicals, including biopolymers. Besides targeting effective C,N&P removal, other issues such as organic micropollutants, gases and odours emissions are considered. Most of the technologies analysed have been tested at pilot- or at full-scale. Tools and methods for their Economic, Environmental, Legal and Social impact assessment are described. The 3R concept is also applied to Innovative Processes design, considering different levels of innovation: Retrofitting, where novel units are included in more conventional processes; Re-Thinking, which implies a substantial flowsheet modification; and Re-Imagining, with completely new conceptions. Tools are presented for Modelling, Optimising and Selecting the most suitable plant layout for each particular scenario from a holistic technical, economic and environmental point of view.
Book Synopsis Chemistry of Multiphase Atmospheric Systems by : Wolfgang Jaeschke
Download or read book Chemistry of Multiphase Atmospheric Systems written by Wolfgang Jaeschke and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 773 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rapidly increasing interest in the problems of air pollution and source-receptor relationships has led to a significant expansion of knowledge in the field of atmospheric chemistry. In general the chemistry of atmospheric trace constituents is governed by the oxygen content of the atmosphere. Upon entering the atmosphere in a more or less reduced state, trace substances are oxidized via various pathways and the generated products are often precursors of acidic compounds. Beside oxidation processes occurring in the gas phase, gaseous compounds are often converted into solid aerosol particles. The various steps within gas-to-particle conversion are constantly interacting with condensation processes, which are caused by the tropospheric water content. Thus in addition to the gaseous state, a liquid and solid state exists within the troposphere. The solid phase consists of atmospheric conversion products or fly ash and mineral dust. The liquid phase consists of water, conversion products and soluble compounds. The chemistry occurring within this system is often referred to as hydrogeneous chemistry. The chemist interprets this term, however, more strictly as reactions which occur only at an interphase between phases. This, however, is not always what happens in the atmosphere. There are indeed heterogeneous processes such as reactions occurring on the surface of dry aerosol particles. But apart from these, we must focus as well on reactions in the homogeneous phase, which are single steps of consecutive reactions running through various phases.
Book Synopsis Frontiers in Chemical Engineering by : National Research Council
Download or read book Frontiers in Chemical Engineering written by National Research Council and published by National Academies Press. This book was released on 1988-02-01 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the next 10 to 15 years, chemical engineers have the potential to affect every aspect of American life and promote the scientific and industrial leadership of the United States. Frontiers in Chemical Engineering explores the opportunities available and gives a blueprint for turning a multitude of promising visions into realities. It also examines the likely changes in how chemical engineers will be educated and take their place in the profession, and presents new research opportunities.
Book Synopsis Ocean-Atmosphere Interactions by : Y. Toba
Download or read book Ocean-Atmosphere Interactions written by Y. Toba and published by The Rosen Publishing Group. This book was released on 2003-08-31 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents an up-to-date analysis of ocean-atmosphere interaction. Well known experts examine diverse subjects such as ocean surface waves, air-sea exchange processes, ocean surface mixed layer, water-mass formation, as well as general circulation of the oceans, El Nino and Southern Oscillation (ENSO), and the deep-ocean circulation. Other areas described are basic dynamics, data analysis techniques, numerical modelling, and remote sensing. This book is primarily aimed at graduate and senior undergraduate courses in the area of ocean-atmosphere research.
