Purification and Chemical Control of Molten Li2BeF4 for a Fluoride Salt Cooled Reactor

Download Purification and Chemical Control of Molten Li2BeF4 for a Fluoride Salt Cooled Reactor PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 263 pages
Book Rating : 4.:/5 (915 download)

DOWNLOAD NOW!


Book Synopsis Purification and Chemical Control of Molten Li2BeF4 for a Fluoride Salt Cooled Reactor by :

Download or read book Purification and Chemical Control of Molten Li2BeF4 for a Fluoride Salt Cooled Reactor written by and published by . This book was released on 2015 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Out of the many proposed generation IV, high-temperature reactors, the molten salt reactor (MSR) is one of the most promising. The first large scale MSR, the molten salt reactor experiment (MSRE), operated from 1965 to 1969 using Li2BeF4, or flibe, as a coolant and solvent for uranium fluoride fuel, at maximum temperatures of 654°C, for over 15000 hours. The MSRE experienced no concept breaking surprises and was considered a success. Newly proposed designs of molten salt reactors use solid fuels, making them less exotic compared to the MSRE. However, any molten salt reactor will require a great deal of research pertaining to the chemical and mechanical mastery of molten salts in order to prepare it for commercialization. To supplement the development of new molten salt reactors, approximately 100 kg of flibe was purified using the standard hydrofluorination process. Roughly half of the purified salt was lithium-7 enriched salt from the secondary loop of the MSRE. Purification rids the salt of impurities and reduces its capacity for corrosion, also known as the redox potential. The redox potential of flibe was measured at various stages of purification for the first time using a dynamic beryllium reference electrode. These redox measurements have been superimposed with metal impurities measurements found by neutron activation analysis. Lastly, reductions of flibe with beryllium metal have been investigated. Over reductions have been performed, which have shown to decrease redox potential while seemingly creating a beryllium-beryllium halide system. Recommendations of the lowest advisable redox potential for corrosion tests are included along with suggestions for future work.

Purification and Chemical Control of Molten Li2BeF4 for a Fluoride Salt Cooled Reactor

Download Purification and Chemical Control of Molten Li2BeF4 for a Fluoride Salt Cooled Reactor PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (932 download)

DOWNLOAD NOW!


Book Synopsis Purification and Chemical Control of Molten Li2BeF4 for a Fluoride Salt Cooled Reactor by :

Download or read book Purification and Chemical Control of Molten Li2BeF4 for a Fluoride Salt Cooled Reactor written by and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Out of the many proposed generation IV, high-temperature reactors, the molten salt reactor (MSR) is one of the most promising. The first large scale MSR, the molten salt reactor experiment (MSRE), operated from 1965 to 1969 using Li2BeF4, or flibe, as a coolant and solvent for uranium fluoride fuel, at maximum temperatures of 654°C, for over 15000 hours. The MSRE experienced no concept breaking surprises and was considered a success. Newly proposed designs of molten salt reactors use solid fuels, making them less exotic compared to the MSRE. However, any molten salt reactor will require a great deal of research pertaining to the chemical and mechanical mastery of molten salts in order to prepare it for commercialization. To supplement the development of new molten salt reactors, approximately 100 kg of flibe was purified using the standard hydrofluorination process. Roughly half of the purified salt was lithium-7 enriched salt from the secondary loop of the MSRE. Purification rids the salt of impurities and reduces its capacity for corrosion, also known as the redox potential. The redox potential of flibe was measured at various stages of purification for the first time using a dynamic beryllium reference electrode. These redox measurements have been superimposed with metal impurities measurements found by neutron activation analysis. Lastly, reductions of flibe with beryllium metal have been investigated. Over reductions have been performed, which have shown to decrease redox potential while seemingly creating a beryllium-beryllium halide system. Recommendations of the lowest advisable redox potential for corrosion tests are included along with suggestions for future work.

Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts

Download Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts PDF Online Free

Author :
Publisher : National Academies Press
ISBN 13 : 0309056845
Total Pages : 148 pages
Book Rating : 4.3/5 (9 download)

DOWNLOAD NOW!


Book Synopsis Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts by : National Research Council

Download or read book Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts written by National Research Council and published by National Academies Press. This book was released on 1997-03-26 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses the technical alternatives for cleanup of radioactive fluoride salts that were the fuel for the Molten Salt Reactor Experiment, a novel nuclear reactor design that was tested in the 1960s at the Oak Ridge National Laboratory in Tennessee. These fluoride salts pose an unusual cleanup challenge. The book discusses alternatives for processing and removing the salts based on present knowledge of fluoride salt chemistry and nuclear reactions of the radioactive constituents.

The Chemistry and Thermodynamics of Molten Salt Reactor Fluoride Solutions

Download The Chemistry and Thermodynamics of Molten Salt Reactor Fluoride Solutions PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 37 pages
Book Rating : 4.3/5 (91 download)

DOWNLOAD NOW!


Book Synopsis The Chemistry and Thermodynamics of Molten Salt Reactor Fluoride Solutions by :

Download or read book The Chemistry and Thermodynamics of Molten Salt Reactor Fluoride Solutions written by and published by . This book was released on 1965 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Enhanced Molten Salt Purification by Electrochemical Methods

Download Enhanced Molten Salt Purification by Electrochemical Methods PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (727 download)

DOWNLOAD NOW!


Book Synopsis Enhanced Molten Salt Purification by Electrochemical Methods by :

Download or read book Enhanced Molten Salt Purification by Electrochemical Methods written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten salts are considered within the Very High Temperature Reactor program as heat transfer media because of their intrinsically favorable thermo-physical properties at temperatures starting from 300 C and extending up to 1200 C. In this context two main applications of molten salt are considered, both involving fluoride-based materials: as primary coolants for a heterogeneous fuel reactor core and as secondary heat transport medium to a helium power cycle for electricity generation or other processing plants, such as hydrogen production. The reference design concept here considered is the Advanced High Temperature Reactor (AHTR), which is a large passively safe reactor that uses solid graphite-matrix coated-particle fuel (similar to that used in gas-cooled reactors) and a molten salt primary and secondary coolant with peak temperatures between 700 and 1000 C, depending upon the application. However, the considerations included in this report apply to any high temperature system employing fluoride salts as heat transfer fluid, including intermediate heat exchangers for gas-cooled reactor concepts and homogenous molten salt concepts, and extending also to fast reactors, accelerator-driven systems and fusion energy systems. The most important initial requirement for heat transfer test of molten salt systems is the establishment of reference coolant materials to use in the experiments. An earlier report produced within the same project (INL/EXT-10-18297) highlighted how thermo-physical properties of the materials that directly impact the heat transfer behavior are strongly correlated to the of composition and impurities concentration of the melt. It is therefore essential to establish laboratory techniques that can measure the melt composition, and to develop purification methods that would allow the production of large quantities of coolant with the desired purity. A companion report titled 'An experimental test plan for the characterization of molten salt thermo-chemistry properties in heat transport systems' describes the options available to reach such objectives and contains extended references to published work. The report highlights how electrochemical methods are the most promising techniques for the development of instrumentation aimed at the measurement of melts composition and for enhanced purification systems. The purpose of this work is to summarize preliminary experimental activities performed at the INL Safety and Tritium Applied Research facility in support of the development of electrochemistry based instrumentation and purification systems. The experiments have been focused on the LiF-BeF2 eutectic (67 and 33 mol%, respectively), also known as flibe.

Corrosion of Candidate Materials in Molten FLiBe Salt for Application in Fluoride-salt Cooled Reactors

Download Corrosion of Candidate Materials in Molten FLiBe Salt for Application in Fluoride-salt Cooled Reactors PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 215 pages
Book Rating : 4.:/5 (13 download)

DOWNLOAD NOW!


Book Synopsis Corrosion of Candidate Materials in Molten FLiBe Salt for Application in Fluoride-salt Cooled Reactors by : Thomas Jonathan Chrobak

Download or read book Corrosion of Candidate Materials in Molten FLiBe Salt for Application in Fluoride-salt Cooled Reactors written by Thomas Jonathan Chrobak and published by . This book was released on 2018 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt:

TMS 2017 146th Annual Meeting & Exhibition Supplemental Proceedings

Download TMS 2017 146th Annual Meeting & Exhibition Supplemental Proceedings PDF Online Free

Author :
Publisher : Springer
ISBN 13 : 3319514938
Total Pages : 777 pages
Book Rating : 4.3/5 (195 download)

DOWNLOAD NOW!


Book Synopsis TMS 2017 146th Annual Meeting & Exhibition Supplemental Proceedings by : The Minerals, Metals & Materials Society TMS

Download or read book TMS 2017 146th Annual Meeting & Exhibition Supplemental Proceedings written by The Minerals, Metals & Materials Society TMS and published by Springer. This book was released on 2017-02-18 with total page 777 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection features papers presented at the 146th Annual Meeting & Exhibition of The Minerals, Metals & Materials Society.

Disposition of the Fluoride Fuel and Flush Salts from the Molten Salt Reactor Experiment at Oak Ridge National Laboratory

Download Disposition of the Fluoride Fuel and Flush Salts from the Molten Salt Reactor Experiment at Oak Ridge National Laboratory PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (88 download)

DOWNLOAD NOW!


Book Synopsis Disposition of the Fluoride Fuel and Flush Salts from the Molten Salt Reactor Experiment at Oak Ridge National Laboratory by :

Download or read book Disposition of the Fluoride Fuel and Flush Salts from the Molten Salt Reactor Experiment at Oak Ridge National Laboratory written by and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Molten Fluoride Fuel Salt Chemistry

Download Molten Fluoride Fuel Salt Chemistry PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 5 pages
Book Rating : 4.:/5 (683 download)

DOWNLOAD NOW!


Book Synopsis Molten Fluoride Fuel Salt Chemistry by :

Download or read book Molten Fluoride Fuel Salt Chemistry written by and published by . This book was released on 1995 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of molten fluorides is traced from their development as fuels in the Molten Salt Reactor Experiment with important factors in their selection being discussed. Key chemical characteristics such as solubility, redox behavior, and chemical activity are explained as they relate to the behavior of molten fluoride fuel systems. Development requirements for fitting the current state of the chemistry to modern nuclear fuel system are described. It is concluded that while much is known about molten fluoride behavior which can be used effectively to reduce the amount of development required for future systems, some significant molten salt chemical questions must still be addressed.

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor

Download Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)

DOWNLOAD NOW!


Book Synopsis Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor by :

Download or read book Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Redox Potential Measurement and Control for the Fluoride-salt-cooled High-temperature Reactor

Download Redox Potential Measurement and Control for the Fluoride-salt-cooled High-temperature Reactor PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 93 pages
Book Rating : 4.:/5 (949 download)

DOWNLOAD NOW!


Book Synopsis Redox Potential Measurement and Control for the Fluoride-salt-cooled High-temperature Reactor by : Kieran Patrick Dolan

Download or read book Redox Potential Measurement and Control for the Fluoride-salt-cooled High-temperature Reactor written by Kieran Patrick Dolan and published by . This book was released on 2015 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fluid Fuel Reactors

Download Fluid Fuel Reactors PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 1016 pages
Book Rating : 4.3/5 (91 download)

DOWNLOAD NOW!


Book Synopsis Fluid Fuel Reactors by : James A. Lane

Download or read book Fluid Fuel Reactors written by James A. Lane and published by . This book was released on 1958 with total page 1016 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Structural Materials for Generation IV Nuclear Reactors

Download Structural Materials for Generation IV Nuclear Reactors PDF Online Free

Author :
Publisher : Woodhead Publishing
ISBN 13 : 0081009127
Total Pages : 686 pages
Book Rating : 4.0/5 (81 download)

DOWNLOAD NOW!


Book Synopsis Structural Materials for Generation IV Nuclear Reactors by : Pascal Yvon

Download or read book Structural Materials for Generation IV Nuclear Reactors written by Pascal Yvon and published by Woodhead Publishing. This book was released on 2016-08-27 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt: Operating at a high level of fuel efficiency, safety, proliferation-resistance, sustainability and cost, generation IV nuclear reactors promise enhanced features to an energy resource which is already seen as an outstanding source of reliable base load power. The performance and reliability of materials when subjected to the higher neutron doses and extremely corrosive higher temperature environments that will be found in generation IV nuclear reactors are essential areas of study, as key considerations for the successful development of generation IV reactors are suitable structural materials for both in-core and out-of-core applications. Structural Materials for Generation IV Nuclear Reactors explores the current state-of-the art in these areas. Part One reviews the materials, requirements and challenges in generation IV systems. Part Two presents the core materials with chapters on irradiation resistant austenitic steels, ODS/FM steels and refractory metals amongst others. Part Three looks at out-of-core materials. Structural Materials for Generation IV Nuclear Reactors is an essential reference text for professional scientists, engineers and postgraduate researchers involved in the development of generation IV nuclear reactors. Introduces the higher neutron doses and extremely corrosive higher temperature environments that will be found in generation IV nuclear reactors and implications for structural materials Contains chapters on the key core and out-of-core materials, from steels to advanced micro-laminates Written by an expert in that particular area

Handbook of Reference Electrodes

Download Handbook of Reference Electrodes PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642361889
Total Pages : 352 pages
Book Rating : 4.6/5 (423 download)

DOWNLOAD NOW!


Book Synopsis Handbook of Reference Electrodes by : György Inzelt

Download or read book Handbook of Reference Electrodes written by György Inzelt and published by Springer Science & Business Media. This book was released on 2013-04-16 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reference Electrodes are a crucial part of any electrochemical system, yet an up-to-date and comprehensive handbook is long overdue. Here, an experienced team of electrochemists provides an in-depth source of information and data for the proper choice and construction of reference electrodes. This includes all kinds of applications such as aqueous and non-aqueous solutions, ionic liquids, glass melts, solid electrolyte systems, and membrane electrodes. Advanced technologies such as miniaturized, conducting-polymer-based, screen-printed or disposable reference electrodes are also covered. Essential know-how is clearly presented and illustrated with almost 200 figures.

Molten Salt Chemistry

Download Molten Salt Chemistry PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 802 pages
Book Rating : 4.3/5 (91 download)

DOWNLOAD NOW!


Book Synopsis Molten Salt Chemistry by : Milton Blander

Download or read book Molten Salt Chemistry written by Milton Blander and published by . This book was released on 1964 with total page 802 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Molten-Salt Reactor Program Semiannual Progress Report for Period Ending ...

Download Molten-Salt Reactor Program Semiannual Progress Report for Period Ending ... PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 198 pages
Book Rating : 4.3/5 (126 download)

DOWNLOAD NOW!


Book Synopsis Molten-Salt Reactor Program Semiannual Progress Report for Period Ending ... by : Oak Ridge National Laboratory

Download or read book Molten-Salt Reactor Program Semiannual Progress Report for Period Ending ... written by Oak Ridge National Laboratory and published by . This book was released on 1965-02 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Molten Salts Chemistry and Technology

Download Molten Salts Chemistry and Technology PDF Online Free

Author :
Publisher : John Wiley & Sons
ISBN 13 : 1118448820
Total Pages : 902 pages
Book Rating : 4.1/5 (184 download)

DOWNLOAD NOW!


Book Synopsis Molten Salts Chemistry and Technology by : Marcelle Gaune-Escard

Download or read book Molten Salts Chemistry and Technology written by Marcelle Gaune-Escard and published by John Wiley & Sons. This book was released on 2014-05-12 with total page 902 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written to record and report on recent research progresses in the field of molten salts, Molten Salts Chemistry and Technology focuses on molten salts and ionic liquids for sustainable supply and application of materials. Including coverage of molten salt reactors, electrodeposition, aluminium electrolysis, electrochemistry, and electrowinning, the text provides researchers and postgraduate students with applications include energy conversion (solar cells and fuel cells), heat storage, green solvents, metallurgy, nuclear industry, pharmaceutics and biotechnology.