Porous Desulfurization Sorbent Pellets Containing a Reactive Metal Oxide and an Inert Zirconium Compound

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ISBN 13 :
Total Pages : 14 pages
Book Rating : 4.:/5 (871 download)

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Book Synopsis Porous Desulfurization Sorbent Pellets Containing a Reactive Metal Oxide and an Inert Zirconium Compound by :

Download or read book Porous Desulfurization Sorbent Pellets Containing a Reactive Metal Oxide and an Inert Zirconium Compound written by and published by . This book was released on 1996 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sorbent pellets for removing hydrogen sulfide from coal gas are prepared by combining a reactive oxide, in particular zinc oxide, with a zirconium compound such as an oxide, silicate, or aluminate of zirconium, and an inorganic binder and pelletizing and calcining the mixture. Alternately, the zinc oxide may be replaced by copper oxide or a combination of copper, molybdenum, and manganese oxides. The pellet components may be mixed in dry form, moistened to produce a paste, and converted to pellets by forming an aqueous slurry of the components and spray drying the slurry, or the reactive oxide may be formed on existing zirconium-containing catalyst-carrier pellets by infusing a solution of a salt of the active metal onto the existing pellets and firing at a high temperature to produce the oxide. Pellets made according to this invention show a high reactivity with hydrogen sulfide and durability such as to be useful over repeated cycles of sorption and regeneration.

Federal Register

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ISBN 13 :
Total Pages : 932 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Federal Register by :

Download or read book Federal Register written by and published by . This book was released on 1997-05-06 with total page 932 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemical Abstracts

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ISBN 13 :
Total Pages : 2762 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Chemical Abstracts by :

Download or read book Chemical Abstracts written by and published by . This book was released on with total page 2762 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Process for the Manufacture of an Attrition Resistant Sorbent Used for Gas Desulfurization

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (953 download)

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Book Synopsis Process for the Manufacture of an Attrition Resistant Sorbent Used for Gas Desulfurization by :

Download or read book Process for the Manufacture of an Attrition Resistant Sorbent Used for Gas Desulfurization written by and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This process produces a sorbent for use in desulfurization of coal gas. A zinc titanate compound and a metal oxide are mixed by milling the compounds in an aqueous medium, the resulting mixture is dried and then calcined, crushed, sleved and formed into pellets for use in a moving-bed reactor. Metal oxides suitable for use as an additive in this process include: magnesium oxide, magnesium oxide plus molybdenum oxide, calcium oxide, yttrium oxide, hafnium oxide, zirconium oxide, cupric oxide, and tin oxide. The resulting sorbent has a percentage of the original zinc or titanium ions substituted for the oxide metal of the chosen additive.

Kinetics of Mn-based Sorbents for Hot Coal Gas Desulfurization

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ISBN 13 :
Total Pages : 23 pages
Book Rating : 4.:/5 (684 download)

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Book Synopsis Kinetics of Mn-based Sorbents for Hot Coal Gas Desulfurization by :

Download or read book Kinetics of Mn-based Sorbents for Hot Coal Gas Desulfurization written by and published by . This book was released on 1996 with total page 23 pages. Available in PDF, EPUB and Kindle. Book excerpt: Currently, the Morgantown Energy Technology Center, Department of Energy (DOE/METC) is actively investigating alternative hot fuel gas desulfurization sorbents for application to the Integrated Gasification Combined Cycle (IGCC). A sorbent must be highly active towards sulfur at high temperatures and pressures, and under varying degrees of reducing atmospheres. Also, it must regenerate nearly ideally to maintain activity over numerous cycles. Furthermore, regeneration must yield a sulfur product which is economically recoverable directly or indirectly. Several metal oxides have been investigated as regenerable sorbents for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot fuel gases. MnO was shown to have an intrinsic reaction rate approximately one order of magnitude greater than the rate or reaction with either CaO or ZnO and two orders of magnitude greater than the reaction rate with V203. Manganese also shows desulfurization potential in the temperature range of 600-700°C where metal oxides currently known to be reactive with H2S are unsatisfactorily. In response to stability difficulties of single and binary metal oxide sorbents, increasing effort is being directed towards incorporation of an inert component into sorbent formulation as witnessed by the various Zn-titanates. Primarily, the inert component increases pore structure integrity while stabilizing the active metal oxide against reduction. This report will address testing of Mn-based sorbents in an ambient pressure fixed-bed reactor. Steady-state H2S concentrations and breakthrough times will be presented.

Pore Structure and Reactivity Changes in Hot Coal Gas Desulfurization Sorbents

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ISBN 13 :
Total Pages : 124 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Pore Structure and Reactivity Changes in Hot Coal Gas Desulfurization Sorbents by :

Download or read book Pore Structure and Reactivity Changes in Hot Coal Gas Desulfurization Sorbents written by and published by . This book was released on 1991 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: The primary objective of the project was the investigation of the pore structure and reactivity changes occurring in metal/metal oxide sorbents used for desulfurization of hot coal gas during sulfidation and regeneration, with particular emphasis placed on the effects of these changes on the sorptive capacity and efficiency of the sorbents. Commercially available zinc oxide sorbents were used as model solids in our experimental investigation of the sulfidation and regeneration processes.

INVESTIGATION ON DURABILITY AND REACTIVITY OF PROMISING METAL OXIDE SORBENTS DURING SULFIDATION AND REGENERATION. QUARTERLY AND FINAL REPORT.

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ISBN 13 :
Total Pages : 99 pages
Book Rating : 4.:/5 (683 download)

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Book Synopsis INVESTIGATION ON DURABILITY AND REACTIVITY OF PROMISING METAL OXIDE SORBENTS DURING SULFIDATION AND REGENERATION. QUARTERLY AND FINAL REPORT. by :

Download or read book INVESTIGATION ON DURABILITY AND REACTIVITY OF PROMISING METAL OXIDE SORBENTS DURING SULFIDATION AND REGENERATION. QUARTERLY AND FINAL REPORT. written by and published by . This book was released on 1998 with total page 99 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at high pressures and high temperatures. Metal oxides such as zinc titanate oxides, zinc ferrite oxide, copper oxide, manganese oxide and calcium oxide, were found to be promising sorbents in comparison with other removal methods such as membrane separations and reactive membrane separations. Some metal oxide sorbents exhibited the quite favorable performance in terms of attrition resistance and sulfur capacity. Experiments on removal reaction of H2S from coal gas mixtures with formulated metal oxide sorbents were conducted in a batch reactor or a differential reactor. The objectives of this research project are to formulate promising metal oxide sorbents for removal of sulfur from coal gas mixtures, to find initial reaction kinetics for the metal oxide-hydrogen sulfide heterogeneous reaction system, to obtain effects of hydrogen, nitrogen and moisture on dynamic absorption and equilibrium absorption at various absorption temperatures. Promising durable metal oxide sorbents with high-sulfur-absorbing capacity were formulated by mixing active metal oxide powders with inert metal oxide powders, and calcining these powder mixtures. The Research Triangle Institute (RTI), a sub-contractor of this research project, will also prepare promising metal oxide sorbents for this research project, plan experiments on removal of sulfur compounds from coal gases with metal oxide, and review experimental results.

Metal-Organic Framework Materials

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Publisher : John Wiley & Sons
ISBN 13 : 1118931580
Total Pages : 1210 pages
Book Rating : 4.1/5 (189 download)

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Book Synopsis Metal-Organic Framework Materials by : Leonard R. MacGillivray

Download or read book Metal-Organic Framework Materials written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2014-09-19 with total page 1210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc

Chemical Oxidation Applications for Industrial Wastewaters

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Publisher : IWA Publishing
ISBN 13 : 1843393077
Total Pages : 361 pages
Book Rating : 4.8/5 (433 download)

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Book Synopsis Chemical Oxidation Applications for Industrial Wastewaters by : Olcay Tunay

Download or read book Chemical Oxidation Applications for Industrial Wastewaters written by Olcay Tunay and published by IWA Publishing. This book was released on 2010-10-12 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the most recent scientific and technological developments (state-of-the-art) in the field of chemical oxidation processes applicable for the efficient treatment of biologically-difficult-to-degrade, toxic and/or recalcitrant effluents originating from different manufacturing processes. It is a comprehensive review of process and pollution profiles as well as conventional, advanced and emerging treatment processes & technologies developed for the most relevant and pollution (wet processing)-intensive industrial sectors. It addresses chemical/photochemical oxidative treatment processes, case-specific treatability problems of major industrial sectors, emerging (novel) as well as pilot/full-scale applications, process integration, treatment system design & sizing criteria (figure-of-merits), cost evaluation and success stories in the application of chemical oxidative treatment processes. Chemical Oxidation Applications for Industrial Wastewaters is an essential reference for lecturers, researchers, industrial and environmental engineers and practitioners working in the field of environmental science and engineering. Visit the IWA WaterWiki to read and share material related to this title: http://www.iwawaterwiki.org/xwiki/bin/view/Articles/CHEMICALOXIDATIONAPPLICATIONSFORINDUSTRIALWASTEWATERS Authors: Professor Olcay Tünay, Professor Isik Kabdasli, Associate Professor Idil Arslan-Alaton and Assistant Professor Tugba Ölmez-Hanci, Environmental Engineering Department, Istanbul Technical University, Turkey.

Mineral Commodity Summaries 2020

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ISBN 13 : 9781411343627
Total Pages : 202 pages
Book Rating : 4.3/5 (436 download)

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Book Synopsis Mineral Commodity Summaries 2020 by : Government Publishing Office

Download or read book Mineral Commodity Summaries 2020 written by Government Publishing Office and published by . This book was released on 2020-05-30 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mineral Commodity Summaries 2019

Combined and Hybrid Adsorbents

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Publisher : Springer Science & Business Media
ISBN 13 : 1402051700
Total Pages : 372 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Combined and Hybrid Adsorbents by : José M. Loureiro

Download or read book Combined and Hybrid Adsorbents written by José M. Loureiro and published by Springer Science & Business Media. This book was released on 2006-10-03 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book follows up an Advanced Research Workshop dedicated to the subject of adsorption. It presents an up-to-date review of the latest achievements in the synthesis, characterization and applications of hybrid organic-inorganic materials and of carbon and combined adsorbents. The modeling of the adsorption process, including the simulation of carbon masks used for both civil and military protection purposes is also addressed. Includes applications in environmental, military and post-disaster situations.

Frontiers in Chemical Engineering

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Publisher : National Academies Press
ISBN 13 : 030903793X
Total Pages : 236 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Frontiers in Chemical Engineering by : National Research Council

Download or read book Frontiers in Chemical Engineering written by National Research Council and published by National Academies Press. This book was released on 1988-02-01 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the next 10 to 15 years, chemical engineers have the potential to affect every aspect of American life and promote the scientific and industrial leadership of the United States. Frontiers in Chemical Engineering explores the opportunities available and gives a blueprint for turning a multitude of promising visions into realities. It also examines the likely changes in how chemical engineers will be educated and take their place in the profession, and presents new research opportunities.

Cement Production Technology

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Publisher : CRC Press
ISBN 13 : 1351335731
Total Pages : 484 pages
Book Rating : 4.3/5 (513 download)

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Book Synopsis Cement Production Technology by : Anjan Kumar Chatterjee

Download or read book Cement Production Technology written by Anjan Kumar Chatterjee and published by CRC Press. This book was released on 2018-04-27 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is an outcome of the author’s active professional involvement in research, manufacture and consultancy in the field of cement chemistry and process engineering. This multidisciplinary title on cement production technology covers the entire process spectrum of cement production, starting from extraction and winning of natural raw materials to the finished products including the environmental impacts and research trends. The book has an overtone of practice supported by the back-up principles.

Carbon-Based Material for Environmental Protection and Remediation

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Publisher : BoD – Books on Demand
ISBN 13 : 1789845866
Total Pages : 190 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Carbon-Based Material for Environmental Protection and Remediation by : Mattia Bartoli

Download or read book Carbon-Based Material for Environmental Protection and Remediation written by Mattia Bartoli and published by BoD – Books on Demand. This book was released on 2020-08-19 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon-Based Material for Environmental Protection and Remediation presents an overview of carbon-based technologies and processes, and examines their usefulness and efficiency for environmental preservation and remediation. Chapters cover topics ranging from pollutants removal to new processes in materials science. Written for interested readers with strong scientific and technological backgrounds, this book will appeal to scientific advisors at private companies, academics, and graduate students.

CO2 Hydrogenation Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527346635
Total Pages : 322 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis CO2 Hydrogenation Catalysis by : Yuichiro Himeda

Download or read book CO2 Hydrogenation Catalysis written by Yuichiro Himeda and published by John Wiley & Sons. This book was released on 2021-06-28 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to the effective catalysts and latest advances in CO2 conversion in chemicals and fuels Carbon dioxide hydrogenation is one of the most promising and economic techniques to utilize CO2 emissions to produce value-added chemicals. With contributions from an international team of experts on the topic, CO2 Hydrogenation Catalysis offers a comprehensive review of the most recent developments in the catalytic hydrogenation of carbon dioxide to formic acid/formate, methanol, methane, and C2+ products. The book explores the electroreduction of carbon dioxide and contains an overview on hydrogen production from formic acid and methanol. With a practical review of the advances and challenges in future CO2 hydrogenation research, the book provides an important guide for researchers in academia and industry working in the field of catalysis, organometallic chemistry, green and sustainable chemistry, as well as energy conversion and storage. This important book: Offers a unique review of effective catalysts and the latest advances in CO2 conversion Explores how to utilize CO2 emissions to produce value-added chemicals and fuels such as methanol, olefins, gasoline, aromatics Includes the latest research in homogeneous and heterogeneous catalysis as well as electrocatalysis Highlights advances and challenges for future investigation Written for chemists, catalytic chemists, electrochemists, chemists in industry, and chemical engineers, CO2 Hydrogenation Catalysis offers a comprehensive resource to understanding how CO2 emissions can create value-added chemicals.

Fluidized-Bed Reactors: Processes and Operating Conditions

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Publisher : Springer
ISBN 13 : 3319395939
Total Pages : 214 pages
Book Rating : 4.3/5 (193 download)

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Book Synopsis Fluidized-Bed Reactors: Processes and Operating Conditions by : John G. Yates

Download or read book Fluidized-Bed Reactors: Processes and Operating Conditions written by John G. Yates and published by Springer. This book was released on 2016-09-27 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fluidized-bed reactor is the centerpiece of industrial fluidization processes. This book focuses on the design and operation of fluidized beds in many different industrial processes, emphasizing the rationale for choosing fluidized beds for each particular process. The book starts with a brief history of fluidization from its inception in the 1940’s. The authors present both the fluid dynamics of gas-solid fluidized beds and the extensive experimental studies of operating systems and they set them in the context of operating processes that use fluid-bed reactors. Chemical engineering students and postdocs as well as practicing engineers will find great interest in this book.

Process Engineering Economics

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Publisher : CRC Press
ISBN 13 : 9780203911396
Total Pages : 442 pages
Book Rating : 4.9/5 (113 download)

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Book Synopsis Process Engineering Economics by : James Riley Couper

Download or read book Process Engineering Economics written by James Riley Couper and published by CRC Press. This book was released on 2003-08-26 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference outlines the fundamental concepts and strategies for economic assessments for informed management decisions in industry. The book illustrates how to prepare capital cost and operating expense estimates, profitability analyses, and feasibility studies, and how to execute sensitivity and uncertainty assessments. From financial reports to opportunity costs and engineering trade-offs, Process Engineering Economics considers a wide range of alternatives for profitable investing and for projecting outcomes in various chemical and engineering fields. It also explains how to monitor costs, finances, and economic limitations at every stage of chemical project design, preparation, and evaluation.