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Author : Albert Hwai-yang Wu
Publisher :
ISBN 13 :
Total Pages : 508 pages
Book Rating : 4.:/5 (7 download)
Download or read book Phase Equilibria for Fluid Mixtures Containing Small and Large Molecules written by Albert Hwai-yang Wu and published by . This book was released on 1988 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : M. B. King
Publisher : Elsevier
ISBN 13 : 1483152413
Total Pages : 604 pages
Book Rating : 4.4/5 (831 download)
Download or read book Phase Equilibrium in Mixtures written by M. B. King and published by Elsevier. This book was released on 2013-10-22 with total page 604 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase Equilibrium in Mixtures deals with phase equilibrium and the methods of correlating, checking, and predicting phase data. Topics covered range from latent heat and vapor pressure to dilute solutions, ideal and near-ideal solutions, and consistency tests. Molecular considerations and their use for the prediction and correlation of data are also discussed. Comprised of nine chapters, this volume begins with an introduction to the role of thermodynamics and the criteria for equilibrium between phases, along with fugacity and the thermodynamic functions of mixing. The discussion then turns to some of the phase phenomena which may be encountered in chemical engineering practice; methods of correlating and extending vapor pressure data and practical techniques for calculating latent heats from these data; the behavior of dilute solutions both at low and high pressures for reacting and non-reacting systems; and the behavior of ideal and near-ideal solutions. The remaining chapters explore non-ideal solutions at normal pressures; practical methods for testing the thermodynamic consistency of phase data; and the extent to which the broad aspects of phase behavior may be interpreted in the light of simple molecular considerations. This book is intended primarily for graduate chemical engineers but should also be of interest to those graduates in physics or chemistry who need to use phase equilibrium data.
Author : Aleksander Kreglewski
Publisher :
ISBN 13 :
Total Pages : 284 pages
Book Rating : 4.:/5 (44 download)
Download or read book Equilibrium Properties of Fluids and Fluid Mixtures written by Aleksander Kreglewski and published by . This book was released on 1984 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : John M. Prausnitz
Publisher : Pearson Education
ISBN 13 : 0132440504
Total Pages : 1150 pages
Book Rating : 4.1/5 (324 download)
Download or read book Molecular Thermodynamics of Fluid-Phase Equilibria written by John M. Prausnitz and published by Pearson Education. This book was released on 1998-10-22 with total page 1150 pages. Available in PDF, EPUB and Kindle. Book excerpt: The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.
Author : R.J. Sadus
Publisher : Elsevier
ISBN 13 : 0444596666
Total Pages : 411 pages
Book Rating : 4.4/5 (445 download)
Download or read book High Pressure Phase Behaviour of Multicomponent Fluid Mixtures written by R.J. Sadus and published by Elsevier. This book was released on 2012-12-02 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: The high pressure phase behaviour of binary fluid mixtures has been extensively studied during the last three decades. There is ample experimental data for a wide variety of binary mixtures and extensive methods for prediction have been developed. In contrast, the investigation of ternary and other multicomponent fluids is in its infancy. Experimental ternary mixture critical data are very rare and theoretical studies have been limited to data correlation rather than genuine prediction. The phase behaviour of ternary and other multicomponent fluid mixtures has many novel aspects which are not manifested in binary mixtures. The properties of ternary mixtures are also likely to be more difficult to characterize experimentally. It is in this context that calculated phase diagrams have an important role in leading the discovery of new phenomena and guiding experimental work. The criteria for phase equilibria of multicomponent fluids with particular emphasis on the critical state are examined in this book, and models for predicting fluid equilibria (e.g., different equations of state) are compared. Particular attention is paid to the critical state of ternary mixtures which has hitherto been largely neglected. The problems associated with predicting ternary equilibria are discussed, and some novel aspects of ternary critical phenomena are illustrated. The books also describes a novel type of critical transition which appears to be a common feature of the equilibria of ternary mixtures. Extensive phase diagrams of a wide range of ternary mixtures including systems containing carbon dioxide, water, nitrogen and tetrafluoromethane as one or more component are presented. The theoretical treatment is detailed in the appendix and a computation of known experimental critical points is also included.
Author : Ulrich K Deiters
Publisher : Elsevier
ISBN 13 : 0444563547
Total Pages : 363 pages
Book Rating : 4.4/5 (445 download)
Download or read book High-Pressure Fluid Phase Equilibria written by Ulrich K Deiters and published by Elsevier. This book was released on 2012-04-26 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book begins with an overview of the phase diagrams of fluid mixtures (fluid = liquid, gas, or supercritical state), which can show an astonishing variety when elevated pressures are taken into account; phenomena like retrograde condensation (single and double) and azeotropy (normal and double) are discussed. It then gives an introduction into the relevant thermodynamic equations for fluid mixtures, including some that are rarely found in modern textbooks, and shows how they can they be used to compute phase diagrams and related properties. This chapter gives a consistent and axiomatic approach to fluid thermodynamics; it avoids using activity coefficients. Further chapters are dedicated to solid-fluid phase equilibria and global phase diagrams (systematic search for phase diagram classes). The appendix contains numerical algorithms needed for the computations. The book thus enables the reader to create or improve computer programs for the calculation of fluid phase diagrams. - introduces phase diagram classes, how to recognize them and identify their characteristic features - presents rational nomenclature of binary fluid phase diagrams - includes problems and solutions for self-testing, exercises or seminars
Author : Ronald L. Cotterman
Publisher :
ISBN 13 :
Total Pages : 502 pages
Book Rating : 4.:/5 (29 download)
Download or read book Phase Equilibria for Complex Fluid Mixtures at High Pressures, Development and Application of Continuous Thermodynamics written by Ronald L. Cotterman and published by . This book was released on 1985 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : G. Ali Mansoori
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (361 download)
Download or read book Phase Equilibrium of Mixtures Consisting of Molecules with Large Size and Shape Differences written by G. Ali Mansoori and published by . This book was released on 1990 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Initial success was achieved in the development of a new and accurate technique for the prediction of the thermodynamic properties of asymmetric mixtures. This technique was applied to industrial modeling of supercritical fluid extraction and retrograde condensation. This work is based on statistical mechanical mixing rules and the conformal solution theory of polar fluid mixtures.
Author : Juan Jose De Pablo
Publisher :
ISBN 13 :
Total Pages : 682 pages
Book Rating : 4.:/5 (33 download)
Download or read book Phase Equilibria for Fluid Mixtures with Special Emphasis on the Critical Region written by Juan Jose De Pablo and published by . This book was released on 1990 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Phase Equilibria and Gas Mixtures Properties written by and published by . This book was released on 1968 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Esteban Brignole
Publisher : Elsevier Inc. Chapters
ISBN 13 : 0128082577
Total Pages : 43 pages
Book Rating : 4.1/5 (28 download)
Download or read book Phase Equilibrium Engineering written by Esteban Brignole and published by Elsevier Inc. Chapters. This book was released on 2013-04-02 with total page 43 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase equilibrium knowledge is required for the design of all sorts of chemical processes that may involve separations, reactions, fluids flow, particle micronization, etc. Indeed, different phase behavior scenarios are required for a rational conceptual process design. The aim of this chapter is to present the possible fluid mixture phase behavior that can be found in binary, ternary, and multicomponent systems. Moreover, representation of phase behavior in terms of phase diagrams is discussed. Dealing with phase diagrams of complex mixtures is not an easy task for beginners; however, very simple concepts are behind the rules for their construction. Phase diagrams are essential tools for phase equilibrium engineering as they provide valuable hints to understand the process and to assess the feasible and optimum operating regions. In this chapter, the “phenomenological” meaning of each phase behavior and its relation with molecular properties is discussed. A special attention is given to binary system phase behavior. Even though, in practice we rarely found such simple mixtures, they furnish a great deal of information for the understanding of multicomponent systems.
Author : A Anderko
Publisher : World Scientific
ISBN 13 : 9814611778
Total Pages : 526 pages
Book Rating : 4.8/5 (146 download)
Download or read book Thermodynamics Of Fluids: Measurement And Correlation written by A Anderko and published by World Scientific. This book was released on 1990-03-01 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a collection of papers, mostly state-of-the-art reviews, describing main topics of current research in Applied Thermodynamics. The papers deal with measurements of thermodynamic properties which are important for process design in chemical and related industries as well as for theoretical investigations of pure fluids and mixtures. Besides measuring techniques, methods are reviewed for the processing and correlation of experimental data.
Author : Y. Arai
Publisher : Springer Science & Business Media
ISBN 13 : 3642562388
Total Pages : 463 pages
Book Rating : 4.6/5 (425 download)
Download or read book Supercritical Fluids written by Y. Arai and published by Springer Science & Business Media. This book was released on 2013-03-07 with total page 463 pages. Available in PDF, EPUB and Kindle. Book excerpt: The potential of supercritical fluid methods is presented in a comprehensive way. On the basis of a careful discussion of physical and chemical principles, the application of this method in process technology is demonstrated.
Author : Lawrence Berkeley Laboratory. Materials and Molecular Research Division
Publisher :
ISBN 13 :
Total Pages : 340 pages
Book Rating : 4.3/5 (91 download)
Download or read book Materials and Molecular Research Division Annual Report written by Lawrence Berkeley Laboratory. Materials and Molecular Research Division and published by . This book was released on 1986 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Equations of State for Strongly Nonideal Fluid Mixtures written by and published by . This book was released on 1981 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A new model has been developed for calculation of fluid-phase equilibria of asymmetric mixtures. This local-composition model extends the quasi-chemical theory of Guggenheim (known to correlate well liquid-state activity coefficients) to fluids of all densities. The model can be applied to any equation of state, contains only one new adjustable parameter per binary pair, and can be extended to multicomponent mixtures of large and small molecules by use of the surface areas of the molecules. Although the local-composition model is a nonrandomness approach, all randomness boundary conditions are met. Significant improvement over the random-mixing model is shown for the prediction of vapor-liquid equilibria of methane/water and ethane/water systems.
Author : American Institute of Chemical Engineers
Publisher :
ISBN 13 :
Total Pages : 1040 pages
Book Rating : 4.3/5 (91 download)
Download or read book Phase Equilibria and Fluid Properties in the Chemical Industry written by American Institute of Chemical Engineers and published by . This book was released on 1980 with total page 1040 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : J. M. Prausnitz
Publisher : Prentice Hall PTR
ISBN 13 :
Total Pages : 632 pages
Book Rating : 4.3/5 (91 download)
Download or read book Molecular Thermodynamics of Fluid-phase Equilibria written by J. M. Prausnitz and published by Prentice Hall PTR. This book was released on 1986 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt: A synthesis of thermodynamics and applied physical chemistry, this volume stresses the importance and convenience of using generalized methods to solve chemical engineering problems.
