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Performance Analysis For Micro Direct Methanol Fuel Cell Through Electrochemical Impedance Spectroscopy And Cyclic Voltammetry
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Book Synopsis Performance Analysis for Micro Direct Methanol Fuel Cell Through Electrochemical Impedance Spectroscopy and Cyclic Voltammetry by : 洪羚境
Download or read book Performance Analysis for Micro Direct Methanol Fuel Cell Through Electrochemical Impedance Spectroscopy and Cyclic Voltammetry written by 洪羚境 and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Direct Methanol Fuel Cells by : Electrochemical Society. Energy Technology Division
Download or read book Direct Methanol Fuel Cells written by Electrochemical Society. Energy Technology Division and published by . This book was released on 2001 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Energy Technology, Physical Electrochemistry and Battery Divisions."
Book Synopsis Equivalent Circuit Modeling and Performance Analysis of PEM Fuel Cells Using Electrochemical Impedance Spectroscopy by : Aparna Mukundrao Dhirde
Download or read book Equivalent Circuit Modeling and Performance Analysis of PEM Fuel Cells Using Electrochemical Impedance Spectroscopy written by Aparna Mukundrao Dhirde and published by . This book was released on 2009 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells by : Samuel Cruz-Manzo
Download or read book Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells written by Samuel Cruz-Manzo and published by Elsevier. This book was released on 2022-06-18 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells: Fundamentals, Modelling, and Applications establishes how the electrochemical and diffusion mechanisms of a polymer electrolyte membrane fuel cell (PEMFC) are related to electrochemical impedance spectroscopy (EIS) measurements using physics-based impedance models derived from fundamental electrode and diffusion theories. The contribution of the different phenomena occurring at the different layers comprising the cathode on the impedance response of the PEMFC is revealed through EIS-modelling analysis. The relation between EIS measurements and polarisation curves representing the performance of PEMFCs is established. Insight is gained into how the EIS response of the PEMFC changes at different operating conditions e.g. relative humidity, load demand, gas reactant stoichiometry and temperature using physics-based impedance models. The application of impedance models with EIS measurements carried out in the individual cells comprising a PEMFC stack is demonstrated, while recent modelling approaches and other impedance models reported in the literature to represent the EIS response of the PEMFC are also considered and discussed. - Provides further understanding of ambiguities during the interpretation of the electrochemical impedance spectrum of the PEMFC - Includes impedance models written in MATLAB® for replication or application to other PEMFC-EIS measurements - Includes impedance spectra of the PEMFC at different operating conditions, electro/diffusion pathways for derivation of the impedance models and flowcharts for application of the impedance models with real-world measured EIS data
Book Synopsis The Effect of Metal Solution Contaminants on the Electro-catalyst Activities of Direct Methanol Fuel Cell by : Soghra Jalil Pour Kivi
Download or read book The Effect of Metal Solution Contaminants on the Electro-catalyst Activities of Direct Methanol Fuel Cell written by Soghra Jalil Pour Kivi and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct methanol fuel cells (DMFCs) are considered a clean source of electrical power for future energy demand, creating a potential to reduce our dependency on fossil fuels. Despite their advantages, including high energy density, efficiency and easy handling and distribution of fuel, the commercialization of DMFCs has suffered from some drawbacks, including methanol crossover and contamination of the system. Metal cation contaminants (such as Ni, Co, etc) introduced through the degradation of fuel cell components (bipolar plate and electro-catalyst layer) can significantly affect the Nafion-membrane properties and overall fuel cell performance. In the current study, a systematic approach is taken to characterize and identify the mechanism of the effect of metal solution contaminants on the activities of electro-catalysts of DMFCs. Cyclic voltammetry and rotating disk electrode (RDE) techniques were utilized in order to characterize the effect of various concentrations (i.e., 2x10-x M (x=1-7)) of six metal solution contaminants (i.e., Co, Ni and Zn with sulfate and nitrate as counter-anions) on the voltammetric properties and electro-catalytic activity of polycrystalline Pt during methanol oxidation reaction (MOR) and oxygen reduction reaction (ORR). The results showed a decrease in the MOR and ORR activities of Pt as the concentration of metal solution increased. The effect of counter-anion on the Pt activity was further investigated. The results showed that a combined effect of counter-anions and metal cations may be responsible for the decrease in the electro-catalytic activity of Pt. The effect of metal solution contaminants on the Nafion-ionomer of anode electro-catalysts was investigated using Nafion-coated Pt electrode. Voltammetric properties and MOR activities of Nafion-coated and bare Pt electrodes in the presence of Ni solution contaminants were characterized using cyclic voltammetry and electrochemical impedance spectroscopy (EIS). The overall results showed a significant negative effect of Ni solution contaminants on the electro-catalytic activity of bare Pt electrode as compared to the Nafion-coated Pt electrode. Based on the results, it appears that Nafion-ionomer film may interact with metal cations (through its sulfonate groups) and repel them away from the Pt active sites, partially inhibiting the negative effect of metal cations on the Pt activity of Nafion-coated Pt electrode. The effect of metal solution contaminants on the carbon-supported platinum nanoparticle (Pt/C) with various Nafion-ionomer distributions and contents (i.e., Nafion-incorporated Pt/C and Nafion-coated Pt/C electrodes) was further investigated. Cyclic voltammetry and EIS techniques were employed to characterize the effect of Ni solution contaminants on the voltammetric properties and MOR activities of Nafion-incorporated and Nafion-coated Pt/C electrodes. The overall results showed a stronger negative effect of Ni solution contaminants on the electro-catalytic activity of Nafion-incorporated Pt/C electrodes as compared to the Nafion-coated Pt/C electrodes. This further confirms previous observations showing the sulfonate groups of Nafion-ionomer film may attract the Ni metal cations, localize them away from the Pt active sites, and subsequently suppress the negative effect of cations on the activity of Nafion-coated Pt/C electrodes.
Book Synopsis Proceedings of the Workshop on Direct Methanol-Air Fuel Cells by : Albert R. Landgrebe
Download or read book Proceedings of the Workshop on Direct Methanol-Air Fuel Cells written by Albert R. Landgrebe and published by . This book was released on 1992 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Performance Analysis for Micro Direct Methanol Fuel Cell with Different Placement Angle by : 謝豐旭
Download or read book Performance Analysis for Micro Direct Methanol Fuel Cell with Different Placement Angle written by 謝豐旭 and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Electrochemical Impedance Spectroscopy in PEM Fuel Cells by : Xiao-Zi (Riny) Yuan
Download or read book Electrochemical Impedance Spectroscopy in PEM Fuel Cells written by Xiao-Zi (Riny) Yuan and published by Springer Science & Business Media. This book was released on 2009-11-25 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Electrochemical Impedance Spectroscopy in PEM Fuel Cells" discusses one of the most powerful and useful diagnostic tools for various aspects of the study of fuel cells: electrochemical impedance spectroscopy (EIS). This comprehensive reference on EIS fundamentals and applications in fuel cells contains information about basic principles, measurements, and fuel cell applications of the EIS technique. Many illustrated examples are provided to ensure maximum clarity and observability of the spectra. "Electrochemical Impedance Spectroscopy in PEM Fuel Cells" will enable readers to explore the frontiers of EIS technology in PEM fuel cell research and other electrochemical systems. As well as being a useful text for electrochemists, it can also help researchers who are unfamiliar with EIS to learn the technique quickly and to use it correctly in their fuel cell research. Managers or entrepreneurs may also find this book a useful guide to accessing the challenges and opportunities in fuel cell technology.
Book Synopsis Performance Analysis of a New Design of Micro Direct Methanol Fuel Cell (-DMFC). by : 林弘益
Download or read book Performance Analysis of a New Design of Micro Direct Methanol Fuel Cell (-DMFC). written by 林弘益 and published by . This book was released on 2007 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology by : Christoph Hartnig
Download or read book Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology written by Christoph Hartnig and published by Elsevier. This book was released on 2012-03-19 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs) technology are promising forms of low-temperature electrochemical power conversion technologies that operate on hydrogen and methanol respectively. Featuring high electrical efficiency and low operational emissions, they have attracted intense worldwide commercialization research and development efforts. These R&D efforts include a major drive towards improving materials performance, fuel cell operation and durability. In situ characterization is essential to improving performance and extending operational lifetime through providing information necessary to understand how fuel cell materials perform under operational loads.This two volume set reviews the fundamentals, performance, and in situ characterization of PEMFCs and DMFCs. Volume 1 covers the fundamental science and engineering of these low temperature fuel cells, focusing on understanding and improving performance and operation. Part one reviews systems fundamentals, ranging from fuels and fuel processing, to the development of membrane and catalyst materials and technology, and gas diffusion media and flowfields, as well as life cycle aspects and modelling approaches. Part two details performance issues relevant to fuel cell operation and durability, such as catalyst ageing, materials degradation and durability testing, and goes on to review advanced transport simulation approaches, degradation modelling and experimental monitoring techniques.With its international team of expert contributors, Polymer electrolyte membrane and direct methanol fuel cell technology Volumes 1 & 2 is an invaluable reference for low temperature fuel cell designers and manufacturers, as well as materials science and electrochemistry researchers and academics. - Covers the fundamental science and engineering of polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs), focusing on understanding and improving performance and operation - Reviews systems fundamentals, ranging from fuels and fuel processing, to the development of membrane and catalyst materials and technology, and gas diffusion media and flowfields, as well as life cycle aspects and modelling approaches - Details performance issues relevant to fuel cell operation and durability, such as catalyst ageing, materials degradation and durability testing, and reviews advanced transport simulation approaches, degradation modelling and experimental monitoring techniques
Book Synopsis Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology by : Christoph Hartnig
Download or read book Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology written by Christoph Hartnig and published by Elsevier. This book was released on 2012-02-20 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs) technology are promising forms of low-temperature electrochemical power conversion technologies that operate on hydrogen and methanol respectively. Featuring high electrical efficiency and low operational emissions, they have attracted intense worldwide commercialization research and development efforts. These R&D efforts include a major drive towards improving materials performance, fuel cell operation and durability. In situ characterization is essential to improving performance and extending operational lifetime through providing information necessary to understand how fuel cell materials perform under operational loads.Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology, Volume 2 details in situ characterization, including experimental and innovative techniques, used to understand fuel cell operational issues and materials performance. Part I reviews enhanced techniques for characterization of catalyst activities and processes, such as X-ray absorption and scattering, advanced microscopy and electrochemical mass spectrometry. Part II reviews characterization techniques for water and fuel management, including neutron radiography and tomography, magnetic resonance imaging and Raman spectroscopy. Finally, Part III focuses on locally resolved characterization methods, from transient techniques and electrochemical microscopy, to laser-optical methods and synchrotron radiography.With its international team of expert contributors, Polymer electrolyte membrane and direct methanol fuel cell technology will be an invaluable reference for low temperature fuel cell designers and manufacturers, as well as materials science and electrochemistry researchers and academics. Polymer electrolyte membrane and direct methanol fuel cell technology is an invaluable reference for low temperature fuel cell designers and manufacturers, as well as materials science and electrochemistry researchers and academics. - Details in situ characterisation of polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs), including the experimental and innovative techniques used to understand fuel cell operational issues and materials performance - Examines enhanced techniques for characterisation of catalyst activities and processes, such as X-ray absorption and scattering, advanced microscopy and electrochemical mass spectrometry - Reviews characterisation techniques for water and fuel management, including neutron radiography and tomography, and comprehensively covers locally resolved characterisation methods, from transient techniques to laser-optical methods
Book Synopsis Review on Micro-Direct Methanol Fuel Cells by : Daniela Falcão
Download or read book Review on Micro-Direct Methanol Fuel Cells written by Daniela Falcão and published by LAP Lambert Academic Publishing. This book was released on 2015-02-18 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fuel cells have unique technological attributes: efficiency, minimization of moving parts and low emissions. The Direct Methanol Fuel Cell (DMFC) has attracted much attention due to its potential applications as a power source for transportation and portable electronic devices. With the advance of micromachining technologies, miniaturization of power sources became one of the trends of evolution of research in this area. Based on the advantages of the scaling laws, miniaturization promises higher efficiency and performance of power generating devices, therefore, Micro-DMFC is an emergent technology. There has been a growing interest in the development of this type of micro cells in the last years, resulting both in experimental studies (operating conditions, cell design and new materials) and in modeling studies. Despite the increase in the knowledge acquired, many challenges are still to be reached. This book provides a detailed comprehensive review both on fundamental and technological aspects of Micro-DMFC. Special attention is devoted to systematization of published results on experimental area and also to a special section dedicated to modeling studies.
Book Synopsis Encyclopedia of Electrochemical Power Sources by : Jürgen Garche
Download or read book Encyclopedia of Electrochemical Power Sources written by Jürgen Garche and published by Newnes. This book was released on 2013-05-20 with total page 4532 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia of Electrochemical Power Sources is a truly interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With a focus on the environmental and economic impact of electrochemical power sources, this five-volume work consolidates coverage of the field and serves as an entry point to the literature for professionals and students alike. Covers the main types of power sources, including their operating principles, systems, materials, and applications Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers Incorporates nearly 350 articles, with timely coverage of such topics as environmental and sustainability considerations
Book Synopsis Experimental Methods and Data Analyses for Polymer Electrolyte Fuel Cells by :
Download or read book Experimental Methods and Data Analyses for Polymer Electrolyte Fuel Cells written by and published by . This book was released on 2005 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Evaluation of the Performance Characteristics of an Alkaline and Direct Methanol Fuel Cell by : Sujith Mohan
Download or read book Evaluation of the Performance Characteristics of an Alkaline and Direct Methanol Fuel Cell written by Sujith Mohan and published by . This book was released on 2009 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: The performance of an alkaline and direct methanol fuel cell was investigated by varying different operational parameters. An alkaline fuel cell test system was designed, assembled and used for investigation under four different electrolyte concentrations and three different levels of anode flow rates. The results of the test revealed that the efficiency of the cell increases with the increase in electrolyte concentration. A model was developed to predict the cell performance. Impedance spectroscopy has been conducted to validate the mathematical model and further investigate ohmic resistance, anode and cathode activation losses and mass transport losses. The results predicted by the model were found in good agreement with the corresponding experimental data. The performance of a direct methanol fuel cell was investigated under five different methanol concentrations. Similar to the alkaline fuel cell, impedance spectroscopy was conducted to measure the ohmic, activation and mass transport losses for all concentrations. The cell performance was then evaluated using methane and ethanol as fuels and was compared with methanol operation. A model to predict the performance of direct methanol fuel cells has been developed and the results predicted by the model were in good agreement with experimental data.
Book Synopsis Scientific and Technical Aerospace Reports by :
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1994 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.
Book Synopsis The Study, Testing, and Development of Direct Methanol Microscale Fuel Cells by : Paul Montagna
Download or read book The Study, Testing, and Development of Direct Methanol Microscale Fuel Cells written by Paul Montagna and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The rapid increase in instability of fossil fuels has led to a more aggressive search for reliable alternative energy. This has led to the rise of fuel cells as a popular and effective source of energy in large-scale applications. However, their development for usage in small-scale applications is still in its early stages. Many factors and concerns including, but not limited to, flow chamber geometry, electrode geometry, fuel molarity, fuel flow rate, gas flow rates, and electrode fabrication methods, must be further explored and analyzed. Once this is done, a feasible micro fuel cell capable of replacing current comparable lithium-ion batteries in powering small electronics may be developed. This thesis presents a review of micro direct methanol fuel cells (DMFC's) and discusses how each of the above parameters, as well as others, factor into DMFC performance. Initial iterations of a mathematical model used to predict the performance of a DMFC as a function of various experimental parameters is also discussed. Several of these factors, including fuel molarity and flow rate, were further explored using the presented experimental setup and procedure. From this, it was concluded that a methanol fuel molarity of 1M and a fuel flow rate of 18 ml/hr resulted in the highest power densities. It should be noted that these parameters were independently tested, using constant standard parameters to isolate a single testing parameter. While both the experimental and model results are promising, they are just the beginning of the modeling and experimental testing required to produce a feasible final product. Future research plans include further refining the mathematical model and performing experimental tests to measure power density as a function of electrode geometry and fuel temperature.
