Palladium Catalyzed Alkyl Carbon Hydrogen Activation

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The Mizoroki-Heck Reaction

Author : Martin Oestreich
Publisher : John Wiley & Sons
ISBN 13 : 9780470716069
Total Pages : 608 pages
Book Rating : 4.7/5 (16 download)

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Book Synopsis The Mizoroki-Heck Reaction by : Martin Oestreich

Download or read book The Mizoroki-Heck Reaction written by Martin Oestreich and published by John Wiley & Sons. This book was released on 2009-02-11 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)

C-H Activation

Author : Jin-Quan Yu
Publisher : Springer
ISBN 13 : 3642123562
Total Pages : 400 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis C-H Activation by : Jin-Quan Yu

Download or read book C-H Activation written by Jin-Quan Yu and published by Springer. This book was released on 2010-06-16 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Table of Contents - Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation - Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds - Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus - Remote C–H Activation via Through-Space Palladium and Rhodium Migrations - Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation - Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins - Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages - Rhodium-Catalyzed C–H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds - Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion - Metal-Catalyzed Oxidations of C–H to C–N Bonds

Palladium-catalyzed Carbon-hydrogen Bond Functionalization Utilizing an Exo-directing Strategy

Author : Zhi Ren (Ph. D.)
Publisher :
ISBN 13 :
Total Pages : 858 pages
Book Rating : 4.:/5 (957 download)

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Book Synopsis Palladium-catalyzed Carbon-hydrogen Bond Functionalization Utilizing an Exo-directing Strategy by : Zhi Ren (Ph. D.)

Download or read book Palladium-catalyzed Carbon-hydrogen Bond Functionalization Utilizing an Exo-directing Strategy written by Zhi Ren (Ph. D.) and published by . This book was released on 2016 with total page 858 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal catalyzed functionalization of carbon-hydrogen bonds (C−H bonds) has become an exponentially growing field. Particularly, Pd-catalyzed methods with various directing groups (DGs) have been developed for site selectivity. In addition, the use of an oxime as a DG proved to be an efficient and removable DG. However, alcohol-based directing strategies are still rare and underdeveloped. The research and development in this dissertation mainly focused on the utilization of masked alcohols as DGs for late stage diversification. With an exo-directing strategy, the syntheses of chemically differentiated vicinal diols and 2-hydroxyalkylphenol derivatives were achieved. Through a series of studies on cyclopalladation of methine groups, the first direct C−H activation complex was prepared and characterized. Additionally, a comprehensive introduction of TM-catalyzed alkylation of aromatic C−H bonds with simple olefins was illustrated.

C-H Activation for Asymmetric Synthesis

Author : Françoise Colobert
Publisher : John Wiley & Sons
ISBN 13 : 3527343407
Total Pages : 294 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis C-H Activation for Asymmetric Synthesis by : Françoise Colobert

Download or read book C-H Activation for Asymmetric Synthesis written by Françoise Colobert and published by John Wiley & Sons. This book was released on 2019-11-11 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides, in one handbook, comprehensive coverage of one of the hottest topics in stereoselective chemistry Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts?asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds?CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)?H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)?H bond activation; amongst other methods. -Covers one of the most rapidly developing fields in organic synthesis and catalysis -Clearly structured in two parts (activation of sp3- and activation of sp2-H bonds) -Edited by two leading experts in C-H activation in asymmetric synthesis CH-Activation for Asymmetric Synthesis will be of high interest to chemists in academia, as well as those in the pharmaceutical and agrochemical industry.

Palladium Catalyzed Oxidation of Hydrocarbons

Author : P. Henry
Publisher : Springer Science & Business Media
ISBN 13 : 940099446X
Total Pages : 449 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Palladium Catalyzed Oxidation of Hydrocarbons by : P. Henry

Download or read book Palladium Catalyzed Oxidation of Hydrocarbons written by P. Henry and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 449 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. The development of the organometallic/ catalysis area has resulted in no small way from many contributions from researchers investigating palladium systems. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium(II) salts and complexes. Such homogeneous reactions include oxidative and nonoxidative coupling of substrates such as olefins, dienes, acetylenes, and aromatics; and various isomerization, disproportionation, hydrogenation, dehydrogenation, car bonylation and decarbonylation reactions, as well as reactions involving formation of bonds between carbon and halogen, nitrogen, sulfur, and silicon. The books by Peter M. Maitlis - The Organic Chemistry of Palladium, Volumes I, II, Academic Press, 1971 - serve to classify and identify the wide variety of reactions, and access to the vast literature is available through these volumes and more recent reviews, including those of J. Tsuji [Accounts Chem. Res. , 6, 8 (1973); Adv. in Organometal. , 17, 141 (1979)], R. F. Heck [Adv. in Catat. , 26, 323 (1977)], and ones by Henry [Accounts Chem. Res. , 6, 16 (1973); Adv. in Organometal. , 13, 363 (1975)]. F. R. Hartley's book - The Chemistry of Platinum and Palladium, App!. Sci. Pub!.

Modern Arylation Methods

Author : Lutz Ackermann
Publisher : John Wiley & Sons
ISBN 13 : 3527627332
Total Pages : 561 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Modern Arylation Methods by : Lutz Ackermann

Download or read book Modern Arylation Methods written by Lutz Ackermann and published by John Wiley & Sons. This book was released on 2009-04-22 with total page 561 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today, arylation methods are belonging to the most important reaction types in organic synthesis. Lutz Ackermann, a young and ambitious professor has gathered a number of top international authors to present the first comprehensive book on the topic. Starting from a historical review, the book covers hot topics like Palladium-catalyzed arylation of N-H and alpha-C-H-acidic Bonds, Copper-catalyzed arylation of N-H and O-H Bonds, direct arylation reactions, carbanion aromatic synthesis, arylation reactions of alkenes, alkynes and much more. This compact source of high quality information is indispensable to synthetic chemists and those working in the pharmaceutical and chemical industry.

Remote C-H Bond Functionalizations

Author : Debabrata Maiti
Publisher : John Wiley & Sons
ISBN 13 : 3527346678
Total Pages : 450 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Remote C-H Bond Functionalizations by : Debabrata Maiti

Download or read book Remote C-H Bond Functionalizations written by Debabrata Maiti and published by John Wiley & Sons. This book was released on 2021-04-26 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to contemporary advancements in the field of distal C-H functionalizations An important and dynamic topic within the modern field of organic synthesis, selective functionalization of C-H bonds can be used in a variety of applications across the pharmaceutical and agrochemical industries. Remote C-H Bond Functionalizations presents an inclusive account of the most recent developments and potential applications of performing variegated functionalizations selectively at the distal positions of organic compounds. Featuring contributions by an international team of experts, this authoritative volume provides deep insight into distal functionalizations, including detailed discussion of mechanisms, the engineering of templates, and the design of strategies. The text covers a diverse range of topics including C-H functionalization of palladium/norbornene catalysis, ruthenium-catalyzed remote functionalization, the non-directed distal C(sp2)-H, functionalization, transition metal catalyzed distal para-selective C-H functionalization, and much more. Reviewing contemporary advancements in the field while laying the foundation for future research, this important resource: Provides the most recent research and thorough coverage of the subject available in a single volume Offers practical information on C-H functionalizations in various industries Includes an up-to-date introduction to distal C-H functionalizations Remote C-H Bond Functionalizations is a must-read for every synthetic chemist, including chemists working with organometallics, organic chemists and researchers, and industrial chemists.

Chelation-assisted Palladium-catalyzed Activation of C-H Bonds

Author : Ramesh Giri
Publisher :
ISBN 13 :
Total Pages : 1280 pages
Book Rating : 4.:/5 (763 download)

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Book Synopsis Chelation-assisted Palladium-catalyzed Activation of C-H Bonds by : Ramesh Giri

Download or read book Chelation-assisted Palladium-catalyzed Activation of C-H Bonds written by Ramesh Giri and published by . This book was released on 2009 with total page 1280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon-hydrogen (C-H) bonds are ubiquitous in organic molecules. Utilization of such abundant chemical moieties as functional group equivalents could shorten route to synthetic targets and provide chemists with new disconnections in retrosynthesis. As such regio- and stereoselective functionalization of unactivated C-H bonds has remained one of the major challenges in organic chemistry. The majority of the transition metals have been rigorously examined for their efficacy in transforming unactivated C-H bonds (pKa >35) into useful functional groups or into C-C bonds. Among those metals, palladium is particularly effective in activating both aromatic (sp2) and aliphatic (sp3) C-H bonds. This thesis explores the reactivity of palladium catalysts in both of these areas. The research herein was conducted using directing groups for C-H cleavage with special focus on utilizing simple functionality such as carboxylic acids. Chapter one details different types of directing groups and their utility in a variety of reactions. Chapters two and three contain details of research on C-heteroatom (C-I and C-O) and C-C bond formation, respectively, with palladium acetate as a catalyst. The iodination and acetoxylation reactions proceed under mild conditions and moderate to excellent levels of diastereoselectivity (up to 99.9%) have been observed with both sp2 and sp3 C-H bonds using oxazoline as the directing group. Mechanistic investigations have been carried out in order to understand the high level of stereoselection and, in this process, a number of palladacycle intermediates have been characterized by X-ray crystallography which led us to assign the absolute stereochemistry of C-H activation. Moreover, the iodination protocol could also be extended to prepare diiodides as intermediates for cyclopropanation which provides a new disconnection approach to construct cyclopropanes. Chapter two discusses C-C bond formation via cross-coupling reactions with organoboron reagents and carbon monoxide using the carboxylic acids as the directing group. Detailed mechanistic investigation along with characterization of intermediate palladacycle formed from sodium toluate have revealed an unprecendented directing ability of carboxylate groups in which the carbonyl oxygen, rather than the O-anion, directs palladium for C-H cleavage.

Palladacycles

Author : Anant Kapdi
Publisher : Elsevier
ISBN 13 : 9780128155059
Total Pages : 0 pages
Book Rating : 4.1/5 (55 download)

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Book Synopsis Palladacycles by : Anant Kapdi

Download or read book Palladacycles written by Anant Kapdi and published by Elsevier. This book was released on 2019-06-15 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles have played a significant role. In recent years, they have found a wide variety of applications, ranging from catalysts for cross-coupling and related reactions, to their more recent application as anticancer agents. This book explores early examples of the use of palladacyclic complexes in catalysis employing azobenzene and hydrazobenzene as coordinating ligands. Its applications in processes such as selective reduction of alkenes, alkynes, or nitroalkanes are also covered. Palladacycles: Catalysis and Beyond reveals the tremendous advances that have taken place in the potential applications of palladacycles as versatile catalysts in academia and industry. It is a valuable resource for synthetic chemists, organometallic chemists, and chemical biologists.

Asymmetric Functionalization of C-H Bonds

Author : Shu-Li You
Publisher : Royal Society of Chemistry
ISBN 13 : 1782621024
Total Pages : 433 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Asymmetric Functionalization of C-H Bonds by : Shu-Li You

Download or read book Asymmetric Functionalization of C-H Bonds written by Shu-Li You and published by Royal Society of Chemistry. This book was released on 2015-08-13 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Asymmetric C-H direct functionalization reactions are one of the most active and fascinating areas of research in organic chemistry due to their significance in the construction of molecular complexity without pre-activation, and the step economy and atom economy features in potential synthetic application. Distinguishing the reactivity among numerous C–H bonds in one single molecule represents one of the most challenging issues in organic synthesis and requires precise reaction design. As such, this field is now receiving increasing attention from researchers. This book provides the first comprehensive review of this field, summarizing the origin, mechanism, scope and applications of the asymmetric C-H bond functionalization reaction. It covers organocatalytic reactions and transition-metal-catalyzed reactions, as well as asymmetric C-H functionalization reactions not described in other books. Written by a leading expert in this field, the book is ideal for postgraduates and researchers working in organic synthesis, catalysis, and organometallic chemistry.

Handbook of Organopalladium Chemistry for Organic Synthesis

Author : Ei-ichi Negishi
Publisher : John Wiley & Sons
ISBN 13 : 0471473812
Total Pages : 1657 pages
Book Rating : 4.4/5 (714 download)

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Book Synopsis Handbook of Organopalladium Chemistry for Organic Synthesis by : Ei-ichi Negishi

Download or read book Handbook of Organopalladium Chemistry for Organic Synthesis written by Ei-ichi Negishi and published by John Wiley & Sons. This book was released on 2003-11-24 with total page 1657 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.

C-H Bond Activation and Catalytic Functionalization II

Author : Pierre H. Dixneuf
Publisher : Springer
ISBN 13 : 3319293192
Total Pages : 213 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis C-H Bond Activation and Catalytic Functionalization II by : Pierre H. Dixneuf

Download or read book C-H Bond Activation and Catalytic Functionalization II written by Pierre H. Dixneuf and published by Springer. This book was released on 2016-03-10 with total page 213 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

C-1 Building Blocks in Organic Synthesis

Author : Piet W. N. M. van Leeuwen
Publisher :
ISBN 13 : 9783131707710
Total Pages : 610 pages
Book Rating : 4.7/5 (77 download)

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Book Synopsis C-1 Building Blocks in Organic Synthesis by : Piet W. N. M. van Leeuwen

Download or read book C-1 Building Blocks in Organic Synthesis written by Piet W. N. M. van Leeuwen and published by . This book was released on 2014-03-12 with total page 610 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is an organic chemistry reference work, focusing on reactions that add a C-1 unit to a substrate.

Palladium-catalyzed Alkyl Carbon-hydrogen Activation

Author : Masayuki Wasa
Publisher :
ISBN 13 : 9781303073205
Total Pages : 808 pages
Book Rating : 4.0/5 (732 download)

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Book Synopsis Palladium-catalyzed Alkyl Carbon-hydrogen Activation by : Masayuki Wasa

Download or read book Palladium-catalyzed Alkyl Carbon-hydrogen Activation written by Masayuki Wasa and published by . This book was released on 2012 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt: The work in this dissertation is divided into two major parts. Part I describes the Pd-catalyzed activation/functionalization of inert alkyl C(sp3 )-H bonds through the development of highly reactive directing groups and identification of compatible ligands that cooperatively promote C(sp3 )-H functionalization. Prior to this dissertation research, methods to selectively functionalize methyl and methylene C(sp 3 )-H bonds at the [beta]-position of carbonyl groups were underdeveloped. Inspired by the indispensable roles of electronically and sterically optimized phosphine (PR3 ) and N- heterocyclic carbene (NHC) ligands in traditional cross-coupling reactions, we have invented a class of highly optimized N- arylamide directing groups that weakly coordinate to Pd, yet promote cleavage of [beta] -C(sp3 )-H bonds and facilitate subsequent conversion into an array of C-C and C-heteroatom bonds. A unique feature of Pd-catalyzed C(sp3 )-H activation reactions using N- arylamide directing groups is that a range of coordinating moieties that are known to compete for the coordination sites around Pd (e.g. , PR3 , NHC, pyridine, CO, acrylates, and DMF) can be accommodated, while maintaining robust C(sp 3 )-H activation. By exploiting the N- arylamide directing group, we have developed the following unprecedented transformations, which will be summarized in five discrete chapters: 1. Pd(0)/PR3 -catalyzed intermolecular arylation of [beta]-C(sp3 )-H bonds. 2. Pd(II)-catalyzed olefination of [beta] -C(sp3 )-H bonds. 3. Pd(II)-catalyzed carbonylation of [beta]-C(sp3 )-H bonds. 4. Pd(II)/amino acid-catalyzed enantioselective activation of cyclopropyl C-H bonds. 5. Pd(II)/quinoline-catalyzed arylation of [beta]-methylene C(sp3 )-H Bonds. Part II of this dissertation addresses applications of this same class of amide directing groups for C(sp2 )-H activation reactions in developing previously unprecedented C(sp2 )-H functionalization reactions. In particular, we have focused our efforts on the following two topics: 1. Pd(II)-catalyzed synthesis of lactams via intramolecular C(sp 2 )-H amination. 2. Pd(0)/PR3 -catalyzed N- arylamide-directed regioselective C-H arylation of pyridines. The versatility and practicality of these reactions in their current forms are evaluated with respect to the efficiency of catalysis and substrate scopes. Key problems and potential solutions are also discussed.

Catalytic Hydrogenation

Author : L. Cervený
Publisher : Elsevier
ISBN 13 : 0080960618
Total Pages : 705 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Catalytic Hydrogenation by : L. Cervený

Download or read book Catalytic Hydrogenation written by L. Cervený and published by Elsevier. This book was released on 1986-08-01 with total page 705 pages. Available in PDF, EPUB and Kindle. Book excerpt: The collection of contributions in this volume presents the most up-to-date findings in catalytic hydrogenation. The individual chapters have been written by 36 top specialists each of whom has achieved a remarkable depth of coverage when dealing with his particular topic. In addition to detailed treatment of the most recent problems connected with catalytic hydrogenations, the book also contains a number of previously unpublished results obtained either by the authors themselves or within the organizations to which they are affiliated.Because of its topical and original character, the book provides a wealth of information which will be invaluable not only to researchers and technicians dealing with hydrogenation, but also to all those concerned with homogeneous and heterogeneous catalysis, organic technology, petrochemistry and chemical engineering.

C-H Bond Activation and Catalytic Functionalization I

Author : Pierre H. Dixneuf
Publisher : Springer
ISBN 13 : 3319246305
Total Pages : 269 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis C-H Bond Activation and Catalytic Functionalization I by : Pierre H. Dixneuf

Download or read book C-H Bond Activation and Catalytic Functionalization I written by Pierre H. Dixneuf and published by Springer. This book was released on 2015-12-18 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

Metal-catalyzed Cross-coupling Reactions

Author : François Diederich
Publisher : John Wiley & Sons
ISBN 13 : 3527612203
Total Pages : 540 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Metal-catalyzed Cross-coupling Reactions by : François Diederich

Download or read book Metal-catalyzed Cross-coupling Reactions written by François Diederich and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon-carbon bond forming reactions are arguably the most important processes in chemistry, as they represent key steps in the building of complex molecules from simple precursors. Among these reactions, metal-catalyzed cross-coupling reactions are extensively employed in a wide range of areas of preparative organic chemistry, ranging from the synthesis of complex natural products, to supramolecular chemistry, and materials science. In this work, a dozen internationally renowned experts and leaders in the field bring the reader up to date by documenting and critically analyzing current developments and uses of metal-catalyzed cross-coupling reactions. A particularly attractive and useful feature, that enhances the practical value of this monograph, is the inclusion of key synthetic protocols, in experimental format, chosen for broad utility and application. This practice-oriented book can offer the practitioner short cuts to ensure they remain up-to-date with the latest developments.